CN108316055A - A kind of fire-retardant paper furniture corrugated paper and preparation method thereof - Google Patents

A kind of fire-retardant paper furniture corrugated paper and preparation method thereof Download PDF

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Publication number
CN108316055A
CN108316055A CN201810261938.7A CN201810261938A CN108316055A CN 108316055 A CN108316055 A CN 108316055A CN 201810261938 A CN201810261938 A CN 201810261938A CN 108316055 A CN108316055 A CN 108316055A
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Prior art keywords
parts
paper
fire
retardant
corrugated paper
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CN201810261938.7A
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Chinese (zh)
Inventor
吴杰
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Ningbo Eon Paper Products Co Ltd
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Ningbo Eon Paper Products Co Ltd
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Priority to CN201810261938.7A priority Critical patent/CN108316055A/en
Publication of CN108316055A publication Critical patent/CN108316055A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07Nitrogen-containing compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/64Alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/12Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34Ignifugeants

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of fire-retardant paper furniture corrugated papers, it is included in 100 parts of magma according to parts by weight and contains 15 parts of modifying agent and 13 parts of fire retardants, wherein the modifying agent includes 50 60 parts of titanium dioxide, 10 15 parts of perlites, 10 15 parts of molybdenum disulfide and 15 parts of rare earth elements by weight;The fire retardant includes 40 50 parts of red phosphorus, 20 30 parts of isocyanuric acid esters, 10 15 parts of hypo-aluminum orthophosphate, 15 parts of sodium hydroxide, 15 parts of maleimide and 15 parts of graphene by weight.Obtained corrugated paper through the invention greatly strengthens the burst index and flame retardant property of corrugated paper so that this corrugated paper has higher intensity and anti-flammability, improves the service life of corrugated case by adding modifying agent and fire retardant in paper making raw material.In addition the sizing agent for using independent research, further increases the intensity of corrugated paper.

