CN108326041B - A kind of helical tapered roll isometric rolling method of large-size titanium alloy ultra-fine grained bar - Google Patents
A kind of helical tapered roll isometric rolling method of large-size titanium alloy ultra-fine grained bar Download PDFInfo
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- 238000012546 transfer Methods 0.000 claims description 8
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- 229910000601 superalloy Inorganic materials 0.000 description 3
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- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
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- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/16—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling wire rods, bars, merchant bars, rounds wire or material of like small cross-section
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- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
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Abstract
Description
技术领域technical field
本发明涉及机械加工技术领域,具体涉及一种大尺寸钛合金超细晶棒材的螺线圆锥辊等距轧制方法。The invention relates to the technical field of mechanical processing, in particular to a spiral conical roller equidistant rolling method of a large-sized titanium alloy ultra-fine grain rod.
背景技术Background technique
采用塑性变形方式制备纳米级材料时其等效应变通常应大于6,传统塑性加工方法很难做到,应用超大塑性变形方法(Severe Plastic Deformation,SPD )能够实现。现代SPD始于Bridgemen 提出的大压力与剪切变形组合成形方式,迅猛发展始于20世纪70年代中期前苏联和西方国家,Segal发展了等通道转角挤压技术(Equal-Channel AngularPressing,ECAP),标志着SPD研究的显微结构时代的到来。近10余年来,成千上万研究成果公开发表。When using plastic deformation to prepare nanoscale materials, its equivalent strain should usually be greater than 6, which is difficult to achieve by traditional plastic processing methods, but can be achieved by applying super plastic deformation method (Severe Plastic Deformation, SPD). Modern SPD began with the combined forming method of high pressure and shear deformation proposed by Bridgemen, and its rapid development began in the former Soviet Union and Western countries in the mid-1970s. Segal developed Equal-Channel Angular Pressing (ECAP), It marks the arrival of the microstructural era of SPD research. In the past 10 years, thousands of research results have been published publicly.
2006年后普遍认可的关于SPD定义:使块体产生超大应变但不明显改变块体几何尺寸,呈现大角度晶界的晶粒细化效果的金属成型方法,可以获得晶粒尺寸在微米级(100-1000nm)和纳米级(小于100nm),都可称为纳米SPD(简称nanoSPD)。由于nanoSPD材料具有大量含高密度位错和高内应力的大角度非平衡晶界组织,使得材料表现出不同于传统粗晶材料的力学行为及变形机理。The generally accepted definition of SPD after 2006: a metal forming method that produces super large strain in the block without significantly changing the geometric size of the block, and presents the grain refinement effect of large-angle grain boundaries. 100-1000nm) and nanoscale (less than 100nm), can be called nano-SPD (referred to as nanoSPD). Because nanoSPD materials have a large number of large-angle non-equilibrium grain boundary structures with high density of dislocations and high internal stress, the materials exhibit mechanical behaviors and deformation mechanisms that are different from traditional coarse-grained materials.
目前现有的加工技术方案:典型的SPD方法有高压扭转(High Pressure Torsion,HPT)、等径转角挤压变形(equal channel angular press-ing,ECAP)、累积叠轧法(Accumulative Roll Bonding,ARB)、扭转挤压(Twist Extrusion,TE)和多向锻造(Multi-Directional Forging,MDF)。Current existing processing technology solutions: typical SPD methods include High Pressure Torsion (HPT), equal channel angular press-ing (ECAP), and Accumulative Roll Bonding (ARB). ), torsional extrusion (Twist Extrusion, TE) and multi-directional forging (Multi-Directional Forging, MDF).
其中,(1)高压扭转变形:将置于支撑槽中的原始样品(块或粉)施加数个GPa的压力,并相对转动上下两砧,使样品发生强烈剪切变形而细化晶粒,高压扭转的特点在于工件为盘状,尺寸较小,直径一般为10-20 mm,厚度为0.2-0.5 mm。Among them, (1) high-pressure torsional deformation: apply several GPa pressure to the original sample (block or powder) placed in the support groove, and rotate the upper and lower anvils relatively, so that the sample undergoes strong shear deformation and refines the grains. The characteristic of high-pressure torsion is that the workpiece is disc-shaped and small in size, generally 10-20 mm in diameter and 0.2-0.5 mm in thickness.
(2)等径角挤压变形:通过模具中两个相交一定角度的等截面通道,将材料由一端向另一端挤出,通过弯曲角对材料运动方向的改变使之产生纯剪切变形,可重复进行该成型过程,剪切应变量随变形道次增加。(2) Equal-diameter angular extrusion deformation: The material is extruded from one end to the other end through two equal-section channels intersecting at a certain angle in the mold, and the change of the moving direction of the material by the bending angle causes it to produce pure shear deformation. The forming process can be repeated with the amount of shear strain increasing with the deformation pass.
