CN108441108A - A kind of low infrared emissivity is compatible with the composite coating and preparation method thereof of low laser reflectivity - Google Patents

A kind of low infrared emissivity is compatible with the composite coating and preparation method thereof of low laser reflectivity Download PDF

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Publication number
CN108441108A
CN108441108A CN201810239306.0A CN201810239306A CN108441108A CN 108441108 A CN108441108 A CN 108441108A CN 201810239306 A CN201810239306 A CN 201810239306A CN 108441108 A CN108441108 A CN 108441108A
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parts
composite coating
oxide
low
compatible
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顾兆栴
郭雪松
陈乐�
孙惠敏
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Nanjing University
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Nanjing University
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K3/2279Oxides; Hydroxides of metals of antimony

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to technical field of function materials more particularly to a kind of low infrared emissivity to be compatible with low laser reflectivity composite coating and preparation method thereof.The composite coating is made of resin binder and functional stuffing, and functional stuffing is the compounded mix of tin-antiomony oxide, samarium oxide, lanthana, sheet Al powder composition;Resin binder is polyester polyurethane.Coating made from coating of the present invention has lower emissivity in infrared band, has lower reflectivity in laser wavelength.Using polyester urethane resin as resin matrix, make it while with good optical property, there is good mechanics and environmental resistance, and preparation method is simple to operation.

