CN108374103B - Cu-Fe-C-Ag alloy - Google Patents
Cu-Fe-C-Ag alloy Download PDFInfo
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- CN108374103B CN108374103B CN201810259079.8A CN201810259079A CN108374103B CN 108374103 B CN108374103 B CN 108374103B CN 201810259079 A CN201810259079 A CN 201810259079A CN 108374103 B CN108374103 B CN 108374103B
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- 229910001316 Ag alloy Inorganic materials 0.000 title claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 84
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 55
- 239000000956 alloy Substances 0.000 claims abstract description 55
- 238000005245 sintering Methods 0.000 claims abstract description 51
- 239000002994 raw material Substances 0.000 claims abstract description 49
- 229910017112 Fe—C Inorganic materials 0.000 claims abstract description 45
- 229910017770 Cu—Ag Inorganic materials 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 238000000498 ball milling Methods 0.000 claims abstract description 9
- 239000011812 mixed powder Substances 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims description 13
- 238000009826 distribution Methods 0.000 claims description 8
- 229910017827 Cu—Fe Inorganic materials 0.000 abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 26
- 239000010949 copper Substances 0.000 description 23
- 229910052799 carbon Inorganic materials 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 7
- 229910000881 Cu alloy Inorganic materials 0.000 description 5
- 229910000846 In alloy Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910000906 Bronze Inorganic materials 0.000 description 3
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 239000010974 bronze Substances 0.000 description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
- 238000012805 post-processing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000713 high-energy ball milling Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0425—Copper-based alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention provides a kind of Cu-Fe-C-Ag alloy, be prepared by the following steps: (1) prepare raw material: the raw material includes Cu-Ag prealloy powder and Fe-C prealloy powder, (2) ball milling mixing: abrading-ball is added and carries out mixed powder, obtain composite powder, (3) hot pressed sintering: composite powder obtained in the step (2) is put into hot-pressed sintering furnace and is sintered, sintering temperature is 800~1000 DEG C, sintering pressure is 45~55MPa, sintering time is 30min~45min, obtains Cu-Fe-C-Ag alloy.The conductivity and tensile strength of Cu-Fe alloy can be improved in the present invention.
Description
Technical field
The present invention relates to composite materials to lead field, in particular to a kind of Cu-Fe-C-Ag alloy.
Background technique
Compared with the copper alloy with high strength and high conductivity of other systems, the fusing point of alloying element Fe is relatively low in Cu-Fe system, is easier to
Melting, and non-miscible gap of Fe and Cu is small, the deformability of alloy is preferable, and machinability is preferable, so closing about Cu-Fe system
The research of gold receives attention, becomes one of the important directions of copper alloy with high strength and high conductivity development.
Currently, high-strength highly-conductive Cu-Fe system alloy mainly utilizes fusion casting to prepare just alloy, then first alloy is carried out subsequent
The processing such as heat treatment, deformation, obtain the Cu-Fe system alloy of final use state.When founding prepares just alloy, due to solidification
Cooling velocity is very fast, it is easy to cause to be dissolved a large amount of Fe element in Cu matrix, the serious electric conductivity for reducing Cu-Fe alloy.Though
So oversaturated Fe is constantly precipitated during subsequent heat treatment, thermomechanical treatment etc., but under low temperature Fe diffusion velocity it is very slow,
It is difficult the Fe that will be dissolved in Cu to be precipitated completely, and solid solution of the Fe in Cu is to reduce the main influence factor of Cu-Fe alloy.Institute
With the electric conductivity in order to improve Cu-Fe alloy, need to reduce solid solution capacity of the Fe in Cu.