(3)累积叠轧法:将原始板材经表面处理后双层堆垛,加热后轧焊在一起,然后从中间剪开送回表面处理后再进行下次轧焊循环,为保证轧制后板材能够焊在一起,每道次的压下量不得低于50%,但ARB加工过程中需要强烈的剪应力条件,不能使用润滑剂,这对轧辊的服役寿命是不利的。(3) Cumulative stacking method: The original sheet is double-stacked after surface treatment, rolled and welded together after heating, and then cut from the middle and sent back to the surface treatment before the next rolling and welding cycle. The plates can be welded together, and the reduction in each pass shall not be less than 50%, but the ARB processing requires strong shear stress conditions, and lubricants cannot be used, which is detrimental to the service life of the rolls.
(4)扭转挤压:Beygelzime等提出该工艺。此方法也是通过剪切变形细化晶粒的成型技术,将柱状坯料挤压通过扭转模,与HPT类似,存在变形不均匀问题,细化晶粒效果低于ECAP和HPT。(4) Torsional extrusion: Beygelzime et al. proposed this process. This method is also a forming technology of grain refinement through shear deformation, extruding the columnar blank through a torsion die. Similar to HPT, there is a problem of uneven deformation, and the grain refinement effect is lower than that of ECAP and HPT.
(5)多向锻造:该工艺通过多次正交改变自由锻方向,获得大变形。此类变形的晶粒细化效果要明显低于ECAP和HPT。(5) Multi-directional forging: This process obtains large deformation by changing the direction of free forging multiple times orthogonally. The grain refinement effect of such deformation is significantly lower than that of ECAP and HPT.
另一类现有的加工技术方案:衍生方法,基本成型原理同以上方法,衍生了很多SPD成型新技术,这些方法力图简化工具设计,降低能耗,提高成材率,提升工件尺寸,升级自动化程度等,其中,包括:Another type of existing processing technology solutions: derivative methods. The basic forming principles are the same as the above methods, and many new SPD forming technologies are derived. These methods try to simplify tool design, reduce energy consumption, increase yield, increase workpiece size, and upgrade automation. etc., which include:
(1)ECAP衍生方法:反复折弯校直(RCS),坯料被放置折弯装置之间,随上模下移,坯料被折弯,变为波浪状;随后用2块平板进行校直,再进行折弯,通过不断重复,在不明显改变坯料尺寸的情况下累积足够的变形,细化材料组织。(1) ECAP derivative method: Repeated bending and straightening (RCS), the blank is placed between the bending devices, and as the upper die moves down, the blank is bent and becomes wavy; then two flat plates are used for straightening, Bending is performed again, and through repeated repetitions, sufficient deformation is accumulated and the material structure is refined without significantly changing the size of the blank.
(2)循环闭式模锻(CCDF),模具由某个截面腔体的下模和一个在腔体内垂直移动的相同截面的冲头组成。将带有石墨润滑剂的充分润滑的样品放入下模中,加热至一定温度。通过冲头将工件压入下模,取出后,沿同一方向围绕Z轴旋转90°,重新插入下模变形。这样,工件在连续的通道之间围绕Z轴旋转90°。以这种方式,分别经受1,3和5次压缩。(2) Cyclic closed die forging (CCDF), the die consists of a lower die of a certain section cavity and a punch of the same section that moves vertically in the cavity. A fully lubricated sample with graphite lubricant is placed in the lower die and heated to a certain temperature. The workpiece is pressed into the lower die by the punch, and after being taken out, it is rotated 90° around the Z axis in the same direction, and the lower die is reinserted to deform. In this way, the workpiece is rotated 90° around the Z axis between successive passes. In this way, 1, 3 and 5 compressions were experienced, respectively.
(3)往复挤压(CEC),模具由两个模腔、一个压缩带和放置于两模腔内的冲头构成。两模腔截面积相等,在同一条轴线上,通过中间的压缩带连接。在挤压过程中,试样在冲头的作用下,到达压缩带,此时,试样将受到正挤压变形,挤压后的工件在另一个模腔的冲头作用下,发生镦粗变形。然后,另一边冲头将工件按上述过程反向压回,完成一个挤压循环。重复以上过程,直至获得所要的应变为止。(3) Reciprocating extrusion (CEC), the die consists of two cavities, a compression belt and a punch placed in the two cavities. The cross-sectional areas of the two cavities are equal, and they are connected on the same axis by a compression belt in the middle. During the extrusion process, the sample reaches the compression belt under the action of the punch. At this time, the sample will be subjected to positive extrusion deformation, and the extruded workpiece will be upsetting under the action of the punch of another die cavity. deformed. Then, the punch on the other side pushes the workpiece back in reverse according to the above process to complete an extrusion cycle. The above process is repeated until the desired strain is obtained.
