CN108342122A - One kind having strong three-dimensional sense and flexible UV embossed printing inks and preparation method thereof - Google Patents
One kind having strong three-dimensional sense and flexible UV embossed printing inks and preparation method thereof Download PDFInfo
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- CN108342122A CN108342122A CN201710058251.9A CN201710058251A CN108342122A CN 108342122 A CN108342122 A CN 108342122A CN 201710058251 A CN201710058251 A CN 201710058251A CN 108342122 A CN108342122 A CN 108342122A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to one kind having strong three-dimensional sense and flexible UV embossed printing inks and preparation method thereof, and the UV embossed printing inks include following components and parts by weight content：13 parts of 35 65 parts of prepolymer, 12 35 parts of monomer, 48 parts of photoinitiator, 10 25 parts of filler and auxiliary agent；When preparation, first photoinitiator is mixed by weight with monomer, by constant temperature water bath heating stirring, photoinitiator is made to be substantially dissolved in monomer；Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed, stood, obtain the UV embossed printing inks.Compared with prior art, UV embossed printing inks curing rate of the present invention is fast, and printing adaptability is excellent, it is not blistering, there is excellent flexibility after film-forming, reduce layer of ink splintering problem caused by later process, it is environmentally protective, performance is stablized, layer of ink texture uniformity is good, and solid is convex to feel strong, good brightness, simple production process, production cost is low, can be used for large-scale industrial production.
Description
Technical field
The invention belongs to safety and environmental protection pigment and technical field of dye, are related to a kind of with strong three-dimensional sense and flexible UV
Embossed printing ink and preparation method thereof.
Background technology
With the development of packaging industry, while people's living standard is continuously improved, both at home and abroad to packaging quality, appearance
It is required that higher and higher and new technique emerges one after another, manufacturing enterprise more and more payes attention to the convex sense effect in post-press finishing.Packet
The surface of dress handicraft product, Local Convex sense effect have become conventional process, and traditional process means are mainly heat pressing process.From
It is to use high temperature hot pressure that the present situation and development trend of convex sense effect, which can be seen that heat pressing process, easily occurs the stocks such as paper
Deformation, and it is easy to make the ink of paper surface to scald, the whole ink high temperature resistance of printed matter is required high.UV type oil
Ink can print various paper, the mute glue of PVC, PET, PP, OPP using external high-performance quality raw materials through continuous technological innovation for many years
The various plastic basis materials such as light film make high-grade label or printed matter, keep printed matter surface more aobvious magnificent.
UV embossed printing inks are a kind of decorative inks, by being printed in gold, silver paperboard and certain high brightness stocks
After brush, cure through UV and generate pseud metal-etching (convex sense) effect, convex sense effect is the contrast pair by picture and text and non-graphic part
Than realizing, such as on the stock for having metallic mirror surface gloss gravure UV embossed printing inks, after UV-light cured film forming so that
No matter printing position, which is appreciated having in terms of vision and feel, erects the effect of coming.UV embossed printing inks are mainly used in top grade, essence
The packages printings such as U.S. unique cigarette, wine, cosmetics, health products, greeting card, food, drug.UV embossed printing inks are relative to traditional molten
For based ink, has the advantages that distinctness：1) UV curing rates are fast, and ink is free of organic solvent, belongs to environment-friendlyink ink；2)
Case hardness is good, adhesive force is good, flexibility is excellent；3) transparent good, clean mark；4) three-dimensional sense is strong, there is prominent feel；5) resistance toization
The property learned sorrow, is resistant to most organic solvent, water and soda acid.
In addition, printing has strong three-dimensional sense, it is not only beautiful, graceful but also generous, thus promote and be exceedingly fast, it is short several
Year, just sizable market is occupied in the high-grade packages printing such as Yan Bao, Jiu Bao, cosmetics field.UV embossed printing inks it is flexible
Property difference be wherein more one of distinct issues, be embodied in printed matter fold and the rear techniques such as cutting in easily rupture, type
Ink itself toughness is not good enough to be the main reason for causing this problem, and passes through and select the better light-cured resin of toughness and activity list
Body can improve the flexibility of UV embossed printing inks.
