CN108325382A - A kind of environmentally friendly particulate composition and preparation method thereof that can purify air - Google Patents
A kind of environmentally friendly particulate composition and preparation method thereof that can purify air Download PDFInfo
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- CN108325382A CN108325382A CN201810200064.4A CN201810200064A CN108325382A CN 108325382 A CN108325382 A CN 108325382A CN 201810200064 A CN201810200064 A CN 201810200064A CN 108325382 A CN108325382 A CN 108325382A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/34—Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8609—Sulfur oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8637—Simultaneously removing sulfur oxides and nitrogen oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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Abstract
The invention discloses a kind of environmentally friendly particulate compositions and preparation method thereof that can purify air, are related to technical field of air purification, including body particles and absorption auxiliary particle, and body particles include the raw material of following part meter:45 ~ 50 parts of modified pearl rock, 20 ~ 25 parts of composite fibre, 20 ~ 25 parts of sepiolite powder, 15 ~ 20 parts of litsea citrate oil, 15 ~ 20 parts of Ludox, 15 ~ 20 parts of nano-titanium dioxide, 12 ~ 14 parts of P-hydroxybenzoic acid, 9 ~ 11 parts of trihydroxy methyl triglycidyl ether and suitable quantity of water.The present invention has preferable air-cleaning function.
Description
Technical field
The present invention relates to technical field of air purification, and in particular to a kind of environmentally friendly particulate composition that can purify air and
Preparation method.
Background technology
With the progress of science and technology, the improvement of people's living standards, requirement of the people to indoor environment, air quality is got over
Come higher.Scientists have detected 500 gas chromatographies from room air, wherein it is common, everybody it is general open all over concern room
Interior pollutant mainly has benzene, formaldehyde, dimethylbenzene and volatile organic compounds etc..Due to most of moderns daily 80~90%
Time spend indoors, thus indoor air pollutants harm to the human body is larger.
Invention content
The object of the present invention is to provide a kind of environmentally friendly particulate composition and preparation method thereof that can purify air, have compared with
Good air-cleaning function.
The present invention provides the following technical solutions:A kind of environmentally friendly particulate composition that can purify air, including main body
Particle and absorption auxiliary particle;
The body particles include the raw material of following part meter:45 ~ 50 parts of modified pearl rock, 20 ~ 25 parts of composite fibre, sepiolite powder
20 ~ 25 parts, 15 ~ 20 parts of litsea citrate oil, 15 ~ 20 parts of Ludox, 15 ~ 20 parts of nano-titanium dioxide, P-hydroxybenzoic acid 12 ~ 14
Part, 9 ~ 11 parts of trihydroxy methyl triglycidyl ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:35 ~ 40 parts of modification infusorial earth, 25 ~ 30 parts of activated carbon, plant source
25 ~ 30 parts of concentrate, 14 ~ 16 parts of trihydroxy ethylamine oleate soap, 14 ~ 16 parts of antiseptic, 8 ~ 10 parts of laurene, ethylenediamine tetra-acetic acid two
5 ~ 8 parts of sodium and suitable quantity of water;
The mass ratio of the body particles and absorption auxiliary particle is 8 ~ 10:1.
Wherein, the plant source concentrate includes the raw material of following part meter:11 ~ 13 parts of Rome chamomile, fish pelargonium 8 ~ 10
1 ~ 3 part of part, in vain 5 ~ 8 parts of the palm, 3 ~ 5 parts of ginger, 3 ~ 5 parts of cloves, 1 ~ 3 part of asparagus fern and loquat;
Aforementioned raw material is weighed according to proportioning, co-grinding is added in the ethanol solution of 15 ~ 25 times of weight, is leached at 55 ~ 65 DEG C
Leaching liquid is obtained by filtration in 15 ~ 20h, and then vacuum distillation obtains plant source concentrate.
Wherein, the preparation method of the modification infusorial earth:Diatomite is added to the 15~30% of 5 ~ 10 times of parts by weight
In manganese chloride solution, 5~6h is stirred under the conditions of 45~55 DEG C, is stood 10 ~ 12h, is isolated sediment, it is heavy to be washed with deionized water
Starch obtains the modification infusorial earth after drying and grinding.