(4)板材连续剪切变形,装置利用上模、下模和下辊构成了两个横截面积有少量差异的相互交叉的通道。将板材送入到模腔内,板材在模腔转角处发生强烈的塑形变形,再从模腔另一侧挤出。在送料辊表面加工出凹槽以用于增加摩擦力。由于变形前后材料的横截面积保持不变的特点,可以在同一模具内反复对板材进行多道次的塑形变形。(4) The plate is continuously sheared and deformed. The device uses the upper die, the lower die and the lower roller to form two intersecting channels with a small difference in cross-sectional area. The plate is fed into the cavity, and the plate undergoes strong plastic deformation at the corner of the cavity, and is then extruded from the other side of the cavity. Grooves are machined on the surface of the feed roll to increase friction. Due to the fact that the cross-sectional area of the material remains unchanged before and after deformation, the plate can be repeatedly deformed in multiple passes in the same mold.
(5)椭圆螺旋等通道挤压法(ECEA),坯料在挤压力的作用下,由圆棒料历经镦拔(圆—椭圆变换)、 扭转(椭圆截面扭转)和反向镦拔(椭圆—圆变换)过程变回圆棒料。金属主要在横截面上产生塑性流动,并累积应变。模具形状利用了圆和椭圆形状的特殊性,其型腔不存在尖角区,使金属易于流动。实现了一次工艺过程多种变形模式的组合。(5) Elliptical spiral equal channel extrusion method (ECEA), under the action of the extrusion force, the billet is subjected to upsetting (circle-ellipse transformation), torsion (elliptical cross-section twist) and reverse upsetting (ellipse —circle transformation) process changes back to round bar. The metal mainly produces plastic flow in the cross section and accumulates strain. The shape of the mold takes advantage of the particularity of the round and oval shape, and the cavity has no sharp corners, making the metal easy to flow. The combination of multiple deformation modes in one process is realized.
(6)连续摩擦角挤压(CFAE),驱动辊旋转并向工件施加压力P抵靠其支撑件。在驱动辊和工件支撑件之间形成第一个挤压通道,第二个通道是固定模具组件中的短槽。片状工件经过一至八次加工,最大等效真实应变可达5.3,片材取向始终保持恒定。(6) Continuous Friction Angular Extrusion (CFAE), which drives the rollers to rotate and applies pressure P to the workpiece against its supports. The first extrusion channel is formed between the drive roll and the workpiece support, and the second channel is a short slot in the stationary die assembly. The sheet workpiece is processed one to eight times, and the maximum equivalent true strain can reach 5.3, and the sheet orientation is always kept constant.
一种HPT衍生方法,适用于管的高压扭转(HPTT),管位于刚性盘内,心轴放入管中,用压缩机在其弹性状态下压缩。由于心轴的轴向压缩,其沿径向膨胀,扩张受到管和圆盘的限制,在管中形成很大的静水应力,在管的两侧产生较大的摩擦力。在保持心轴固定的情况下,通过外部扭矩旋转盘实现管的变形。在扭转过程中,变形模式为局部剪切,剪切面法向为管的径向,剪切方向平行于圆周方向。A HPT-derived method suitable for high pressure torsion of tubes (HPTT), where the tube is located in a rigid disk, the mandrel is placed in the tube, and is compressed in its elastic state with a compressor. Due to the axial compression of the mandrel, it expands in the radial direction, and the expansion is limited by the tube and the disc, creating a large hydrostatic stress in the tube and creating a large friction force on both sides of the tube. Deformation of the tube is achieved by rotating the disk with external torque while keeping the mandrel stationary. During the torsion process, the deformation mode is local shear, the normal direction of the shear plane is the radial direction of the tube, and the shear direction is parallel to the circumferential direction.
一种TE衍生方法,超高扭转(STS),通过局部加热和冷却使该区域比另外两个部分变形抗力低,使扭转应变(TS)区域局部化。在产生TS区的同时,杆沿着纵向轴线移动,因此在整个杆上连续产生超大塑性应变。这种新工艺STS包括相对于杆的其他部分产生局部软区以及区域沿纵向的运动的杆。STS的一个重要特征是杆的横截面尺寸在应变时保持不变。A TE-derived method, superhigh torsion (STS), localizes the torsional strain (TS) region by localized heating and cooling that makes the region less resistant to deformation than the other two parts. Simultaneously with the creation of the TS zone, the rod is moved along the longitudinal axis, thus continuously producing super large plastic strains throughout the rod. This new process STS includes rods that create localized soft zones and regions of movement in the longitudinal direction relative to the rest of the rod. An important feature of STS is that the cross-sectional dimensions of the rod remain unchanged under strain.