Description

A kind of low infrared emissivity is compatible with composite coating and its preparation of low laser reflectivity Method
Technical field
Low laser reflectivity is compatible with the invention belongs to technical field of function materials more particularly to a kind of low infrared emissivity to answer Close coating and preparation method thereof.
Background technology
Aircraft is because Aerodynamic Heating and engine work in flight course, and surface generates a large amount of infra-red radiations, wherein greatly Part can by Atmospheric Absorption, but for the infra-red radiation of atmospheric window wave band (0.3~1.3 μm, 3~5 μm and 8~14 μm) due to It can not be easy to be captured by infrared detector by atmospheric attenuation, cause itself to expose and destroyed by enemy's weapons of system.
Laser has high directionality, monochromaticjty, coherence, makes itself and conventional microwave radar ratio, has resolving power high, anti- Interference performance is strong, good concealment, small, light weight advantage, and laser technology has been widely used in modern weapons system. Currently, laser acquisition includes mainly the Nd that wavelength is 1.06 μm:YAG laser and 10.6 μm of CO2 lasers.
Under IT-based warfare environment, single camouflage material has been unable to meet the camouflage needs of modern war, with elder generation Into the extensive use of multiband detecting devices afield, infrared camouflage material is also towards more multiband electromagnetism such as energy compatible lasers The multiple spectra camouflage material direction of wave camouflage is developed.
Invention content
Of the existing technology in order to solve the problems, such as, a kind of low infrared emissivity of present invention offer is compatible with low laser reflectivity Composite coating and preparation method thereof.Coating made from the coating keeps low-launch-rate in 3~5um and 8~14um infrared bands While, there is lower reflectivity in the laser wavelength of 1.06um and 10.6um.
In order to achieve the above object, the technical solution adopted by the present invention is:It is anti-that a kind of low infrared emissivity is compatible with low laser The composite coating for penetrating rate, is mainly made of filler and resin matrix, and filler is samarium oxide, lanthana, flake aluminum, tin-antiomony oxide The compounded mix of composition;Resin matrix is polyurethane resin.The composition of the composite coating and the parts by weight of component are as follows:
5~15 parts of samarium oxide
5~15 parts of lanthana
1~5 part of flake aluminum
10~20 parts of tin-antiomony oxide
80~120 parts of organic solvent
20~30 parts of polyurethane resin.
Wherein the flake aluminum is leafing-type aluminium powder, and particle size is 10~15um, and average grain diameter is about 13um.
Wherein the organic solvent is one kind in propylene glycol methyl ether acetate or butyl acetate or acetone.
Wherein the resin is polyester polyurethane, has good adhesiveness, mechanical strength and light transmission.
Wherein the tin-antiomony oxide is a kind of semi-conducting material, while itself is with low infrared emissivity and in laser There is certain absorption at wavelength.
Wherein the samarium oxide, lanthana are rare earth oxide, have strong absorb to laser.
The invention also discloses the preparation methods that low infrared emissivity is compatible with the composite coating of low laser reflectivity, main to wrap Include following steps:
(1) quantitative tin-antiomony oxide, lanthana, samarium oxide powder are weighed by corresponding proportion, are added into organic solvent, Auxiliary agent gas-phase silica is added, is ground in high speed dispersor using zirconium oxide bead or bead, dispersant rotating speed 1000r/ Min, time about 2h;
(2) sheet Al powder, dispersant and levelling agent are added after taking out the grinding bead in step (1) acquired solution, in height Disperse in fast dispersion machine, dispersant rotating speed 800r/min, time about 10min;
(3) AB components (this glue and the solidification of polyester urethane resin is added according to the ratio in step (2) acquired solution Agent), it stirs evenly;
(4) by the solution obtained by step (3) with spraying equipment keep 20cm high perpendicular mists be sprayed at specification be 50 × On the tinplate of 120mm, several times, overall thickness is about 60~80 μm to continuous spray.Room temperature is determined to dry to obtain related painting in wet environment Layer.
Infrared emittance and the test of laser diffusion rate are carried out to gained coating.
The beneficial effects of the invention are as follows:Functional stuffing selects tin-antiomony oxide, samarium oxide, lanthana, sheet Al powder to form Compounded mix coordinates the collective effect of resin binder and auxiliary agent, so that it is had lower emissivity in infrared band, in laser Wave band has lower reflectivity.Using polyester urethane resin as resin matrix, make it with good optical While energy, there is good mechanics and environmental resistance, and the preparation method is simple to operation.
Description of the drawings
Fig. 1 is that the low infrared emissivity prepared by embodiment 3 is compatible with low laser reflectivity composite coating in 3~5um wave bands Infrared emittance collection of illustrative plates.
Fig. 2 is that the low infrared emissivity prepared by embodiment 3 is compatible with low laser reflectivity composite coating in 8~14um wave bands Infrared emittance collection of illustrative plates.
Fig. 3 is that the low infrared emissivity prepared by embodiment 3 is compatible with low laser reflectivity composite coating in 0.80~1.30 μ The diffusing reflection rate collection of illustrative plates of m wave bands.
Fig. 4 is that the low infrared emissivity prepared by embodiment 3 is compatible with low laser reflectivity composite coating in 8~12 mu m wavebands Diffusing reflection rate collection of illustrative plates.
Fig. 5 is the scanning electron microscope phenogram of coating prepared by embodiment 3.
Specific implementation mode
With reference to embodiment, the present invention is furture elucidated, it should be understood that following specific implementation modes are only used for It is bright the present invention rather than limit the scope of the invention.
Embodiment 1:
A kind of low infrared emissivity is compatible with the composite coating of low laser reflectivity, the composite coating mainly by filler and Resin matrix forms, and filler is the compounded mix of tin-antiomony oxide, samarium oxide, lanthana, sheet Al powder composition;Resin matrix is poly- Ester type polyurethane.The composition of the composite coating and the parts by weight of component are as follows:
5 parts of samarium oxide
5 parts of lanthana
1 part of flake aluminum
10 parts of tin-antiomony oxide
80 parts of organic solvent
20 parts of polyurethane resin
Wherein the flake aluminum is leafing-type aluminium powder, and particle size is 8~20um, and average grain diameter is about 13um.
Wherein the organic solvent is one kind in propylene glycol methyl ether acetate or butyl acetate or acetone.
Preparation method mainly includes the following steps that:
(1) quantitative lanthana, samarium oxide, tin-antiomony oxide are weighed by corresponding ratio, be dissolved in organic molten In agent, auxiliary agent gas-phase silica is added, 2h is disperseed with 1000r/min in dispersion machine using zirconium oxide bead.
(2) flake aluminum, dispersant and levelling agent are added in step (1) acquired solution, with 1000r/ in dispersion machine Min disperses 20min.
(3) polyurethane resin and curing agent are added in step (2) acquired solution, is disperseed with 800r/min in dispersion machine 5min。
(4) by the solution obtained by step (3) with spraying equipment keep 20cm high perpendicular mists be sprayed at specification be 50 × On the tinplate of 120mm, continuous spray controls three times, and overall thickness is about 60~80 μm.Constant temperature is determined to dry to obtain phase in wet environment Close coating.
(5) related infrared and laser activity is carried out to gained coating to test.
The above-mentioned coating being prepared is 0.30 in the average emitted rate of 3~5um wave bands;In being averaged for 8~14um wave bands Emissivity is 0.38;Laser reflectivity at 1.06um wavelength is 0.65;Laser reflectivity at 10.6um wavelength is 0.68;
Embodiment 2:
It is substantially the same manner as Example 1, the difference is that, the composition of the composite coating and the parts by weight of component are such as Under:
15 parts of samarium oxide
15 parts of lanthana
5 parts of flake aluminum
20 parts of tin-antiomony oxide
120 parts of organic solvent
30 parts of polyurethane resin
Thus the coating being prepared is 0.25 in the average emitted rate of 3~5um wave bands;In being averaged for 8~14um wave bands Emissivity is 0.30;Laser reflectivity at 1.06um wavelength is 0.68;Laser reflectivity at 10.6um wavelength is 0.71;
Embodiment 3:
It is substantially the same manner as Example 1, the difference is that, the composition of the composite coating and the parts by weight of component are such as Under:
5 parts of samarium oxide
5 parts of lanthana
3 parts of flake aluminum
15 parts of tin-antiomony oxide
100 parts of organic solvent
25 parts of polyurethane resin
Thus the coating scanning electron microscope phenogram such as Fig. 5 being prepared is 0.51 in the average emitted rate of 3~5um wave bands (Fig. 1);It is 0.54 (Fig. 2) in the average emitted rate of 8~14um wave bands;Laser reflectivity at 1.06um wavelength is 0.56 (Fig. 3);It is 0.28 (Fig. 4) in 10.6um laser wavelength reflectivity.
The infrared low-emissivity effect of example 1,2 is better than example 3, but laser antiradar reflectivity is ineffective, both comprehensive From the point of view of performance, especially far infrared band is compatible with 10.6 mum wavelength laser, and example 3 is preferable embodiment.
Above-described embodiment only to illustrate the invention, and not limitation of the present invention, person of ordinary skill in the field It will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention are added, specifically The selection etc. of mode, belongs to scope of the invention, and scope of patent protection of the invention should be defined by the claims.

