Summary of the invention
The present invention is directed to solve one of above-mentioned technical problem at least to a certain extent.For this purpose, the present invention provides one kind
Industrial waste water high-efficiency processing equipment is filtered based on electrochemistry and film.
The technical solution of the present invention is to provide one kind to filter industrial waste water high-efficiency processing equipment based on electrochemistry and film, special
Sign is: comprising:
Wastewater oil separating treatment set is removed the oil in waste water by multichannel aggregation and Electrostatic Absorption;
Wastewater electrolytic processing set divides the pollutant in waste water in solid form by applying action of low-voltage pulse electric flocculation mechanism
From generating hydroxyl electrolysis water and organic pollutant decomposed removal in a manner of Strong oxdiative;
Pollutant in waste liquid in solid form is passed through ultrafiltration membrane for its mistake using ultrafiltration membrane filter by wastewater membrane separation set
Filter separation;Amounts of residual contamination in water is removed using disc-type reverse osmosis membrane separation technology;
Discharge purified water set, for water to carry out last purification and discharge by treated;
The wastewater electrolytic processing set includes liquid-storing box and electrolyte tank, and the top side inside the liquid-storing box is provided with one
Chemical tank is provided with a medicament delivery mouth at the top of the chemical tank, and the bottom of the chemical tank is provided with a sprinkler head, described
The bottom of chemical tank is provided with a mixing component;Action of low-voltage pulse electric flocculation equipment is provided in the middle part of the electrolyte tank, it is described low
Pressing pulse electro-flocculation equipment includes shell, includes the pole plate that multiple groups are arranged in parallel in the shell, is provided in the shell
Power supply, the pole plate are all connected with the power supply;
The wastewater membrane separation set includes concentration liquid case, ultrafiltration membrance filter cylinder and osmosis filtration cylinder, the ultrafiltration membrane mistake
Filter cylinder connects the electrolyte tank, and the middle part in the ultrafiltration membrance filter cylinder is horizontally disposed ultrafiltration membrane filter, the ultrafiltration membrane
Filter includes upper fixed ring and lower fixed ring, and fixed ring and the lower fixed ring fit in the ultrafiltration membrance filter
On the side wall of cylinder, ultrafiltration membrane is provided between fixed ring and the lower fixed ring, the ultrafiltration membrance filter cylinder is in institute
The top for stating ultrafiltration membrane filter is provided with pipeline, and the upper pipeline, which connects the concentration liquid case, will filter out the concentrate taken
It is transmitted to the concentration liquid case, the lower part of the ultrafiltration membrance filter cylinder is provided with lower pipeline, and the lower pipeline connects the reverse osmosis
Through filter cylinder.
Preferably, the wastewater oil separating treatment set includes pretreatment box, stands oil removal box and Electrostatic Absorption case, institute
It states standing oil removal box and the Electrostatic Absorption case is connected to floating oil collecting case, the pretreatment box is to be processed for storing
Waste water, described to stand the oil that top is drawn after oil removal box is used to stand, the Electrostatic Absorption case will be in waste water by Electrostatic Absorption
Oil removal.
Preferably, it is provided with a hydraulic cylinder at the top of the standing oil removal box, the hydraulic cylinder is extended by telescopic rod
Inside the standing oil removal box, the bottom level of the telescopic rod is provided with a fixed plate, is provided with oil transportation in the fixed plate
Pipe, the bottom of the fixed plate have been placed equidistant with multiple oil-suckers, and the oil-sucker is all connected to the petroleum pipeline, the oil transportation
Pipe is connected to the floating oil collecting case.
Preferably, the Electrostatic Absorption case is connected to the liquid-storing box.
Preferably, the discharge purified water set includes cartridge filter and delivery pipe.
Preferably, the first filter layer, the second filter layer and third filter layer are arranged at intervals in the cartridge filter.
Preferably, it is provided with cotton yarn filter screen in first filter layer, it is living that load sulphur is provided in second filter layer
Property charcoal particle is provided with one layer of nanofiltration membrane in the third filter layer.
Preferably, the ultrafiltration membrane uses ceramic honey comb ultrafiltration membrane.
Preferably, the osmosis filtration cylinder is connected with a feedback pipeline, and the feedback pipeline is connected to the liquid-storing box.