Wherein, the modified pearl rock includes the raw material of following part meter:25 ~ 30 parts of perlite, zeolite molecular sieve 14 ~ 16
Part, 5 ~ 8 parts of barium zirconate, 5 ~ 8 parts of turpentine oil, 3 ~ 5 parts of diaminodiphenyl-methane, 3 ~ 5 parts of liquid rosin resin, phthalic acid
1 ~ 3 part of 1 ~ 3 part of diisobutyl ester, 1 ~ 3 part of stearic acid and 1- ethoxy -2- oil-based imidazolines.
Wherein, the preparation method of the modified pearl rock is:According to proportioning by perlite, zeolite molecular sieve, barium zirconate, neighbour
Phthalic acid diisobutyl ester is uniformly mixed, and is added into 5 ~ 10 times of parts by weight water, and suspension is formed, and turpentine oil, two are then added
Aminodiphenylmethane, liquid rosin resin, stearic acid and 1- ethoxy -2- oil-based imidazolines, are uniformly dispersed, at 55 ~ 65 DEG C
Under the conditions of dry, crush, cross 300 ~ 400 mesh sieve to obtain the final product.
Wherein, the composite fibre includes the raw material of following part meter:17 ~ 21 parts of tossa, 5 ~ 11 parts of bombax cotton, stone
1 ~ 5 part of 1 ~ 5 part of cotton fiber and viscose rayon;
The preparation method of assorted fibre is:
(1), tossa and bombax cotton are put into the phenolic resin aqueous solution that mass fraction is 16 ~ 18% impregnate 25 ~ 45min,
It takes out, washes and dry;
(2), asbestos fibre is put into the potassium hydroxide solution that mass fraction is 22 ~ 27% and impregnates 25 ~ 35min, keep impregnating temperature
Degree is 35 ~ 45 DEG C, is taken out, and is washed and dry;
(3), aforementioned tossa, bombax cotton and asbestos fibre mixed according to proportioning, be then added viscose rayon, stirring is equal
It is even, obtain the composite fibre.
The present invention provides a kind of preparation method for the environmentally friendly particulate composition that can purify air, includes the following steps:
(1), prepare body particles
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil are mixed according to proportioning, are uniformly dispersed, it is dry to containing
Water rate is 5 ~ 10%, and modified pearl rock, P-hydroxybenzoic acid, Ludox, trihydroxy methyl three-glycidyl then is added according to proportioning
Ether and suitable quantity of water, are uniformly dispersed, low temperature drying, and water spray is granulated, and obtains the body particles;
(2), prepare absorption auxiliary particle
According to proportioning by modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, laurene, second
Edetate disodium and suitable quantity of water mixing, are uniformly dispersed, low temperature drying, water spray is granulated, and obtains the absorption auxiliary particle;
(3), by body particles and absorption auxiliary particle according to proportioning be uniformly mixed, obtain it is described can purify air environmental protection
Grain composition.
Beneficial effects of the present invention:It is specific as follows with preferable air-cleaning function:
(1), the present invention using body particles and adsorb auxiliary particle it is combined by the way of obtain particulate composition, to Interior Space
Main polluted gas such as formaldehyde, toluene, dimethylbenzene and sulfur dioxide, nitrogen dioxide, carbon monoxide etc. in gas have good
Selection absorption and photocatalytic degradation function, additionally it is possible to effectively sterilize, absorption minute dusts, eliminate the unusual smell, substantially increase indoor
Air quality improves environment;Body particles have absorption and photocatalytic degradation double action, and absorption auxiliary particle is for absorbing master
Minute dusts in moisture that body particle is generated through photocatalytic degradation, absorption air, moreover it is possible to effective antibacterial and remove peculiar smell, main body
Particle and absorption auxiliary particle cooperate so that particulate composition long action time, had good sustained release effect;
(2), the present invention using modified pearl rock, composite fibre, sepiolite powder, litsea citrate oil, Ludox, nano-titanium dioxide,
P-hydroxybenzoic acid, trihydroxy methyl triglycidyl ether and suitable quantity of water prepare body particles, first will according to proportioning in preparation process
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil mixing, are uniformly dispersed, drying to moisture content is 5 ~ 10%, is adopted
In such a way so that nano-titanium dioxide enters the hole of sepiolite powder under the action of litsea citrate oil, and composite fibre exists
Under the action of litsea citrate oil and nano-titanium dioxide overlap joint adherency forms new fiber-sepiolite structure, which has more preferable