In the prior art frequently with the methods of deformation, heat treatment, high-intensity magnetic field, multi-element alloyed, but cannot all solve well
Certainly this problem.Such as: Ag is considered as that damage Cu alloy conductive acts on the smallest element, but utilizes Ag to Cu-Fe alloy
The Cu-Fe-Ag alloy of alloying preparation is carried out, but is still dissolved 2.5% or more Fe in its as cast condition Cu matrix；And Ag also drops
The low stability of Fe phase fiber, causes Fe phase to be roughened at 350 DEG C or more, and reduction limits the use temperature range of alloy；And
And use Ag alloying higher cost.The Fe being dissolved in Cu can not be equally reduced to very low state by other methods.
In order to more effectively reduce the Fe being dissolved in Cu, it is necessary to provide a kind of Cu-Fe-C-Ag alloy.
Summary of the invention
The purpose of the present invention is to provide a kind of Cu-Fe-C-Ag alloys, can efficiently reduce the Fe being dissolved in Cu-, mention
The high electric conductivity of Cu-Fe alloy, also improves the stability of Fe phase fiber, Fe phase will not be caused to be roughened at 350 DEG C or more,
The use temperature range of alloy is improved, and reduces the preparation cost of alloy.
To achieve the goals above, the invention provides the following technical scheme:
A kind of Cu-Fe-C-Ag alloy, Cu-Fe-C-Ag alloy are prepared by the following steps:
(1) prepare raw material: raw material includes Cu-Ag prealloy powder and Fe-C prealloy powder,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 800~1000 DEG C of (such as 820 DEG C, 830 DEG C, 840 DEG C, 850 DEG C, 860 DEG C, 870 DEG C, 880 DEG C, 890 DEG C, 900 DEG C, 910
DEG C, 920 DEG C, 930 DEG C, 940 DEG C, 950 DEG C, 960 DEG C, 970 DEG C, 980 DEG C, 990 DEG C), sintering pressure be 45~55MPa (such as
46MPa, 47MPa, 48MPa, 49MPa, 50MPa, 51MPa, 52MPa, 53MPa, 54MPa), sintering time is 30min~45min
(such as 31min, 32min, 33min, 34min, 35min, 36min, 37min, 38min, 39min, 40min, 41min, 42min,
43min, 44min),
Obtain the Cu-Fe-C-Ag alloy of Fe-C even particle distribution.
It is a kind of novel high-strength highly-conductive Cu alloy by Cu-Fe-C-Ag alloy prepared by above-mentioned steps, C and Cu is utilized
Mutually exclusive effect in Fe-Cu-C ternary system, therefore C is added, and into Cu in order to give full play to this work of C
With using Cu-Ag prealloy powder, Fe-C prealloy powder hot pressed sintering preparation Cu-Fe-C-Ag alloy.Cu-Fe-C-Ag obtained
It is 54%~66%IACS that the tensile strength of alloy, which is greater than 570MPa, conductivity,.
In alloy of the invention, the partial size of Cu-Ag prealloy powder is 10~50 μm as a preferred implementation manner,.
When the partial size of Cu-Ag prealloy powder is 10~50 μm, Fe-C particle can be more evenly distributed in Cu-Ag matrix.Fe-C is closed in advance
The size of bronze is 50~120nm (such as 60nm, 70nm, 80nm, 90nm, 100nm, 50nm~80nm, 50nm~70nm, 60
~80nm, 60nm~110nm, 70~80nm, 80~100nm, 100~120nm).The Fe-C alloyed powder is commercial product, when
It so can also conventionally prepare, can be prepared by vacuum atomizing furnace, by the raw material iron and carburant of required proportion
It is atomized into powder particle after melting, is then prepared into the Fe-C alloyed powder of required granularity by high-energy ball milling again.Make in the present invention
Fe-C alloyed powder particle size is 50~120nm, Fe-C alloy powder particles it is oversized, will lead to disperse and then causes
Precipitation strength effect reduction；Fe-C alloy powder particles it is undersized, be easy to be dissolved in Fe in Cu, electric conductivity be deteriorated, but also
It is easy to happen reunion.
Further, the size of Fe-C prealloy powder is 60~80nm.In the reasonable scope, the size of Fe-C prealloy powder
Smaller, dispersion-strengthened action is bigger, but its surface can be bigger simultaneously, easier to dissolve into Cu matrix.
