CN108329503A - A kind of antistatic ebonite set - Google Patents

A kind of antistatic ebonite set Download PDF

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Publication number
CN108329503A
CN108329503A CN201810134871.0A CN201810134871A CN108329503A CN 108329503 A CN108329503 A CN 108329503A CN 201810134871 A CN201810134871 A CN 201810134871A CN 108329503 A CN108329503 A CN 108329503A
Authority
CN
China
Prior art keywords
titanium dioxide
ebonite
antistatic
coating
ebonite set
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810134871.0A
Other languages
Chinese (zh)
Inventor
贺锐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Hengsheng Antistatic Products Co Ltd
Original Assignee
Dongguan Hengsheng Antistatic Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Hengsheng Antistatic Products Co Ltd filed Critical Dongguan Hengsheng Antistatic Products Co Ltd
Priority to CN201810134871.0A priority Critical patent/CN108329503A/en
Publication of CN108329503A publication Critical patent/CN108329503A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/042Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C08J7/0423Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08Oxides
    • C23C14/083Oxides of refractory metals or yttrium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

The present invention relates to cutting ferrule fields, specifically disclose a kind of antistatic ebonite set, and the ebonite set is made of rubber material, and the surface of rubber material is equipped with titanium dioxide coating, and anti-static coating is coated on the surface of titanium dioxide coating.The ebonite set is by being kneaded and vulcanizing after mixing raw material, then injection molding, prepares titanium dioxide coating by magnetron sputtering method in ebonite set outer surface, finally coats anti-static coating on the surface of titanium dioxide coating.A kind of antistatic ebonite set of the present invention, which solves the problems, such as that ebonite set easy tos produce electrostatic in the prior art, is easy aging, to be influenced to use, to improve the coefficient safe to use and service life of ebonite set.

Description

A kind of antistatic ebonite set
Technical field
The present invention relates to cutting ferrule fields, specifically disclose a kind of antistatic ebonite set.
Background technology
Ebonite set is commonly used in installation file, card and other items.With the development of intelligent cards, card is as modern society In essential authentication article, it will usually carry and frequently use, and mounted in ebonite set in card, can because Electrostatic is generated with objects frictions such as clothings, contacting card to user brings certain trouble or even larger electrostatic that can make card Piece damages.On the other hand, ebonite set of rubber material due to being made, and regular contacted with air can be easy aging, after aging Ebonite set can make to be difficult to recognize mounted in internal card or file and pollute file or card, influence because character changes It uses.
Invention content
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide a kind of antistatic ebonites Set, solving the problems, such as that the easy ebonite set of ebonite is easy to produce static electricity in the prior art, aging occurs influences to use.
To achieve the above object, the present invention uses following scheme.
A kind of antistatic ebonite set, is made of rubber material, it is characterised in that:The surface of rubber material is equipped with titanium dioxide Titanium coating, titanium dioxide coating are equipped with anti-static coating.Titanium dioxide coating can improve the anti-aging of rubber material surface Intensity, moreover it is possible to prevent the rubber that ebonite covers from being contacted with air, prevent the extraneous factor for causing ageing of rubber.
On the one hand, rubber material is by silicon rubber, chlorinated paraffin, titanium dioxide, methyl phenyl silicone oil, tert butyl phenolic resin Composition.
On the other hand, the anti-static coating is by hexamethylene diisocyanate, acrylic styrene copolymer, second Oxygroup cocoalkyl amines, surfactant composition.
Further, anti-static coating further includes cumarin.Chlorinated paraffin is added in rubber material has fluorescence Effect, can shine when night, convenient for find, prevent ebonite set lose.And cumarin is as a kind of organic After ebonite set is added in luminescent material, its luminous intensity at night is further improved, ebonite is made to be sleeved on the situation for not having light to lack light Under it is more obvious.
In one embodiment, card set can be by preparation method, by silicon rubber, chlorinated paraffin, titanium dioxide, methylbenzene It is kneaded and vulcanizes after base silicone oil, tert butyl phenolic resin mixing, then injection molding is ebonite set, is passed through in ebonite set outer surface Magnetron sputtering method prepares titanium dioxide coating, finally coats anti-static coating on the surface of titanium dioxide coating.
Beneficial effects of the present invention:Efficiently solve the problems, such as that ebonite covers easy to produce static electricity, easy to aging in the prior art, from And improve the coefficient safe to use and service life of ebonite set.
Specific implementation mode
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real The content that the mode of applying refers to not is limitation of the invention.
Ebonite set can be prepared by the following method, by silicon rubber, chlorinated paraffin, titanium dioxide, methyl phenyl silicone oil, uncle Butyl phenolic resin is according to 12:1:3:1:After 0.5 mass ratio mixing, it is added in kneading machine and is kneaded, be then added to vulcanization Vulcanize in machine, injection molding is ebonite set in preset die later;Ebonite is sleeved in magnetron sputtering coater, with titanium dioxide Titanium is target, and TiO 2 coating film layer is formed on ebonite set surface;Then by hexamethylene diisocyanate, acrylate-benzene Ethylene copolymer, ethyoxyl cocoalkyl amines, surfactant are according to 3:1:6:0.5:0.2 mass ratio mixing after, be added with Mixture quality ratio is 1:1 ethyl alcohol and the adhesive of mixture gross mass 1/10, coating materials are formed after stirring Material forms anti-static coating later by being screen printed onto coating slurry on the superficial layer of card set after dry.
The above content is only presently preferred embodiments of the present invention, for those of ordinary skill in the art, according to the present invention Thought, there will be changes in the specific implementation manner and application range, and the content of the present specification should not be construed as to the present invention Limitation.