Description

A kind of fire-retardant paper furniture corrugated paper and preparation method thereof
Technical field
The present invention relates to paper technology, especially a kind of fire-retardant paper furniture corrugated paper and preparation method thereof.
Background technology
Paper furniture, which is furniture of the material based on papery, can be referred to as paper furniture.Such as corrugated paper furniture.Paper furniture is normal Material is corrugated paper, is distinguished in technique less with the carton in packaging logistics field, surface is exactly brown paper, is only selected With best material, the bearing capacity of itself is stronger, and bigger load-bearing may be implemented by structure design.These furniture are most All be import paper, water proofing property is fine, can waterproof 5 minutes or more, therefore be easy to clean, it is only necessary to be cleaned with wet cloth Just.Compared to antique traditional furniture, the cost of paper furniture is not low, but relative to the antique traditional furniture for having brand, having design, some are general The cost of logical paper furniture or lower, price is also much lower.But still there is certain ask in traditional paper furniture Topic, as anti-flammability is not high.
Invention content
A kind of the main purpose of the present invention is to provide overall construction intensities higher, more environmentally friendly fire-retardant paper furniture With corrugated paper and preparation method thereof.
To achieve the above objectives, the technical solution adopted by the present invention is:A kind of fire-retardant paper furniture corrugated paper, it is described Corrugated paper is included in 100 parts of magma according to parts by weight and contains 1-5 parts of modifying agent and 1-3 parts of fire retardants, wherein the modifying agent Include 50-60 parts of titanium dioxide, 10-15 parts of perlites, 10-15 parts of molybdenum disulfide and 1-5 parts of rare earth elements by weight;It is described Fire retardant is by weight including 40-50 parts of red phosphorus, 20-30 parts of isocyanuric acid esters, 10-15 parts of hypo-aluminum orthophosphate, 1-5 parts of hydrogen Sodium oxide molybdena, 1-5 parts of maleimide and 1-5 parts of graphene.
The surface of the corrugated paper is coated with sizing agent, and wherein sizing agent includes 20-30 parts of nanometer butyronitrile rubbers by weight Glue, 10-15 part epoxy resin, 5-10 parts of phenol-formaldehyde resin modified, 5-10 parts of hydrogels, 20-30 parts of urea and 40-50 parts of water.
A kind of preparation method of fire-retardant paper furniture corrugated paper, includes the following steps:
Step 1: choosing paper making raw material, water is added to carry out bubble slurry, puts into pulper and crush, paper making raw material is made to dissociate into paper pulp;
Step 2: the paper pulp passes through pressurized screen successively and scummer removes impurity;
Step 3: the paper pulp after removal of impurities, which is input to mill, carries out mashing processing, magma is made;
Step 4: 1-5 parts of modifying agent and 1-3 parts of fire retardants are added into 100 parts of magma by weight, it is sufficiently stirred, then Moisture removal is removed, the copy paper that moisture content is 10-20% is obtained and starches,
Step 5: it is 15-25% that copy paper slurry, which is sent to wet end molding dehydration to mass dryness fraction,;
Step 6: slurry after molding is delivered to press section, the slurry press dewatering to mass dryness fraction is 40-50% by press section, so Sizing agent is uniformly applied to by paper surface using sizing applicator afterwards;
Step 7: the sized corrugated paper semi-finished product in surface are put into drying cylinder, temperature is adjusted to 105-110 DEG C, moisture content is in 2- 4%, after being placed on indoor standing 24 hours, further takes out to be placed at aeration-drying and place 24 hours, you can obtain fire-retardant papery man Tool corrugated paper.
The paper making raw material includes 20-30 parts of 70-80 parts of sawdust and waste paper by weight.
The preparation method of the modifying agent is by 50-60 parts of titanium dioxide, 10-15 parts of perlites, 10-15 parts of molybdenum disulfide It is uniformly mixed, then heats while stirring, heating temperature is 200-250 DEG C, is pulverized after cooling with 1-5 parts of rare earth elements End is up to modifying agent.
The preparation method of the fire retardant is first by 40-50 parts of red phosphorus, 20-30 parts of isocyanuric acid esters, 10-15 parts of time Aluminum phosphate and 1-5 parts of graphene are uniformly mixed, and are then placed in reaction kettle, and heating temperature is 600-700 DEG C, heating time 30min is cooled to after 200 DEG C again plus 1-5 parts of sodium hydroxide, 1-5 parts of maleimide, heating time 15min is cooling Grind into powder is up to fire retardant afterwards.
The preparation method of the sizing agent be by 20-30 parts of nanometer nitrile rubbers, 10-15 parts of epoxy resin, 5-10 parts Phenol-formaldehyde resin modified, 5-10 part hydrogel, 20-30 parts of urea and 40-50 parts of water, 50-60 DEG C is heated to after stirring evenly makes respectively Ingredient all dissolves, and waits for that temperature is reduced to room temperature naturally.
Titanium dioxide in the modifying agent can improve the adhesion strength between each raw material, pearl as binder The effect of rock can do thermal insulation material, improve heat resistance, and molybdenum disulfide is used as lubricant, rare earth element promotion above-mentioned active ingredient is sent out It waves, the final intensity for improving corrugated paper.
10-15 parts of hypo-aluminum orthophosphate, 1-5 parts of sodium hydroxide, 1-5 parts of maleimide and 1-5 parts of graphene
Red phosphorus in the fire retardant and isocyanuric acid ester have efficient fire retardant, can improve fire retardancy.Hypo-aluminum orthophosphate There is good thermal stability and anti-flammability with maleimide.Graphene is then used to send out the effect of promoting fire-retardant active ingredient It waves, finally improves its fire retardancy.The properties of corrugated paper made from production method using the present invention and substance index are complete The full requirements for meeting corrugated paper.
Nanometer nitrile rubber, epoxy resin, phenol-formaldehyde resin modified in the sizing agent, can increase substantially top sizing Effect, enhance corrugated paper ring crush intensity.In addition hydrogel is added in corrugated paper Cypres base-material, sizing can be improved The hydrophobicity of paper after agent sizing, while the surface tension between various composition phases can also be improved, it is allowed to be formed uniform and stable Dispersion.