In alloy of the invention, raw material includes that Cu-Ag prealloy powder and Fe-C are closed in advance as a preferred implementation manner,
Bronze, the Cu-Ag prealloy powder account for the 85-90wt% (such as 86%, 87%, 88%, 89%) of the raw material, the Fe-C
Prealloy powder account for the raw material 10-15wt% such as 11%, 12%, 13%, 14%).
In alloy of the invention, the C in the Fe-C prealloy powder accounts for the pre- conjunction as a preferred implementation manner,
Bronze 0.8-1.8wt% (such as: 0.9wt%, 1.0wt%, 1.1wt%, 1.2wt%, 1.3wt%, 1.4wt%,
1.5wt%, 1.6wt%, 1.7wt%).
In alloy of the invention, the Ag content in the Cu-Ag prealloy powder is as a preferred implementation manner,
0.5~3wt% (such as: 0.5wt%, 0.6wt%, 0.7wt%, 0.8wt%, 0.8~1.2wt%, 0.9wt%, 1.0wt%,
1.0~1.2wt%, 1.1wt%, 1.2wt%, 1.3wt%, 1.4wt%, 1.5wt%, 1.6wt%, 1.7wt%, 1.8wt%,
1.9wt%, 2.0wt%, 2.1wt%, 2.2wt%, 2.3wt%, 2.4wt%, 2.5wt%, 2.7wt%, 2.9wt%).Ag contains
Amount is up to 3wt%, effectively reduces the cost of raw material.
In alloy of the invention, C content is too low have been will lead to more Fe and has dissolved in Cu-Ag matrix, is led to alloy
Electrically unfavorable, C content is excessively high to will form graphite or Fe3C etc..
It as a preferred implementation manner, further include alloy post-processing step in the step of preparing alloy of the present invention, it will
The Cu-Fe-C-Ag system alloy that (3) the hot pressed sintering step obtains is post-processed, and Cu-Fe-C-Ag system alloy finished product is obtained.
It is highly preferred that the post-processing is one of heat treatment, deformation process, magnetic field processing or a variety of；The post-processing is conventional
Processing.
Analysis is it is found that a kind of Cu-Fe-C-Ag alloy disclosed by the invention, mainly realizes following technical effect: utilizing C
With mutually exclusive effect of the Cu in Fe-Cu-C ternary system, and Ag ratio Fe is utilized first to be dissolved in Cu, the suppression to Fe solid solution
Production is used, therefore C and Ag is added into Cu.And in order to give full play to this effect of C and Ag, using Cu-Ag prealloy powder,
Fe-C prealloy powder hot pressed sintering prepares Cu-Fe-C-Ag alloy, has developed novel high-strength highly-conductive Cu alloy.
Ag ratio Fe is utilized first to be dissolved in Cu, to the inhibiting effect of Fe solid solution, controls diffusion of the Fe into Cu matrix, greatly
Width reduces the solid solution capacity of Fe in Cu-Ag matrix.The conductivity and tensile strength of Cu-Fe alloy can be improved in the method for the present invention, obtains
The tensile strength of the alloy arrived is greater than 570MPa, conductivity 54-66%IACS.
Specific embodiment
Below in conjunction with embodiment, the present invention will be described in detail.The mode of the explanation of each example through the invention provide and
The unrestricted present invention.In fact, those skilled in the art will be clear that, the case where not departing from the scope or spirit of the invention
Under, it can modify in the present invention and modification.For example, being illustrated or described as the feature of a part of one embodiment can be used for
Another embodiment, to generate another embodiment.Thus, it may be desirable to the present invention include be included into appended claims and
Such modifications and variations in the range of its equivalent.
