CN108441348A - A kind of antifouling cleaning agent of ornament materials and preparation method thereof - Google Patents
A kind of antifouling cleaning agent of ornament materials and preparation method thereof Download PDFInfo
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- CN108441348A CN108441348A CN201810346353.5A CN201810346353A CN108441348A CN 108441348 A CN108441348 A CN 108441348A CN 201810346353 A CN201810346353 A CN 201810346353A CN 108441348 A CN108441348 A CN 108441348A
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- ornament materials
- corrosion inhibiter
- cleaning agent
- agent
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- 239000000463 material Substances 0.000 title claims abstract description 41
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 38
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 230000007797 corrosion Effects 0.000 claims abstract description 66
- 238000005260 corrosion Methods 0.000 claims abstract description 66
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 30
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 30
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 30
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 29
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 29
- 230000000740 bleeding effect Effects 0.000 claims abstract description 28
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims abstract description 24
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims abstract description 24
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 24
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims abstract description 24
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 24
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229960001484 edetic acid Drugs 0.000 claims abstract description 22
- -1 propylene glycol-polyethylene Chemical group 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 18
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical group [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 229920004890 Triton X-100 Polymers 0.000 claims description 6
- 239000013504 Triton X-100 Substances 0.000 claims description 6
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229920000428 triblock copolymer Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- 230000001934 delay Effects 0.000 claims description 2
- 230000008595 infiltration Effects 0.000 claims description 2
- 238000001764 infiltration Methods 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 7
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000004020 conductor Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Detergent Compositions (AREA)
Abstract
The present invention provides antifouling cleaning agents of a kind of ornament materials and preparation method thereof, the cable of the present invention coats refractory insulating layer in the external of conductor, the cleaning agent ingredient of the present invention includes acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, nonylphenol polyoxyethylene ether, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent, and mentioned component constitutes a technical solution that can solve the problems, such as ornament materials decontamination by reasonably matching.It solves the problems, such as current ornament materials difficulty cleaning or needs strong solvent that could clean, only needing one piece of dry towel to dip can light decontamination.
Description
Technical field
The invention belongs to cleaning agent technical fields, and in particular, to a kind of antifouling cleaning agent of ornament materials and its preparation side
Method.
Background technology
Application of the decorative fabric in terms of furniture and interior decoration is more and more extensive, but currently on the market without real
To facilitate product easy to clean, general product be all to need strong solvent such as butanone, and absolute alcohol etc. is cleaned, still, in general life
In work will not often these spare abrasive cleaners, and store when there are certain inflammable and explosive danger.And at present so-called antifouling
Cleaning series be all separately from the faces PVC PU layer, for factory different structure otherwise with preparation anti-fouling material, match
Expect that the loss of production process is relatively higher, it is of high cost.
To solve the above-mentioned problems, the purpose of the present invention is a kind of antifouling cleaning agent of ornament materials of research and development and its preparation sides
Method.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of antifouling cleaning agent of ornament materials and preparation sides
Method.
The antifouling cleaning agent of a kind of ornament materials provided according to an aspect of the present invention, the antifouling cleaning of the ornament materials
Agent includes the raw material of following parts by weight：21-45 parts acrylic resin modified, 2-14 parts of methylisobutylketone, ethylenediamine tetraacetic
2-15 parts of acetic acid, 2-5 parts of hydrochloric acid, 4-7 parts of hydrogen fluoride ammonia, 2.1-3.3 parts of emulsifier, delays 3-17 parts of nonylphenol polyoxyethylene ether
Lose 1.3-2.8 parts of agent, 2.1-3.5 parts of bleeding agent.
Preferably, the antifouling cleaning agent of the ornament materials includes the raw material of following parts by weight：It is acrylic resin modified
21-35 parts, 2-11 parts of methylisobutylketone, 5-15 parts of ethylenediamine tetra-acetic acid, 4-17 parts of nonylphenol polyoxyethylene ether, 3-5 parts of hydrochloric acid,
5-7 parts of hydrogen fluoride ammonia, 2.3-3.3 parts of emulsifier, 1.5-2.8 parts of corrosion inhibiter, 2.6-3.5 parts of bleeding agent.