国内外对于钛合金超细晶工艺的专利报道相对较少。中南大学周科朝等人在专利【CN 103014574 A】提及了一种TC18超细晶钛合金的制备方法,其中提及详细的热处理及多道次镦拔的超细晶工艺参数。此工艺采用多向镦拔的方式进行变形,属于传统锻造方法。因单道次变形区范围和穿深较小,为了获得超细晶组织,一般需要8-10道次以上的反复变形。周期长,效率低,并且一般存在明显的变形不均匀现象。There are relatively few patent reports on the ultrafine grain process of titanium alloys at home and abroad. In the patent [CN 103014574 A], Zhou Kechao et al. of Central South University mentioned a preparation method of TC18 ultra-fine grain titanium alloy, which mentioned detailed heat treatment and ultra-fine grain process parameters of multi-pass upsetting. This process uses multi-directional upsetting for deformation, which belongs to the traditional forging method. Due to the small range and penetration depth of the deformation zone in a single pass, in order to obtain an ultra-fine grain structure, more than 8-10 passes of repeated deformation are generally required. The period is long, the efficiency is low, and there is generally obvious deformation inhomogeneity.
上海交通大学王立强等人在专利【CN 103572186 A】中提及了采用等径弯曲通道变形制备超细晶钛基复合材料的方法,此方法本专利背景介绍已提出,虽然可反复进行剧烈塑性变形,但变形后尺寸为10X10 X100mm,难以满足工业级需求。西北工业大学杜随更在专利【CN 1446935 A】中提及了一种超细晶材料的制备方法。此方法主要集中于表面产生超细晶。虽然变形程度高,可反复变形,但只限于制备表面纳米晶,无法做到由心部到表面的整体超细晶。Wang Liqiang et al. of Shanghai Jiaotong University mentioned in the patent [CN 103572186 A] a method for preparing ultra-fine-grained titanium-based composite materials by using equal-diameter curved channel deformation. This method has been proposed in the background of this patent, although severe plastic deformation can be repeated , but the deformed size is 10X10X100mm, which is difficult to meet industrial-grade needs. Du Suigeng of Northwestern Polytechnical University mentioned a preparation method of ultrafine-grained materials in the patent [CN 1446935 A]. This method mainly focuses on the generation of ultrafine grains on the surface. Although the degree of deformation is high and it can be repeatedly deformed, it is limited to the preparation of surface nanocrystals, and cannot achieve the overall ultrafine grain from the core to the surface.
东北大学刘国怀等人在专利【CN 107030111 A】提及了一种等厚度超细晶TC4钛合金板材的制备方法。此方法与专利背景介绍中的累积叠轧类似,该过程需要强烈的剪应力条件,载荷较大,对其尺寸条件限制较大,只能制备板材,无法制备棒材。从钛合金超细晶工艺的论文报道而言,其大多使用ECAP、HPT的方式对钛合金进行变形,所涉及的制品尺寸较小,难以产生工业级整体超细晶的大尺寸块体材料。Liu Guohuai et al. of Northeastern University mentioned a preparation method of an equal-thickness ultrafine-grained TC4 titanium alloy sheet in the patent [CN 107030111 A]. This method is similar to the cumulative stack rolling in the introduction of the patent background. This process requires strong shear stress conditions, the load is large, and the size conditions are limited. Only sheets can be prepared, but bars cannot be prepared. From the paper reports on the ultrafine grain process of titanium alloys, most of them use ECAP and HPT to deform titanium alloys. The size of the products involved is small, and it is difficult to produce large-sized bulk materials with industrial-grade overall ultrafine grains.
综合分析可知:现有专利或论文中提及的钛合金超细晶工艺,均采用传统HPT、ECAP和ARB等方法在极高的载荷下制备小尺寸的均匀超细晶材料,目前都只限于实验室研制,难以制备工业级整体超细晶的大尺寸材料。Comprehensive analysis shows that the titanium alloy ultra-fine grain processes mentioned in the existing patents or papers all use traditional HPT, ECAP and ARB methods to prepare small-sized uniform ultra-fine grain materials under extremely high loads. It is difficult to prepare large-scale materials with industrial-grade monolithic ultrafine grains by laboratory development.
发明内容SUMMARY OF THE INVENTION
本发明目的在于提供一种大尺寸钛合金超细晶棒材的螺线圆锥辊等距轧制方法,以解决上述背景技术中提出的尺寸受限、载荷大和效率低等问题。The purpose of the present invention is to provide a helical conical roll equidistant rolling method for large-sized titanium alloy ultra-fine grain bars, so as to solve the problems of limited size, large load and low efficiency proposed in the above background technology.
