CN108328718A - A kind of generating means of fulvic acid chelated iron ion - Google Patents
A kind of generating means of fulvic acid chelated iron ion Download PDFInfo
- Publication number
- CN108328718A CN108328718A CN201810374575.8A CN201810374575A CN108328718A CN 108328718 A CN108328718 A CN 108328718A CN 201810374575 A CN201810374575 A CN 201810374575A CN 108328718 A CN108328718 A CN 108328718A
- Authority
- CN
- China
- Prior art keywords
- iron
- fulvic acid
- metal derby
- acid chelated
- generating means
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 51
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 title claims abstract description 22
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000002509 fulvic acid Substances 0.000 title claims abstract description 22
- 229940095100 fulvic acid Drugs 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000003415 peat Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims 1
- -1 iron ion Chemical class 0.000 abstract description 18
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 11
- 229910001448 ferrous ion Inorganic materials 0.000 abstract description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 10
- 235000014413 iron hydroxide Nutrition 0.000 abstract description 5
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- 239000012773 agricultural material Substances 0.000 abstract 1
- 239000013535 sea water Substances 0.000 description 7
- 241000195493 Cryptophyta Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 230000000243 photosynthetic effect Effects 0.000 description 2
- 230000035806 respiratory chain Effects 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 102000018832 Cytochromes Human genes 0.000 description 1
- 108010052832 Cytochromes Proteins 0.000 description 1
- 108091006149 Electron carriers Proteins 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 241000206572 Rhodophyta Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of generating means of fulvic acid chelated iron ion, structure includes metallic rod, container made of iron, humic peat, metal derby；The inside of wherein container made of iron is filled with humic peat, and metal derby is buried in the center of humic peat, and the upside of metal derby is equipped with several metallic rods.Advantage：1）Ferrous ion complex compound can be discharged into environment long-term and stably, can be used for ocean water quality and promoted and the fields such as Agricultural Materials；2）It is acted using the ionization tendency of metal itself, is not required to additionally power or add catalyst；3）Fulvic acid chelated iron ion can be effectively absorbed and utilized compared to iron oxide, iron hydroxide etc. by organism.
Description
Technical field
A kind of generating means of fulvic acid chelated iron ion of the present invention, belongs to technical field of water treatment equipment.
Background technology
Organism usually converts iron ion to ferrous ion, iron of the organism as complexing is incorporated into, such as fulvic acid iron
Deng.Ferrous ion plays a significant role in the respiratory chain complex of organism as electron carrier, although its content is micro-
Amount, but when lacking, entire respiratory chain can be limited and be related to organism vital movement.Even for the photosynthetic work such as such as plant
With biology, as the cytochromes in photosynthetic electron transport system（Hemoprotein）, lack ferrous ion also and can limit and is whole
A vital movement.Such as in the soil, due to the shortage of ferrous ion, the yellowing phenomenon of rice can substantially reduce yield and product
Matter；In the prior art by ferric ion, such as iron sulfide, iron hydroxide, iron oxide etc. is used for plant culture additive, but efficiency
It is extremely low, it is not easy to be absorbed by plants.
The phenomenon of ferrous ion deficiency is referred to as burning extra large phenomenon in seawater, and brown alga, red algae etc. can be caused to be converted into lime
Algae, and the productivity of calcareous algae is very low, to make ocean become barren.Therefore, use the reefs of steel to increase in the prior art
Add the content of Iron In Seawater ion.But the iron ion in steel reefs is used as iron hydroxide and iron oxide to exist mostly, it is insoluble
Yu Shui, it is difficult to be used by organism；In addition, steel reef surface is covered by the oxidation film of iron hydroxide and iron oxide, the life of iron ion
It is greatly reduced at effect.
Invention content
Proposed by the present invention is a kind of generating means of fulvic acid chelated iron ion, and its purpose is to provide one kind can be to agriculture
The device for stablizing release ferrous ion complex compound in field or seawater, two can be efficiently used with the biology ensured in farmland or seawater
Valence iron ion carries out vital movement, effectively prevent burning the generation of extra large phenomenon or rice yellowing.
Technical solution of the invention：A kind of generating means of fulvic acid chelated iron ion, structure includes metallic rod
1, container made of iron 2, humic peat 3, metal derby 4；The inside of wherein container made of iron 2 is filled with humic peat 3, humic peat 3
The embedded metal derby 4 in center, the upside of metal derby 4 are equipped with several metallic rods 1.
