CN108318175A - A kind of gas pressure sensor device based on graphene conductive characteristic - Google Patents

A kind of gas pressure sensor device based on graphene conductive characteristic Download PDF

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Publication number
CN108318175A
CN108318175A CN201810110663.7A CN201810110663A CN108318175A CN 108318175 A CN108318175 A CN 108318175A CN 201810110663 A CN201810110663 A CN 201810110663A CN 108318175 A CN108318175 A CN 108318175A
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CN
China
Prior art keywords
graphene film
single crystal
crystal silicon
silicon plate
circular single
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810110663.7A
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Chinese (zh)
Inventor
刘灿昌
万磊
孔维旭
刘文晓
秦志昌
周长城
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Shandong University of Technology
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Shandong University of Technology
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Application filed by Shandong University of Technology filed Critical Shandong University of Technology
Priority to CN201810110663.7A priority Critical patent/CN108318175A/en
Publication of CN108318175A publication Critical patent/CN108318175A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L7/00Measuring the steady or quasi-steady pressure of a fluid or a fluent solid material by mechanical or fluid pressure-sensitive elements
    • G01L7/02Measuring the steady or quasi-steady pressure of a fluid or a fluent solid material by mechanical or fluid pressure-sensitive elements in the form of elastically-deformable gauges
    • G01L7/08Measuring the steady or quasi-steady pressure of a fluid or a fluent solid material by mechanical or fluid pressure-sensitive elements in the form of elastically-deformable gauges of the flexible-diaphragm type
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L9/00Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
    • G01L9/02Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means by making use of variations in ohmic resistance, e.g. of potentiometers, electric circuits therefor, e.g. bridges, amplifiers or signal conditioning
    • G01L9/04Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means by making use of variations in ohmic resistance, e.g. of potentiometers, electric circuits therefor, e.g. bridges, amplifiers or signal conditioning of resistance-strain gauges

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Measuring Fluid Pressure (AREA)

Abstract

The present invention is difficult to the present situation measured for gas in closed vessel pressure, proposes a kind of gas in closed vessel device for pressure measurement.Pressure sensor closed container device is made of cylindrical container, low-pressure gas, circular single crystal silicon plate and graphene film.The bridge circuit signal extracting device is made of power supply, resistance, ammeter, voltmeter, switch and conducting wire.Into container, direction is bent under the action of low-pressure gas for circular single crystal silicon plate and graphene film, graphene film length changes, the resistance of graphene film changes with length, corresponding electric current and voltage change will be formed on bridge circuit signal extraction circuit, acquire the variable signal, the resistance variations that graphene film can be obtained by conversion obtain gas in container pressure.