Stability and slow release, then by fiber-sepiolite structure and modified pearl rock, P-hydroxybenzoic acid, Ludox, three hydroxyl first
Base triglycidyl ether and suitable quantity of water are mixed according to proportioning, with the liquid evaporation in Ludox, fiber-sepiolite structure and are changed
Property perlite mutually bond, by granulation of spraying water again, obtain body particles, wherein fiber-sepiolite structure primarily serves light
Catalytic degradation acts on, and modified pearl rock plays suction-operated, and the two combines, and can effectively purify air, and action time is more
Long;
(3), the present invention using modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, bay
Alkene, disodium ethylene diamine tetraacetate and suitable quantity of water prepare absorption auxiliary particle, and plant source concentrate is infiltrated in activated carbon and modified silicon
It is mutually coordinated with antiseptic and laurene in the pore structure of diatomaceous earth, antibacterial action can be played, the gold in air is effectively killed
The bacteriums such as color staphylococcus, Escherichia coli have virus, germ, the acarid etc. in room air and inhibit and kill work(well
Energy.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
A kind of environmentally friendly particulate composition that can purify air, including body particles and absorption auxiliary particle;
The body particles include the raw material of following part meter:45 parts of modified pearl rock, 20 parts of composite fibre, 20 parts of sepiolite powder,
15 ~ part of litsea citrate oil, 15 ~ part of Ludox, 15 parts of nano-titanium dioxide, 12 parts of P-hydroxybenzoic acid, trihydroxy methyl three are shunk sweet
9 parts of oily ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:35 parts of modification infusorial earth, 25 parts of activated carbon, plant source concentrate
25 parts, 14 parts of trihydroxy ethylamine oleate soap, 14 parts of antiseptic, 8 parts of laurene, 5 parts of disodium ethylene diamine tetraacetate and suitable quantity of water;
The mass ratio of the body particles and absorption auxiliary particle is 8:1.
Wherein,
The plant source concentrate includes the raw material of following part meter:11 parts of Rome chamomile, 8 parts of fish pelargonium, the white palm 5 parts, ginger 3
1 part of part, 3 parts of cloves, 1 part of asparagus fern and loquat;
Aforementioned raw material is weighed according to proportioning, co-grinding is added in the ethanol solution of 15 times of weight, leach 15 at 55 DEG C ~
Leaching liquid is obtained by filtration in 20h, and then vacuum distillation obtains plant source concentrate.
Wherein,
The preparation method of the modification infusorial earth:Diatomite is added into 15% manganese chloride solution of 5 times of parts by weight, 45
5h is stirred under the conditions of DEG C, is stood 10h, is isolated sediment, sediment is washed with deionized water, the modification is obtained after drying and grinding
Diatomite.
Wherein,
The modified pearl rock includes the raw material of following part meter:25 parts of perlite, 14 parts of zeolite molecular sieve, 5 parts of barium zirconate, turpentine
5 parts of oil, 3 parts of diaminodiphenyl-methane, 3 parts of liquid rosin resin, 1 part of diisobutyl phthalate, 1 part of stearic acid and 1-
1 part of ethoxy -2- oil-based imidazolines.
Wherein,
The preparation method of the modified pearl rock is:According to proportioning by perlite, zeolite molecular sieve, barium zirconate, phthalic acid
Diisobutyl ester is uniformly mixed, and is added into 5 times of parts by weight water, and suspension is formed, and turpentine oil, diamino-diphenyl first is then added
Alkane, liquid rosin resin, stearic acid and 1- ethoxy -2- oil-based imidazolines, are uniformly dispersed, are dried under the conditions of 55 DEG C, crush,
300 ~ mesh is crossed to sieve to obtain the final product.
Wherein,
The composite fibre includes the raw material of following part meter:17 parts of tossa, 5 parts of bombax cotton, 1 part of asbestos fibre and viscose glue
1 part of fiber;
The preparation method of assorted fibre is:
(1), tossa and bombax cotton are put into the phenolic resin aqueous solution that mass fraction is 16% impregnate 25min, take out,
It washes and dries;
(2), asbestos fibre is put into the potassium hydroxide solution that mass fraction is 22% and impregnates 25min, it is 35 to keep soaking temperature
DEG C, it takes out, washes and dry;
(3), aforementioned tossa, bombax cotton and asbestos fibre mixed according to proportioning, be then added viscose rayon, stirring is equal
It is even, obtain the composite fibre.