Claims (5)

1. a kind of low infrared emissivity is compatible with the composite coating of low laser reflectivity, which is characterized in that by resin binder and work( Energy filler composition, functional stuffing are the compounded mix of tin-antiomony oxide, samarium oxide, lanthana, sheet Al powder composition;Resin binder For polyester polyurethane.
2. composite coating according to claim 1, which is characterized in that the composition of its raw material and the parts by weight of component are such as Under:
5~15 parts of samarium oxide
5~15 parts of lanthana
1~5 part of flake aluminum
10~20 parts of tin-antiomony oxide
80~120 parts of organic solvent
20~30 parts of polyurethane resin.
3. composite coating according to claim 2, which is characterized in that the sheet Al powder is float type Al powder, Particle size is 10~15 μm.
4. composite coating according to claim 2, which is characterized in that the organic solvent is propylene glycol methyl ether acetate Or one kind in butyl acetate or acetone.
5. a kind of low infrared emissivity is compatible with the preparation method of low laser reflectivity composite coating, which is characterized in that including following Step:
(1) quantitative tin-antiomony oxide, samarium oxide, lanthanum oxide powder are weighed by corresponding proportion, be added into organic solvent, is added Auxiliary agent gas-phase silica is ground using zirconium oxide bead or bead in high speed dispersor, dispersant rotating speed 1000r/min, when Between about 2h;
(2) sheet Al powder, dispersant and levelling agent are added after taking out the grinding bead in step (1) acquired solution, in high speed point It dissipates and disperses in machine, dispersant rotating speed 800r/min, time about 10min;
(3) this glue and curing agent of polyester urethane resin is added according to the ratio in step (2) acquired solution, stirs evenly;
(4) it is 50 × 120mm to keep 20cm high perpendicular mists to be sprayed at specification with spraying equipment the solution obtained by step (3) Tinplate on, several times, overall thickness is about 60~80 μm to continuous spray;Room temperature is determined to dry to obtain coating in wet environment.
CN201810239306.0A 2018-03-22 2018-03-22 A kind of low infrared emissivity is compatible with the composite coating and preparation method thereof of low laser reflectivity Pending CN108441108A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111944181A (en) * 2020-07-08 2020-11-17 中国航发北京航空材料研究院 Method for reducing infrared emissivity of polyimide resin matrix composite material
CN114087923A (en) * 2021-11-24 2022-02-25 中国人民解放军63983部队 Laser compatible coating camouflage material and preparation method thereof
CN115651514A (en) * 2022-09-28 2023-01-31 中国人民解放军陆军工程大学 Infrared and laser compatible stealth coating with self-healing function and good mechanical properties

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867382A (en) * 2017-03-17 2017-06-20 南京大学 A kind of compatible laser and infrared camouflage coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867382A (en) * 2017-03-17 2017-06-20 南京大学 A kind of compatible laser and infrared camouflage coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111944181A (en) * 2020-07-08 2020-11-17 中国航发北京航空材料研究院 Method for reducing infrared emissivity of polyimide resin matrix composite material
CN114087923A (en) * 2021-11-24 2022-02-25 中国人民解放军63983部队 Laser compatible coating camouflage material and preparation method thereof
CN114087923B (en) * 2021-11-24 2023-05-12 中国人民解放军63983部队 Laser compatible coating camouflage material and preparation method thereof
CN115651514A (en) * 2022-09-28 2023-01-31 中国人民解放军陆军工程大学 Infrared and laser compatible stealth coating with self-healing function and good mechanical properties

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