Invention content
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide a kind of safety and environmental protection, performances
Stablize, economic and practical it is good have strong three-dimensional sense and flexible UV embossed printing inks.
Another object of the present invention is just to provide the preparation with strong three-dimensional sense and flexible UV embossed printing inks
Method.
The purpose of the present invention can be achieved through the following technical solutions：
One kind having strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：Prepolymer
35-65 parts, 12-35 parts of monomer, 4-8 parts of photoinitiator, 1-3 parts of 10-25 parts of filler and auxiliary agent.
There is strong three-dimensional sense and flexible UV embossed printing inks described in as a preferred technical solution, including with the following group
Point and parts by weight content：45-60 parts of prepolymer, 20-30 parts of monomer, 5-7 parts of photoinitiator, 12-20 parts of filler and auxiliary agent 1-2
Part.
The prepolymer is selected from the one or two of epoxy acrylate or aliphatic urethane acrylate.
The prepolymer is pressed by epoxy acrylate and aliphatic urethane acrylate as a preferred technical solution,
Mass ratio is 4-8:1-3 is mixed.
The monomer is selected from the one or two of trimethylolpropane trimethacrylate or glycol diacrylate.
The monomer is by trimethylolpropane trimethacrylate and ethylene glycol diacrylate as a preferred technical solution,
Ester is 1-2 in mass ratio:1 mixes.
The photoinitiator is selected from Alpha-hydroxy phenylcyclohexyl ketone.
The filler is polypropylene.
The auxiliary agent is selected from commercially available BYK-371 levelling agents.
A kind of preparation method with strong three-dimensional sense and flexible UV embossed printing inks, this method specifically include following step
Suddenly：
Step (1)：It stocks up by following components and parts by weight content：
1-3 parts of 35-65 parts of prepolymer, 12-35 parts of monomer, 4-8 parts of photoinitiator, 10-25 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
In the prepolymer selected in the present invention, epoxy acrylate has excellent flexibility, and fixed line speed is fast, low viscous
The advantage of degree, low cost, plays a decisive role to the flexibility after polymer film forming；Aliphatic urethane acrylate molecular structure
In there is ammonia ester bond, long chain diol unit provides good flexibility in molecule, forms soft segment microphase-separated area, and polyurethane sheet
Ammonia ester bond then provides hard section microfacies area in body, this soft-hard microphase-separated impart the excellent flexibility of polyurethane film and compared with
Good hardness.By the compounding of above two prepolymer, so that the flexibility of UV embossed printing inks is significantly improved and printing effect is good, matter
Amount is stablized, and the printed matter high to safe and environment-friendly, health requirements, such as food packaging, tobacco and wine packaging are can be applied to.
Compared with prior art, the invention has the characteristics that：
1) curing rate is fast, and printing adaptability is excellent, not blistering, has excellent flexibility, road after reduction after film-forming
Layer of ink splintering problem caused by process；
2) raw material is environmental protection material, and VOC emission is few, therefore does not have the residual of toxic organic compound in printed matter, is protected
The wholesomeness for having demonstrate,proved printed matter ensures the health of operating personnel；
3) performance is stablized, and layer of ink texture uniformity is good, and solid is convex to feel strong, good brightness；
4) simple production process, production cost is low, can be used for large-scale industrial production.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
Formula：Epoxy acrylate：35kg
Aliphatic urethane acrylate：15kg
Trimethylolpropane trimethacrylate：23kg
Alpha-hydroxy phenylcyclohexyl ketone：6kg
Polypropylene：20kg
BYK-371：1kg
Total weight is 100kg
1.1 weigh dispensing：It is weighed respectively in each raw material to different stainless steel barrels by above-mentioned formula, it is spare；
1.2 initiators dissolve：23kg trimethylolpropane trimethacrylates are placed in agitator, under stirring,
6kg Alpha-hydroxy phenylcyclohexyl ketones are added thereto, until initiator is completely dissolved, continuation constant temperature stirs 1 hour heated at constant temperature；
1.3 dispersion：After Alpha-hydroxy phenylcyclohexyl ketone fully dissolves, 35kg epoxy acrylates, 15kg is then added
Aliphatic urethane acrylate, 1kg BYK-371 and 20kg polypropylene, are placed on mechanical high-speed blender, stir 1 hour,
It is stirred, stands a period of time, the UV gravure embossed printing inks i.e. prepared after stable system.
