CN108441053B - Low-cost water-based quick-drying silver paint - Google Patents

Low-cost water-based quick-drying silver paint Download PDF

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Publication number
CN108441053B
CN108441053B CN201810389913.5A CN201810389913A CN108441053B CN 108441053 B CN108441053 B CN 108441053B CN 201810389913 A CN201810389913 A CN 201810389913A CN 108441053 B CN108441053 B CN 108441053B
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water
drying
coating
quick
rotating speed
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CN108441053A (en
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王立明
王立全
易斌
杨慧
桑红源
周博
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Tianjin Ziming Paint Manufacturing Co ltd
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Tianjin Ziming Paint Manufacturing Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a low-cost water-based quick-drying silvery coating, which is characterized in that: comprises the following components: 5-10 parts of oily aluminum pigment; 2-4 parts of a film-forming assistant; 50-65 parts of water-dispersible acrylic resin; 10-20 parts of deionized water; 2-5 parts of an aqueous thickening agent. The invention has the advantages of scientific and reasonable design, safety, environmental protection, low cost, easy construction, quick drying, high glossiness, strong chemical resistance and good coating effect, and is a water-based quick-drying silvery coating with higher innovativeness and low cost.

Description

Low-cost water-based quick-drying silver paint
Technical Field
The invention belongs to the technical field of coatings, relates to a naturally drying coating applied to metal, plastic and glass, and particularly relates to a low-cost water-based quick-drying silvery coating.
Background
At present, common silver coating products for metal decoration and surface protection in the market are air-drying acrylic paint, air-drying polyester ammonia paint, air-drying alkyd paint and the like, which are all oily products, and have the general defects that: all are prepared by using harmful volatile solvents such as toluene, dimethylbenzene, ethyl acetate, butyl acetate and the like. The construction condition requirement is high, the damage to the environment is great, and the probability of respiratory diseases, reproductive system diseases, cancers and other malignant diseases of operators and users is greatly increased.
Along with the development of science and technology, the water paint with safety and environmental protection is more and more popular among people. However, the main raw materials for preparing the water paint, such as water-based resin, water-based aluminum pigment and the like, have the characteristics of high cost, unsatisfactory coating effect, difficult construction, slow drying speed, low glossiness, poor chemical resistance and lower solid content than that of oil resin, so that the produced water paint has higher cost and poor coating effect or cannot meet the process requirements of actual production. The invention aims to solve the problem of high cost of the existing water paint, and simultaneously has the characteristics of quick drying, high glossiness, strong chemical resistance and good coating effect.
Through a search for a patent publication, no patent publication that is the same as the present patent application is found.
Disclosure of Invention
The invention aims to provide the water-based silvery coating which has the advantages of scientific and reasonable design, safety, environmental protection, low cost, easy construction, quick drying, high glossiness, strong chemical resistance and good coating effect.
The technical problem to be solved by the invention is realized by the following technical scheme:
a low-cost water-based quick-drying silvery paint is characterized in that: comprises the following components:
Figure BDA0001643187400000011
moreover, the aqueous thickener comprises the following components:
Figure BDA0001643187400000021
the preparation method of the aqueous thickener comprises the following steps:
(1) adding deionized water into the reaction kettle;
(2) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 500R/min, and adding a water-based dispersant into the reaction kettle;
(3) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 1000R/min, and sequentially adding deionized water, polyvinyl alcohol, organic bentonite and fumed silica under the stirring state;
(4) stirring is continued for 1 hour to obtain the aqueous thickener.
Moreover, the pigment ratio of the coating is 0.2-0.4.
Moreover, the pH value of the coating is 6.8-7.5.
The invention has the advantages and beneficial effects that:
1. the water-based quick-drying silver paint with low cost has the advantages that the price of the water-based metal pigment is far higher than that of the oil-based metal pigment, and the price of most of water-based resin is also higher, so that the cost of the water-based silver paint is far higher than that of the oil-based silver paint. The invention is researched and improved on the basis of the oily aluminum pigment, and can prepare the water-based silver powder coating with low cost, good decorative effect, easy construction and high drying speed by matching with the water-dispersible acrylic resin.
2. The low-cost water-based quick-drying silvery coating can ensure that the drying speed, the hardness and the coating effect of the coating are optimal at the moment by controlling the pigment ratio to be 0.2-0.4.
3. The low-cost water-based quick-drying silvery coating can control the pH value of the coating to be about 7 by adding the independently developed water-based thickening agent into the coating, and the pH value is the most popular pH value in the coating industry. The pH value is not suitable for generating mould and is not easy to generate phenomena such as pulverization, foaming and the like.
4. The invention has the advantages of scientific and reasonable design, safety, environmental protection, low cost, easy construction, quick drying, high glossiness, strong chemical resistance and good coating effect, and is a water-based quick-drying silvery coating with higher innovativeness and low cost.
Detailed Description
The present invention is further illustrated by the following specific examples, which are intended to be illustrative, not limiting and are not intended to limit the scope of the invention.
Example one
The water-based quick-drying silvery paint with low cost is characterized in that: comprises the following components:
Figure BDA0001643187400000031
the aqueous thickening agent comprises the following components:
Figure BDA0001643187400000032
the preparation method of the water-based thickener comprises the following steps:
(1) adding deionized water into the reaction kettle;
(2) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 500R/min, and adding a water-based dispersant into the reaction kettle;
(3) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 1000R/min, and sequentially adding deionized water, polyvinyl alcohol, organic bentonite and fumed silica under the stirring state;
(4) stirring is continued for 1 hour to obtain the aqueous thickener.
Example two
The water-based quick-drying silvery paint with low cost is characterized in that: comprises the following components:
Figure BDA0001643187400000033
the aqueous thickening agent comprises the following components:
Figure BDA0001643187400000034
Figure BDA0001643187400000041
the preparation method of the water-based thickener comprises the following steps:
(1) adding deionized water into the reaction kettle;
(2) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 500R/min, and adding a water-based dispersant into the reaction kettle;
(3) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 1000R/min, and sequentially adding deionized water, polyvinyl alcohol, organic bentonite and fumed silica under the stirring state;
(4) stirring is continued for 1 hour to obtain the aqueous thickener.
EXAMPLE III
The water-based quick-drying silvery paint with low cost is characterized in that: comprises the following components:
Figure BDA0001643187400000042
the aqueous thickening agent comprises the following components:
Figure BDA0001643187400000043
the preparation method of the water-based thickener comprises the following steps:
(1) adding deionized water into the reaction kettle;
(2) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 500R/min, and adding a water-based dispersant into the reaction kettle;
(3) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 1000R/min, and sequentially adding deionized water, polyvinyl alcohol, organic bentonite and fumed silica under the stirring state;
(4) stirring is continued for 1 hour to obtain the aqueous thickener.
The water-dispersible acrylic resin is acrylic resin capable of being dispersed in water, and the water-dispersible acrylic resin applied in the embodiment of the invention is purchased from Tianjin Ziming chemical company Limited; the product model is BX-701.
The aqueous dispersant of the present invention was purchased from Effa corporation under the product number 4560.
The components mentioned above can also be selected from other components commonly used in the coating field, and are not limited to the specific sources in the specification.
The cost of the oily aluminum pigment used in the invention is far lower than that of the water-based pigment on the market, and the specific price is as follows:
item Price (Yuan/kilogram)
Oily aluminum pigment 20-30
Water-based aluminum pigment (resin coating type) 100-120
Water-based aluminum pigment (organosilicon coating type) 120-200
As can be seen from the above table, the cost savings of the waterborne coatings produced using the oil-based aluminum pigments is at least 75% over other waterborne coatings on the market.
Although the embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that: various substitutions, changes and modifications are possible without departing from the spirit and scope of the invention and the appended claims, and therefore the scope of the invention is not limited to the embodiments disclosed.