Description

A kind of gas pressure sensor device based on graphene conductive characteristic
Technical field
Patent of the present invention is a kind of gas pressure detection unit, especially a kind of to be used for gas pressure measurement device, is belonged to Art of pressure sensors.
Background technology
Pressure sensor is widely used in automotive system, industrial stokehold, medical diagnosis and monitoring and environmental monitoring In.In pressure sensor, film thickness is the principal element for determining Sensitivity in Pressure Sensors.Monocrystalline silicon can deformation film be One of most widely used material.But integrated piezoresistance sensor is complicated, of high cost in the presence of processing on monocrystalline silicon thin film asks Topic.The resistance uniformity of piezoresistance sensor is difficult to accurately ensure, becomes and restrict what monocrystalline silicon thin film pressure sensor technique improved Problem.Graphene film has the advantages that ultra-thin, intensity super large, the spy changed with length with excellent electric conductivity and resistance Property.Existing graphene processing technology can manufacture the good film of large area, consistency, be pressure sensor and piezoresistance sensor Good alternative materials.Bridge circuit be it is a kind of there is highly sensitive and accuracy measuring circuit, can be with using nonequilibrium bridge The accurate resistance for measuring variation, and then the pressure of gas is measured indirectly.
The present invention can be widely applied to the gas pressure detection work in the fields such as meteorology, chemical industry.
Invention content
The present invention is difficult to the present situation measured for gas in closed vessel pressure, proposes a kind of gas in closed vessel pressure Measuring device.
Scheme is used by patent of the present invention solves its technical problem:The gas pressure based on graphene conductive characteristic Force measuring device, including pressure sensor closed container device, bridge circuit signal extracting device two parts.The pressure sensing Device closed container device, it is characterised in that:The pressure sensor closed container device is by cylindrical container, low-pressure gas, circle Shape monocrystalline silicon plate and graphene film composition.It is filled with low-pressure gas in the cylindrical container so that circular single crystal silicon plate is always It curves inwardly;The circular single crystal silicon plate radius is 2mm, and thickness is 20 μm, is consolidated in cylindrical container upper opening position, with Cylindrical container forms closed container together;The graphene film length is 1mm, and width is 500 μm, thickness 0.35nm, It is adhered to circular single crystal silicon plate lower surface by van der waals force;The graphene film both ends connect conducting wire, are separately connected The both ends a, b of bridge circuit.
The bridge circuit signal extracting device is made of power supply, resistance, ammeter, voltmeter, switch and conducting wire, special Sign is:The power cathode is connect by conducting wire with switch right end, and switch left end is connect by conducting wire with bridge circuit left end, Bridge circuit upper end is connect by conducting wire with ammeter left end, and ammeter right end is connect by conducting wire with voltmeter upper end, voltage Table lower end is connect by conducting wire with bridge circuit lower end, and bridge circuit right end is connect by conducting wire with positive pole;The graphite For alkene film as a resistance on bridge circuit, the both ends a, b on bridge circuit are separately connected a, b two of graphene film End, initial resistivity value when graphene film does not deform is the resistance value of other three fixed value resistances on bridge circuit.
Into container, direction is bent under the action of low-pressure gas for circular single crystal silicon plate and graphene film, graphene film Length changes, and the resistance of graphene film changes with length, will be formed on bridge circuit signal extraction circuit corresponding Electric current and voltage change, acquire the variable signal, the resistance variations of graphene film can be obtained by conversion, obtain container Interior gas pressure.
When circular single crystal silicon plate deforms upon, the numerical value of voltmeter is read, obtaining the pressure difference at plectane center isWherein, P is that container external and internal pressure is poor, and E is the elasticity modulus of circular single crystal silicon plate material, b For the width of graphene film, l is the length of graphene film, and h is the thickness of circular single crystal silicon plate, UgIt is shown for voltmeter Value, a are the radius of circular single crystal silicon plate, and γ is Poisson's ratio, UsFor supply voltage.
The present invention has the following advantages that compared with prior art:
1. graphene film is ultra-thin, intensity super large, the influence to measurement result is small, has excellent electric conductivity.
2. the bridge circuit based on graphene piezoresistance sensor, which is one kind, having the characteristics that highly sensitive and accuracy, utilization are non- Balanced bridge can accurately measure the resistance of variation, measure the pressure of gas indirectly.
Description of the drawings
Fig. 1 pressure sensor closed container schematic diagrames;
Fig. 2 bridge circuit signal extraction schematic diagrames;
Fig. 3 film circular single crystal silicon plate schematic diagrames;
In figure, 1, circular single crystal silicon plate 2, graphene film 3, cylindrical container 4, low-pressure gas 5, ammeter 6, Voltmeter 7, resistance 8, power supply 9, switch 10, resistance 11, resistance
Specific implementation mode
It is described in further detail below in conjunction with attached drawing:
The agent structure of the present embodiment includes pressure sensor closed container device, bridge circuit signal extracting device two Point.The pressure sensor closed container device is thin by cylindrical container 3, low-pressure gas 4, circular single crystal silicon plate 1 and graphene Film 2 forms.Low-pressure gas 4 is filled in the cylindrical container 3 so that circular single crystal silicon plate 1 always curves inwardly;The circle 1 radius of monocrystalline silicon plate is 2mm, and thickness is 20 μm, is consolidated in 3 top of cylindrical container, is formed together with cylindrical container 3 closed Container;2 length of the graphene film is 1mm, and width is 500 μm, thickness 0.35nm, is consolidated under circular single crystal silicon plate 1 Surface, inside closed container;2 both ends of the graphene film connect conducting wire, are separately connected the both ends a, b of bridge circuit.
The bridge circuit signal extracting device by power supply 8, resistance 7, resistance 10, resistance 11, ammeter 5, voltmeter 6, Switch 9 and conducting wire composition, it is characterised in that:8 cathode of the power supply is connect by conducting wire with 9 right end of switch, and 9 left end of switch passes through Conducting wire is connect with bridge circuit left end, and bridge circuit upper end is connect by conducting wire with 5 left end of ammeter, and 5 right end of ammeter passes through Conducting wire is connect with 6 upper end of voltmeter, and 6 lower end of voltmeter is connect by conducting wire with bridge circuit lower end, and bridge circuit right end passes through Conducting wire is connect with 8 anode of power supply;The graphene film 2 is as a resistance on bridge circuit, a, b two on bridge circuit End is separately connected the both ends a, b of graphene film 2, and initial resistivity value when graphene film 2 does not deform is bridge-type electricity The resistance value of 11 3 road resistance 7, resistance 10 and resistance fixed value resistances.
Into container, direction is bent under the action of low-pressure gas 4 for circular single crystal silicon plate 1 and graphene film 2, graphene 2 length of film changes, and then the resistance of graphene film 2 changes with length, on bridge circuit signal extraction circuit just Corresponding electric current and voltage change can be formed, the variable signal is acquired, the resistance that graphene film 2 can be obtained by conversion becomes Change, obtains gas in container pressure.
When circular single crystal silicon plate 1 deforms upon, the numerical value of voltmeter 6 is read, obtaining the pressure difference at plectane center isWherein, P is that container external and internal pressure is poor, and E is the springform of circular single crystal silicon plate material Amount, b are the width of graphene film, and l is the length of graphene film, and h is the thickness of circular single crystal silicon plate, UgIt is aobvious for voltmeter Indicating value, a are the radius of circular single crystal silicon plate, and γ is Poisson's ratio, UsFor supply voltage.
Example 1:The length of graphene film is 1mm, and width is 500 μm, thickness 0.35nm, the half of circular single crystal silicon plate Diameter is 2mm, and circular single crystal silicon plate material Poisson's ratio is 0.35, and the elasticity modulus of circular single crystal silicon plate is 190GPa, external power supply For 2V.
When circular single crystal silicon plate bends, it is 920mV to drive graphene film bending, reading voltmeter numerical value, is calculated It is 13280Pa to obtain pressure difference, it is known that external container is atmospheric pressure, then container internal pressure is 88045Pa.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the scope of the present invention.It is all Within the spirit and principles in the present invention, made by any modification, equivalent replacement and improvement, should be included in of the present invention Within protection domain.