1.4 potting package：It is accurately weighed by packed weight in quantitative UV embossed printing inks to ink tank, covers cover and close
Envelope, it is labelled to obtain UV embossed printing ink finished products.
Embodiment 2
Formula：Epoxy acrylate：40kg
Aliphatic urethane acrylate：15kg
Trimethylolpropane trimethacrylate：20kg
Alpha-hydroxy phenylcyclohexyl ketone：6kg
Polypropylene：18kg
BYK-371：1kg
Total weight is 100kg
2.1 weigh dispensing：It is weighed respectively in each raw material to different stainless steel barrels by above-mentioned formula, it is spare；
2.2 initiators dissolve：20kg trimethylolpropane trimethacrylates are placed in agitator, under stirring,
6kg Alpha-hydroxy phenylcyclohexyl ketones are added thereto, until initiator is completely dissolved, continuation constant temperature stirs 1 hour heated at constant temperature；
2.3 dispersion：After Alpha-hydroxy phenylcyclohexyl ketone fully dissolves, 40kg epoxy acrylates, 15kg is then added
Aliphatic urethane acrylate, 1kgBYK-371 and 18kg polypropylene, are placed on mechanical high-speed blender, stir 1 hour, will
It is stirred, and stands a period of time, the UV gravure embossed printing inks i.e. prepared after stable system.
2.4 potting package：It is accurately weighed by packed weight in quantitative UV embossed printing inks to ink tank, covers cover and close
Envelope, it is labelled to obtain UV embossed printing ink finished products.
Embodiment 3
Formula：Epoxy acrylate：48kg
Aliphatic urethane acrylate：12kg
Trimethylolpropane trimethacrylate：10kg
Glycol diacrylate：10kg
Alpha-hydroxy phenylcyclohexyl ketone：6kg
Polypropylene：13kg
BYK-371：1kg
Total weight is 100kg
3.1 weigh dispensing：It is weighed respectively in each raw material to different stainless steel barrels by above-mentioned formula, it is spare；
3.2 initiators dissolve：10kg trimethylolpropane trimethacrylates and 10kg hexanediyl esters are placed in
In agitator, under stirring, 6kg Alpha-hydroxy phenylcyclohexyl ketones are added thereto, heated at constant temperature is until initiator is complete
Dissolving continues constant temperature and stirs 1 hour；
3.3 dispersion：After Alpha-hydroxy phenylcyclohexyl ketone fully dissolves, 48kg epoxy acrylates, 12kg is then added
Aliphatic urethane acrylate, 1kgBYK-371 and 13kg polypropylene, are placed on mechanical high-speed blender, stir 1 hour, will
It is stirred, and stands a period of time, the UV gravure embossed printing inks i.e. prepared after stable system.
3.4 potting package：It is accurately weighed by packed weight in quantitative UV embossed printing inks to ink tank, covers cover and close
Envelope, it is labelled to obtain UV embossed printing ink finished products.
Embodiment 4
The present embodiment has strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：In advance
1 part of 35 parts of polymers, 12 parts of monomer, 4 parts of photoinitiator, 10 parts of filler and auxiliary agent.
Wherein, prepolymer is aliphatic urethane acrylate；Monomer is trimethylolpropane trimethacrylate；It is light-initiated
Agent is selected from Alpha-hydroxy phenylcyclohexyl ketone；Filler is polypropylene；Auxiliary agent is selected from commercially available BYK-371 levelling agents.
