CN108410353A - A kind of two-component glass heat-insulating coating and preparation method thereof - Google Patents
A kind of two-component glass heat-insulating coating and preparation method thereof Download PDFInfo
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- 239000011521 glass Substances 0.000 title claims abstract description 93
- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 title claims description 35
- 239000000843 powder Substances 0.000 claims abstract description 96
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 70
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims abstract description 52
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000009413 insulation Methods 0.000 claims abstract description 35
- 239000002131 composite material Substances 0.000 claims abstract description 34
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011344 liquid material Substances 0.000 claims abstract description 31
- 239000008367 deionised water Substances 0.000 claims abstract description 26
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 26
- -1 trihydroxy methyl Chemical group 0.000 claims abstract description 21
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004327 boric acid Substances 0.000 claims abstract description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- 125000005456 glyceride group Chemical group 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011324 bead Substances 0.000 claims description 55
- 239000002994 raw material Substances 0.000 claims description 38
- 238000002156 mixing Methods 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 30
- 239000002002 slurry Substances 0.000 claims description 27
- 238000001035 drying Methods 0.000 claims description 25
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 20
- 239000011812 mixed powder Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 238000000498 ball milling Methods 0.000 claims description 16
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 15
- 238000000227 grinding Methods 0.000 claims description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 15
- 239000010703 silicon Substances 0.000 claims description 15
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 15
- 235000012239 silicon dioxide Nutrition 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 11
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 11
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 11
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 10
- 239000000292 calcium oxide Substances 0.000 claims description 10
- 235000012255 calcium oxide Nutrition 0.000 claims description 10
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims description 10
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 10
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 10
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 5
- 239000001739 pinus spp. Substances 0.000 claims description 5
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 229940036248 turpentine Drugs 0.000 claims description 5
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004005 microsphere Substances 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 238000004134 energy conservation Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
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- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a kind of two-component glass heat-insulating coatings and preparation method thereof, are related to technical field of coatings, including liquid material component and powder component；Liquid material component includes：Organic siliconresin, dimethyl ether, fatty glyceride, trihydroxy methyl triglycidyl ether, diisobutyl phthalate, n-butanol and deionized water；Powder component includes：Modified glass microspheres, improved silica, boric acid graphene composite powder and sodium metasilicate.The present invention has good heat insulation.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a double-component glass heat-insulating coating and a preparation method thereof.
Background
The heat effect of the current global environment is aggravated, and energy conservation and emission reduction are the problems commonly faced by the world building industry. The energy conservation of the building is to reduce the energy consumption of the building for heating and cooling under the condition of ensuring the comfortable temperature of the room. The glass is widely applied to buildings as a transparent material, and researches show that the heat transfer coefficient of common glass is 3.2 times that of a wall body and 5 times that of a roof. In addition, due to the transparency of the common glass, light can directly reach the other side from one side of the glass, so that the space inside the glass is irradiated by sunlight to be heated. Therefore, the improvement of the heat insulation effect of the glass window is an important link for energy conservation and emission reduction of buildings.
In the prior art, products such as film, heat insulation paper, metal coated heat insulation glass and the like are generally adopted to realize the heat insulation of glass windows, but the products generally have the problems of poor heat insulation effect and the like.
Disclosure of Invention
The invention aims to provide a double-component glass heat-insulating coating and a preparation method thereof, and the double-component glass heat-insulating coating has a good heat-insulating effect.
The invention provides the following technical scheme: a double-component glass heat insulation coating comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 65-85 parts of organic silicon resin, 10-15 parts of dipropylene glycol dimethyl ether, 10-15 parts of fatty glyceride, 8-12 parts of trihydroxymethyl triglycidyl ether, 3-6 parts of diisobutyl phthalate, 2-5 parts of n-butyl alcohol and 30-35 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 20-30 parts of modified glass beads, 10-15 parts of modified silicon dioxide, 4-8 parts of boric acid-graphene composite powder and 2-5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 10 to 20.