Claims (1)

1. the pressure sensor closed container device by cylindrical container (3), low-pressure gas (4), circular single crystal silicon plate (1) and Graphene film (2) forms;It is filled with low-pressure gas (4) in the cylindrical container (3) so that circular single crystal silicon plate (1) is always It curves inwardly;Circular single crystal silicon plate (1) radius is 2mm, and thickness is 20 μm, is consolidated in above cylindrical container (3), with circle Column type container (3) forms closed container together;Graphene film (2) length is 1mm, and width is 500 μm, and thickness is 0.35nm is consolidated in circular single crystal silicon plate (1) lower surface, inside closed container;Graphene film (2) both ends, which connect, leads Line is separately connected the both ends a, b of bridge circuit;The work of circular single crystal silicon plate (1) and graphene film (2) in low-pressure gas (4) It being bent with the lower direction into container, graphene film (2) length changes, and the resistance of graphene film (2) changes with length, Corresponding electric current and voltage change will be formed on bridge circuit signal extraction circuit, acquires the variable signal, by conversion The resistance variations that can obtain graphene film (2) obtain gas in container pressure;When circular single crystal silicon plate (1) deforms upon When, the numerical value of voltmeter (6) is read, obtaining the pressure difference at plectane center isWherein, P Poor for container external and internal pressure, E is the elasticity modulus of circular single crystal silicon plate material, and b is the width of graphene film, and l is graphene The length of film, h are the thickness of circular single crystal silicon plate, UgFor voltmeter show value, a is the radius of circular single crystal silicon plate, and γ is Poisson's ratio, UsFor supply voltage.
CN201810110663.7A 2018-02-05 2018-02-05 A kind of gas pressure sensor device based on graphene conductive characteristic Pending CN108318175A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108999477A (en) * 2018-09-18 2018-12-14 吉林医药学院 A kind of antitheft sylinder and graphene antitheft sylinder

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CN107359235A (en) * 2017-08-14 2017-11-17 中北大学 A kind of graphene pressure sensor
CN206659811U (en) * 2016-12-02 2017-11-24 华东师范大学 A kind of wearable plantar pressure measuring device based on fexible film pressure sensor
CN107488267A (en) * 2017-07-18 2017-12-19 电子科技大学 High resistive redox grapheme material being modified based on bead and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN206659811U (en) * 2016-12-02 2017-11-24 华东师范大学 A kind of wearable plantar pressure measuring device based on fexible film pressure sensor
CN107488267A (en) * 2017-07-18 2017-12-19 电子科技大学 High resistive redox grapheme material being modified based on bead and preparation method thereof
CN107359235A (en) * 2017-08-14 2017-11-17 中北大学 A kind of graphene pressure sensor

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108999477A (en) * 2018-09-18 2018-12-14 吉林医药学院 A kind of antitheft sylinder and graphene antitheft sylinder
CN108999477B (en) * 2018-09-18 2020-11-06 吉林医药学院 Anti-theft cylinder lock and graphene anti-theft cylinder lock

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