A kind of preparation method for the environmentally friendly particulate composition that can purify air is provided in the present embodiment, including is walked as follows
Suddenly:
(1), prepare body particles
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil are mixed according to proportioning, are uniformly dispersed, it is dry to containing
Water rate is 5%, and modified pearl rock, P-hydroxybenzoic acid, Ludox, trihydroxy methyl triglycidyl ether then is added according to proportioning
And suitable quantity of water, it is uniformly dispersed, low temperature drying, water spray is granulated, and obtains the body particles;
(2), prepare absorption auxiliary particle
According to proportioning by modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, laurene, second
Edetate disodium and suitable quantity of water mixing, are uniformly dispersed, low temperature drying, water spray is granulated, and obtains the absorption auxiliary particle;
(3), by body particles and absorption auxiliary particle according to proportioning be uniformly mixed, obtain it is described can purify air environmental protection
Grain composition.
Embodiment 2
A kind of environmentally friendly particulate composition that can purify air, including body particles and absorption auxiliary particle;
The body particles include the raw material of following part meter:50 parts of modified pearl rock, 25 parts of composite fibre, 25 parts of sepiolite powder,
20 parts of litsea citrate oil, 20 parts of Ludox, 20 parts of nano-titanium dioxide, 14 parts of P-hydroxybenzoic acid, trihydroxy methyl three-glycidyl
11 parts of ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:40 parts of modification infusorial earth, 30 parts of activated carbon, plant source concentrate
30 parts, 16 parts of trihydroxy ethylamine oleate soap, 16 parts of antiseptic, 10 parts of laurene, 8 parts of disodium ethylene diamine tetraacetate and suitable quantity of water;
The mass ratio of the body particles and absorption auxiliary particle is 10:1.
Wherein,
The plant source concentrate includes the raw material of following part meter:13 parts of Rome chamomile, 10 parts of fish pelargonium, the white palm 8 parts, ginger
3 parts of 5 parts, 5 parts of cloves, 3 parts of asparagus fern and loquat;
Aforementioned raw material is weighed according to proportioning, co-grinding is added in the ethanol solution of 25 times of weight, 20h, mistake are leached at 65 DEG C
Filter obtains leaching liquid, and then vacuum distillation obtains plant source concentrate.
Wherein,
The preparation method of the modification infusorial earth:Diatomite is added into 30% manganese chloride solution of 10 times of parts by weight,
6h is stirred under the conditions of 55 DEG C, 12h is stood, isolates sediment, sediment is washed with deionized water, and described change is obtained after drying and grinding
Property diatomite.
Wherein,
The modified pearl rock includes the raw material of following part meter:30 parts of perlite, 16 parts of zeolite molecular sieve, 8 parts of barium zirconate, turpentine
8 parts of oil, 5 parts of diaminodiphenyl-methane, 5 parts of liquid rosin resin, 3 parts of diisobutyl phthalate, 3 parts of stearic acid and 1-
3 parts of ethoxy -2- oil-based imidazolines.
The preparation method of the modified pearl rock is:According to proportioning by perlite, zeolite molecular sieve, barium zirconate, adjacent benzene two
Diisobutyl formate is uniformly mixed, and is added into 10 times of parts by weight water, and suspension is formed, and turpentine oil, diamino two is then added
Phenylmethane, liquid rosin resin, stearic acid and 1- ethoxy -2- oil-based imidazolines, are uniformly dispersed, are dried under the conditions of 65 DEG C
It is dry, it crushes, crosses 400 mesh and sieve to obtain the final product.
Wherein,
The composite fibre includes the raw material of following part meter:21 parts of tossa, 11 parts of bombax cotton, 5 parts of asbestos fibre and viscous
5 parts of glue fiber;
The preparation method of assorted fibre is:
(1), tossa and bombax cotton are put into the phenolic resin aqueous solution that mass fraction is 18% impregnate 45min, take out,
It washes and dries;
(2), asbestos fibre is put into the potassium hydroxide solution that mass fraction is 27% and impregnates 35min, it is 45 to keep soaking temperature
DEG C, it takes out, washes and dry;
(3), aforementioned tossa, bombax cotton and asbestos fibre mixed according to proportioning, be then added viscose rayon, stirring is equal
It is even, obtain the composite fibre.