Wherein, the material comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 67-80 parts of organic silicon resin, 11-14 parts of dipropylene glycol dimethyl ether, 11-14 parts of fatty glyceride, 9-11 parts of trihydroxymethyl triglycidyl ether, 4-5 parts of diisobutyl phthalate, 3-4 parts of n-butyl alcohol and 31-34 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 22-28 parts of modified glass beads, 11-14 parts of modified silicon dioxide, 5-7 parts of boric acid-graphene composite powder and 3-4 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 10 to 20.
Wherein, the material comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 75 parts of organic silicon resin, 12.5 parts of dipropylene glycol dimethyl ether, 12.5 parts of fatty glyceride, 10 parts of trihydroxymethyl triglycidyl ether, 4.5 parts of diisobutyl phthalate, 3.5 parts of n-butanol and 32.5 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 25 parts of modified glass beads, 12.5 parts of modified silicon dioxide, 6 parts of boric acid-graphene composite powder and 3.5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 15.
the modified glass bead comprises the following raw materials in parts by weight: 5-8 parts of absolute ethyl alcohol, 5-8 parts of hollow glass beads, 1-2 parts of nano ATO powder, 0.3-0.5 part of carbonyl nickel powder, 0.3-0.5 part of aluminum hydroxide, 0.08-0.12 part of polyvinylpyrrolidone, 0.08-0.12 part of ferric oxide, 0.05-0.08 part of boric acid, 0.05-0.08 part of sodium trimetaphosphate and 6-9 parts of silica sol.
The preparation method of the modified glass beads comprises the following steps:
(1) adding nano ATO powder and sodium trimetaphosphate into absolute ethyl alcohol according to a ratio, uniformly dispersing to obtain an ATO slurry dispersion system, putting the ATO slurry dispersion system into a magnetic stirrer, stirring for 30-60 min, adding polyvinylpyrrolidone, and continuously dispersing to prepare ATO slurry;
(2) adding hollow glass beads, carbonyl nickel powder, aluminum hydroxide, iron oxide and boric acid into silica sol according to a ratio at room temperature, and uniformly stirring and dispersing to obtain hollow glass bead dispersion slurry;
(3) and mixing the ATO slurry and the hollow glass bead dispersion slurry, uniformly stirring, drying at the temperature of 60-90 ℃, and grinding to obtain the modified glass beads.
The preparation method of the boric acid-graphene composite powder comprises the following steps:
(1) mixing boric acid and graphene according to a ratio of 1: 2-3, and drying to obtain mixed powder;
(2) taking the nano titanium dioxide, the mixed powder and the absolute ethyl alcohol according to a ratio of 1: 20-25: mixing at a ratio of 45-50, and ultrasonically dispersing for 2-3 hours;
(3) putting the mixed powder subjected to ultrasonic dispersion into a nylon ball milling tank, taking agate balls as grinding balls, and controlling the mass ratio of the balls to the materials to be 8-9: 1, continuously ball-milling for 3-4 h in a ball mill at the rotating speed of 200-300 r/min;
(4) and pouring the mixed powder and the agate balls after ball milling into a powder tray, drying at 60-75 ℃, sieving, taking out the agate balls, and obtaining the boric acid-graphene composite powder.
Wherein the modified silicon dioxide comprises the following raw materials in parts by weight: 15-20 parts of silicon dioxide, 4-5 parts of nano silicon nitride, 4-5 parts of quick lime, 1-2 parts of stearic acid, 1-2 parts of turpentine, 0.8-1.2 parts of diaminodiphenylmethane, 0.5-0.9 part of sodium tripolyphosphate, 0.3-0.5 part of polyoxyethylene lauryl ether, 0.3-0.5 part of diisobutyl phthalate and 16-20 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50-65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130-150 ℃, mixing and stirring for 40-60 min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 700-800 r/min for 3-4 h, drying at 60-70 ℃, and grinding to obtain the nano-silicon dioxide/sodium tripolyphosphate composite material.
The invention provides a preparation method of a double-component glass heat insulation coating, which comprises the following steps:
(1) preparing the powder component
Weighing modified glass beads, modified silicon dioxide, boric acid-graphene composite powder and sodium silicate according to the proportion, mixing, and uniformly dispersing to obtain a powder component;
(2) preparation of the liquid Material component
Weighing organic silicon resin, dipropylene glycol dimethyl ether, fatty acid glyceride, trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water according to the proportion, uniformly dispersing at the rotating speed of 200-400 r/min at the temperature of 50-60 ℃ to obtain a liquid material component, adding the obtained powder material component, heating to 65-70 ℃, dispersing at the rotating speed of 100-200 r/min for 30-50 min, and cooling to obtain the double-component glass heat insulation coating.
