CN108384512A - A kind of historical relic repairing binder and preparation method thereof and application method - Google Patents
A kind of historical relic repairing binder and preparation method thereof and application method Download PDFInfo
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- CN108384512A CN108384512A CN201810307087.5A CN201810307087A CN108384512A CN 108384512 A CN108384512 A CN 108384512A CN 201810307087 A CN201810307087 A CN 201810307087A CN 108384512 A CN108384512 A CN 108384512A
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- tanning
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- 239000011230 binding agent Substances 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002383 tung oil Substances 0.000 claims abstract description 31
- 235000013871 bee wax Nutrition 0.000 claims abstract description 29
- 239000012166 beeswax Substances 0.000 claims abstract description 23
- 235000006040 Prunus persica var persica Nutrition 0.000 claims abstract description 17
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 244000144730 Amygdalus persica Species 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims description 28
- 239000000853 adhesive Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 23
- 239000003292 glue Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000084 colloidal system Substances 0.000 claims description 9
- 239000006260 foam Substances 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 4
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 4
- 244000082204 Phyllostachys viridis Species 0.000 claims description 4
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 4
- 239000011425 bamboo Substances 0.000 claims description 4
- 239000007767 bonding agent Substances 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims 2
- 239000004615 ingredient Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 230000002045 lasting effect Effects 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 6
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 240000005809 Prunus persica Species 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000010437 gem Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000005491 wire drawing Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 244000086363 Pterocarpus indicus Species 0.000 description 2
- 235000009984 Pterocarpus indicus Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(II,IV) oxide Inorganic materials O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 244000132059 Carica parviflora Species 0.000 description 1
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
- C09J191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of historical relic repairing binder and preparation method thereof and application method, the specific ingredient of wherein historical relic repairing binder includes rosin 40 50%, beeswax 30 40%, tung oil 5 10%, peach gum 5 10%.
Description
Technical field
The invention patent relates to historical relics to repair field, specifically, being a kind of bonding used in historical relic repair process
Agent.
Background technology
Conventional damascene processes are one of most representative craft and techniques in the decoration of China period of Ming and Qing imperial palace, include mainly
Hundred treasured are inlayed, lacquerware is inlayed, filigree inlaying three classes form.Once eaves decoration in building, furniture furnishings, life appliance are widely used in
On bullion.The typical feature of mosaic technology is that various jewels and jade material clouds are integrated, show its color it is gorgeous,
Material it is various, technique fine, the basic skills of making are to be decorated bonding with groove.By the material to vary in color according to design
Pattern splicing to together, reaching remarkably true to life, lively, the bizarre and motley decorative effect of image.Palace Museum collection
In historical relic, most mosaic technology implements are all made of ancient sticky wax glue and are bonded, and involved material is varied：Insert material
Including organic material (bamboo and wood tooth angle, pearl, coral, amber, shell, coconut husk etc.) and inorganic material (various jewels, jade, glass
Glass, ceramics etc.)；Base material is mainly hardwood material (narra, rosewood), lacquerware and noble metal.
Just because of material is various, processing technology is complicated, at the beginning of making not all inserts and base material can consolidation it is viscous
Connect, due to time passage, history chaos caused by war and adhesive self deterioration, be now hidden in Palace Museum to inlay opening for class historical relic viscous de-
It is more universal to fall phenomenon.But ancient adhesive formulation technique is lost for a long time, boiling method also has no way of finding out about it.In recent years,
New chemical adhesives is commonly used in historical relic in repairing, but new chemical binder is easy to damage historical relic, also, some are viscous
Agent, such as epoxies chemical glue are tied, hardness is very high after solidification, and colloid penetrates into inside base material or gap, it is difficult to it removes, it can be to base material
Larger damage is generated, and irreversible.Other acrylic compounds chemical glue, solvent can then lead to historical relic ontology or bonding base
The case where material fades, pollution convered structure.
Invention content
The present invention is directed to the deficiency of existing binder, provides novel binder and preparation method thereof and user
Method.Specifically the present invention provides a kind of historical relic repairing binder, it is characterised in that：Including rosin 40-50%, beeswax 30-
40%, tung oil 5-10%, peach gum 5-10%.
Further, it is characterised in that：Each component content is respectively rosin 50%, beeswax 39%, tung oil 5%, peach gum
6%.
