CN108424624A - A kind of HI high impact enhancing polyethylene naphthalate composite material - Google Patents
A kind of HI high impact enhancing polyethylene naphthalate composite material Download PDFInfo
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- CN108424624A CN108424624A CN201810337446.1A CN201810337446A CN108424624A CN 108424624 A CN108424624 A CN 108424624A CN 201810337446 A CN201810337446 A CN 201810337446A CN 108424624 A CN108424624 A CN 108424624A
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- Prior art keywords
- polyethylene naphthalate
- composite material
- high impact
- ethylene
- glass fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of HI high impacts to enhance polyethylene naphthalate composite material, which is made of polyethylene naphthalate, glass fibre, processing aid, and component is by weight percentage:Polyethylene naphthalate 55~80%, toughener 3~10%, glass fibre 10~40%, processing aid 0.3~3%, a kind of HI high impact enhancing polyethylene naphthalate composite material has higher mechanical performance, heat resistance, preferable gas barrier property are suitable for manufacture electric equipment products, engineering goods, auto parts and components and other heat resistant products.
Description
Technical field：
The present invention relates to technical field of polymer materials more particularly to a kind of HI high impact to enhance polyethylene naphthalate
Composite material.
Background technology：
Polyethylene naphthalate is poly- (2,6-naphthalenedicarboxylic acid glycol ester), and abbreviation PEN is a kind of novel thermoplastic
Property polyester, the structure of PEN resins is similar to PET, it with naphthalene nucleus replace PET in phenyl ring.The properties almost all of PEN is excellent
In PET, there are many excellent performances.The fusing point of PEN is 256 DEG C, close with PET, and glass transition temperature is 118 DEG C, than PET high
Go out 40 DEG C or more, temperature is used for a long time at 155 DEG C or more, product size is stablized, and percent thermal shrinkage is less than PET, PA etc..EN has excellent
Good mechanical property.The tensile strength ratio PET high about 35% of PEN, and the stable mechanical property of PEN, even if in high temperature, high humidity
In the case of degree, elasticity modulus, intensity, creep and service life can still keep relative stability.
The feature that polyethylene naphthalate protrudes is that gas barrier property is good, and the air-tightness of the film of same thickness, PEN is far above
General-purpose plastics polyethylene, polypropylene, polystyrene, also above the engineering plastics such as polyamide, PPS, PET.Experiment shows PEN pairs
4 times of the barrier property ratio PET high of O2, it is 5 times high to the barrier property of CO2, it is 3.5 times high to the barrier property of vapor.
The chemical stability of polyethylene naphthalate is excellent.Ester group in its strand is met water and can be decomposed, but its water
It is only the 1/4 of PET to solve speed.PEN stablizes organic solvent, and acid and alkali resistance ability is better than PET, just because of poly- naphthalenedicarboxylic acid second
Diol ester has the performances such as excellent heat-resisting, barrier properties for gases, is widely used in the industries such as packing film and container.
With the continuous expansion of the purposes of polyethylene naphthalate material, especially in electronic apparatus, machinery zero
Application on part, product require material to have higher performance, the performance of polyethylene naphthalate resin material can not meet
It is required that, therefore it is required that developing the composite material of the polyethylene naphthalate of higher performance.
Invention content：
The purpose of the present invention is for disadvantage present on the prior art, HI high impact is carried out to polyethylene naphthalate
Enhancing is modified, and provides a kind of polyethylene naphthalate composite material with high intensity, high rigidity, high tenacity.
The technical solution adopted in the present invention has：A kind of HI high impact enhancing polyethylene naphthalate composite material, institute
State nanocomposite constituents is by weight percentage：
Polyethylene naphthalate 55~80%,
Toughener 3~10%,
Glass fibre 10~40%,
Processing aid 0.3~3%.
Further, the polyethylene naphthalate is poly- (2,6-naphthalenedicarboxylic acid glycol ester).
Further, the glass fibre is chopped glass fiber, and length is 3~10mm, and filament diameter is 5~15um.
Further, the toughener is the copolymer or ethylene-acrylic acid of ethylene-methyl methacrylate glycidol fat
Methyl esters-glycidyl methacrylate random terpolymer.
Further, the processing aid be plasticizer, stabilizer, releasing agent, dyestuff, pigment, one kind in filler or
Several mixtures.
The present invention has the advantages that：The present invention changes to carrying out HI high impact enhancing to polyethylene naphthalate
Property, a kind of performance of HI high impact of the invention enhancing polyethylene naphthalate composite material is significantly improved.
Specific implementation mode：
In order to achieve the goal above, the technical solution of the present invention is to provide a kind of HI high impacts to enhance poly- naphthalenedicarboxylic acid ethylene glycol
Ester composite material, it is characterised in that：It includes that the raw material of following weight percent proportioning is made：
Polyethylene naphthalate 55~80%,
Toughener 3~10%,
Glass fibre 10~40%,
Processing aid 0.5~3%.
Wherein polyethylene naphthalate is poly- (2,6- (ethylene naphthalate)s).
Wherein toughener is the copolymer or ethylene-methyl acrylate-first of ethylene-methyl methacrylate ethylene oxidic ester
Base glycidyl acrylate random terpolymer.
Wherein glass fibre is chopped strand, and preferred length is 3~10mm, and filament diameter is 5~15um.
It can also further contain it in a kind of HI high impact enhancing polyethylene naphthalate composite material of the present invention
Its processing aid, such as plasticizer, stabilizer, releasing agent, filler, dyestuff, pigment and other resins for assigning other characteristics, only
Otherwise damage the effect of the present invention.