The invention has the beneficial effects that: the heat insulation material has good heat insulation effect, and comprises the following specific components:
(1) the invention adopts liquid material components and powder material components according to the proportion of 1: 10-20 to obtain the special glass surface heat insulation coating, the addition amount of the powder components is small, the preparation cost can be reduced, and through a large number of tests, the liquid material components and the powder components are mixed according to the ratio of 1: 15, the film-forming property, the heat-insulating property and the like of the obtained coating can reach the best; the coating is prepared by taking organic silicon resin, dipropylene glycol dimethyl ether and fatty acid glyceride as main raw materials, taking trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water as auxiliary raw materials to obtain liquid material components, taking the liquid material components as matrix raw materials, and not only having good performances of film forming, weather resistance, water resistance, salt mist resistance and the like, but also providing a good dispersion system for powder materials, so that the two components have synergistic effect and the heat insulation effect of the coating is further improved; the powder components are prepared from the modified glass beads, the modified silicon dioxide, the boric acid-graphene composite powder and the sodium silicate, the addition amount is small, but the heat insulation performance is excellent, the excellent heat insulation effect can be achieved only by adding a small amount of powder components, and meanwhile, the light transmittance of the invention can be ensured;
(2) the powder components of the invention, wherein the modified glass beads are prepared from raw materials such as absolute ethyl alcohol, hollow glass beads, nano ATO powder, carbonyl nickel powder, aluminum hydroxide and polyvinylpyrrolidone, and the hollow glass beads have the advantages of light weight, low heat conduction, high strength, good chemical stability and the like, but in order to achieve the effect of reducing the addition of the powder, the hollow glass beads need to be modified while reducing the manufacturing cost, and the modified hollow glass beads have better heat insulation, dispersion and flow properties because of a composite structure absorbed with the nano ATO powder and the carbonyl nickel powder, and can also improve the stability and ageing resistance of a coating, and increase the toughness and reinforcement;
(3) according to the invention, boric acid-graphene composite powder is added into the raw materials, and the nano titanium dioxide and absolute ethyl alcohol are adopted for ball milling to form a fly ash-graphene composite structure, so that the structure is compact, the adsorption performance and the bonding performance are stronger, the compactness of the coating after film forming is enhanced, the heat insulation effect can be improved, the glossiness of the coating is also improved, and the coating is not easy to age.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. These examples are intended to illustrate the invention and are not intended to limit the scope of the invention.
Example 1
A double-component glass heat insulation coating comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 65 parts of organic silicon resin, 10 parts of dipropylene glycol dimethyl ether, 10 parts of fatty glyceride, 8 parts of trihydroxymethyl triglycidyl ether, 3 parts of diisobutyl phthalate, 2-5 parts of n-butyl alcohol and 30 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 20 parts of modified glass beads, 10 parts of modified silicon dioxide, 4 parts of boric acid-graphene composite powder and 2 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 10.
wherein,
the modified glass bead comprises the following raw materials in parts by weight: 5 parts of absolute ethyl alcohol, 5 parts of hollow glass beads, 1 part of nano ATO powder, 0.3 part of carbonyl nickel powder, 0.3 part of aluminum hydroxide, 0.08 part of polyvinylpyrrolidone, 0.08 part of ferric oxide, 0.05 part of boric acid, 0.05 part of sodium trimetaphosphate and 6 parts of silica sol.
Wherein,
the preparation method of the modified glass beads comprises the following steps:
(1) adding nano ATO powder and sodium trimetaphosphate into absolute ethyl alcohol according to a ratio, uniformly dispersing to obtain an ATO slurry dispersion system, putting into a magnetic stirrer, stirring for 30min, adding polyvinylpyrrolidone, and continuously dispersing to obtain ATO slurry;
(2) adding hollow glass beads, carbonyl nickel powder, aluminum hydroxide, iron oxide and boric acid into silica sol according to a ratio at room temperature, and uniformly stirring and dispersing to obtain hollow glass bead dispersion slurry;
(3) and mixing the ATO slurry and the hollow glass bead dispersion slurry, uniformly stirring, drying at 60 ℃, and grinding to obtain the modified glass beads.