Preferably, the antifouling cleaning agent of the ornament materials includes the raw material of following parts by weight：It is acrylic resin modified
27 parts, 4 parts of methylisobutylketone, 9 parts of ethylenediamine tetra-acetic acid, 12 parts of nonylphenol polyoxyethylene ether, 4 parts of hydrochloric acid, 6 parts of hydrogen fluoride ammonia,
2.8 parts of emulsifier, 1.9 parts of corrosion inhibiter, 2.8 parts of bleeding agent.
Preferably, the emulsifier is nonylphenol polyoxyethylene ether.
Preferably, the corrosion inhibiter includes main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 7-9:6-13:5-7；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
Preferably, the bleeding agent includes 20-40 parts of aqueous levelling agent, 30-50 parts of polyoxyethylene ether, 5-20 parts of White Mineral Oil
With 7-15 parts of sulfosuccinate sodium.
A kind of preparation method of the antifouling cleaning agent of ornament materials, the method comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 15-20min under the conditions of 30-50 DEG C, mixed liquor two is added under the conditions of 32-47 DEG C
Hot 11-25min；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
Preferably, it is described it is acrylic resin modified be modified using acid.
Compared with prior art, the present invention has following advantageous effect：
1, the antifouling cleaning agent of a kind of ornament materials provided by the invention, cleaning agent ingredient of the invention include modified acroleic acid tree
Fat, methylisobutylketone, ethylenediamine tetra-acetic acid, nonylphenol polyoxyethylene ether, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, infiltration
Agent, mentioned component constitute a technical solution that can solve the problems, such as ornament materials decontamination by reasonably matching.It solves and works as
The problem of front decoration material difficulty cleans or needs strong solvent that could clean, only needing one piece of dry towel to dip can light decontamination.
2, the antifouling cleaning agent of a kind of ornament materials provided by the invention, the corrosion inhibiter being added in formula are a kind of to be based on surface
Activating agent coordinated regulation effect Block copolymer type highly efficiency compositional corrosion inhibiter, the composite corrosion inhibitor have it is environmental-friendly,
Effect is efficient, effect stability, synergistic effect are good, and dosage lacks and the series of advantages such as preparation method is simple.It can promote to clean
The reaction process of agent improves cleaning, detergency ability.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.
Embodiment 1
The antifouling cleaning agent of a kind of ornament materials provided in this embodiment, the antifouling cleaning of the ornament materials
Agent includes the raw material of following parts by weight：Acrylic resin modified 45 parts, 2 parts of methylisobutylketone, ethylenediamine tetra-acetic acid 15
Part, 3 parts of nonylphenol polyoxyethylene ether, 5 parts of hydrochloric acid, 4 parts of hydrogen fluoride ammonia, 3.3 parts of emulsifier, 1.3 parts of corrosion inhibiter, bleeding agent 3.5
Part.
Preferably, the emulsifier is nonylphenol polyoxyethylene ether.
Preferably, the corrosion inhibiter includes main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 9:6:7；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
Preferably, the bleeding agent include 40 parts of aqueous levelling agent, 30 parts of polyoxyethylene ether, 20 parts of White Mineral Oil and
7 parts of sulfosuccinate sodium.
A kind of preparation method of the antifouling cleaning agent of ornament materials, the method comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 15min under the conditions of 50 DEG C, mixed liquor two is heated into 11min under the conditions of 47 DEG C；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
Preferably, it is described it is acrylic resin modified be modified using acid.
Embodiment 2
The antifouling cleaning agent of a kind of ornament materials provided in this embodiment, the antifouling cleaning of the ornament materials
Agent includes the raw material of following parts by weight：Acrylic resin modified 21 parts, 14 parts of methylisobutylketone, ethylenediamine tetra-acetic acid 2
Part, 17 parts of nonylphenol polyoxyethylene ether, 2 parts of hydrochloric acid, 7 parts of hydrogen fluoride ammonia, 2.1 parts of emulsifier, 2.8 parts of corrosion inhibiter, bleeding agent 2.1
Part.
Preferably, the emulsifier is nonylphenol polyoxyethylene ether.
Preferably, the corrosion inhibiter includes main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 7:13:5；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
Preferably, the bleeding agent include 20 parts of aqueous levelling agent, 50 parts of polyoxyethylene ether, 5 parts of White Mineral Oil and
15 parts of sulfosuccinate sodium.