本发明一种大尺寸钛合金超细晶棒材的螺线圆锥辊等距轧制方法,包括以下步骤:The present invention is a spiral conical roller equidistant rolling method of a large-size titanium alloy ultra-fine grain rod, comprising the following steps:
S1:选取直径尺寸D为40-150mm,长度为300-5000mm的钛合金坯料;S1: Select a titanium alloy billet with a diameter D of 40-150mm and a length of 300-5000mm;
S2:将上述钛合金坯料放置加热炉内加热至800-1120℃,加热时间为:钛合金坯料直径D×(0.6~0.8)min;S2: Place the above titanium alloy billet in a heating furnace and heat it to 800-1120°C, and the heating time is: the diameter of the titanium alloy billet D×(0.6~0.8)min;
S3:将加热后的钛合金坯料从加热炉转运至斜轧机导料槽内,转运时间为5-20s;S3: Transfer the heated titanium alloy billet from the heating furnace to the guide trough of the skew rolling mill, and the transfer time is 5-20s;
S4:在斜轧机的导料槽内进行送料,将钛合金坯料送入斜轧机入口和出口之间的变形区,钛合金坯料在变形区内螺旋运动直至变形结束,得到直径为Dm的TC18钛合金棒材棒材,其中m为轧制次数,轧制一次得到的TC18钛合金棒材的直径为D1,轧制两次得到的TC18钛合金棒材的直径为D2,以此类推;S4: Feeding is carried out in the guide groove of the skew rolling mill, and the titanium alloy billet is sent to the deformation zone between the entrance and the exit of the skew rolling mill. The titanium alloy billet moves spirally in the deformation zone until the deformation ends, and the TC18 titanium with a diameter of Dm is obtained. Alloy bar and bar, where m is the number of rollings, the diameter of the TC18 titanium alloy bar obtained by rolling once is D1, the diameter of the TC18 titanium alloy bar obtained by rolling twice is D2, and so on;
S5:重复上述S2-S4步骤,对钛合金坯料进行2-8次螺旋轧制得到TC18钛合金整体超细晶棒材;S5: Repeat the above steps S2-S4, and perform 2-8 spiral rolling on the titanium alloy billet to obtain a TC18 titanium alloy integral ultra-fine grain rod;
所述斜轧机为二辊斜轧机,轧辊均为单锥形轧辊,轧辊上设置有螺线轧槽,且螺线轧槽的旋进方向与钛合金坯料轧制过程中的旋进方向相同,锥角γ1为17-19度,且轧辊咬入钛合金坯料的圆弧半径r为60-400mm,轧辊送进角α为19-21度,轧辊的辗轧角β为17-19度,两个轧辊之间的辊距Dg为钛合金坯料直径D的87%-95%,轧辊转速n为30-55r/min;The skew rolling mill is a two-roll skew rolling mill, the rolls are all single-tapered rolls, the rolls are provided with spiral grooves, and the precession direction of the spiral grooves is the same as the precession direction of the titanium alloy billet rolling process, The cone angle γ1 is 17-19 degrees, and the arc radius r of the roll bite into the titanium alloy billet is 60-400mm, the roll feeding angle α is 19-21 degrees, and the rolling angle β of the roll is 17-19 degrees. The roll distance Dg between each roll is 87%-95% of the diameter D of the titanium alloy billet, and the roll speed n is 30-55r/min;
所述钛合金坯料为大尺寸TC18钛合金棒材;The titanium alloy blank is a large-sized TC18 titanium alloy bar;
所述S5步骤中重复轧制过程的加热时间均为TC18钛合金棒材直径Dm×(0.3~0.4)min。The heating time of the repeated rolling process in the S5 step is the diameter of the TC18 titanium alloy bar Dm×(0.3-0.4) min.
优选地,轧辊小端面设置为圆弧面,且圆弧面半径为60-400mm。Preferably, the small end face of the roll is set as a circular arc surface, and the radius of the circular arc surface is 60-400 mm.
优选地,孔型椭圆度系数为导板距Dd与辊距Dg之比,S4步骤中钛合金坯料在变形区内采用孔型椭圆度系数为1.25-1.4进行轧制。Preferably, the pass ovality coefficient is the ratio of the guide plate distance D d to the roll distance Dg. In step S4, the titanium alloy billet is rolled in the deformation zone with a pass ovality coefficient of 1.25-1.4.
优选地,在钛合金坯料轧制过程中,两个轧辊之间的辊距Dg固定不变,有利于实现多道次重复轧制。Preferably, in the process of rolling the titanium alloy billet, the roll distance Dg between the two rolls is fixed, which is beneficial to realize multiple passes of repeated rolling.
优选地,螺线轧槽的螺距ι为6~15mm,齿高h为6~15mm。Preferably, the pitch ι of the helical rolling groove is 6-15mm, and the tooth height h is 6-15mm.
优选地,在S5步骤重复轧制过程中,变形区形状保持不变。Preferably, during the repeated rolling process in step S5, the shape of the deformation zone remains unchanged.