Preferably, the mixing component includes a partition, and the partition is located above the bottom of described dose of case, it is described every
Plate center is vertically connected with a rotating roller upwards, and multiple groups agitating paddle is provided in the rotating roller;Prolong the bottom of the rotating roller
It extends to the lower partition and is connected with a driving motor, the driving motor is located at the chemical tank bottom, and the driving motor is used
In the driving rotating roller rotation.
The beneficial effects of the present invention are: one kind of the invention is based on electrochemistry and film filters industrial waste water high-efficiency processing equipment
Wastewater oil separating treatment set, wastewater electrolytic processing set, wastewater membrane separation set and discharge purified water set are provided with to cooperate
Waste water is handled, wastewater oil separating treatment set, is removed the oil in waste water by multichannel aggregation and Electrostatic Absorption;
Wastewater electrolytic processing set separates the pollutant in waste water in solid form by applying action of low-voltage pulse electric flocculation mechanism, leads to
It crosses electrolysis water generation hydroxyl and organic pollutant is decomposed into removal in a manner of Strong oxdiative;Wastewater membrane separation set, using ultrafiltration
Pollutant in waste liquid in solid form is separated by filtration by membrane filter by ultrafiltration membrane;Using disc-type reverse osmosis membrane point
Amounts of residual contamination in water is removed from technology;Discharge purified water set, for water to carry out last purification and discharge by treated.
The present invention realizes Treated sewage reusing after being able to achieve waste water full automatic processing, while reaching national emission request.Raw water succession
Fluctuation is smaller on water sample influence after processing, is also saved consumed by enterprise's production while reducing processing cost and uses water.
Detailed description of the invention
Above-mentioned and/or additional aspect of the invention and advantage will become from the description of the embodiment in conjunction with the following figures
Obviously and it is readily appreciated that, in which:
Fig. 1 is structural schematic diagram of the invention;
Appended drawing reference: wastewater oil separating treatment set 1, pretreatment box 11 stand oil removal box 12, Electrostatic Absorption case 13, and oil slick is received
Header 14, hydraulic cylinder 5, telescopic rod 51, fixed plate 52, petroleum pipeline 54, oil-sucker 55;
Wastewater electrolytic processing set 2, liquid-storing box 21, electrolyte tank 22, chemical tank 23, medicament delivery mouth 24, sprinkler head 25, stirring group
Part, partition 6, rotating roller 61, agitating paddle 62, driving motor 63, action of low-voltage pulse electric flocculation equipment 26, shell, pole plate 27, power supply
28;
Wastewater membrane separation set 3, is concentrated liquid case 31, ultrafiltration membrance filter cylinder 32, osmosis filtration cylinder 33, feedback pipeline 34, ultrafiltration
Membrane filter, upper fixed ring 7, lower fixed ring 70, ultrafiltration membrane 71, upper pipeline 72, lower pipeline 73;
Discharge purified water set 4, cartridge filter 41, delivery pipe 42, the first filter layer 8, cotton yarn filter screen 81, the second filter layer 82 carry
Sulphur active carbon particle 83, third filter layer 84, nanofiltration membrane 85.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end
Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached
The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, if any term " center ", "upper", "lower", "vertical", "horizontal",
The orientation or positional relationship of the instructions such as "top", "bottom", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, and is only
For the convenience of describing the present invention and simplifying the description, rather than the device or element of indication or suggestion meaning must have specific side
Position is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc.
Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can be machine
Tool connection, is also possible to be electrically connected;It can be directly connected, two members can also be can be indirectly connected through an intermediary
Connection inside part.For the ordinary skill in the art, above-mentioned term can be understood in this hair as the case may be
Concrete meaning in bright.
It is specifically described first below in conjunction with attached drawing according to an embodiment of the present invention a kind of based on electrochemistry and film filtering industry
Waste water high-efficiency processing equipment.
As shown in Figure 1, one kind of the invention is based on electrochemistry and film filters industrial waste water high-efficiency processing equipment, feature exists
In: comprising: wastewater oil separating treatment set 1, wastewater electrolytic processing set 2, wastewater membrane separation set 3 and discharge purified water set
4 are handled waste water to cooperate.
Wastewater oil separating treatment set 1 is removed the oil in waste water by multichannel aggregation and Electrostatic Absorption;It is described useless
Water-oil separation processing set 1 includes pretreatment box 11, stands oil removal box 12 and Electrostatic Absorption case 13, the standing oil removal box 12
It is connected to floating oil collecting case 14 with the Electrostatic Absorption case 13, the pretreatment box 11 is used to store waste water to be processed,
Described to stand the oil that top is drawn after oil removal box 12 is used to stand, the Electrostatic Absorption case 13 will be in waste water by Electrostatic Absorption
Oil removal.