A kind of preparation method for the environmentally friendly particulate composition that can purify air is provided in the present embodiment, including is walked as follows
Suddenly:
(1), prepare body particles
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil are mixed according to proportioning, are uniformly dispersed, it is dry to containing
Water rate is 10%, and modified pearl rock, P-hydroxybenzoic acid, Ludox, trihydroxy methyl triglycidyl ether then is added according to proportioning
And suitable quantity of water, it is uniformly dispersed, low temperature drying, water spray is granulated, and obtains the body particles;
(2), prepare absorption auxiliary particle
According to proportioning by modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, laurene, second
Edetate disodium and suitable quantity of water mixing, are uniformly dispersed, low temperature drying, water spray is granulated, and obtains the absorption auxiliary particle;
(3), by body particles and absorption auxiliary particle according to proportioning be uniformly mixed, obtain it is described can purify air environmental protection
Grain composition.
Embodiment 3
A kind of environmentally friendly particulate composition that can purify air, including body particles and absorption auxiliary particle;
The body particles include the raw material of following part meter:47.5 parts of modified pearl rock, 22.5 parts of composite fibre, sepiolite powder
22.5 parts, 17.5 parts of litsea citrate oil, 17.5 parts of Ludox, 17.5 parts of nano-titanium dioxide, 13 parts of P-hydroxybenzoic acid, three hydroxyl first
10 parts of base triglycidyl ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:37.5 parts of modification infusorial earth, 27.5 parts of activated carbon, plant source are dense
27.5 parts of contracting liquid, 15 parts of trihydroxy ethylamine oleate soap, 15 parts of antiseptic, 9 parts of laurene, 6.5 parts of disodium ethylene diamine tetraacetate and suitable
Measure water;
The mass ratio of the body particles and absorption auxiliary particle is 9:1.
Wherein,
The plant source concentrate includes the raw material of following part meter:112 parts of Rome chamomile, 9 parts of fish pelargonium, the white palm 6 parts, ginger
2 parts of 4 parts, 4 parts of cloves, 2 parts of asparagus fern and loquat;
Aforementioned raw material is weighed according to proportioning, co-grinding is added in the ethanol solution of 20 times of weight, 18h, mistake are leached at 60 DEG C
Filter obtains leaching liquid, and then vacuum distillation obtains plant source concentrate.
Wherein,
The preparation method of the modification infusorial earth:Diatomite is added into 20% manganese chloride solution of 8 times of parts by weight, 50
5.5h is stirred under the conditions of DEG C, 11h is stood, isolates sediment, sediment is washed with deionized water, and described change is obtained after drying and grinding
Property diatomite.
The modified pearl rock includes the raw material of following part meter:27 parts of perlite, 15 parts of zeolite molecular sieve, 6 parts of barium zirconate,
6 parts of turpentine oil, 4 parts of diaminodiphenyl-methane, 4 parts of liquid rosin resin, 2 parts of diisobutyl phthalate, 2 parts of stearic acid
With 2 parts of 1- ethoxy -2- oil-based imidazolines.
Wherein,
The preparation method of the modified pearl rock is:According to proportioning by perlite, zeolite molecular sieve, barium zirconate, phthalic acid
Diisobutyl ester is uniformly mixed, and is added into 8 times of parts by weight water, and suspension is formed, and turpentine oil, diamino-diphenyl first is then added
Alkane, liquid rosin resin, stearic acid and 1- ethoxy -2- oil-based imidazolines, are uniformly dispersed, are dried under the conditions of 60 DEG C, crush,
350 mesh are crossed to sieve to obtain the final product.
Wherein,
The composite fibre includes the raw material of following part meter:20 parts of tossa, 8 parts of bombax cotton, 3 parts of asbestos fibre and viscose glue
3 parts of fiber;
The preparation method of assorted fibre is:
(1), tossa and bombax cotton are put into the phenolic resin aqueous solution that mass fraction is 17% impregnate 35min, take out,
It washes and dries;
(2), asbestos fibre is put into the potassium hydroxide solution that mass fraction is 25% and impregnates 30min, it is 40 to keep soaking temperature
DEG C, it takes out, washes and dry;
(3), aforementioned tossa, bombax cotton and asbestos fibre mixed according to proportioning, be then added viscose rayon, stirring is equal
It is even, obtain the composite fibre.