The preparation method of the also same historical relic repairing binder of the present invention, it is characterised in that：
Beeswax is poured into hot pot, melting temperature is 120~180 DEG C, is kept stirring using glass stirring rod；
Wait for that beeswax is melted into liquid and colophony powder is sprinkled into pot again completely, meanwhile, it is stirred continuously；
Tung oil is added after rosin dissolves completely and peach gum is added, is constantly stirred；When starting to calculate tanning at this time
Between；
Temperature is boiled at 280 DEG C or so, until 20 minutes whens can remove glue pot from fire, and under liquid condition point
It heats and uses again in flat small crucible, when to use.
Further, it is characterised in that：The preparation method of the tung oil is as follows
Tung oil is removed moisture removal by a using the method for open firing, is judged by having seen whether foam, when not having in oil
Moisture is to remove when foam；
Particulate manganese dioxide is added after b moisture removals, continues tanning to no foam；
Suitable Pb is added in c3O4, continue to boil, be sufficiently stirred.
Further, it is characterised in that：The temperature of tanning is 170~300 DEG C, and the time is about a hour.
Further, it is characterised in that：Further include the steps that whether test tung oil is boiled into after step c, specially will
A little oil instills in cold water, if it is to be boiled into enter water not dissipating, otherwise continues tanning stirring.
The present invention also provides a kind of application methods of preceding claim historical relic repairing binder, it is characterised in that：Including
Following steps：
1) adhesive is placed in the heating plate of adjustable temperature by heating and melting binder, and temperature is adjusted to tanning temperature
It about 200 DEG C, is used when dissolve fully is liquid；
2) bonding plane is thoroughly cleaned, bonding plane is thoroughly cleaned using alcohol, the unsuitable cold, humidity of bonding operating environment is not
It is preferably excessively high, ensure bonding plane drying when bonding, if convered structure is inanimate matter stone material, adhesive surface appropriate heating can be operated
Temperature is less than 100 DEG C.
3) it is uniformly smeared on bonding plane both sides, adhesive is easier to condense at this time, and heat gun is needed to assist caking agent,
Ensure that colloid is liquid when bonding.
4) when being bonded, the operating time is more urgent, and bonding plane will be squeezed moderately when contacting, it is ensured that bonding agent comes into full contact with.
Extruding can make extra adhesive overspill, be purged after to be solidified, can be rejected using bamboo knife, can also use second
Alcohol cleans.
Invention effect：
The historical relic repairing adhesive of the present invention, organic, environmentally friendly, boiling method is easy to operate, with obvious effects, meets historical relic and repaiies
Multiple invertibity principle.Firm bonding is realized in the case of minimum of interference, and it is embedding to be very suitable for inlaying a variety of gem and jades in historical relic
Part is bonding with different substrate materials.
Specific implementation mode
In order to make those skilled in the art be better understood from the present invention, the present invention is made with reference to implementation further
Detailed description.
The historical relic repairing binder of the present invention, including：Rosin 40-50%, beeswax 30-40%, boiled wood oil 5-10%, peach gum
5-10%.
The preparation method of the historical relic repairing binder of the present invention is as follows：
Prepare the stove fire of tanning adhesive, the stainless-steel pan at thick bottom first.Then, rosin is crushed, grinds, then by bee
Wax is cut into small pieces with spare.
Stove fire is adjusted to just prosperous, pot is positioned on fire, is now poured into beeswax in pot, does not stop to stir using glass stirring rod
It mixes, waits for that beeswax is melted into liquid and colophony powder is sprinkled into pot again completely, meanwhile, it is stirred continuously.It is noted that not during tanning
It stirs disconnectedly.
Tung oil is added after rosin dissolves completely and peach gum is added, is constantly stirred.When starting to calculate tanning at this time
Between, tanning can remove glue pot at 20 minutes from fire, and is divided in flat small crucible under liquid condition, so as to
Use is heated when use again.Simultaneously note that the glue sample outer wall in packing sticks tanning time, tanning temperature mark label, so as to
Relevant information is understood in use.The adhesive dispensed is placed and is cooled down on one side, the adhesive after cooling is
Solid-state needs to be again heated to complete liquid when reusing.
