CN107200541A - A kind of waste straw composite board and preparation method thereof - Google Patents

A kind of waste straw composite board and preparation method thereof Download PDF

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Publication number
CN107200541A
CN107200541A CN201710483315.XA CN201710483315A CN107200541A CN 107200541 A CN107200541 A CN 107200541A CN 201710483315 A CN201710483315 A CN 201710483315A CN 107200541 A CN107200541 A CN 107200541A
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parts
waste straw
mixture
composite board
straw composite
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胡贤根
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Hefei Feng Feng Agriculture Co Ltd
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Hefei Feng Feng Agriculture Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/30Oxides other than silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/30Oxides other than silica
    • C04B14/305Titanium oxide, e.g. titanates
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The invention discloses a kind of waste straw composite board, include the raw material of following parts by weight:20 30 parts of epoxy glue, 8 12 parts of modifying agent, 80 100 parts of waste straw, 10 15 parts of tackifier, 68 parts of gypsum, 6 12 parts of oyster shell whiting, 24 parts of nano zine oxide, 13 parts of nano titanium oxide, 37 parts of waterproofing agent, 79 parts of fire retardant, 8 14 parts of attapulgite, 25 35 parts of water.The present invention waste straw composite board have intensity height, good moisture resistance, good stability of the dimension, it is corrosion-resistant, prevent it is fire-retardant, elegant in appearance the characteristics of, sheet material avoids the problem of fugitive base, haftplatte and difficult demoulding, largely agricultural stalk is used, reduce cost, resource has been saved, continuous production is realized, production efficiency is substantially increased, technique is concise, with higher practical value and good application prospect.

Description

A kind of waste straw composite board and preparation method thereof
Technical field
Technical field is utilized the present invention relates to agricultural stalk, and in particular to a kind of waste straw composite board and its preparation side Method.
Background technology
Wood-based plate development trend just rapidly to by timber be raw material be transformed into various wood substitutes be raw material transformation.With Agricultural crop straw is primary raw material, Composite wheat straw plate material is produced, with various excellent physical and mechanical properties, incrustation performance And suitability for secondary processing, have become a kind of environment-friendly sheet of high intensity.Such sheet material, is a kind of completely different with conventional panels Bearing structure material, can be applied to architectural engineering, packaging and furniture finishing etc. field, as substitute conventional panels revolutionary character Sheet material.This sheet material has good heat-insulation and heat-preservation, a sound absorbing noise-resistant function, and product strength is big, Anti-moth-eating, anti-mildew, nonflammable, Wood utilization developing Liao Xin roads are substituted for stalk.
The stalk of China has substantial amounts of residue every year, often has centralized burning stalk phenomenon, that is, causes environment Severe contamination, result in the huge waste of resource again.Stalk possesses the spies such as light weight, cost low, fibroid is strong, high insulating effect Point.Agricultural crop straw is the byproduct of quantity maximum in agricultural production, and in recent years, rural economic development is very fast, house condition Improve, 80% family has used electrical equipment and liquefied gas, some use biogas, and warming turns to electricity consumption and uses coal.Therefore, agriculture The people are reduced year by year for the utilization rate of stalk, or even the direct burning having, so, and very big pollution can be not only caused to environment, Bigger economic loss is caused sometimes, and according to data introduction, national stalk comprehensive utilization rate is 24% or so.Agricultural crop straw It is a kind of important physical resources, disposal irrelevantly not only causes the wasting of resources, more seriously environment is caused brokenly It is bad, how to carry out stalk and convert on the spot and deep processing, as assistant officer it is to be solved the problem of, improve stalk utilization, to sustainable agriculture Village's expanding economy, must produce far-reaching influence.Therefore, the straw utilization mode that reform traditional falls behind, develops straw circulating It is economical imperative, how to solve the reasonable whereabouts of stalk, effective Utilizing question and seem particularly urgent, all parts of the country are all positive Explore new way, new method that straw circulating is recycled.