A kind of preparation method for the environmentally friendly particulate composition that can purify air is provided in the present embodiment, including is walked as follows
Suddenly:
(1), prepare body particles
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil are mixed according to proportioning, are uniformly dispersed, it is dry to containing
Water rate is 5 ~ 10%, and modified pearl rock, P-hydroxybenzoic acid, Ludox, trihydroxy methyl three-glycidyl then is added according to proportioning
Ether and suitable quantity of water, are uniformly dispersed, low temperature drying, and water spray is granulated, and obtains the body particles;
(2), prepare absorption auxiliary particle
According to proportioning by modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, laurene, second
Edetate disodium and suitable quantity of water mixing, are uniformly dispersed, low temperature drying, water spray is granulated, and obtains the absorption auxiliary particle;
(3), by body particles and absorption auxiliary particle according to proportioning be uniformly mixed, obtain it is described can purify air environmental protection
Grain composition.
Present invention has been described in detail with reference to the aforementioned embodiments, for those skilled in the art, according to
So can be with technical scheme described in the above embodiments is modified, or which part technical characteristic is equally replaced
It changes.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention
Protection domain within.
Claims (8)
1. a kind of environmentally friendly particulate composition that can purify air, which is characterized in that including body particles and absorption auxiliary particle;
The body particles include the raw material of following part meter:45 ~ 50 parts of modified pearl rock, 20 ~ 25 parts of composite fibre, sepiolite powder
20 ~ 25 parts, 15 ~ 20 parts of litsea citrate oil, 15 ~ 20 parts of Ludox, 15 ~ 20 parts of nano-titanium dioxide, P-hydroxybenzoic acid 12 ~ 14
Part, 9 ~ 11 parts of trihydroxy methyl triglycidyl ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:35 ~ 40 parts of modification infusorial earth, 25 ~ 30 parts of activated carbon, plant source
25 ~ 30 parts of concentrate, 14 ~ 16 parts of trihydroxy ethylamine oleate soap, 14 ~ 16 parts of antiseptic, 8 ~ 10 parts of laurene, ethylenediamine tetra-acetic acid two
5 ~ 8 parts of sodium and suitable quantity of water;
The mass ratio of the body particles and absorption auxiliary particle is 8 ~ 10:1.
2. the environmentally friendly particulate composition according to claim 1 that air can be purified, which is characterized in that including body particles
With absorption auxiliary particle;
The body particles include the raw material of following part meter:47.5 parts of modified pearl rock, 22.5 parts of composite fibre, sepiolite powder
22.5 parts, 17.5 parts of litsea citrate oil, 17.5 parts of Ludox, 17.5 parts of nano-titanium dioxide, 13 parts of P-hydroxybenzoic acid, three hydroxyl first
10 parts of base triglycidyl ether and suitable quantity of water;
The absorption auxiliary particle includes the raw material of following part meter:37.5 parts of modification infusorial earth, 27.5 parts of activated carbon, plant source are dense
27.5 parts of contracting liquid, 15 parts of trihydroxy ethylamine oleate soap, 15 parts of antiseptic, 9 parts of laurene, 6.5 parts of disodium ethylene diamine tetraacetate and suitable
Measure water;
The mass ratio of the body particles and absorption auxiliary particle is 9:1.
3. the environmentally friendly particulate composition according to claim 1 that air can be purified, which is characterized in that the plant source is dense
Contracting liquid includes the raw material of following part meter:11 ~ 13 parts of Rome chamomile, 8 ~ 10 parts of fish pelargonium, in vain 5 ~ 8 parts of the palm, 3 ~ 5 parts of ginger, fourth
1 ~ 3 part of 3 ~ 5 parts fragrant, 1 ~ 3 part of asparagus fern and loquat;
Aforementioned raw material is weighed according to proportioning, co-grinding is added in the ethanol solution of 15 ~ 25 times of weight, is leached at 55 ~ 65 DEG C
Leaching liquid is obtained by filtration in 15 ~ 20h, and then vacuum distillation obtains plant source concentrate.
4. the environmentally friendly particulate composition according to claim 1 that air can be purified, which is characterized in that the modified diatom
The preparation method of soil:Diatomite is added into 15~30% manganese chloride solution of 5 ~ 10 times of parts by weight, in 45~55 DEG C of items
5~6h is stirred under part, 10 ~ 12h is stood, isolates sediment, sediment is washed with deionized water, and described change is obtained after drying and grinding
Property diatomite.