Advantages of the present invention：
1）Ferrous ion complex compound can be discharged into environment long-term and stably, can be used for ocean water quality and promoted and agriculture material
The fields such as material；
2）It is acted using the ionization tendency of metal itself, is not required to additionally power or add catalyst；
3）Fulvic acid chelated iron ion can be effectively absorbed and utilized compared to iron oxide, iron hydroxide etc. by organism.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of the generating means of fulvic acid chelated iron ion.
1 it is metallic rod in figure, 2 be container made of iron, 3 be humic peat, 4 is metal derby.
Specific implementation mode
Technical scheme of the present invention is described further below according to attached drawing.
As shown in Figure 1, a kind of generating means of fulvic acid chelated iron ion, structure include metallic rod 1, container made of iron 2,
Humic peat 3, metal derby 4；The inside of wherein container made of iron 2 is filled with humic peat 3, and metal is buried in the center of humic peat 3
The upside of block 4, metal derby 4 is equipped with several metallic rods 1.
The metallic rod 1 and metal derby 4 uses nickel, tin, zinc, metal of the ionization tendencies such as copper less than iron.
The container made of iron 2 can make different shape, such as sphere, cube etc. as needed.
In use, being fixed on water-bed by container made of iron 2 or being inserted into moist soil, due to the metal being inclined to high ionization
Electronics can be pressed to the metal with low ionization tendency, container made of iron 2 is the anode that electronics flows to metal, and ionization tendency is less than iron
Metal derby 4 and metallic rod 1 be cathode；For example, tin by seawater by the chlorion in water（Oxidant Cl-）Corrosion, makes seawater
In tin and iron electrode plate ionization, iron ion and chloropexia form iron chloride（FeCl2）.Iron ion analysis in iron ware 2
Go out and moved to metal derby 4, iron ion passes through the humic peat 3 that water impregnates, and reacts shape with the fulvic acid contained in humic peat 3
It at the complex compound of fulvic acid iron, chelate, is finally dissipated by metallic rod 1, fulvic acid chelated iron ion is released into environment
In.
Technical solution using the present invention can constantly generate fulvic acid chelated iron ion, to environment in seawater and soil
In organism provide ferrous ion to promote vital movement, prevent ferrous ion shortage cause to burn sea and rice turn yellow it is existing
As.Meanwhile ferrous ion can also kill the spore of calcareous algae.Promote the stable development of the marine eco-environment.
Claims (4)
1. a kind of generating means of fulvic acid chelated iron ion, it is characterized in that including metallic rod（1）, container made of iron（2）, humic mud
Charcoal（3）, metal derby（4）；Wherein container made of iron（2）Inside be filled with humic peat（3）, humic peat（3）Center it is embedded
Metal derby（4）, metal derby（4）Upside be equipped with several metallic rods（1）.
2. the generating means of a kind of fulvic acid chelated iron ion according to claim 1, it is characterized in that the metallic rod
（1）And metal derby（4）It is less than the metal of iron, including nickel, tin, zinc, copper using ionization tendency.
3. the generating means of a kind of fulvic acid chelated iron ion according to claim 1, it is characterized in that the irony is held
Device（2）For sphere or cube.