Wastewater electrolytic processing set 2 makes the pollutant in waste water with solid-state shape by applying action of low-voltage pulse electric flocculation mechanism
Formula separation generates hydroxyl by electrolysis water and organic pollutant is decomposed removal;The wastewater electrolytic processing set 2 includes to deposit
Liquid case 21 and electrolyte tank 22, the top side inside the liquid-storing box 21 are provided with a chemical tank 23, the top of the chemical tank 23
Portion is provided with a medicament delivery mouth 24, and the bottom of the chemical tank 23 is provided with a sprinkler head 25, and sprinkler head 25 is used for medicament
Medicament in case 23 is uniformly sprayed in liquid-storing box 21, and the bottom of the chemical tank 23 is provided with a mixing component.
The middle part of the electrolyte tank 22 is provided with action of low-voltage pulse electric flocculation equipment 26, the action of low-voltage pulse electric flocculation equipment 26
Include the pole plate 27 that multiple groups are arranged in parallel including shell, in the shell, is provided with power supply 28, the pole plate in the shell
27 are all connected with the power supply 28.Action of low-voltage pulse electric flocculation equipment 26 connects direct current at work, to the pole plate 27 of multiple groups parallel connection,
Electric field is generated between pole plate 27, water to be processed is made to flow into the gap of pole plate 27.Electrification can occur for the pole plate 27 being powered at this time
Reaction is learned, Al3+ or Fe2+ plasma is dissolved out and hydrolyzes in water and flocculation reaction occurs, in the process, while being occurred electrical
Floating, redox heating functioin, these effects as a result, turning dissolubility in water, colloid and suspended pollutant effectively
Change and removes.Effect including following several respects: (1) flocculation: the anodes such as soluble anode such as iron, aluminium pass to direct current
After electricity, after anode loses electronics, metal cation Fe2+, Al3+ are formed, generates metal hydroxides glue with the OH- in solution
Body flocculant, this kind of hydrogen in statu nascendi oxide active is high, adsorption capacity is strong, with colloid, suspended matter, the soluble contaminant in raw water
Object, bacterium, virus etc., which combine, generates larger flock, is removed through precipitating, air bearing.(2) air bearing act on: in electrolytic process when
When voltage reaches the decomposition voltage of water, hydrogen and oxygen is precipitated respectively on cathode and anode, the gas of generation is with dispersion degree pole
The form of high micro-bubble occurs, be adhered to each other with pollutants such as colloid, emulsus oil in raw water shift to the water surface and by
Removal.The bubble that electric flocculation generates is much smaller than the bubble that pressure floatation air generates, thus its air bearing ability is stronger, goes to pollutant
Except effect is also more preferable.(3) oxidation: the oxidation in electrolytic process divides direct oxidation and indirect oxidation.Direct oxidation, i.e.,
Pollutant directly loses electronics in anode and aoxidizes.Indirect oxidation, using the lower anion of electrode potential in solution,
Such as OH-, Cl- lose the active material [ O ] for being electronically generated new stronger oxidant, Cl2 etc. in anode, utilize these activity
Substance makes pollutant lose electronics, oxygenolysis is played, to reduce BOD5, CODcr in stoste, ammonia nitrogen etc..(4) it restores
Effect: reduction point direct-reduction and indirect reduction in electrolytic process.Direct-reduction, i.e. pollutant obtain directly on cathode
Reduction occurs to electronics.Indirect reduction, i.e., the sun in pollutant are electric in so that electrolyte from obtaining in first in cathode
Middle high price or low-valent metal sun are from being directly reduced to cation or precipitated metal at a low price in obtaining electronics on cathode.