Wherein,
the preparation method of the boric acid-graphene composite powder comprises the following steps:
(1) mixing boric acid and graphene according to the ratio of 1:2, and drying to obtain mixed powder;
(2) taking nano titanium dioxide, mixed powder and absolute ethyl alcohol according to a ratio of 1: 20: 45, and ultrasonically dispersing for 2 hours;
(3) putting the mixed powder after ultrasonic dispersion into a nylon ball milling tank, taking agate balls as grinding balls, and controlling the mass ratio of the balls to the materials to be 8: 1, continuously ball-milling for 3 hours in a ball mill at the rotating speed of 200 r/min;
(4) and pouring the mixed powder and the agate balls after ball milling into a powder tray, drying at 60 ℃, sieving, taking out the agate balls, and obtaining the boric acid-graphene composite powder.
Wherein,
the modified silicon dioxide comprises the following raw materials in parts by weight: 15 parts of silicon dioxide, 4 parts of nano silicon nitride, 4 parts of quick lime, 1 part of stearic acid, 1 part of turpentine, 0.8 part of diaminodiphenylmethane, 0.5 part of sodium tripolyphosphate, 0.3 part of polyoxyethylene lauryl ether, 0.3 part of diisobutyl phthalate and 16 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130 ℃, mixing and stirring for 40min, cooling to room temperature, adding the rest raw materials, stirring at a rotating speed of 700r/min for 3h, drying at 60 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment provides a preparation method of a two-component glass heat insulation coating, which comprises the following steps:
(1) preparing the powder component
Weighing modified glass beads, modified silicon dioxide, boric acid-graphene composite powder and sodium silicate according to the proportion, mixing, and uniformly dispersing to obtain a powder component;
(2) preparation of the liquid Material component
Weighing organic silicon resin, dipropylene glycol dimethyl ether, fatty glyceride, trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water according to the proportion, uniformly dispersing at the rotating speed of 200r/min at the temperature of 50 ℃ to obtain a liquid material component, then adding the obtained powder material component, heating to 65 ℃, dispersing at the rotating speed of 100r/min for 30min, and cooling to obtain the double-component glass heat insulation coating.
Example 2
A double-component glass heat insulation coating comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 85 parts of organic silicon resin, 15 parts of dipropylene glycol dimethyl ether, 15 parts of fatty glyceride, 12 parts of trihydroxymethyl triglycidyl ether, 6 parts of diisobutyl phthalate, 5 parts of n-butanol and 35 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 30 parts of modified glass beads, 15 parts of modified silicon dioxide, 8 parts of boric acid-graphene composite powder and 5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 20.
wherein,
the modified glass bead comprises the following raw materials in parts by weight: 8 parts of absolute ethyl alcohol, 8 parts of hollow glass beads, 2 parts of nano ATO powder, 0.5 part of carbonyl nickel powder, 0.5 part of aluminum hydroxide, 0.12 part of polyvinylpyrrolidone, 0.12 part of ferric oxide, 0.08 part of boric acid, 0.08 part of sodium trimetaphosphate and 9 parts of silica sol.
The preparation method of the modified glass beads comprises the following steps:
(1) adding nano ATO powder and sodium trimetaphosphate into absolute ethyl alcohol according to a ratio, uniformly dispersing to obtain an ATO slurry dispersion system, putting into a magnetic stirrer, stirring for 60min, adding polyvinylpyrrolidone, and continuously dispersing to obtain ATO slurry;
(2) adding hollow glass beads, carbonyl nickel powder, aluminum hydroxide, iron oxide and boric acid into silica sol according to a ratio at room temperature, and uniformly stirring and dispersing to obtain hollow glass bead dispersion slurry;
(3) and mixing the ATO slurry and the hollow glass bead dispersion slurry, uniformly stirring, drying at 90 ℃, and grinding to obtain the modified glass beads.
