CN108329725A - A kind of aqueous shale diatom ooze coating and preparation method thereof - Google Patents

A kind of aqueous shale diatom ooze coating and preparation method thereof Download PDF

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Publication number
CN108329725A
CN108329725A CN201810178897.5A CN201810178897A CN108329725A CN 108329725 A CN108329725 A CN 108329725A CN 201810178897 A CN201810178897 A CN 201810178897A CN 108329725 A CN108329725 A CN 108329725A
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CN
China
Prior art keywords
parts
agent
shale diatom
diatom ooze
minutes
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Pending
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CN201810178897.5A
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Chinese (zh)
Inventor
丁桂生
杨宏远
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Jiangsu Green Products Ecological Science & Technology Co Ltd
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Jiangsu Green Products Ecological Science & Technology Co Ltd
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Priority to CN201810178897.5A priority Critical patent/CN108329725A/en
Publication of CN108329725A publication Critical patent/CN108329725A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of aqueous shale diatom oozes and preparation method thereof, are prepared by the following each component of parts by weight:1~2 part of cellulose, 1.5~2.5 parts of dispersant, 1~2 part of wetting agent, 0.7~1.5 part of antifoaming agent, 15~25 parts of antifreezing agent, 1~2 part of PH conditioning agents, 140~160 parts of titanium dioxide, 200~240 parts of shale diatom powder, 65~85 parts of kaolin, 40~50 parts of bentonite, 5~7 parts of coalescents, 160~180 parts of lotion, 1~2 part of antiseptic, 10 ~ 12 parts of thickener, 280~300 parts of water.Above-mentioned aqueous shale diatom ooze, fugitive color, stain resistance be not good;Additionally, due to the selection of instant component and proportioning, make that the aqueous shale diatom ooze structural capacity is strong, stability is good, has good workability, scrub resistance is good, and has adjusting air humidity, the function of the harmful substances such as formaldehyde in air of degrading, hence it is evident that improve indoor air quality.