Preferably, the tung oil is prior boiled boiled wood oil, and specific boiling method is as follows, and iron pan is placed in stove
On, tung oil is removed into moisture removal using the method for open firing, is judged by having seen whether foam, when not having foam in oil
Moisture is to remove.Particulate manganese dioxide is added after moisture removal, continues tanning to no foam and adds Pb3O4, continue
Tanning, is sufficiently stirred.The method whether test oil is boiled into is to instill a little oil in cold water, if it is to be boiled into enter water not dissipating.It endures
Remove fiery cooling immediately after, the temperature of tanning is 170~300 DEG C.Time is about a hour.
Manganese dioxide has the function of promoting oxygen uptake during tung oil boils, and has and peroxide decomposition is promoted to put
The effect of oxygen, plays the role of drier；Pb3O4Have the function of being catalyzed tung oil polymerization, oxide is promoted to generate, is to promote paulownia
Fry dried food ingredients gives birth to the drier activator of polymerisation.
With reference to specific embodiment illustratively the solution of the present invention：
The solution of the present invention rejects the adhesive formulation of ratio difference, has screened three groups on the basis of many experiments
Valid data are illustrated in connection with specific embodiments.Bonding base material is the griotte of surface roughness about 600# and common hard
Matter timber.Sample block is rectangular, the thick 1CM of length of side 4CM.
Embodiment 1：Rosin 50%, beeswax 35%, tung oil 5%, peach gum 10%.
Preparation method is as follows
By 175 gram particle shape beeswaxs, pours into iron pan, be placed on stove fire, it is lasting to be slowly heated.It waits for that beeswax dissolves completely, spreads
Enter 250 grams of colophony powder, be stirred continuously using glass bar to dissolving completely, then, is added 25 grams and passes through the tung oil of tanning, 50 grams of peaches
Glue particle.Constantly, it is sufficiently stirred.Tanning temperature gradually rises to about 300 DEG C, and glue colo is gradually deepened, lasting tanning
It 20 minutes, is constantly stirred.Then, glue pot is removed from fire, is poured into measuring cup by 100 milliliters respectively, start to calculate cold
The solidifying time.About 120 minutes, colloid thoroughly solidified.
Embodiment 2：Rosin 50%, beeswax 39%, tung oil 5%, peach gum 6%.
Preparation method is as follows
By 195 gram particle shape beeswaxs, pours into iron pan, be placed on stove fire, it is lasting to be slowly heated.It waits for that beeswax dissolves completely, spreads
Enter 250 grams of colophony powder, be stirred continuously using glass bar to dissolving completely, then, is added 25 grams and passes through the tung oil of tanning, 30 grams of peaches
Glue particle.Constantly, it is sufficiently stirred.Tanning temperature gradually rises to about 300 DEG C, and glue colo is gradually deepened, lasting tanning
20 minutes, finally there is micro- wire drawing shape.Then, glue pot is removed from fire, is poured into measuring cup by 100 milliliters respectively, start to count
Calculate condensation time.About 150 minutes, colloid thoroughly solidified.
Embodiment 3：Rosin 45%, beeswax 40%, tung oil 10%, peach gum 5%.
Preparation method is as follows
By 200 gram particle shape beeswaxs, pours into iron pan, be placed on stove fire, it is lasting to be slowly heated.It waits for that beeswax dissolves completely, spreads
Enter 225 grams of colophony powder, be stirred continuously using glass bar to dissolving completely, then, is added 50 grams and passes through the tung oil of tanning, 25 grams of peaches
Glue particle.Constantly, it is sufficiently stirred.Tanning temperature gradually rises to about 300 DEG C, and glue colo is gradually deepened, lasting tanning
20 minutes, finally there is micro- wire drawing shape.Then, glue pot is removed from fire, is poured into measuring cup by 100 milliliters respectively, start to count
Calculate condensation time.About 200 minutes, colloid thoroughly solidified.
Embodiment 4：Rosin 40%, beeswax 40%, tung oil 10%, peach gum 10%.
Preparation method is as follows
By 200 gram particle shape beeswaxs, pours into iron pan, be placed on stove fire, it is lasting to be slowly heated.It waits for that beeswax dissolves completely, spreads
Enter 200 grams of colophony powder, be stirred continuously using glass bar to dissolving completely, then, 100 grams of tung oil by tanning is added.Constantly
Ground is sufficiently stirred.Tanning temperature gradually rises to about 300 DEG C, and glue colo is gradually deepened, lasting tanning 20 minutes, finally
There is micro- wire drawing shape.Then, glue pot is removed from fire, is poured into measuring cup by 100 milliliters respectively, start to calculate condensation time.