The preparation method of the present embodiment UV embossed printing inks, specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
1 part of 35 parts of prepolymer, 12 parts of monomer, 4 parts of photoinitiator, 10 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
Embodiment 5
The present embodiment has strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：In advance
3 parts of 65 parts of polymers, 35 parts of monomer, 8 parts of photoinitiator, 25 parts of filler and auxiliary agent.
Wherein, prepolymer is 5 in mass ratio by epoxy acrylate and aliphatic urethane acrylate:2 mix；
Monomer is 2 in mass ratio by trimethylolpropane trimethacrylate and glycol diacrylate:1 mixes；Photoinitiator
Selected from Alpha-hydroxy phenylcyclohexyl ketone；Filler is polypropylene；Auxiliary agent is selected from commercially available BYK-371 levelling agents.
The preparation method of the present embodiment UV embossed printing inks, specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
3 parts of 65 parts of prepolymer, 35 parts of monomer, 8 parts of photoinitiator, 25 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
Embodiment 6
The present embodiment has strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：In advance
1 part of 45 parts of polymers, 20 parts of monomer, 5 parts of photoinitiator, 12 parts of filler and auxiliary agent.
Wherein, prepolymer is 4 in mass ratio by epoxy acrylate and aliphatic urethane acrylate:3 mix；
Monomer is glycol diacrylate；Photoinitiator is selected from Alpha-hydroxy phenylcyclohexyl ketone；Filler is polypropylene；Auxiliary agent is selected from city
The BYK-371 levelling agents sold.
The preparation method of the present embodiment UV embossed printing inks, specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
1 part of 45 parts of prepolymer, 20 parts of monomer, 5 parts of photoinitiator, 12 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
Embodiment 7
The present embodiment has strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：In advance
1 part of 56 parts of polymers, 24 parts of monomer, 6 parts of photoinitiator, 17 parts of filler and auxiliary agent.
Wherein, prepolymer is epoxy acrylate；Monomer is glycol diacrylate；Photoinitiator is selected from Alpha-hydroxy ring
Hexyl Benzophenone；Filler is polypropylene；Auxiliary agent is selected from commercially available BYK-371 levelling agents.
The preparation method of the present embodiment UV embossed printing inks, specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
1 part of 56 parts of prepolymer, 24 parts of monomer, 6 parts of photoinitiator, 17 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
Embodiment 8
The present embodiment has strong three-dimensional sense and flexible UV embossed printing inks, including following components and parts by weight content：In advance
2 parts of 60 parts of polymers, 30 parts of monomer, 7 parts of photoinitiator, 20 parts of filler and auxiliary agent.
Wherein, prepolymer is aliphatic urethane acrylate；Monomer is trimethylolpropane trimethacrylate；It is light-initiated
Agent is selected from Alpha-hydroxy phenylcyclohexyl ketone；Filler is polypropylene；Auxiliary agent is selected from commercially available BYK-371 levelling agents.
The preparation method of the present embodiment UV embossed printing inks, specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
2 parts of 60 parts of prepolymer, 30 parts of monomer, 7 parts of photoinitiator, 20 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, is made light-initiated
Agent is substantially dissolved in monomer；
Step (3)：Under stirring, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed,
It stands, obtains the UV embossed printing inks.
The above description of the embodiments is intended to facilitate ordinary skill in the art to understand and use the invention.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without having to go through creative labor.Therefore, the present invention is not limited to the above embodiments, ability
Field technique personnel announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be the present invention's
Within protection domain.
Claims (10)
1. one kind having strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that contain including following components and parts by weight
Amount：1-3 parts of 35-65 parts of prepolymer, 12-35 parts of monomer, 4-8 parts of photoinitiator, 10-25 parts of filler and auxiliary agent.