The present invention a kind of HI high impact enhancing polyethylene naphthalate composite material preparation method not especially by
Limit, a kind of HI high impact of the invention enhances polyethylene naphthalate composite material can be by with such as extruder (single spiral shell
Bar or double screw extruder), hot rolling, kneader, the kneading such as kneading machine and prepare, in these, from the angle of production efficiency
For, blend preferably is prepared with single screw rod or double screw extruder, the temperature of extrusion is usually 240-300 DEG C, preferably
250-280℃.The sequence of each component for mixing the present invention is typically not critical, can by those skilled in the art Lai
It determines.
The present invention will be described in further detail in following embodiments, but the present invention should not be limited by these embodiments
System.
Compound prepared by each embodiment is molded into the standard batten of test, the physics in each embodiment by standard size
Performance is tested by international standard respectively.
The present invention is verified by following example：
Polyethylene naphthalate：PEN, Japanese Di Ren companies.
Toughener：The copolymer of ethylene-methyl methacrylate ethylene oxidic ester, AX8900, Arkema
Ethylene-methyl acrylate-glycidyl methacrylate random terpolymer, AX8840, Acker agate are public
Department
Glass fibre：ECS11-03-534, the production of Chinese glass megalith group；
Antioxidant：Antioxidant 1076 is produced by German BASF；
Releasing agent：PETS is produced by Shanghai Lang Te companies.
The present invention is verified by following example, and detailed data result see the table below：
Embodiment 1-4 formula tables and performance test results
Can significantly it be found out by the experimental result of examples detailed above, a kind of HI high impact of the invention enhances poly- naphthalenedicarboxylic acid second
The performance of terephthalate composite is significantly improved.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
It for member, can also make several improvements without departing from the principle of the present invention, these improvement also should be regarded as the present invention's
Protection domain.
Claims (5)
1. a kind of HI high impact enhances polyethylene naphthalate composite material, it is characterised in that：The nanocomposite constituents are pressed
Weight percent is：
Polyethylene naphthalate 55~80%,
Toughener 3~10%,
Glass fibre 10~40%,
Processing aid 0.3~3%.
2. HI high impact according to claim 1 enhances polyethylene naphthalate composite material, it is characterised in that：It is described
Polyethylene naphthalate be poly- (2,6- (ethylene naphthalate)s).
3. HI high impact according to claim 1 enhances polyethylene naphthalate composite material, it is characterised in that：It is described
Glass fibre is chopped glass fiber, and length is 3~10mm, and filament diameter is 5~15um.
4. HI high impact according to claim 1 enhances polyethylene naphthalate composite material, it is characterised in that：It is described
Toughener is the copolymer or ethylene-methyl acrylate-Glycidyl methacrylate of ethylene-methyl methacrylate glycidol fat
Glyceride random terpolymer.
5. HI high impact according to claim 1 enhances polyethylene naphthalate composite material, it is characterised in that：It is described
Processing aid is the mixture of one or more of plasticizer, stabilizer, releasing agent, dyestuff, pigment, filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810337446.1A CN108424624A (en) | 2018-04-16 | 2018-04-16 | A kind of HI high impact enhancing polyethylene naphthalate composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810337446.1A CN108424624A (en) | 2018-04-16 | 2018-04-16 | A kind of HI high impact enhancing polyethylene naphthalate composite material |
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| Publication Number | Publication Date |
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| CN108424624A true CN108424624A (en) | 2018-08-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810337446.1A Pending CN108424624A (en) | 2018-04-16 | 2018-04-16 | A kind of HI high impact enhancing polyethylene naphthalate composite material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112831160A (en) * | 2020-12-30 | 2021-05-25 | 广州辰东新材料有限公司 | Thermoplastic polyester composite material resistant to automobile power battery electrolyte and preparation and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001181491A (en) * | 1999-12-28 | 2001-07-03 | Polyplastics Co | Flame-retardant polyester resin composition |
| CN103396658A (en) * | 2013-07-11 | 2013-11-20 | 旭阳化学技术研究院有限公司 | Polyethylene naphthalate resin composition and preparation method thereof |
| CN103788598A (en) * | 2014-01-29 | 2014-05-14 | 厦门市天宇塑料工业有限公司 | Anti-yellowing anti-separation flame-retardant enhanced PBT composition and use thereof |
| CN106674969A (en) * | 2009-07-17 | 2017-05-17 | 阿科玛股份有限公司 | Polycarbonate/polyester and polycarbonate/polyamide composition having improved impact resistance |
-
2018
- 2018-04-16 CN CN201810337446.1A patent/CN108424624A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001181491A (en) * | 1999-12-28 | 2001-07-03 | Polyplastics Co | Flame-retardant polyester resin composition |
| CN106674969A (en) * | 2009-07-17 | 2017-05-17 | 阿科玛股份有限公司 | Polycarbonate/polyester and polycarbonate/polyamide composition having improved impact resistance |
| CN103396658A (en) * | 2013-07-11 | 2013-11-20 | 旭阳化学技术研究院有限公司 | Polyethylene naphthalate resin composition and preparation method thereof |
| CN103788598A (en) * | 2014-01-29 | 2014-05-14 | 厦门市天宇塑料工业有限公司 | Anti-yellowing anti-separation flame-retardant enhanced PBT composition and use thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112831160A (en) * | 2020-12-30 | 2021-05-25 | 广州辰东新材料有限公司 | Thermoplastic polyester composite material resistant to automobile power battery electrolyte and preparation and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180821 |
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| RJ01 | Rejection of invention patent application after publication |