Description

A kind of aqueous shale diatom ooze coating and preparation method thereof
Technical field
The present invention relates to diatom ooze coating fields, more particularly to a kind of aqueous shale diatom ooze and preparation method thereof.
Background technology
Aqueous shale diatom ooze is made of high-performance environment protection type lotion, is to have to adjust humidity, is purified the function of air Type interior wall coating.With higher structural capacity, stability, application property, scrub resistance.Aqueous shale diatom ooze coating it is main at Membrane substance is styrene-acrylic emulsion, its effect is that the other components bonding in coating is integral.After coating, which is dried, to harden, energy It is attached to and is formed uniform continuous and tough and tensile by painting substrate surface and carry nano aperture protective film.Film has stronger resistance to Performance is cleaned, anti-pollution characteristic is strong;Nano-pore in coating has stronger physical adsorbability and photocatalytic, long-acting can dispel room The harmful substances such as peculiar smell and formaldehyde in interior air adjust the humidity of air, moreover it is possible to induce a certain amount of anion, be a Itself environmental protection can improve the ideal coating of environment again.Existing aqueous diatom coating, which exists, keeps resistance to soiling poor, and function is unknown Aobvious problem.
Invention content
Based on this, it is necessary to provide a kind of high-environmental, multi-functional, the good aqueous shale diatom ooze of resistance to soiling and its system Preparation Method.
A kind of aqueous shale diatom ooze, is prepared by the following each component of parts by weight:1~2 part of cellulose, dispersant 1.5~2.5 parts, 1~2 part of wetting agent, 0.7~1.5 part of antifoaming agent, 15~25 parts of antifreezing agent, 1~2 part of PH conditioning agents, titanium dioxide 140~160 parts, 200~240 parts of shale diatom powder, 65~85 parts of kaolin, 40~50 parts of bentonite, 5~7 parts of coalescents, 160~180 parts of lotion, 1~2 part of antiseptic, 10 ~ 12 parts of thickener, 280~300 parts of water.
Further, a kind of preparation method of aqueous shale diatom ooze is:
(1)It adds water in a mixing bowl, cellulose is slowly added under stirring, stir 15~25 minutes.
(2)Then dispersant, wetting agent, antifoaming agent, antifreezing agent, PH conditioning agents are sequentially added into a mixing bowl, low speed stirs It mixes 5-10 minutes, is uniformly mixed.
(3)Sequentially add titanium dioxide, bentonite, kaolin, shale diatom powder, high-speed stirred 50 minutes or more, detection Fineness≤30 μm carry out next procedure after qualified.
(4)Then coalescents, antifoaming agent, lotion, antiseptic are sequentially added, stirring at low speed is defoamed for 5-10 minutes.
(5)Thickener is slowly added under stirring, the additive amount apparent viscosity of wherein polyurethane thickener is adjusted, 10-20 minutes are stirred up to the aqueous shale diatom ooze.
Further, the cellulose uses hydroxyethyl cellulose, the dispersant to use dispersant 5040, the defoaming Agent uses mineral oil antifoam agent, the antifreezing agent that propylene glycol, the titanium dioxide is used to use rutile type titanium white, the antibacterial Agent uses antiseptic Kathon CG 87.
Further, the thickener includes that 612 thickener of polyurethane and 935 thickeners, weight are divided into:Polyurethane thickens 7 parts of agent, 935 3 parts of thickeners.
Above-mentioned aqueous shale diatom ooze, fugitive color, stain resistance be not good;Additionally, due to the choosing of instant component and proportioning Select, when making the high aqueous shale diatom ooze viscosity, construction will not drop, good water-retaining property, stability is good, has good workability, resistance to Time property is good, has excellent adhesive force, it is long to elastically keep the time.
Specific implementation mode
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
Embodiment 1
A kind of aqueous shale diatom ooze, is prepared by the following each component of parts by weight:2 parts of cellulose, 2 parts of dispersant, wetting 2 parts of agent, 1 part of antifoaming agent, 15 parts of antifreezing agent, 2 parts of PH conditioning agents, 150 parts of titanium dioxide, 220 parts of shale diatom powder, kaolin 80 Part, 50 parts of bentonite, 5 parts of coalescents, 180 parts of lotion, 1 part of antiseptic, 10 parts of thickener, 280 parts of water.
The present invention preparation method be:
(1)It adds water in a mixing bowl, cellulose is slowly added under stirring, stir 15~25 minutes.
(2)Then dispersant, wetting agent, antifoaming agent, antifreezing agent, PH conditioning agents are sequentially added into a mixing bowl, low speed stirs It mixes 5-10 minutes, is uniformly mixed.
(3)Sequentially add titanium dioxide, bentonite, kaolin, shale diatom powder, high-speed stirred 50 minutes or more, detection Fineness≤30 μm carry out next procedure after qualified.
(4)Then coalescents, antifoaming agent, lotion, antiseptic are sequentially added, stirring at low speed is defoamed for 5-10 minutes.
(5)Thickener is slowly added under stirring, the additive amount apparent viscosity of wherein polyurethane thickener is adjusted, 10-20 minutes are stirred up to the aqueous shale diatom ooze.
Embodiment 2
A kind of aqueous shale diatom ooze, is prepared by the following each component of parts by weight:2 parts of cellulose, 2.5 parts of dispersant, profit 1.5 parts of humectant, 1.5 parts of antifoaming agent, 10 parts of antifreezing agent, 1.5 parts of PH conditioning agents, 140 parts of titanium dioxide, 240 parts of shale diatom powder are high 90 parts of ridge soil, 50 parts of bentonite, 4 parts of coalescents, 165 parts of lotion, 2 parts of antiseptic, 10 parts of thickener, 280 parts of water.
The present invention preparation method be:
(1)It adds water in a mixing bowl, cellulose is slowly added under stirring, stir 15~25 minutes.
(2)Then dispersant, wetting agent, antifoaming agent, antifreezing agent, PH conditioning agents are sequentially added into a mixing bowl, low speed stirs It mixes 5-10 minutes, is uniformly mixed.
(3)Sequentially add titanium dioxide, bentonite, kaolin, shale diatom powder, high-speed stirred 50 minutes or more, detection Fineness≤30 μm carry out next procedure after qualified.
(4)Then coalescents, antifoaming agent, lotion, antiseptic are sequentially added, stirring at low speed is defoamed for 5-10 minutes.
(5)Thickener is slowly added under stirring, the additive amount apparent viscosity of wherein polyurethane thickener is adjusted, 10-20 minutes are stirred up to the aqueous shale diatom ooze.
Embodiment 3
A kind of aqueous shale diatom ooze, is prepared by the following each component of parts by weight:2 parts of cellulose, 2.5 parts of dispersant, profit 2 parts of humectant, 1.5 parts of antifoaming agent, 25 parts of antifreezing agent, 2 parts of PH conditioning agents, 150 parts of titanium dioxide, 230 parts of shale diatom powder, kaolin 65 parts, 40 parts of bentonite, 6 parts of coalescents, 180 parts of lotion, 2 parts of antiseptic, 12 parts of thickener, 280 parts of water.
The present invention preparation method be:
1)It adds water in a mixing bowl, cellulose is slowly added under stirring, stir 15~25 minutes.
(2)Then dispersant, wetting agent, antifoaming agent, antifreezing agent, PH conditioning agents are sequentially added into a mixing bowl, low speed stirs It mixes 5-10 minutes, is uniformly mixed.
(3)Sequentially add titanium dioxide, bentonite, kaolin, shale diatom powder, high-speed stirred 50 minutes or more, detection Fineness≤30 μm carry out next procedure after qualified.
(4)Then coalescents, antifoaming agent, lotion, antiseptic are sequentially added, stirring at low speed is defoamed for 5-10 minutes.
(5)Thickener is slowly added under stirring, the additive amount apparent viscosity of wherein polyurethane thickener is adjusted, 10-20 minutes are stirred up to the aqueous shale diatom ooze.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but can not Therefore it is interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for those of ordinary skill in the art, Without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection model of the present invention It encloses.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (4)