Wherein,
the preparation method of the boric acid-graphene composite powder comprises the following steps:
(1) mixing boric acid and graphene according to the proportion of 1: 3, and drying to obtain mixed powder;
(2) taking nano titanium dioxide, mixed powder and absolute ethyl alcohol according to a ratio of 1: 25: mixing at a ratio of 50, and ultrasonically dispersing for 3 hours;
(3) putting the mixed powder after ultrasonic dispersion into a nylon ball milling tank, taking agate balls as grinding balls, and controlling the mass ratio of the balls to materials to be 9: 1, continuously ball-milling for 4 hours in a ball mill at the rotating speed of 300 r/min;
(4) and pouring the mixed powder and the agate balls after ball milling into a powder tray, drying at 75 ℃, sieving, taking out the agate balls, and obtaining the boric acid-graphene composite powder.
Wherein,
the modified silicon dioxide comprises the following raw materials in parts by weight: 20 parts of silicon dioxide, 5 parts of nano silicon nitride, 5 parts of quick lime, 2 parts of stearic acid, 2 parts of turpentine, 1.2 parts of diaminodiphenylmethane, 0.9 part of sodium tripolyphosphate, 0.5 part of polyoxyethylene lauryl ether, 0.5 part of diisobutyl phthalate and 20 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 150 ℃, mixing and stirring for 60min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 800r/min for 4h, drying at 70 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment provides a preparation method of a two-component glass heat insulation coating, which comprises the following steps:
(1) preparing the powder component
Weighing modified glass beads, modified silicon dioxide, boric acid-graphene composite powder and sodium silicate according to the proportion, mixing, and uniformly dispersing to obtain a powder component;
(2) preparation of the liquid Material component
Weighing organic silicon resin, dipropylene glycol dimethyl ether, fatty glyceride, trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water according to the proportion, uniformly dispersing at the rotating speed of 400r/min at the temperature of 60 ℃ to obtain a liquid material component, then adding the obtained powder material component, heating to 70 ℃, dispersing at the rotating speed of 200r/min for 50min, and cooling to obtain the double-component glass heat insulation coating.
Example 3
A double-component glass heat insulation coating comprises a liquid material component and a powder material component;
the liquid material comprises the following raw materials in parts by weight: 75 parts of organic silicon resin, 12.5 parts of dipropylene glycol dimethyl ether, 12.5 parts of fatty glyceride, 10 parts of trihydroxymethyl triglycidyl ether, 4.5 parts of diisobutyl phthalate, 3.5 parts of n-butanol and 32.5 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 25 parts of modified glass beads, 12.5 parts of modified silicon dioxide, 6 parts of boric acid-graphene composite powder and 3.5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 15.
wherein,
the modified glass bead comprises the following raw materials in parts by weight: 6.5 parts of absolute ethyl alcohol, 6.5 parts of hollow glass beads, 1.5 parts of nano ATO powder, 0.4 part of carbonyl nickel powder, 0.4 part of aluminum hydroxide, 0.1 part of polyvinylpyrrolidone, 0.1 part of ferric oxide, 0.06 part of boric acid, 0.06 part of sodium trimetaphosphate and 8 parts of silica sol.
The preparation method of the modified glass beads comprises the following steps:
(1) adding nano ATO powder and sodium trimetaphosphate into absolute ethyl alcohol according to a ratio, uniformly dispersing to obtain an ATO slurry dispersion system, putting into a magnetic stirrer, stirring for 40min, adding polyvinylpyrrolidone, and continuously dispersing to obtain ATO slurry;
(2) adding hollow glass beads, carbonyl nickel powder, aluminum hydroxide, iron oxide and boric acid into silica sol according to a ratio at room temperature, and uniformly stirring and dispersing to obtain hollow glass bead dispersion slurry;
(3) and mixing the ATO slurry and the hollow glass bead dispersion slurry, uniformly stirring, drying at 80 ℃, and grinding to obtain the modified glass beads.