本发明与现有技术相比,本发明的有益效果是:Compared with the prior art, the present invention has the following beneficial effects:
(1)变形区穿深大,能够获得大尺寸整体超细晶组织。斜轧过程中材料内部的塑性变形由两部分组成,一是轧辊间的压缩变形,此变形为周期性间断变形,另一部分是持续发生的扭转变形。压缩和扭转变形的叠加使斜轧过程中变形区内产生明显区别于常规锻造的三维剧烈塑性变形;(2)斜轧前后棒材直径保持不变可往复进行多道次轧制。斜轧过程存在宽展,高温合金坯料横截面内的等效直径保持不变;(3)连续稳定局部变形,轧制载荷小,变形过程平稳。斜轧过程中工件与高温合金坯料的实际接触面积仅为高温合金坯料表面积的很小一部分,为局部接触变形,因而载荷小;(4)压-扭复合三维剧烈变形,能够获得理想的晶粒细化效果。(1) The deformation zone has a large penetration depth, and a large-scale overall ultra-fine grain structure can be obtained. The plastic deformation inside the material during skew rolling consists of two parts, one is the compression deformation between the rolls, which is periodic intermittent deformation, and the other is the continuous torsional deformation. The superposition of compression and torsion deformation produces three-dimensional severe plastic deformation in the deformation zone during the skew rolling process, which is obviously different from that of conventional forging; (2) The diameter of the bar remains unchanged before and after skew rolling, and multi-pass rolling can be performed. There is widening in the skew rolling process, and the equivalent diameter in the cross section of the superalloy billet remains unchanged; (3) continuous and stable local deformation, the rolling load is small, and the deformation process is stable. During the skew rolling process, the actual contact area between the workpiece and the superalloy billet is only a small part of the surface area of the superalloy billet, which is a local contact deformation, so the load is small; (4) The compression-torsion composite three-dimensional severe deformation can obtain ideal grains Refinement effect.
附图说明Description of drawings
图1为本发明轧辊示意图。Figure 1 is a schematic diagram of the roll of the present invention.
图2为原始组织晶粒示意图。Figure 2 is a schematic diagram of the original structure grains.
图3为本发明实施例一轧制次数为2次示意图。FIG. 3 is a schematic diagram showing that the number of rollings is 2 in the first embodiment of the present invention.
图4为本发明实施例一轧制次数为6次示意图。FIG. 4 is a schematic diagram showing that the number of rollings is 6 times in the first embodiment of the present invention.
图5为本发明斜轧过程各模具相对位置。Fig. 5 is the relative position of each die during the skew rolling process of the present invention.
图6为本发明斜轧过程各模具相对位置俯视图。FIG. 6 is a plan view of the relative positions of the dies during the skew rolling process of the present invention.
图7为本发明斜轧穿过程各模具相对位置左视图。FIG. 7 is a left side view of the relative positions of the various dies during the skew rolling process of the present invention.
图8为本发明斜轧过程变形区示意图。FIG. 8 is a schematic diagram of the deformation zone during the skew rolling process of the present invention.
附图标记:1-轧辊、2-钛合金坯料、3-导板。Reference numerals: 1-roller, 2-titanium alloy billet, 3-guide plate.
具体实施方式Detailed ways
本发明一种大尺寸钛合金超细晶棒材的螺线圆锥辊等距轧制方法,包括以下步骤:The present invention is a spiral conical roller equidistant rolling method of a large-size titanium alloy ultra-fine grain rod, comprising the following steps:
S1:选取直径尺寸D为40-150mm,长度为300-5000mm的钛合金坯料2;S1: Select a
S2:将上述钛合金坯料2放置加热炉内加热至800-1120℃,加热时间为:钛合金坯料2直径D×(0.6~0.8)min;S2: Place the above-mentioned
S3:将加热后的钛合金坯料2从加热炉转运至斜轧机导料槽内,转运时间为5-20s;S3: transfer the heated
S4:在斜轧机的导料槽内进行送料,将钛合金坯料2送入斜轧机入口和出口之间的变形区,钛合金坯料2在变形区内螺旋运动直至变形结束,得到直径为Dm的TC18钛合金棒材棒材,其中m为轧制次数,轧制一次得到的TC18钛合金棒材的直径为D1,轧制两次得到的TC18钛合金棒材的直径为D2,以此类推;S4: Feeding is carried out in the guide groove of the skew rolling mill, and the
S5:重复上述S2-S4步骤,对钛合金坯料2进行2-8次螺旋轧制得到TC18钛合金整体超细晶棒材;S5: Repeat the above steps S2-S4, and perform 2-8 spiral rolling on the
所述斜轧机为二辊斜轧机,所述轧辊1均为单锥形轧辊1,轧辊1上设置有螺线轧槽,且螺线轧槽的旋进方向与钛合金坯料2轧制过程中的旋进方向相同,锥角γ1为17-19度,且轧辊1咬入钛合金坯料2的圆弧半径r为60-400mm,轧辊1送进角α为19-21度,轧辊1的辗轧角β为17-19度,两个轧辊1之间的辊距Dg为钛合金坯料2直径D的87%-95%,轧辊1转速n为30-55r/min;The skew rolling mill is a two-roll skew rolling mill, the
所述钛合金坯料2为大尺寸TC18钛合金棒材;The
所述S5步骤中重复轧制过程的加热时间均为TC18钛合金棒材直径Dm×(0.3~0.4)min。The heating time of the repeated rolling process in the S5 step is the diameter of the TC18 titanium alloy bar Dm×(0.3-0.4) min.