A kind of preparation method of the antifouling cleaning agent of ornament materials, the method comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 20min under the conditions of 30 DEG C, mixed liquor two is heated into 25min under the conditions of 32 DEG C；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
Preferably, it is described it is acrylic resin modified be modified using acid.
Embodiment 3
The antifouling cleaning agent of a kind of ornament materials provided in this embodiment, the antifouling cleaning of the ornament materials
Agent includes the raw material of following parts by weight：Acrylic resin modified 35 parts, 2 parts of methylisobutylketone, ethylenediamine tetra-acetic acid 15
Part, 4 parts of nonylphenol polyoxyethylene ether, 5 parts of hydrochloric acid, 5 parts of hydrogen fluoride ammonia, 3.3 parts of emulsifier, 1.5 parts of corrosion inhibiter, bleeding agent 3.5
Part.
Preferably, the emulsifier is nonylphenol polyoxyethylene ether.
Preferably, the corrosion inhibiter includes main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 9:13:7；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
Preferably, the bleeding agent include 40 parts of aqueous levelling agent, 50 parts of polyoxyethylene ether, 20 parts of White Mineral Oil and
15 parts of sulfosuccinate sodium.
A kind of preparation method of the antifouling cleaning agent of ornament materials, the method comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 20min under the conditions of 30 DEG C, mixed liquor two is heated into 25min under the conditions of 32 DEG C；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
Preferably, it is described it is acrylic resin modified be modified using acid.
Embodiment 4
The antifouling cleaning agent of a kind of ornament materials provided in this embodiment, the antifouling cleaning agent of the ornament materials include such as
The raw material of lower parts by weight：Acrylic resin modified 27 parts, 4 parts of methylisobutylketone, 9 parts of ethylenediamine tetra-acetic acid, nonyl phenol
12 parts of polyoxyethylene ether, 4 parts of hydrochloric acid, 6 parts of hydrogen fluoride ammonia, 2.8 parts of emulsifier, 1.9 parts of corrosion inhibiter, 2.8 parts of bleeding agent.
Preferably, the emulsifier is nonylphenol polyoxyethylene ether.
Preferably, the corrosion inhibiter includes main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 8:8:6；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
Preferably, the bleeding agent include 30 parts of aqueous levelling agent, 40 parts of polyoxyethylene ether, 12 parts of White Mineral Oil and
8 parts of sulfosuccinate sodium.
A kind of preparation method of the antifouling cleaning agent of ornament materials, the method comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 18min under the conditions of 40 DEG C, mixed liquor two is heated into 14min under the conditions of 38 DEG C；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
Preferably, it is described it is acrylic resin modified be modified using acid.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of antifouling cleaning agent of ornament materials, it is characterised in that：The antifouling cleaning agent of the ornament materials includes
The raw material of following parts by weight：21-45 parts acrylic resin modified, 2-14 parts of methylisobutylketone, ethylenediamine tetra-acetic acid 2-
15 parts, 3-17 parts of nonylphenol polyoxyethylene ether, 2-5 parts of hydrochloric acid, 4-7 parts of hydrogen fluoride ammonia, 2.1-3.3 parts of emulsifier, corrosion inhibiter
1.3-2.8 2.1-3.5 parts of part, bleeding agent.
2. the antifouling cleaning agent of a kind of ornament materials according to claim 1, it is characterised in that：The ornament materials is antifouling
Cleaning agent includes the raw material of following parts by weight：21-35 parts acrylic resin modified, 2-11 parts of methylisobutylketone, ethylenediamine tetraacetic
5-15 parts of acetic acid, 3-5 parts of hydrochloric acid, 5-7 parts of hydrogen fluoride ammonia, 2.3-3.3 parts of emulsifier, delays 4-17 parts of nonylphenol polyoxyethylene ether
Lose 1.5-2.8 parts of agent, 2.6-3.5 parts of bleeding agent.
3. the antifouling cleaning agent of a kind of ornament materials according to claim 1, it is characterised in that：The ornament materials is antifouling
Cleaning agent includes the raw material of following parts by weight：Acrylic resin modified 27 parts, 4 parts of methylisobutylketone, ethylenediamine tetra-acetic acid 9
Part, 12 parts of nonylphenol polyoxyethylene ether, 4 parts of hydrochloric acid, 6 parts of hydrogen fluoride ammonia, 2.8 parts of emulsifier, 1.9 parts of corrosion inhibiter, bleeding agent 2.8
Part.