Wastewater membrane separation set 3, passes through ultrafiltration membrane for the pollutant in waste liquid in solid form using ultrafiltration membrane filter
It is separated by filtration;Amounts of residual contamination in water is removed using disc-type reverse osmosis membrane separation technology;The wastewater membrane disjoint set
Closing 3 includes concentration liquid case 31, ultrafiltration membrance filter cylinder 4132 and osmosis filtration cylinder 4133, and the ultrafiltration membrance filter cylinder 4132 connects
The electrolyte tank 22 is connect, the middle part in the ultrafiltration membrance filter cylinder 4132 is horizontally disposed ultrafiltration membrane filter, the ultrafiltration membrane
Filter includes upper fixed ring 7 and lower fixed ring 70, and fixed ring 7 and the lower fixed ring 70 fit in the ultrafiltration
On the side wall of film cartridge filter 4132, ultrafiltration membrane 71 is provided between fixed ring 7 and the lower fixed ring 70, it is described super
Membrane filtration cylinder 4132 is provided with upper pipeline 72 in the top of the ultrafiltration membrane filter, and the upper pipeline 72 connects the concentration
Liquid case 31 will filter out the concentrate taken and be transmitted to the concentration liquid case 31, and the lower part of the ultrafiltration membrance filter cylinder 4132 is provided with
Lower pipeline 73, the lower pipeline 73 connect the osmosis filtration cylinder 4133.
Discharge purified water set 4, for water to carry out last purification and discharge by treated;The discharge purified water set 4
It include cartridge filter 41 and delivery pipe 42;The first filter layer 8, the second filter layer 82 and are arranged at intervals in the cartridge filter 41
Three filter layers 84;It is provided with cotton yarn filter screen 81 in first filter layer 8, it is living that load sulphur is provided in second filter layer 82
Property charcoal particle 83 is provided with one layer of nanofiltration membrane 85 in the third filter layer 84;The ultrafiltration membrane 71 is super using ceramic honey comb
Filter membrane.
In a preferred embodiment of the present invention, the top for standing oil removal box 12 is provided with a hydraulic cylinder 5, described hydraulic
Cylinder 5 is extended inside the standing oil removal box 12 by telescopic rod 51, and it is fixed that the bottom level of the telescopic rod 51 is provided with one
Plate 52 is provided with petroleum pipeline 54 in the fixed plate 52, and the bottom of the fixed plate 52 has been placed equidistant with multiple oil-suckers 55, institute
It states oil-sucker 55 and is all connected to the petroleum pipeline 54, the petroleum pipeline 54 is connected to the floating oil collecting case 14;When waste water is stood
Later, hydraulic cylinder 5 drives telescopic rod 51 to move down, and fixed plate 52 is driven to move down, and is oil of the contact of oil-sucker 55 to wastewater surface, then
Oil is detached, is reached in floating oil collecting case 14 by petroleum pipeline 54.
In a preferred embodiment of the present invention, the Electrostatic Absorption case 13 is connected to the liquid-storing box 21 for will tentatively locate
Waste water after reason is transmitted to liquid-storing box 21 and is further processed.
In a preferred embodiment of the present invention, the osmosis filtration cylinder 4133 is connected with a feedback pipeline 34, and described time
Defeated pipeline 34 is connected to the liquid-storing box 21, and the water after processing can be re-transmitted to liquid-storing box 21 and carried out by feedback pipeline 34
Secondary treatment or repeatedly processing.
In a preferred embodiment of the present invention, the mixing component includes a partition 6, and the partition 6 is located at described dose
Above the bottom of case, 6 center of partition is vertically connected with a rotating roller 61 upwards, is provided with multiple groups in the rotating roller 61 and stirs
Mix paddle 62;The bottom of the rotating roller 61 extends to 6 lower part of partition and is connected with a driving motor 63, the driving motor 63
In 23 bottom of chemical tank, for driving the rotating roller 61 to rotate, the rotation of rotating roller 61 drives stirs the driving motor 63
The rotation of paddle 62 is mixed to stir to the waste water in liquid-storing box 21, the medicament in chemical tank 23 is mixed in waste water.
Present invention is mainly applied to Industrial Waste Water Treatments, main includes three aspects: (1) the static and electric suction of Wastewater Pretreatment
Attached degreasing unit.(2) pollutant component is decomposed with electric flocculation and electrolysis based on low-voltage pulse current effect, separation.(3) lead to
Cross ultrafiltration and reverse osmosis Combined Treatment further remove amounts of residual contamination realize processed waste water meet production Treated sewage reusing or
National emission request realizes the effect of zero discharge of industrial waste water.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any
One or more embodiment or examples in can be combined in any suitable manner.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is not considered as limiting the invention, those skilled in the art are not departing from the principle of the present invention and objective
In the case where can make changes, modifications, alterations, and variations to the above described embodiments within the scope of the invention.