The content of the invention
For the defect of prior art, it is an object of the invention to provide a kind of waste straw composite board, the waste straw Composite board have intensity height, good moisture resistance, good stability of the dimension, it is corrosion-resistant, anti-fire-retardant, elegant in appearance the characteristics of, sheet material is kept away Exempt from the problem of fugitive base, haftplatte and difficult demoulding, largely used agricultural stalk, reduced cost, save resource, the company of realization Continuous metaplasia production, substantially increases production efficiency, and technique is concise, with higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that:
The invention provides a kind of waste straw composite board, include the raw material of following parts by weight:
20-30 parts of epoxy glue, 8-12 parts of modifying agent, 80-100 parts of waste straw, 10-15 parts of tackifier, 6-8 parts of gypsum, shell 6-12 parts of powder, 2-4 parts of nano zine oxide, 1-3 parts of nano titanium oxide, 3-7 parts of waterproofing agent, 7-9 parts of fire retardant, attapulgite 8- 14 parts, 25-35 parts of water.
Preferably, the waste straw composite board includes the raw material of following parts by weight:
It is 25 parts of epoxy glue, 10 parts of modifying agent, 90 parts of waste straw, 13 parts of tackifier, 7 parts of gypsum, 9 parts of oyster shell whiting, nano oxidized 3 parts of zinc, 2 parts of nano titanium oxide, 5 parts of waterproofing agent, 8 parts of fire retardant, 11 parts of attapulgite, 30 parts of water.
Preferably, the modifying agent is that aqueous citric acid solution, aqueous oxalic acid, aqueous maleic acid compare 2 according to weight: 2:The mixture of 3 compositions, the aqueous citric acid solution, aqueous oxalic acid, the mass fraction of aqueous maleic acid are 15- 20%。
Preferably, the waste straw is rice straw, maize straw, reed straw, compares 3 according to weight:1:2 compositions it is mixed Compound.
Preferably, the binding agent is sticky rice juice, white glue with vinyl, urea-formaldehyde glue, compares 3 according to weight:2:The mixture of 1 composition.
Preferably, the waterproofing agent is paraffin and rosin according to weight ratio 2:The mixture of 1 composition.
Preferably, the fire retardant is dicyandiamide, trbasic zinc phosphate and the magnesium hydroxide of 85% concentration, compares 1 according to weight:3:1 The mixture of composition.
The present invention also provides a kind of preparation method of waste straw composite board, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, is dried at 70-80 DEG C to moisture and is 10%-12%, then sends the mixture after drying into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, Crush 80 mesh sieves and obtain mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 300-400r/min, is stirred Mix 20-40 minutes, add oyster shell whiting, nano zine oxide, nano titanium oxide, continue to stir 10-20 minutes, obtain mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 20-30 minutes, speed of agitator 200-300 r/min, then mixture is spread into shaper In, at 80-90 DEG C, suppressed 10-12 minutes to its pressure for applying 40-50MPa, the waste straw composite plate invented Material.
Preferably, the preparation process of the waste straw composite board is:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, and it is 11% to be dried at 75 DEG C to moisture, Then the mixture after drying is sent into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, crush 80 Mesh sieve obtains mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 350r/min, stirring 30 Minute, oyster shell whiting, nano zine oxide, nano titanium oxide are added, continues to stir 15 minutes, obtains mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 25 minutes, speed of agitator 250r/min, then mixture is spread in shaper, 85 At DEG C, suppressed 11 minutes to its pressure for applying 45MPa, the waste straw composite board invented.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of waste straw composite board of the present invention using rice straw, maize straw, reed straw as primary raw material, with These agricultural wastes are major ingredient, on the one hand take full advantage of resource, solve the problem of such discarded object is accumulated for a long time, and due to The string rubbish such as stalk is seen everywhere, inexhaustible, thus use it for produce sheet material cost it is relatively low, meet national hair Open up the strategic requirement of recycling economy, environmental protection.
(2)The nano zine oxide and nano titanium oxide of a kind of waste straw composite board addition of the present invention, on the one hand The anti-wear performance of sheet material can be improved, on the other hand the two has preferable disinfection effect, coordinates the oyster shell whiting of addition, several persons Synergy, has preferable antimildew and antibacterial performance, substantially increases the environmental-protecting performance of sheet material.