4. a kind of generating means of fulvic acid chelated iron ion as described in claim 1, which is characterized in that in use, by iron
Matter container（2）It is fixed on water-bed or is inserted into moist soil, under moist environment, container made of iron（2）It is that electronics flows to metal
Anode, ionization tendency are less than the metal derby of iron（4）And metallic rod（1）It is cathode, iron ware（2）In Iron pick up and to
Metal derby（4）It is mobile；Iron ion passes through the humic peat that water impregnates（3）, with humic peat（3）The fulvic acid reaction shape inside contained
At the complex compound of fulvic acid iron, chelate, finally by metallic rod（1）It dissipates, fulvic acid chelated iron ion is released into ring
In border.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810374575.8A CN108328718A (en) | 2018-04-24 | 2018-04-24 | A kind of generating means of fulvic acid chelated iron ion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810374575.8A CN108328718A (en) | 2018-04-24 | 2018-04-24 | A kind of generating means of fulvic acid chelated iron ion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108328718A true CN108328718A (en) | 2018-07-27 |
Family
ID=62933488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810374575.8A Pending CN108328718A (en) | 2018-04-24 | 2018-04-24 | A kind of generating means of fulvic acid chelated iron ion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108328718A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109364883A (en) * | 2018-10-31 | 2019-02-22 | 北京师范大学 | A kind of humic acid modified Nano Fe2O3Material preparation method and the application for removing estradiol |
| CN111682229A (en) * | 2020-06-24 | 2020-09-18 | 中国海洋大学 | Humic acid-Fe composite modified anode, preparation method and application thereof, and seabed microbial fuel cell |
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|---|---|---|---|---|
| CN87100497A (en) * | 1987-01-26 | 1988-08-10 | 中国科学院海洋研究所技术开发公司 | Ferrous ion source is prevented and kill off hydrogen sulfide in the sea farming |
| JP2004066223A (en) * | 2002-06-10 | 2004-03-04 | Shunji Nishi | Electrolyte waste water treatment device, electrode used for the device and power generation device |
| JP2006116527A (en) * | 2004-09-27 | 2006-05-11 | Toshihiro Kido | Method and apparatus for modifying water |
| JP2008148678A (en) * | 2006-12-15 | 2008-07-03 | Kuniaki Ogami | Generator for divalent-iron ion |
| CN101698521A (en) * | 2009-11-17 | 2010-04-28 | 重庆大学 | Method for electrically restoring soil and underground water |
| CN102725234A (en) * | 2010-01-27 | 2012-10-10 | 中川特殊钢株式会社 | Fine iron mixture, method for utilizing fine iron mixture, and process for producing fine iron mixture |
| CN103601597A (en) * | 2013-12-04 | 2014-02-26 | 云南康本生物技术有限公司 | Humic acid compound fertilizer prepared by peat fermentation and preparation method thereof |
| WO2016024408A1 (en) * | 2014-08-14 | 2016-02-18 | 石井商事株式会社 | Iron supplying member for environmental water, iron supplying member maintenance method and method for supplying iron to environmental water |
| CN107597826A (en) * | 2017-10-27 | 2018-01-19 | 中国环境科学研究院 | The preparation method and applications of charcoal base compost fulvic acid composite |
| CN208249968U (en) * | 2018-04-24 | 2018-12-18 | 南京林业大学 | A kind of generating device of fulvic acid chelated iron ion |
-
2018
- 2018-04-24 CN CN201810374575.8A patent/CN108328718A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87100497A (en) * | 1987-01-26 | 1988-08-10 | 中国科学院海洋研究所技术开发公司 | Ferrous ion source is prevented and kill off hydrogen sulfide in the sea farming |
| JP2004066223A (en) * | 2002-06-10 | 2004-03-04 | Shunji Nishi | Electrolyte waste water treatment device, electrode used for the device and power generation device |
| JP2006116527A (en) * | 2004-09-27 | 2006-05-11 | Toshihiro Kido | Method and apparatus for modifying water |
| JP2008148678A (en) * | 2006-12-15 | 2008-07-03 | Kuniaki Ogami | Generator for divalent-iron ion |
| CN101698521A (en) * | 2009-11-17 | 2010-04-28 | 重庆大学 | Method for electrically restoring soil and underground water |
| CN102725234A (en) * | 2010-01-27 | 2012-10-10 | 中川特殊钢株式会社 | Fine iron mixture, method for utilizing fine iron mixture, and process for producing fine iron mixture |
| CN103601597A (en) * | 2013-12-04 | 2014-02-26 | 云南康本生物技术有限公司 | Humic acid compound fertilizer prepared by peat fermentation and preparation method thereof |
| WO2016024408A1 (en) * | 2014-08-14 | 2016-02-18 | 石井商事株式会社 | Iron supplying member for environmental water, iron supplying member maintenance method and method for supplying iron to environmental water |
| CN107597826A (en) * | 2017-10-27 | 2018-01-19 | 中国环境科学研究院 | The preparation method and applications of charcoal base compost fulvic acid composite |
| CN208249968U (en) * | 2018-04-24 | 2018-12-18 | 南京林业大学 | A kind of generating device of fulvic acid chelated iron ion |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109364883A (en) * | 2018-10-31 | 2019-02-22 | 北京师范大学 | A kind of humic acid modified Nano Fe2O3Material preparation method and the application for removing estradiol |
| CN111682229A (en) * | 2020-06-24 | 2020-09-18 | 中国海洋大学 | Humic acid-Fe composite modified anode, preparation method and application thereof, and seabed microbial fuel cell |
| CN111682229B (en) * | 2020-06-24 | 2022-07-15 | 中国海洋大学 | Humic acid-Fe composite modified anode, preparation method and application thereof, and seabed microbial fuel cell |
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