About 300 minutes, colloid thoroughly solidified.
Comparative example 1：Rosin 50%, beeswax 40%, tung oil 10%
Preparation method is as follows
By 200 gram particle shape beeswaxs, pours into iron pan, be placed on stove fire, it is lasting to be slowly heated.It waits for that beeswax dissolves completely, spreads
Enter 250 grams of colophony powder, is stirred continuously using glass bar to dissolving completely, 50 grams of boiled tung oil are added.Constantly, fully
Stirring.Tanning temperature gradually rises to about 300 DEG C, and glue colo is gradually deepened, lasting tanning 20 minutes.Then, by glue pot
It removes from fire, is poured into measuring cup by 100 milliliters respectively, start to calculate condensation time.About 100 minutes, colloid thoroughly solidified.
Through overtesting, the performance indicator of the binder of embodiments above is as follows：
The adhesive for showing rosin and beeswax the mixing tanning as primary raw material by above-mentioned experiment, is added being added
After agent, there is different degrees of improvement on adhesive property.It is added after additive tung oil, adhesion strength and ageing-resistant intensity are equal
There is promotion.Compare in mobility and curing rate：The glue sample mobility that tung oil is added is more preferable, lower in room temperature,
The promotion of mobile performance is bonding uniformly and effectively ensures.Condensation time is significantly improved.But additive cross it is at most greasy
Sense is strong, and cohesive force weakens, and consolidation is excessively slow.
Meanwhile a variety of substrate bonding experiments are carried out to the adhesive samples C-3 (embodiment 2) that tung oil, peach gum is added, show
The adhesive is preferable to the feasibility of the historical relic bonding of different substrate materials.With extensive adaptability.
| Sample number into spectrum | Sample substrates | Sample adhesives | Adhesive strength | Remarks |
| C-3 | Timber | Stone material | 2.75MPa | Five groups of sample means |
| C-3 | Stone material | Stone material | 2.81MPa | Five groups of sample means |
| C-3 | Metal | Stone material | 2.18MPa | Five groups of sample means |
| C-3 | Ceramics | Stone material | 2.11MPa | Five groups of sample means |
Note：In this reports, C-3 encodes for adhesive laboratory.After screening, directly quote herein.
The hot melt adhesive shows to boil temperature between 170~300 DEG C by the experiment of the time and temperature of heating tanning,
The suitable adhesive of adhesion strength can be obtained, is advisable with 280 DEG C or so.Tanning temperature is excessively high, and overlong time then makes gluing
Agent accelerated ageing reduces adhesion strength, and crystallization situation occurs.It should be noted that in practical applications, the adhesive is again
The aging action of heating temperature and tanning too long.It should give and give up in due course, use new product.
Illustrate the bond operation method of binder of the present invention below：
1) adhesive is placed in the heating plate of adjustable temperature by heating and melting binder, and temperature is adjusted to tanning temperature
It about 220 DEG C, is used when dissolve fully is liquid；
2) bonding plane is thoroughly cleaned, bonding plane is thoroughly cleaned using alcohol, it, can be with if convered structure is inanimate matter stone material
To cohesive body appropriate heating.
3) it is uniformly smeared on bonding plane both sides, adhesive is easier to condense at this time, and heat gun is needed to assist caking agent,
Ensure that colloid is liquid when bonding.
4) when being bonded, the operating time is more urgent, and bonding plane will be squeezed moderately when contacting, it is ensured that bonding agent comes into full contact with.
Extruding can make extra adhesive overspill, be purged after to be solidified, can be rejected using bamboo knife, can also use wine
Seminal plasma is clean.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.In addition, although having used some specific terms, these terms to be only in this specification
For convenience of explanation, it does not limit the present invention in any way.
Claims (7)
1. a kind of historical relic repairing binder, it is characterised in that：Including rosin 40-50%, beeswax 30-40%, tung oil 5-10%, peach
Glue 5-10%.
2. binder according to claim 1, it is characterised in that：Each component content is respectively rosin 50%, beeswax
39%, tung oil 5%, peach gum 6%.