Wherein,
the preparation method of the boric acid-graphene composite powder comprises the following steps:
(1) mixing boric acid and graphene according to the ratio of 1:2.5, and drying to obtain mixed powder;
(2) taking nano titanium dioxide, mixed powder and absolute ethyl alcohol according to a ratio of 1: 22: 47, and ultrasonically dispersing for 2.5 hours;
(3) putting the mixed powder after ultrasonic dispersion into a nylon ball milling tank, taking agate balls as grinding balls, and controlling the mass ratio of the balls to the materials to be 8.5: 1, continuously ball-milling for 3.5 hours in a ball mill at the rotating speed of 250 r/min;
(4) and pouring the mixed powder and the agate balls after ball milling into a powder tray, drying at 65 ℃, sieving, taking out the agate balls, and obtaining the boric acid-graphene composite powder.
Wherein,
the modified silicon dioxide comprises the following raw materials in parts by weight: 17.5 parts of silicon dioxide, 4.5 parts of nano silicon nitride, 4.5 parts of quick lime, 1.5 parts of stearic acid, 1.5 parts of turpentine, 1 part of diaminodiphenylmethane, 0.7 part of sodium tripolyphosphate, 0.4 part of polyoxyethylene lauryl ether, 0.4 part of diisobutyl phthalate and 18 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 55 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 140 ℃, mixing and stirring for 50min, cooling to room temperature, adding the rest raw materials, stirring at a rotating speed of 750r/min for 3.5h, drying at 65 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment provides a preparation method of a two-component glass heat insulation coating, which comprises the following steps:
(1) preparing the powder component
Weighing modified glass beads, modified silicon dioxide, boric acid-graphene composite powder and sodium silicate according to the proportion, mixing, and uniformly dispersing to obtain a powder component;
(2) preparation of the liquid Material component
Weighing organic silicon resin, dipropylene glycol dimethyl ether, fatty glyceride, trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water according to the proportion, uniformly dispersing at the rotating speed of 300r/min at the temperature of 55 ℃ to obtain a liquid material component, then adding the obtained powder material component, heating to 68 ℃, dispersing at the rotating speed of 150r/min for 40min, and cooling to obtain the double-component glass heat insulation coating.
While the invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes can be made and equivalents can be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (9)
1. A double-component glass heat insulation coating is characterized by comprising a liquid component and a powder component;
the liquid material comprises the following raw materials in parts by weight: 65-85 parts of organic silicon resin, 10-15 parts of dipropylene glycol dimethyl ether, 10-15 parts of fatty glyceride, 8-12 parts of trihydroxymethyl triglycidyl ether, 3-6 parts of diisobutyl phthalate, 2-5 parts of n-butyl alcohol and 30-35 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 20-30 parts of modified glass beads, 10-15 parts of modified silicon dioxide, 4-8 parts of boric acid-graphene composite powder and 2-5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 10 to 20.
2. The two-component glass thermal insulation coating according to claim 1, characterized by comprising a liquid component and a powder component;
the liquid material comprises the following raw materials in parts by weight: 67-80 parts of organic silicon resin, 11-14 parts of dipropylene glycol dimethyl ether, 11-14 parts of fatty glyceride, 9-11 parts of trihydroxymethyl triglycidyl ether, 4-5 parts of diisobutyl phthalate, 3-4 parts of n-butyl alcohol and 31-34 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 22-28 parts of modified glass beads, 11-14 parts of modified silicon dioxide, 5-7 parts of boric acid-graphene composite powder and 3-4 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 10 to 20.
3. The two-component glass thermal insulation coating according to claim 1, characterized by comprising a liquid component and a powder component;
the liquid material comprises the following raw materials in parts by weight: 75 parts of organic silicon resin, 12.5 parts of dipropylene glycol dimethyl ether, 12.5 parts of fatty glyceride, 10 parts of trihydroxymethyl triglycidyl ether, 4.5 parts of diisobutyl phthalate, 3.5 parts of n-butanol and 32.5 parts of deionized water;
the powder material comprises the following raw materials in parts by weight: 25 parts of modified glass beads, 12.5 parts of modified silicon dioxide, 6 parts of boric acid-graphene composite powder and 3.5 parts of sodium silicate;
the mixing ratio of the powder component to the liquid component is 1: 15.