Claims (5)

1. a kind of antistatic ebonite set, is made of rubber material, it is characterised in that:The surface of rubber material is equipped with titanium dioxide Coating, titanium dioxide coating are equipped with anti-static coating.
2. antistatic ebonite set according to claim 1, it is characterised in that:The rubber material is by silicon rubber, chlorination stone Wax, titanium dioxide, methyl phenyl silicone oil, tert butyl phenolic resin composition.
3. antistatic ebonite set according to claim 1, it is characterised in that:The anti-static coating is different by hexa-methylene two Cyanate, acrylic styrene copolymer, ethyoxyl cocoalkyl amines, surfactant composition.
4. antistatic ebonite set according to claim 1, it is characterised in that:Anti-static coating further includes cumarin.
5. a kind of preparation method of any antistatic ebonite sets of claim 1-4, it is characterised in that:By silicon rubber, chlorine It is kneaded and vulcanizes after fossil waxes, titanium dioxide, methyl phenyl silicone oil, tert butyl phenolic resin mixing, then injection molding is hard Gum cover prepares titanium dioxide coating, finally on the surface of titanium dioxide coating in ebonite set outer surface by magnetron sputtering method Coat anti-static coating.
CN201810134871.0A 2018-02-09 2018-02-09 A kind of antistatic ebonite set Pending CN108329503A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810134871.0A CN108329503A (en) 2018-02-09 2018-02-09 A kind of antistatic ebonite set

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810134871.0A CN108329503A (en) 2018-02-09 2018-02-09 A kind of antistatic ebonite set

Publications (1)

Publication Number Publication Date
CN108329503A true CN108329503A (en) 2018-07-27

Family

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Family Applications (1)

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CN201810134871.0A Pending CN108329503A (en) 2018-02-09 2018-02-09 A kind of antistatic ebonite set

Country Status (1)

Country Link
CN (1) CN108329503A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111020578A (en) * 2019-12-10 2020-04-17 湖南工学院 Preparation process of high-hardness machining tool

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201981386U (en) * 2010-12-30 2011-09-21 洪桂焕 Antistatic coated rubber roller
CN105219093A (en) * 2015-11-04 2016-01-06 东莞星海丰电子有限公司 A kind of silica gel product and preparation technology thereof
EP2520421B1 (en) * 2011-05-06 2016-02-24 Apollo Tyres Global R&D B.V. Method and device for manufacturing an antistatic vehicle tire

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201981386U (en) * 2010-12-30 2011-09-21 洪桂焕 Antistatic coated rubber roller
EP2520421B1 (en) * 2011-05-06 2016-02-24 Apollo Tyres Global R&D B.V. Method and device for manufacturing an antistatic vehicle tire
CN105219093A (en) * 2015-11-04 2016-01-06 东莞星海丰电子有限公司 A kind of silica gel product and preparation technology thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
东莞市大普防静电设备有限公司: "你还在买外处理的防静电硬胶套吗", 《百度》 *
祁广生: "《现代机器故障诊断学》", 31 July 1991 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111020578A (en) * 2019-12-10 2020-04-17 湖南工学院 Preparation process of high-hardness machining tool

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Application publication date: 20180727