Embodiment 1
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 70~120nm
1.2wt%C prealloy powder, the mass percent of C is 1.2wt% in Fe-C alloy powder, and Cu accounts for the 88.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 11wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 900 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-11wt% (Fe-C) -0.5wt%Ag alloy of Fe-1.2wt%C even particle distribution must have been prepared.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 603MPa, and conductivity is
62.8%IACS.
Embodiment 2
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 70~120nm
1.0wt%C prealloy powder, the mass percent of C is 1.0wt% in Fe-C alloy powder, and Cu accounts for the 84.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 15wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 800 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-15wt% (Fe-C) -0.5wt%Ag alloy of Fe-1.0wt%C even particle distribution must have been prepared.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 678MPa, and conductivity is
57.6%IACS.
Embodiment 3
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 50~80nm
1.1wt%C prealloy powder, the mass percent of C is 1.1wt% in Fe-C alloy powder, and Cu accounts for the 86.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 13wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 820 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-13wt% (Fe-C) -0.5wt%Ag alloy of Fe-1.1wt%C even particle distribution must have been prepared.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 664MPa, and conductivity is
58.6%IACS.
Embodiment 4
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 50~80nm
1.1wt%C prealloy powder, the mass percent of C is 1.1wt% in Fe-C alloy powder, and Cu accounts for the 89.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 10wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 820 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-10wt% (Fe-C) -0.5wt%Ag alloy of Fe-1.1wt%C even particle distribution must have been prepared.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 605MPa, and conductivity is
60.5%IACS.
Embodiment 5
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 50~80nm
1.1wt%C prealloy powder, the mass percent of C is 1.1wt% in Fe-C alloy powder, and Cu accounts for the 88.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 11wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 820 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-11wt% (Fe-C) -0.5wt%Ag alloy that Fe-1.1wt%C even particle distribution must have been prepared, that is, exist
The content of Fe-C is 11wt% in alloy.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 618MPa, conductivity 64%
IACS。
Embodiment 6
(1) prepare raw material: raw material includes 10~50 μm of Cu-Ag prealloy powder and the Fe- having a size of 60~80nm
1.1wt%C prealloy powder, the mass percent of C is 1.1wt% in Fe-C alloy powder, and Cu accounts for the 87.5wt% of the raw material,
Ag accounts for the 0.5wt% of the raw material, and Fe-C prealloy powder accounts for the 12wt% of the raw material,
(2) ball milling mixing: being added abrading-ball and carry out powder mixing machine, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 820 DEG C, sintering pressure 50MPa, sintering time 30min,
Cu-12wt% (Fe-C) -0.5wt%Ag alloy of Fe-1.1wt%C even particle distribution must have been prepared.
The alloy of embodiment preparation is tested for the property, the tensile strength of alloy is 642MPa, conductivity 58%
IACS。
Embodiment 7-11 and comparative example 1-2
Embodiment 7-11 and comparative example 1-3 in addition to raw material proportioning and raw material granularity are different from embodiment 1, other techniques with
Embodiment 1 is identical.The raw material dosage relationship of embodiment 7-11 and comparative example 1-3 and raw material granularity referring to table 1, corresponding embodiment and
The performance test results of the alloy of comparative example preparation are referring to table 1.As can be seen from Table 1, the performance of embodiment 7,8,9,10,11
(tensile strength and conductivity) is significantly better than comparative example 1,2 and 3.
The raw material dosage relationship and raw material granularity and corresponding product performance table of table 1 embodiment 7-11 and comparative example 1-3
Embodiment 12-16
For embodiment 12-16 in addition to hot pressed sintering is different from embodiment 1, other techniques are same as Example 1.Embodiment
The performance test results for the alloy product that the hot pressed sintering of 12-16 is obtained referring to table 2, corresponding embodiment and comparative example are referring to table 2.
As can be seen from Table 2, the performance (tensile strength and conductivity) of embodiment 12,13,14 is significantly better than embodiment 15,16.