5. the environmentally friendly particulate composition according to claim 1 that air can be purified, which is characterized in that the modified pearl
Rock includes the raw material of following part meter:25 ~ 30 parts of perlite, 14 ~ 16 parts of zeolite molecular sieve, 5 ~ 8 parts of barium zirconate, 5 ~ 8 parts of turpentine oil,
3 ~ 5 parts of diaminodiphenyl-methane, 3 ~ 5 parts of liquid rosin resin, 1 ~ 3 part of diisobutyl phthalate, 1 ~ 3 part of stearic acid and
1 ~ 3 part of 1- ethoxy -2- oil-based imidazolines.
6. the environmentally friendly particulate composition according to claim 5 that air can be purified, which is characterized in that the modified pearl
The preparation method of rock is:Perlite, zeolite molecular sieve, barium zirconate, diisobutyl phthalate are uniformly mixed according to proportioning,
It is added into 5 ~ 10 times of parts by weight water, forms suspension, turpentine oil, diaminodiphenyl-methane, liquid rosin tree is then added
Fat, stearic acid and 1- ethoxy -2- oil-based imidazolines, are uniformly dispersed, are dried under the conditions of 55 ~ 65 DEG C, crush, and cross 300 ~ 400
Mesh sieves to obtain the final product.
7. the environmentally friendly particulate composition according to claim 1 that air can be purified, which is characterized in that the composite fibre
Include the raw material of following part meter:17 ~ 21 parts of tossa, 5 ~ 11 parts of bombax cotton, 1 ~ 5 part of asbestos fibre and viscose rayon 1 ~ 5
Part;
The preparation method of assorted fibre is:
(1), tossa and bombax cotton are put into the phenolic resin aqueous solution that mass fraction is 16 ~ 18% impregnate 25 ~ 45min,
It takes out, washes and dry;
(2), asbestos fibre is put into the potassium hydroxide solution that mass fraction is 22 ~ 27% and impregnates 25 ~ 35min, keep impregnating temperature
Degree is 35 ~ 45 DEG C, is taken out, and is washed and dry;
(3), aforementioned tossa, bombax cotton and asbestos fibre mixed according to proportioning, be then added viscose rayon, stirring is equal
It is even, obtain the composite fibre.
8. a kind of preparation method for the environmentally friendly particulate composition that air can be purified according to claim 1 ~ 7 any one of them,
It is characterised in that it includes following steps:
(1), prepare body particles
Composite fibre, sepiolite powder, nano-titanium dioxide and litsea citrate oil are mixed according to proportioning, are uniformly dispersed, it is dry to containing
Water rate is 5 ~ 10%, and modified pearl rock, P-hydroxybenzoic acid, Ludox, trihydroxy methyl three-glycidyl then is added according to proportioning
Ether and suitable quantity of water, are uniformly dispersed, low temperature drying, and water spray is granulated, and obtains the body particles;
(2), prepare absorption auxiliary particle
According to proportioning by modification infusorial earth, activated carbon, plant source concentrate, trihydroxy ethylamine oleate soap, antiseptic, laurene, second
Edetate disodium and suitable quantity of water mixing, are uniformly dispersed, low temperature drying, water spray is granulated, and obtains the absorption auxiliary particle;
(3), by body particles and absorption auxiliary particle according to proportioning be uniformly mixed, obtain it is described can purify air environmental protection
Grain composition.
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CN113069877A (en) * | 2021-04-13 | 2021-07-06 | 南京华东电子真空材料有限公司 | High-air-suction-rate environment-friendly hydrogen and water absorbent |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101456698A (en) * | 2008-10-24 | 2009-06-17 | 北京崇高纳米科技有限公司 | Rapid forming high intensity and high functional diatomite composition and method for making the same |
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2018
- 2018-03-12 CN CN201810200064.4A patent/CN108325382A/en not_active Withdrawn
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101456698A (en) * | 2008-10-24 | 2009-06-17 | 北京崇高纳米科技有限公司 | Rapid forming high intensity and high functional diatomite composition and method for making the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113069877A (en) * | 2021-04-13 | 2021-07-06 | 南京华东电子真空材料有限公司 | High-air-suction-rate environment-friendly hydrogen and water absorbent |
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