The paper making raw material includes that sawdust and waste paper adapt to the whole society effectively using waste caused by every profession and trade Energy conservation and environmental protection and the circular economy spirit advocated.
A kind of fire-retardant paper furniture corrugated paper and preparation method thereof that the present invention obtains, technique effect is by making Modifying agent and fire retardant are added in paper material, greatly strengthen the burst index and flame retardant property of corrugated paper so that this corrugated paper Have higher intensity and anti-flammability, improves the service life of corrugated case.In addition the sizing agent for using independent research, into one Step improves the intensity of corrugated paper.
Specific implementation mode
It is described below for disclosing the present invention so that those skilled in the art can realize the present invention.It is excellent in being described below Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious modifications.
Embodiment 1:
A kind of fire-retardant paper furniture corrugated paper provided in this embodiment, the corrugated paper are included in 100 parts according to parts by weight Contain 3 parts of modifying agent and 3 parts of fire retardants in magma, wherein the modifying agent includes 50 parts of titanium dioxide, 10 parts of treasure by weight Zhu Yan, 10 parts of molybdenum disulfide and 1 part of rare earth element;The fire retardant is by weight including 40 parts of red phosphorus, 20 parts of isocyanuric acids Ester, 10 parts of hypo-aluminum orthophosphate, 1 part of sodium hydroxide, 1 part of maleimide and 1 part of graphene.
The surface of the corrugated paper be coated with sizing agent, wherein sizing agent by weight include 20 parts of nanometer nitrile rubbers, 10 parts of epoxy resin, 5 parts of phenol-formaldehyde resin modified, 5 parts of hydrogels, 20 parts of urea and 40 parts of water.
A kind of preparation method of fire-retardant paper furniture corrugated paper, includes the following steps:
Step 1: choosing paper making raw material, water is added to carry out bubble slurry, puts into pulper and crush, paper making raw material is made to dissociate into paper pulp;
Step 2: the paper pulp passes through pressurized screen successively and scummer removes impurity;
Step 3: the paper pulp after removal of impurities, which is input to mill, carries out mashing processing, magma is made;
Step 4: 3 parts of modifying agent and 3 parts of fire retardants are added into 100 parts of magma by weight, it is sufficiently stirred, then removes Moisture obtains the copy paper that moisture content is 10-20% and starches,
Step 5: it is 15-25% that copy paper slurry, which is sent to wet end molding dehydration to mass dryness fraction,;
Step 6: slurry after molding is delivered to press section, the slurry press dewatering to mass dryness fraction is 40-50% by press section, so Sizing agent is uniformly applied to by paper surface using sizing applicator afterwards;
Step 7: the sized corrugated paper semi-finished product in surface are put into drying cylinder, temperature is adjusted to 105-110 DEG C, moisture content is in 2- 4%, after being placed on indoor standing 24 hours, further takes out to be placed at aeration-drying and place 24 hours, you can obtain fire-retardant papery man Tool corrugated paper.
The paper making raw material includes 30 parts of 70 parts of sawdust and waste paper by weight.
The preparation method of the modifying agent is by 50 parts of titanium dioxide, 10 parts of perlites, 10 parts of molybdenum disulfide and 1 part of rare earth Element is uniformly mixed, and is then heated while stirring, and heating temperature is 200-250 DEG C, and grind into powder is up to modified after cooling Agent.
The preparation method of the fire retardant is first by 40 parts of red phosphorus, 20 parts of isocyanuric acid esters, 10 parts of hypo-aluminum orthophosphate and 1 The graphene of part is uniformly mixed, and is then placed in reaction kettle, and heating temperature is 600-700 DEG C, heating time 30min, to be cooled After to 200 DEG C again plus 1 part of sodium hydroxide, 1 part of maleimide, heating time 15min, it is cooling after grind into powder to obtain the final product Fire retardant.
The preparation method of the sizing agent is by 20 parts of nanometer nitrile rubbers, 10 parts of epoxy resin, 5 parts of modified phenolic resin Fat, 5 parts of hydrogels, 20 parts of urea and 40 parts of water, 50-60 DEG C is heated to after stirring evenly makes each ingredient all dissolve, and waits for temperature Naturally it is reduced to room temperature.
The pop strength of corrugated paper made from the present embodiment is 730Kpa, and ring crush index is 8.1 Nm/g.This watt simultaneously The excellent flame retardancy of stupefied paper, average ignition time are 50s.
Embodiment 2:
A kind of fire-retardant paper furniture corrugated paper provided in this embodiment and preparation method thereof is substantially same as Example 1, It includes 60 parts of titanium dioxide, 15 parts of perlites, 15 parts of molybdenum disulfide and 5 parts of rare earths that difference, which is the modifying agent by weight, Element.
The pop strength of corrugated paper made from the present embodiment is 700KPa, and ring crush index is 7.9 Nm/g.This watt simultaneously The excellent flame retardancy of stupefied paper, average ignition time are 50s.
Embodiment 3:
A kind of fire-retardant paper furniture corrugated paper provided in this embodiment and preparation method thereof is substantially same as Example 1, Difference be the fire retardant by weight include 50 parts red phosphorus, 30 parts of isocyanuric acid esters, 15 parts of hypo-aluminum orthophosphate, 5 parts Sodium hydroxide, 5 parts of maleimide and 5 parts of graphene.
The pop strength of corrugated paper made from the present embodiment is 710KPa, and ring crush index is 8.0 Nm/g.This watt simultaneously The excellent flame retardancy of stupefied paper, average ignition time are 50s.
Embodiment 4:
A kind of fire-retardant paper furniture corrugated paper provided in this embodiment and preparation method thereof is substantially same as Example 1, It includes 30 parts of nanometer nitrile rubbers, 15 parts of epoxy resin, 10 parts of modified phenolic that difference, which is the sizing agent by weight, Resin, 10 parts of hydrogels, 30 parts of urea and 50 parts of water.
The pop strength of corrugated paper made from the present embodiment is 750KPa, and ring crush index is 8.3 Nm/g.This watt simultaneously The excellent flame retardancy of stupefied paper, average ignition time are 50s.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and Improvement is both fallen in the range of claimed invention.The present invention claims protection domain by appended claims and its Equivalent defines.