4. the antifouling cleaning agent of a kind of ornament materials according to claim 1, it is characterised in that：The emulsifier is nonyl phenol
Polyoxyethylene ether.
5. the antifouling cleaning agent of a kind of ornament materials according to claim 1, it is characterised in that：The corrosion inhibiter includes main slow
Lose agent, auxiliary corrosion inhibiter, surfactant and deionized water；
The main corrosion inhibiter, auxiliary corrosion inhibiter, surfactant mass ratio be 7-9:6-13:5-7；
The main corrosion inhibiter is polyethylene glycol propylene glycol-polyethylene glycol triblock copolymer；
The auxiliary corrosion inhibiter is Triton X-100；
The surfactant is cetyl trimethylammonium bromide.
6. a kind of preparation method of the antifouling cleaning agent of ornament materials according to claim 1, it is characterised in that：The infiltration
Agent includes 7-15 parts of 20-40 parts of aqueous levelling agent, 30-50 parts of polyoxyethylene ether, 5-20 parts of White Mineral Oil and sulfosuccinate sodium.
7. a kind of preparation method of the antifouling cleaning agent of ornament materials according to claim 1, it is characterised in that：The method
Comprise the concrete steps that：
Step 1: weighing acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid, polyoxyethylene nonyl phenyl according to parts by weight
Vinethene, hydrochloric acid, hydrogen fluoride ammonia, emulsifier, corrosion inhibiter, bleeding agent；
Step 2: taking acrylic resin modified, methylisobutylketone, ethylenediamine tetra-acetic acid mixing, mixed liquor one is obtained；
Step 3: taking nonylphenol polyoxyethylene ether, hydrochloric acid, the mixing of hydrogen fluoride ammonia, mixed liquor two is obtained；
Step 4: mixed liquor one is heated 15-20min under the conditions of 30-50 DEG C, mixed liquor two is added under the conditions of 32-47 DEG C
Hot 11-25min；
Step 5: respectively to after heating mixed liquor one and mixed liquor two in be added emulsifier, corrosion inhibiter, bleeding agent, after stirring
Mixing, you can.
8. a kind of preparation method of the antifouling cleaning agent of ornament materials according to claim 1, it is characterised in that：The modification
Acrylic resin is modified using acid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810346353.5A CN108441348A (en) | 2018-04-18 | 2018-04-18 | A kind of antifouling cleaning agent of ornament materials and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810346353.5A CN108441348A (en) | 2018-04-18 | 2018-04-18 | A kind of antifouling cleaning agent of ornament materials and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103850120A (en) * | 2014-02-18 | 2014-06-11 | 苏州贝斯特装饰新材料有限公司 | Formula, preparation method and application of antifouling treating agent for decorative material |
| CN104004610A (en) * | 2014-06-17 | 2014-08-27 | 厦门大学 | Wall face tile cleaning agent and preparing method thereof |
| CN106191877A (en) * | 2016-08-11 | 2016-12-07 | 黄平县力星清洗剂生产有限公司 | A kind of abluent for cleaning dyeing apparatus surface smut |
| CN106367219A (en) * | 2016-08-11 | 2017-02-01 | 黄平县力星清洗剂生产有限公司 | Cleaning compound used for cleaning concrete mortar dirt and application thereof |
-
2018
- 2018-04-18 CN CN201810346353.5A patent/CN108441348A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103850120A (en) * | 2014-02-18 | 2014-06-11 | 苏州贝斯特装饰新材料有限公司 | Formula, preparation method and application of antifouling treating agent for decorative material |
| CN104004610A (en) * | 2014-06-17 | 2014-08-27 | 厦门大学 | Wall face tile cleaning agent and preparing method thereof |
| CN106191877A (en) * | 2016-08-11 | 2016-12-07 | 黄平县力星清洗剂生产有限公司 | A kind of abluent for cleaning dyeing apparatus surface smut |
| CN106367219A (en) * | 2016-08-11 | 2017-02-01 | 黄平县力星清洗剂生产有限公司 | Cleaning compound used for cleaning concrete mortar dirt and application thereof |
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Application publication date: 20180824 |