(3)A kind of waste straw composite board addition waterproofing agent of the present invention makes it have certain mould proof heat insulation effect, Traditional stalk board short life, inflammable, poor water resistance shortcoming are evaded significantly;The attapulgite of addition, with larger ratio table Area, can effectively be crosslinked with other materials, form fine and close paste elastomer, do not encroached on by thermal expansion, freezing up, so that The sheet material of preparation has an excellent weatherability, and can be in absorption air pollutant, reached the work of preferable purification air With.
(4)A kind of waste straw composite board addition of the present invention has that intensity is high, moisture resistance is good, dimensional stability Good, corrosion-resistant, anti-fire-retardant, elegant in appearance the characteristics of, sheet material avoids the problem of fugitive base, haftplatte and difficult demoulding, largely uses Agricultural stalk, reduces cost, has saved resource, realize continuous production, substantially increases production efficiency, and technique is concise, With higher practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to In the scope of protection of the invention.
Embodiment 1.
A kind of waste straw composite board of the present embodiment, includes the raw material of following parts by weight:
20 parts of epoxy glue, 8 parts of modifying agent, 80 parts of waste straw, 10 parts of tackifier, 6 parts of gypsum, 6 parts of oyster shell whiting, nano zine oxide 2 parts, 1 part of nano titanium oxide, 3 parts of waterproofing agent, 7 parts of fire retardant, 8 parts of attapulgite, 25 parts of water.
Modifying agent in the present embodiment is aqueous citric acid solution, aqueous oxalic acid, aqueous maleic acid according to weight ratio 2:2:The mixture of 3 compositions, the aqueous citric acid solution, aqueous oxalic acid, the mass fraction of aqueous maleic acid are 15%。
Waste straw in the present embodiment is rice straw, maize straw, reed straw, compares 3 according to weight:1:2 compositions Mixture.
Binding agent in the present embodiment is sticky rice juice, white glue with vinyl, urea-formaldehyde glue, compares 3 according to weight:2:The mixture of 1 composition.
Waterproofing agent in the present embodiment is paraffin and rosin according to weight ratio 2:The mixture of 1 composition.
Fire retardant in the present embodiment is dicyandiamide, trbasic zinc phosphate and the magnesium hydroxide of 85% concentration, compares 1 according to weight:3:1 The mixture of composition.
A kind of preparation method of waste straw composite board of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, and it is 10% to be dried at 70 DEG C to moisture, Then the mixture after drying is sent into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, crush 80 Mesh sieve obtains mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 300r/min, stirs 20- 40 minutes, oyster shell whiting, nano zine oxide, nano titanium oxide are added, continues to stir 10 minutes, obtains mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 20 minutes, the r/min of speed of agitator 200, then mixture is spread in shaper, 80 At DEG C, suppressed 10 minutes to its pressure for applying 40MPa, the waste straw composite board invented.
Embodiment 2.
A kind of waste straw composite board of the present embodiment, includes the raw material of following parts by weight:
30 parts of epoxy glue, 12 parts of modifying agent, 100 parts of waste straw, 15 parts of tackifier, 8 parts of gypsum, 12 parts of oyster shell whiting, nano oxygen Change 4 parts of zinc, 3 parts of nano titanium oxide, 7 parts of waterproofing agent, 9 parts of fire retardant, 14 parts of attapulgite, 35 parts of water.
Modifying agent in the present embodiment is aqueous citric acid solution, aqueous oxalic acid, aqueous maleic acid according to weight ratio 2:2:The mixture of 3 compositions, the aqueous citric acid solution, aqueous oxalic acid, the mass fraction of aqueous maleic acid are 20%。
Waste straw in the present embodiment is rice straw, maize straw, reed straw, compares 3 according to weight:1:2 compositions Mixture.
Binding agent in the present embodiment is sticky rice juice, white glue with vinyl, urea-formaldehyde glue, compares 3 according to weight:2:The mixture of 1 composition.
Waterproofing agent in the present embodiment is paraffin and rosin according to weight ratio 2:The mixture of 1 composition.
Fire retardant in the present embodiment is dicyandiamide, trbasic zinc phosphate and the magnesium hydroxide of 85% concentration, compares 1 according to weight:3:1 The mixture of composition.