Claims (7)

1. a kind of fire-retardant paper furniture corrugated paper, which is characterized in that the corrugated paper is included in 100 parts of originals according to parts by weight In slurry contain 1-5 part modifying agent and 1-3 parts of fire retardants, wherein the modifying agent by weight including 50-60 parts of titanium dioxide, 10-15 parts of perlites, 10-15 parts of molybdenum disulfide and 1-5 parts of rare earth elements;The fire retardant includes 40-50 parts by weight Red phosphorus, 20-30 part isocyanuric acid ester, 10-15 parts of hypo-aluminum orthophosphate, 1-5 parts of sodium hydroxide, 1-5 parts of maleimide and 1-5 parts of graphene.
2. a kind of fire-retardant paper furniture corrugated paper according to claim 1, which is characterized in that the table of the corrugated paper Face is coated with sizing agent, and wherein sizing agent includes 20-30 parts of nanometer nitrile rubbers, 10-15 parts of epoxy resin, 5-10 by weight The phenol-formaldehyde resin modified, 5-10 parts of hydrogels, 20-30 parts of urea and 40-50 parts of water of part.
3. a kind of preparation method of fire-retardant paper furniture corrugated paper as claimed in claim 1 or 2, which is characterized in that packet Include following steps:
Step 1: choosing paper making raw material, water is added to carry out bubble slurry, puts into pulper and crush, paper making raw material is made to dissociate into paper pulp;
Step 2: the paper pulp passes through pressurized screen successively and scummer removes impurity;
Step 3: the paper pulp after removal of impurities, which is input to mill, carries out mashing processing, magma is made;
Step 4: 1-5 parts of modifying agent and 1-3 parts of fire retardants are added into 100 parts of magma by weight, it is sufficiently stirred, then Moisture removal is removed, the copy paper that moisture content is 10-20% is obtained and starches;
Step 5: it is 15-25% that copy paper slurry, which is sent to wet end molding dehydration to mass dryness fraction,;
Step 6: slurry after molding is delivered to press section, the slurry press dewatering to mass dryness fraction is 40-50% by press section, so Sizing agent is uniformly applied to by paper surface using sizing applicator afterwards;
Step 7: the sized corrugated paper semi-finished product in surface are put into drying cylinder, temperature is adjusted to 105-110 DEG C, moisture content is in 2- 4%, after being placed on indoor standing 24 hours, further takes out to be placed at aeration-drying and place 24 hours, you can obtain fire-retardant papery man Tool corrugated paper.
4. a kind of preparation method of fire-retardant paper furniture corrugated paper according to claim 4, it is characterised in that:It is described Paper making raw material includes 20-30 parts of 70-80 parts of sawdust and waste paper by weight.
5. a kind of preparation method of fire-retardant paper furniture corrugated paper according to claim 4, it is characterised in that:It is described The preparation method of modifying agent is by 50-60 parts of titanium dioxide, 10-15 parts of perlites, 10-15 parts of molybdenum disulfide and 1-5 parts of rare earths Element is uniformly mixed, and is then heated while stirring, and heating temperature is 200-250 DEG C, and grind into powder is up to modified after cooling Agent.
6. a kind of preparation method of fire-retardant paper furniture corrugated paper according to claim 4, it is characterised in that:It is described The preparation method of fire retardant is first by 40-50 parts of red phosphorus, 20-30 parts of isocyanuric acid esters, 10-15 parts of hypo-aluminum orthophosphate and 1-5 The graphene of part is uniformly mixed, and is then placed in reaction kettle, and heating temperature is 600-700 DEG C, heating time 30min, to be cooled Add 1-5 parts of sodium hydroxide, 1-5 parts of maleimide, heating time 15min, grind into powder after cooling after to 200 DEG C again Up to fire retardant.
7. a kind of preparation method of fire-retardant paper furniture corrugated paper according to claim 4, it is characterised in that:It is described The preparation method of sizing agent be by 20-30 parts of nanometer nitrile rubbers, 10-15 parts of epoxy resin, 5-10 parts of phenol-formaldehyde resin modified, 5-10 parts of hydrogels, 20-30 parts of urea and 40-50 parts of water, 50-60 DEG C is heated to after stirring evenly makes each ingredient all dissolve, Wait for that temperature is reduced to room temperature naturally.
CN201810261938.7A 2018-03-28 2018-03-28 A kind of fire-retardant paper furniture corrugated paper and preparation method thereof Pending CN108316055A (en)

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CN110080030A (en) * 2019-04-18 2019-08-02 襄阳金飞环彩色包装有限公司 A kind of preparation method of fire-retardant anti-forge paper

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Application publication date: 20180724