3. a kind of preparation method of historical relic repairing binder described in claim 1, it is characterised in that：
1) beeswax is poured into hot pot, melting temperature is 120~180 DEG C, is kept stirring using glass stirring rod；
2) wait for that beeswax is melted into liquid and colophony powder is sprinkled into pot again completely, meanwhile, it is stirred continuously；
3) tung oil is added after rosin dissolves completely and peach gum particle is added, is constantly stirred；Start to calculate tanning at this time
Time；
4) tanning temperature until 20 minutes whens can remove glue pot from fire, and is dispensed at 280 DEG C or so under liquid condition
It heats and uses again in flat small crucible, when to use.
4. preparation method according to claim 3, it is characterised in that：The preparation method of the tung oil is as follows
Tung oil is removed moisture removal by a using the method for open firing, is judged by having seen whether foam, when not having foam in oil
Shi Shuifen is to remove；
Particulate manganese dioxide is added after b moisture removals, continues tanning to no foam；
Suitable Pb is added in c3O4, continue to boil, be sufficiently stirred.
5. preparation method according to claim 4, it is characterised in that：The temperature of tanning is 170~300 DEG C, and the time is about
One hour.
6. preparation method according to claim 4, it is characterised in that：Further include whether test tung oil is endured after step c
At the step of, specially by a little oil instill cold water in, if enter water dissipate be boiled into, otherwise continue tanning stirring.
7. a kind of application method of historical relic repairing binder described in claim 1, it is characterised in that：Include the following steps：
1) adhesive is placed in the heating plate of adjustable temperature by heating and melting binder, and temperature is adjusted to tanning temperature about 200
DEG C, it is used when dissolve fully is liquid；
2) bonding plane is thoroughly cleaned, bonding plane is thoroughly cleaned using alcohol, the unsuitable cold, humidity of bonding operating environment should not mistake
Height ensures bonding plane drying when bonding, can be to adhesive surface appropriate heating, operation temperature if convered structure is inanimate matter stone material
Less than 100 DEG C.
3) it is uniformly smeared on bonding plane both sides, adhesive is easier to condense at this time, and heat gun is needed to assist caking agent, it is ensured that
Colloid is liquid when bonding.
4) when being bonded, the operating time is more urgent, and bonding plane will be squeezed moderately when contacting, it is ensured that bonding agent comes into full contact with.It squeezes
It can make extra adhesive overspill, be purged, can be rejected using bamboo knife after to be solidified, ethyl alcohol can also be used clear
It is clean.
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| CN201810307087.5A CN108384512B (en) | 2018-04-08 | 2018-04-08 | Cultural relic repair binder and preparation method and use method thereof |
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| CN108384512B CN108384512B (en) | 2020-03-20 |
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Cited By (2)
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| CN109468103A (en) * | 2018-11-13 | 2019-03-15 | 柏秀颖 | A kind of bonding restorative procedure of porcelain historical relic |
| CN110452663A (en) * | 2019-09-11 | 2019-11-15 | 久智光电子材料科技有限公司 | Quartz ware binder and preparation method thereof, the application in quartz ware processing |
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| CN102477281A (en) * | 2010-11-22 | 2012-05-30 | 上海恒耐陶瓷技术有限公司 | Novel high-strength impact-resistant bonding agent |
| CN105713555A (en) * | 2016-03-01 | 2016-06-29 | 吴持跃 | Binding agent used for porcelain cultural relic repair and preparation method thereof |
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| CN102477281A (en) * | 2010-11-22 | 2012-05-30 | 上海恒耐陶瓷技术有限公司 | Novel high-strength impact-resistant bonding agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109468103A (en) * | 2018-11-13 | 2019-03-15 | 柏秀颖 | A kind of bonding restorative procedure of porcelain historical relic |
| CN110452663A (en) * | 2019-09-11 | 2019-11-15 | 久智光电子材料科技有限公司 | Quartz ware binder and preparation method thereof, the application in quartz ware processing |
| CN110452663B (en) * | 2019-09-11 | 2021-01-08 | 久智光电子材料科技有限公司 | Quartz product binder, preparation method thereof and application thereof in quartz product processing |
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| CN108384512B (en) | 2020-03-20 |
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