A kind of preparation method of waste straw composite board of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, and it is 12% to be dried at 80 DEG C to moisture, Then the mixture after drying is sent into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, crush 80 Mesh sieve obtains mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 400r/min, stirring 40 Minute, oyster shell whiting, nano zine oxide, nano titanium oxide are added, continues to stir 20 minutes, obtains mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 30 minutes, the r/min of speed of agitator 300, then mixture is spread in shaper, 90 At DEG C, suppressed 12 minutes to its pressure for applying 50MPa, the waste straw composite board invented.
Embodiment 3.
A kind of waste straw composite board of the present embodiment, includes the raw material of following parts by weight:
It is 25 parts of epoxy glue, 10 parts of modifying agent, 90 parts of waste straw, 13 parts of tackifier, 7 parts of gypsum, 9 parts of oyster shell whiting, nano oxidized 3 parts of zinc, 2 parts of nano titanium oxide, 5 parts of waterproofing agent, 8 parts of fire retardant, 11 parts of attapulgite, 30 parts of water.
Modifying agent in the present embodiment is aqueous citric acid solution, aqueous oxalic acid, aqueous maleic acid according to weight ratio 2:2:The mixture of 3 compositions, the aqueous citric acid solution, aqueous oxalic acid, the mass fraction of aqueous maleic acid are 18%。
Waste straw in the present embodiment is rice straw, maize straw, reed straw, compares 3 according to weight:1:2 compositions Mixture.
Binding agent in the present embodiment is sticky rice juice, white glue with vinyl, urea-formaldehyde glue, compares 3 according to weight:2:The mixture of 1 composition.
Waterproofing agent in the present embodiment is paraffin and rosin according to weight ratio 2:The mixture of 1 composition.
Fire retardant in the present embodiment is dicyandiamide, trbasic zinc phosphate and the magnesium hydroxide of 85% concentration, compares 1 according to weight:3:1 The mixture of composition.
A kind of preparation method of waste straw composite board of the present embodiment, comprises the following steps:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, and it is 11% to be dried at 75 DEG C to moisture, Then the mixture after drying is sent into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, crush 80 Mesh sieve obtains mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 350r/min, stirring 30 Minute, oyster shell whiting, nano zine oxide, nano titanium oxide are added, continues to stir 15 minutes, obtains mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 25 minutes, speed of agitator 250r/min, then mixture is spread in shaper, 85 At DEG C, suppressed 11 minutes to its pressure for applying 45MPa, the waste straw composite board invented.
The performance test results of agricultural stalk regeneration fire preventing and heat insulating board prepared by various embodiments above are as follows:
Tensile strength Mpa Thermal conductivity factor mW/(m·k) Fire protecting performance Thickness swelling rate %
Embodiment 1 15 24 B1 4
Embodiment 2 14 22 B1 5
Embodiment 3 15 25 B1 4
Comparative example 8 80 B2 9
The present invention a kind of waste straw composite board have intensity height, good moisture resistance, good stability of the dimension, it is corrosion-resistant, deter Combustion, it is elegant in appearance the characteristics of, sheet material avoids the problem of fugitive base, haftplatte and difficult demoulding, has largely used agricultural stalk, reduces Cost, has saved resource, has realized continuous production, substantially increases production efficiency, and technique is concise, with higher practical valency Value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It may be appreciated other embodiment.

Claims (9)

1. a kind of waste straw composite board, it is characterised in that include the raw material of following parts by weight:
20-30 parts of epoxy glue, 8-12 parts of modifying agent, 80-100 parts of waste straw, 10-15 parts of tackifier, 6-8 parts of gypsum, shell 6-12 parts of powder, 2-4 parts of nano zine oxide, 1-3 parts of nano titanium oxide, 3-7 parts of waterproofing agent, 7-9 parts of fire retardant, attapulgite 8- 14 parts, 25-35 parts of water.
2. a kind of waste straw composite board according to claim 1, it is characterised in that the waste straw composite board Include the raw material of following parts by weight:
It is 25 parts of epoxy glue, 10 parts of modifying agent, 90 parts of waste straw, 13 parts of tackifier, 7 parts of gypsum, 9 parts of oyster shell whiting, nano oxidized 3 parts of zinc, 2 parts of nano titanium oxide, 5 parts of waterproofing agent, 8 parts of fire retardant, 11 parts of attapulgite, 30 parts of water.