Claims (3)

1. A low-cost water-based quick-drying silvery paint is characterized in that: the coating consists of the following components:
Figure RE-FDF0000009602810000011
wherein, the water-based thickener comprises the following components:
Figure RE-FDF0000009602810000012
the preparation method of the water-based thickener comprises the following steps:
(1) adding deionized water into the reaction kettle;
(2) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 500R/min, and adding a water-based dispersant into the reaction kettle;
(3) controlling the rotating speed of a stirring paddle in the reaction kettle, setting the rotating speed to be 1000R/min, and sequentially adding deionized water, polyvinyl alcohol, organic bentonite and fumed silica under the stirring state;
(4) stirring is continued for 1 hour to obtain the aqueous thickener.
2. A low cost aqueous quick-drying silvery paint according to claim 1, wherein: the pigment ratio of the coating is 0.2-0.4.
3. A low cost aqueous quick-drying silvery paint according to claim 1, wherein: the pH value of the coating is 6.8-7.5.
CN201810389913.5A 2018-04-27 2018-04-27 Low-cost water-based quick-drying silver paint Active CN108441053B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602188A (en) * 2013-11-28 2014-02-26 王立明 Water-based paint applied in aluminum-plastic plates and color steel coiled material
CN105315812A (en) * 2014-08-04 2016-02-10 谢朝杰 Quick-drying water-based paint
CN106867362A (en) * 2017-02-06 2017-06-20 中山蓝海洋水性涂料有限公司 Quick-drying water-based metal anticorrosive paint and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634377B (en) * 2016-12-30 2019-06-07 徐州海太新材料科技有限公司 A kind of aqueous metallic finishe and preparation method thereof suitable for common aluminium powder

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602188A (en) * 2013-11-28 2014-02-26 王立明 Water-based paint applied in aluminum-plastic plates and color steel coiled material
CN105315812A (en) * 2014-08-04 2016-02-10 谢朝杰 Quick-drying water-based paint
CN106867362A (en) * 2017-02-06 2017-06-20 中山蓝海洋水性涂料有限公司 Quick-drying water-based metal anticorrosive paint and preparation method thereof

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