1. a kind of aqueous shale diatom ooze, which is characterized in that be prepared by the following each component of parts by weight:Cellulose 1~2 Part, 1.5~2.5 parts of dispersant, 1~2 part of wetting agent, 0.7~1.5 part of antifoaming agent, 15~25 parts of antifreezing agent, PH conditioning agents 1~2 Part, 140~160 parts of titanium dioxide, 200~240 parts of shale diatom powder, 65~85 parts of kaolin, 40~50 parts of bentonite, film forming helps 5~7 parts of agent, 160~180 parts of lotion, 1~2 part of antiseptic, 10~12 parts of thickener, 280~300 parts of water.
2. aqueous shale diatom ooze according to claim 1, which is characterized in that preparation method is:
(1) it adds water in a mixing bowl, cellulose is slowly added under stirring, stir 15~25 minutes.
(2) and then into a mixing bowl dispersant, wetting agent, antifoaming agent, antifreezing agent, PH conditioning agents, stirring at low speed 5- are sequentially added It 10 minutes, is uniformly mixed.
(3) titanium dioxide, bentonite, kaolin, shale diatom powder are sequentially added, high-speed stirred 50 minutes or more detects fineness ≤ 30 μm, next procedure is carried out after qualified.
(4) coalescents, antifoaming agent, lotion, antiseptic are then sequentially added, stirring at low speed is defoamed for 5-10 minutes.
(5) thickener is slowly added under stirring, the additive amount apparent viscosity of wherein polyurethane thickener is adjusted, stirring 10-20 minutes up to the aqueous shale diatom ooze.
3. aqueous shale diatom ooze according to claim 1, which is characterized in that the cellulose uses hydroxy ethyl fiber Element, the dispersant use dispersant 5040, the antifoaming agent that mineral oil antifoam agent, the antifreezing agent is used to use propylene glycol, The titanium dioxide uses rutile type titanium white, the antiseptic to use antiseptic Kathon CG 87.
4. aqueous shale diatom ooze according to claim 1, which is characterized in that the thickener includes that polyurethane 612 increases Thick dose and 935 thickeners, weight are divided into:7 parts of polyurethane thickener, 935 3 parts of thickeners.
CN201810178897.5A 2018-03-05 2018-03-05 A kind of aqueous shale diatom ooze coating and preparation method thereof Pending CN108329725A (en)

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Application Number Priority Date Filing Date Title
CN201810178897.5A CN108329725A (en) 2018-03-05 2018-03-05 A kind of aqueous shale diatom ooze coating and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852302A (en) * 2021-01-13 2021-05-28 爱上佳环保新材料有限公司 Anti-freezing diatom milk and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006114848A1 (en) * 2005-04-12 2006-11-02 Kabushiki Kaisha Nippankenkyusho Coating material for controlling attachment of alga and shellfish
CN105838158A (en) * 2016-06-03 2016-08-10 浙江天女集团制漆有限公司 Stain-resistant mould-proof diatom ooze coating and preparation method thereof
CN106673491A (en) * 2017-01-06 2017-05-17 深圳光天建材有限公司 Water-based diatom ooze and preparation method thereof
CN106673595A (en) * 2016-12-29 2017-05-17 欧亚绿邦(北京)科技有限公司 Water-based diatom ooze coating and preparation method thereof
CN106905834A (en) * 2017-04-13 2017-06-30 明光市国星凹土有限公司 A kind of concave convex rod sterilization water-repellent paint and preparation method
CN107118647A (en) * 2017-06-20 2017-09-01 东台市明山石涂料有限公司 A kind of elastic outer wall paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006114848A1 (en) * 2005-04-12 2006-11-02 Kabushiki Kaisha Nippankenkyusho Coating material for controlling attachment of alga and shellfish
CN105838158A (en) * 2016-06-03 2016-08-10 浙江天女集团制漆有限公司 Stain-resistant mould-proof diatom ooze coating and preparation method thereof
CN106673595A (en) * 2016-12-29 2017-05-17 欧亚绿邦(北京)科技有限公司 Water-based diatom ooze coating and preparation method thereof
CN106673491A (en) * 2017-01-06 2017-05-17 深圳光天建材有限公司 Water-based diatom ooze and preparation method thereof
CN106905834A (en) * 2017-04-13 2017-06-30 明光市国星凹土有限公司 A kind of concave convex rod sterilization water-repellent paint and preparation method
CN107118647A (en) * 2017-06-20 2017-09-01 东台市明山石涂料有限公司 A kind of elastic outer wall paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852302A (en) * 2021-01-13 2021-05-28 爱上佳环保新材料有限公司 Anti-freezing diatom milk and preparation method thereof

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Application publication date: 20180727