4. the two-component glass thermal insulation coating according to claim 1, wherein the modified glass beads comprise the following raw materials in parts by weight: 5-8 parts of absolute ethyl alcohol, 5-8 parts of hollow glass beads, 1-2 parts of nano ATO powder, 0.3-0.5 part of carbonyl nickel powder, 0.3-0.5 part of aluminum hydroxide, 0.08-0.12 part of polyvinylpyrrolidone, 0.08-0.12 part of ferric oxide, 0.05-0.08 part of boric acid, 0.05-0.08 part of sodium trimetaphosphate and 6-9 parts of silica sol.
5. The two-component glass thermal insulation coating according to claim 4, wherein the preparation method of the modified glass beads comprises the following steps:
(1) adding nano ATO powder and sodium trimetaphosphate into absolute ethyl alcohol according to a ratio, uniformly dispersing to obtain an ATO slurry dispersion system, putting the ATO slurry dispersion system into a magnetic stirrer, stirring for 30-60 min, adding polyvinylpyrrolidone, and continuously dispersing to prepare ATO slurry;
(2) adding hollow glass beads, carbonyl nickel powder, aluminum hydroxide, iron oxide and boric acid into silica sol according to a ratio at room temperature, and uniformly stirring and dispersing to obtain hollow glass bead dispersion slurry;
(3) and mixing the ATO slurry and the hollow glass bead dispersion slurry, uniformly stirring, drying at the temperature of 60-90 ℃, and grinding to obtain the modified glass beads.
6. The two-component glass heat insulation coating as claimed in claim 1, wherein the preparation method of the boric acid-graphene composite powder material comprises the following steps:
(1) mixing boric acid and graphene according to a ratio of 1: 2-3, and drying to obtain mixed powder;
(2) taking the nano titanium dioxide, the mixed powder and the absolute ethyl alcohol according to a ratio of 1: 20-25: mixing at a ratio of 45-50, and ultrasonically dispersing for 2-3 hours;
(3) putting the mixed powder subjected to ultrasonic dispersion into a nylon ball milling tank, taking agate balls as grinding balls, and controlling the mass ratio of the balls to the materials to be 8-9: 1, continuously ball-milling for 3-4 h in a ball mill at the rotating speed of 200-300 r/min;
(4) and pouring the mixed powder and the agate balls after ball milling into a powder tray, drying at 60-75 ℃, sieving, taking out the agate balls, and obtaining the boric acid-graphene composite powder.
7. The two-component glass thermal insulation coating according to claim 1, wherein the modified silica comprises the following raw materials in parts by weight: 15-20 parts of silicon dioxide, 4-5 parts of nano silicon nitride, 4-5 parts of quick lime, 1-2 parts of stearic acid, 1-2 parts of turpentine, 0.8-1.2 parts of diaminodiphenylmethane, 0.5-0.9 part of sodium tripolyphosphate, 0.3-0.5 part of polyoxyethylene lauryl ether, 0.3-0.5 part of diisobutyl phthalate and 16-20 parts of deionized water.
8. The two-component glass thermal insulation coating according to claim 7, wherein the modified silica is prepared by the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50-65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130-150 ℃, mixing and stirring for 40-60 min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 700-800 r/min for 3-4 h, drying at 60-70 ℃, and grinding to obtain the nano-silicon dioxide/sodium tripolyphosphate composite material.
9. A preparation method of the two-component glass heat insulation coating according to any one of claims 1 to 8, characterized by comprising the following steps:
(1) preparing the powder component
Weighing modified glass beads, modified silicon dioxide, boric acid-graphene composite powder and sodium silicate according to the proportion, mixing, and uniformly dispersing to obtain a powder component;
(2) preparation of the liquid Material component
Weighing organic silicon resin, dipropylene glycol dimethyl ether, fatty acid glyceride, trihydroxymethyl triglycidyl ether, diisobutyl phthalate, n-butyl alcohol and deionized water according to the proportion, uniformly dispersing at the rotating speed of 200-400 r/min at the temperature of 50-60 ℃ to obtain a liquid material component, adding the obtained powder material component, heating to 65-70 ℃, dispersing at the rotating speed of 100-200 r/min for 30-50 min, and cooling to obtain the double-component glass heat insulation coating.
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