轧辊1小端面设置为圆弧面,且圆弧面半径为60-400mm。The small end face of the
孔型椭圆度系数为导板距Dd与辊距Dg之比,S4步骤中钛合金坯料2在变形区内采用孔型椭圆度系数为1.25-1.4进行轧制。The pass ovality coefficient is the ratio of the guide plate distance D d to the roll distance Dg. In step S4, the
在钛合金坯料2轧制过程中,两个轧辊1之间的辊距Dg固定不变,有利于实现多道次重复轧制。During the rolling process of the
螺线轧槽的螺距ι为6~15mm,齿高h为6~15mm。The pitch ι of the helical rolling groove is 6~15mm, and the tooth height h is 6~15mm.
在S5步骤重复轧制过程中,变形区形状保持不变。During the repeated rolling process in step S5, the shape of the deformation zone remains unchanged.
本发明中轧辊1小端面为圆弧面,这可以快速将圆柱形钛合金坯料2变为椭圆柱形,为恒定辊缝螺旋轧制时提供足够的变形量;轧辊1主体形状为单锥形,锥角与辗轧角相等,与普通轧辊1相比,外径压缩变形区长度增加到2倍长度,轧件经过比普通轧制更长的变形区后,累积可发生大的塑性变形;采用较大椭圆度系数轧制,钛合金坯料2被拽入轧辊1后,横断面变为椭圆形,在螺旋前进过程中,由于椭圆长轴半径大于轧辊1间距,钛合金坯料2一直承受轧辊1的小变形量压缩,变形区任意点旋转一圈,被轧辊1压缩两次;可反复多次实现螺旋轧制,由于大的椭圆度,螺旋轧制后的棒材直径大于辊距,变形后的轧件可以反复多次在同一变形参数条件下,被反复轧制,这样可以获得更大的变形量;采用大送进角和大辗轧角,可以获得更加稳定的螺旋前进动力,以适应大塑性变形的需求,且通过该圆锥辊上的螺线轧槽的助力变形,在原有变形基础上,再叠加小范围的压缩及弯曲剪切变形,最终实现超大塑性变形,达到细化晶粒的作用。In the present invention, the small end face of the
一般以再结晶温度区分材料加工的类型,再结晶温度以上为热加工,再结晶温度以下为冷加工,现有技术制备超细晶均采用冷加工,由于变形量不够,只能以位错累计获得较小的晶粒,但是这种晶粒热稳定性差,不能进行热处理。本专利的目的是获得能够热处理的晶粒,即通过累积大变形通过再结晶的方式获得超细晶,从而区别于传统的冷加工区别开。Generally, the type of material processing is distinguished by the recrystallization temperature. Above the recrystallization temperature is hot processing, and below the recrystallization temperature is cold processing. In the existing technology, cold processing is used to prepare ultrafine grains. Small grains, but such grains have poor thermal stability and cannot be heat treated. The purpose of this patent is to obtain grains that can be heat treated, that is, to obtain ultrafine grains by means of recrystallization by accumulating large deformation, thereby distinguishing them from traditional cold working.
因此本专利为大尺寸TC18整体超细晶棒材的工业化制备提供了一个现实性的选择。Therefore, this patent provides a realistic choice for the industrialized preparation of large-sized TC18 integral ultra-fine grained rods.
实施例一:Example 1:
采用上述技术参数,设计加工螺旋轧制轧辊1如图1所示;Using the above technical parameters, the design and processing of the
S1:主要变形参数选用钛合金TC18,直径D为100mm,长度为800mm;螺旋轧辊1的咬入圆弧半径r为60mm,圆锥辊锥角γ1为18°,送进角α为20°,辗轧角β为18°,螺旋轧辊1螺距ι为13mm,齿高h为9mm,轧辊1间距Dg为坯料直径D的88%,椭圆度系数为1.25,轧辊1转速n为32r/min;S1: Titanium alloy TC18 is selected as the main deformation parameters, the diameter D is 100mm, and the length is 800mm; the bite arc radius r of the
S2:在加热炉中加热钛合金圆柱坯料至850℃,加热时间为80分钟;S2: Heat the titanium alloy cylindrical billet to 850°C in a heating furnace, and the heating time is 80 minutes;
S3:将加热到温的坯料从加热炉转运至斜轧机导料槽内,转运时间10s;S3: Transfer the heated billet from the heating furnace to the guide trough of the skew rolling mill, and the transfer time is 10s;
S4:坯料在变形区内螺旋运动直至变形结束;S4: The billet moves spirally in the deformation zone until the deformation ends;
S5:反复轧制2次和6次取样分析,其对于钛合金晶粒细化的作用显著,晶粒尺寸细小, 且重复轧制过程的加热时间为:TC18钛合金棒材直径Dm×(0.3~0.4)min,其中m为轧制次数,轧制一次得到的TC18钛合金棒材的直径为D1,轧制两次,是采用直径为D1的TC18钛合金棒材作为坯料进行再次轧制,得到的TC18钛合金棒材的直径为D2,以此类推,复轧制过程中,变形区形状保持不变。S5: Repeated rolling 2 times and 6 times sampling analysis, it has a significant effect on the grain refinement of titanium alloy, the grain size is small, and the heating time of the repeated rolling process is: TC18 titanium alloy bar diameter Dm × (0.3 ~0.4) min, where m is the number of rollings, the diameter of the TC18 titanium alloy bar obtained by rolling once is D1, and rolling twice is to use the TC18 titanium alloy bar with a diameter of D1 as the billet for re-rolling, The diameter of the obtained TC18 titanium alloy bar is D2, and so on. During the re-rolling process, the shape of the deformation zone remains unchanged.