3. a kind of waste straw composite board according to claim 1 or 2, it is characterised in that the modifying agent is lemon Aqueous acid, aqueous oxalic acid, aqueous maleic acid compare 2 according to weight:2:The mixture of 3 compositions, the citric acid is water-soluble Liquid, aqueous oxalic acid, the mass fraction of aqueous maleic acid are 15-20%.
4. a kind of waste straw composite board according to claim 1 or 2, it is characterised in that the waste straw is rice Stalk, maize straw, reed straw, compare 3 according to weight:1:The mixture of 2 compositions.
5. a kind of waste straw composite board according to claim 1 or 2, it is characterised in that the binding agent is glutinous rice Juice, white glue with vinyl, urea-formaldehyde glue, compare 3 according to weight:2:The mixture of 1 composition.
6. a kind of waste straw composite board according to claim 1 or 2, it is characterised in that the waterproofing agent is paraffin With rosin according to weight ratio 2:The mixture of 1 composition.
7. a kind of waste straw composite board according to claim 1 or 2, it is characterised in that the fire retardant is 85% Dicyandiamide, trbasic zinc phosphate and the magnesium hydroxide of concentration, compare 1 according to weight:3:The mixture of 1 composition.
8. a kind of method for preparing waste straw composite board as claimed in claim 1 or 2, it is characterised in that including following step Suddenly:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, is dried at 70-80 DEG C to moisture and is 10%-12%, then sends the mixture after drying into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, Crush 80 mesh sieves and obtain mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 300-400r/min, is stirred Mix 20-40 minutes, add oyster shell whiting, nano zine oxide, nano titanium oxide, continue to stir 10-20 minutes, obtain mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 20-30 minutes, speed of agitator 200-300 r/min, then mixture is spread into shaper In, at 80-90 DEG C, suppressed 10-12 minutes to its pressure for applying 40-50MPa, the waste straw composite plate invented Material.
9. a kind of preparation method of waste straw composite board according to claim 8, it is characterised in that the step For:
Step one, weigh on request and prepare each component raw material;
Step 2, after waste straw is cleaned with clear water, is transported in dryer, and it is 11% to be dried at 75 DEG C to moisture, Then the mixture after drying is sent into UV sterilizing chamber again, then waste straw is added in high speed disintegrator, crush 80 Mesh sieve obtains mixture A;
Step 3, tackifier, modifying agent, gypsum, water is added in homogenizer, speed of agitator is 350r/min, stirring 30 Minute, oyster shell whiting, nano zine oxide, nano titanium oxide are added, continues to stir 15 minutes, obtains mixture B;
Step 4, mixture B, epoxy glue, fire retardant, waterproofing agent, concave convex rod are prepared by mixture step A three prepared by step 2 Soil is added in homogenizer, is stirred 25 minutes, speed of agitator 250r/min, then mixture is spread in shaper, 85 At DEG C, suppressed 11 minutes to its pressure for applying 45MPa, the waste straw composite board invented.
CN201710483315.XA 2017-06-23 2017-06-23 A kind of waste straw composite board and preparation method thereof Withdrawn CN107200541A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108214805A (en) * 2018-01-26 2018-06-29 兰州理工大学 A kind of preparation method of corn stalk composite artificial plate
CN108687928A (en) * 2018-05-25 2018-10-23 柳州市林道科技有限公司 A kind of environment friendly artificial board and its manufacturing process
CN111775263A (en) * 2019-04-03 2020-10-16 万华禾香板业有限责任公司 Shaving board and production method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108214805A (en) * 2018-01-26 2018-06-29 兰州理工大学 A kind of preparation method of corn stalk composite artificial plate
CN108687928A (en) * 2018-05-25 2018-10-23 柳州市林道科技有限公司 A kind of environment friendly artificial board and its manufacturing process
CN111775263A (en) * 2019-04-03 2020-10-16 万华禾香板业有限责任公司 Shaving board and production method thereof

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