The hot pressed sintering condition and properties of product table of 2 embodiment 12-16 of table
Embodiment 17-18 and comparative example 4
Embodiment 17-18 and comparative example 4 are other than the content of Ag simple substance in alloy is different from embodiment 1, other techniques
Parameter is the same as embodiment 1.The content of Ag simple substance and the performance of obtained alloy ginseng in embodiment 17-18 and the alloy of comparative example 4
It is shown in Table 3.As can be seen from Table 3, as the ratio of Ag increases in comparative example 4, tensile strength and conductivity all obviously do not improve.
The technological parameter and results of property of table 3 embodiment 17-18 and comparative example 4
Claims (7)
1. a kind of Cu-Fe-C-Ag alloy, which is characterized in that the Cu-Fe-C-Ag alloy is prepared by the following steps:
(1) prepare raw material: the raw material includes Cu-Ag prealloy powder and Fe-C prealloy powder,
(2) ball milling mixing: being added abrading-ball and carry out mixed powder, obtain composite powder,
(3) hot pressed sintering: composite powder obtained in the step (2) being put into hot-pressed sintering furnace and is sintered, sintering temperature
Degree is 800~1000 DEG C, and sintering pressure is 45~55MPa, and sintering time is 30min~45min,
Obtain the Cu-Fe-C-Ag alloy of Fe-C even particle distribution；
The Cu-Ag prealloy powder accounts for the 85-90wt% of the raw material, and the Fe-C prealloy powder accounts for the 10- of the raw material
15wt%；
C content in the Fe-C prealloy powder is 0.9-1.8wt%；
Ag content in the Cu-Ag prealloy powder is 0.5~3wt%.
2. alloy according to claim 1, which is characterized in that the partial size of the Cu-Ag prealloy powder is 10~50 μm.
3. alloy according to claim 1, which is characterized in that the size of the Fe-C prealloy powder is 50~120nm.
4. alloy according to claim 1, which is characterized in that the size of the Fe-C prealloy powder is 60~110nm.
5. alloy according to claim 1, which is characterized in that the size of the Fe-C prealloy powder is 50~80nm.
6. alloy according to claim 1, which is characterized in that C content in the Fe-C prealloy powder is 0.9~
1.2wt%.
7. alloy according to claim 1, which is characterized in that C content in the Fe-C prealloy powder is 1.0~
1.2wt%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810259079.8A CN108374103B (en) | 2018-03-27 | 2018-03-27 | Cu-Fe-C-Ag alloy |
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| CN201810259079.8A CN108374103B (en) | 2018-03-27 | 2018-03-27 | Cu-Fe-C-Ag alloy |
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| CN108374103A CN108374103A (en) | 2018-08-07 |
| CN108374103B true CN108374103B (en) | 2019-10-29 |
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| CN107267802A (en) * | 2016-03-31 | 2017-10-20 | Ｊｘ金属株式会社 | The manufacture method of copper alloy plate and copper alloy plate |
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2018
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| US3401024A (en) * | 1965-10-04 | 1968-09-10 | Mallory & Co Inc P R | Electrical contact material |
| CN1687479A (en) * | 2005-06-09 | 2005-10-26 | 上海交通大学 | Method for preparing composite Cu-Fe-Ag nano material at original position with high intensity and high conductance |
| CN104263985A (en) * | 2014-09-24 | 2015-01-07 | 西安理工大学 | Preparation method of self-hard reinforced Cu-FeC composite material |
| CN107267802A (en) * | 2016-03-31 | 2017-10-20 | Ｊｘ金属株式会社 | The manufacture method of copper alloy plate and copper alloy plate |
| CN105839038A (en) * | 2016-04-08 | 2016-08-10 | 东北大学 | Preparation method for high-strength high-conductivity Cu-Ag-Fe alloy |
Non-Patent Citations (1)
| Title |
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| Effect of Ag addition on the as-cast microstructure of Cu–8 wt.% Fe in situ composites;Zhixiong Xie,et al.;《Journal of Alloys and Compounds》;20100826;第508卷;第322页左栏第1段，第323页左栏第2段 * |
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