基于上述实例,原始组织如图2所示,图中以β晶粒为主,β晶粒平均尺寸为80um;其采用本发明方法,图3为轧制次数为2的典型钛合金晶粒图,其中晶粒尺寸为8um左右,晶粒细化程度为90%;图4为轧制次数为6的钛合金晶粒图,其中晶粒尺寸为2.5um左右,晶粒细化程度为96.88%。其工作原理如图8所示,轧辊1与导板3之间的位置关系如图5、图6和图7所示。Based on the above example, the original structure is shown in Figure 2. In the figure, β grains are dominant, and the average size of the β grains is 80um. The method of the present invention is adopted. Figure 3 is a typical titanium alloy grain diagram with 2 rolling times. , the grain size is about 8um, and the grain refinement degree is 90%; Figure 4 is the grain diagram of the titanium alloy with 6 rolling times, in which the grain size is about 2.5um, and the grain refinement degree is 96.88%. . The working principle is shown in FIG. 8 , and the positional relationship between the
综上所述:本发明提供的一种大尺寸TC18钛合金整体超细晶棒材的螺线圆锥辊等辊距轧制方法,通过设计螺线圆锥辊的外形,且保持变形区内辊距不变,采用超大变形区孔型椭圆度系数进行反复多道次轧制,逐步累积为超大塑性变形;而且,本方法可进行多道次螺旋轧制,对于不同种类钛合金,轧制次数在2-8范围内,对于钛合金晶粒细化的作用最佳,所获的整体超细晶尺寸最小。该工艺适用于各种尺寸规格和种类的钛合金棒材低载荷连续剧烈塑性变形。用于制备1000~3000nm的整体细晶/超细晶棒材。并可克服现有剧烈塑性变形工艺载荷大,只能加工小尺寸工件的不足。To sum up, the present invention provides a method for rolling a large-size TC18 titanium alloy integral ultra-fine-grained bar with helical tapered rolls with equal roll spacing, by designing the shape of the helical tapered rolls and maintaining the roll spacing in the deformation zone. Unchanged, the pass ovality coefficient in the super deformation zone is used for repeated multi-pass rolling, and the super plastic deformation is gradually accumulated; moreover, this method can carry out multi-pass spiral rolling. For different types of titanium alloys, the rolling times are Within the range of 2-8, the effect on grain refinement of titanium alloy is the best, and the overall ultrafine grain size obtained is the smallest. This process is suitable for continuous severe plastic deformation of titanium alloy bars of various sizes and types under low load. It is used to prepare the overall fine-grained/ultra-fine-grained rods of 1000~3000nm. It can overcome the shortcomings of the existing severe plastic deformation process that the load is large and only small-sized workpieces can be processed.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. The equivalent replacement or change of the inventive concept thereof shall be included within the protection scope of the present invention.
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CN112059309B (en) * | 2020-08-26 | 2022-08-19 | 深圳宏友金钻石工具有限公司 | Round equipment is articulated to bar |
CN115301731B (en) * | 2022-08-12 | 2023-10-31 | 索罗曼(常州)合金新材料有限公司 | Equidistant rolling method for spiral conical rollers of large-size titanium alloy bars |
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JPS6054209A (en) * | 1983-08-31 | 1985-03-28 | Kawasaki Steel Corp | Skew rolling mill for manufacturing seamless steel pipe |
SU1328030A1 (en) * | 1985-08-01 | 1987-08-07 | Предприятие П/Я М-5481 | Method of twisting bar stock |
JPS6244523A (en) * | 1985-08-20 | 1987-02-26 | Sumitomo Metal Ind Ltd | Manufacture of austenitic stainless steel bar |
JP3785916B2 (en) * | 2000-10-02 | 2006-06-14 | 住友金属工業株式会社 | Rolling method for seamless metal pipe |
CN1546715A (en) * | 2003-11-29 | 2004-11-17 | 燕山大学 | Ultrafine Grain Medium and High Carbon Steel Shaft Parts and Its Manufacturing Technology |
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CN104971940A (en) * | 2014-04-14 | 2015-10-14 | 西安中泰新材料科技有限公司 | Screw rolling method and screw rolling device for titanium rod |
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