2. according to claim 1 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that including
Following components and parts by weight content：45-60 parts of prepolymer, 20-30 parts of monomer, 5-7 parts of photoinitiator, 12-20 parts of filler and
1-2 parts of auxiliary agent.
3. according to claim 2 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Prepolymer be selected from the one or two of epoxy acrylate or aliphatic urethane acrylate.
4. according to claim 3 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Prepolymer by epoxy acrylate and aliphatic urethane acrylate be 4-8 in mass ratio:1-3 is mixed.
5. according to claim 2 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Monomer be selected from the one or two of trimethylolpropane trimethacrylate or glycol diacrylate.
6. according to claim 5 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Monomer by trimethylolpropane trimethacrylate and glycol diacrylate be 1-2 in mass ratio:1 mixes.
7. according to claim 2 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Photoinitiator be selected from Alpha-hydroxy phenylcyclohexyl ketone.
8. according to claim 2 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Filler be polypropylene.
9. according to claim 2 a kind of with strong three-dimensional sense and flexible UV embossed printing inks, which is characterized in that described
Auxiliary agent be selected from commercially available BYK-371 levelling agents.
10. a kind of preparation method with strong three-dimensional sense and flexible UV embossed printing inks as described in claim 1, feature
It is, this method specifically includes following steps：
Step (1)：It stocks up by following components and parts by weight content：
1-3 parts of 35-65 parts of prepolymer, 12-35 parts of monomer, 4-8 parts of photoinitiator, 10-25 parts of filler and auxiliary agent；
Step (2)：First photoinitiator is mixed with monomer by weight, by constant temperature water bath heating stirring, photoinitiator is made to fill
Divide and is dissolved in monomer；
Step (3)：Under stirrings, prepolymer, auxiliary agent and filler are sequentially added by weight, is thoroughly mixed, stand,
Obtain the UV embossed printing inks.
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| CN201710058251.9A CN108342122A (en) | 2017-01-23 | 2017-01-23 | One kind having strong three-dimensional sense and flexible UV embossed printing inks and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102457A (en) * | 2017-12-29 | 2018-06-01 | 江苏乘鹰新材料股份有限公司 | UV embossed printing ink compositions and preparation method thereof |
| CN109852131A (en) * | 2018-12-12 | 2019-06-07 | 杭州全为包装印刷有限公司 | A kind of flexible simulation gravure printing ink and preparation method thereof |
| CN114621629A (en) * | 2021-11-24 | 2022-06-14 | 浙江画之都文化创意有限公司 | Imitation metal etching decorative picture |
| CN114654912A (en) * | 2022-04-18 | 2022-06-24 | 江苏大亚印务有限公司 | UV (ultraviolet) embossed oiled paper product for gravure printing machine and manufacturing method thereof |
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| CN101665641A (en) * | 2009-09-25 | 2010-03-10 | 林国顺 | Ultraviolet curing embossed printing ink |
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| CN101665641A (en) * | 2009-09-25 | 2010-03-10 | 林国顺 | Ultraviolet curing embossed printing ink |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102457A (en) * | 2017-12-29 | 2018-06-01 | 江苏乘鹰新材料股份有限公司 | UV embossed printing ink compositions and preparation method thereof |
| CN109852131A (en) * | 2018-12-12 | 2019-06-07 | 杭州全为包装印刷有限公司 | A kind of flexible simulation gravure printing ink and preparation method thereof |
| CN114621629A (en) * | 2021-11-24 | 2022-06-14 | 浙江画之都文化创意有限公司 | Imitation metal etching decorative picture |
| CN114621629B (en) * | 2021-11-24 | 2023-03-03 | 浙江画之都文化创意有限公司 | Imitation metal etching decorative picture |
| CN114654912A (en) * | 2022-04-18 | 2022-06-24 | 江苏大亚印务有限公司 | UV (ultraviolet) embossed oiled paper product for gravure printing machine and manufacturing method thereof |
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Application publication date: 20180731 |