CN108314967A - A kind of preparation method of novel super-high performance basement waterproofing material - Google Patents
A kind of preparation method of novel super-high performance basement waterproofing material Download PDFInfo
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- CN108314967A CN108314967A CN201810030250.8A CN201810030250A CN108314967A CN 108314967 A CN108314967 A CN 108314967A CN 201810030250 A CN201810030250 A CN 201810030250A CN 108314967 A CN108314967 A CN 108314967A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B11/00—Layered products comprising a layer of bituminous or tarry substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B11/00—Layered products comprising a layer of bituminous or tarry substances
- B32B11/04—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B11/046—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
The invention discloses a kind of preparation methods of novel super-high performance basement waterproofing material, it is related to building material field, include the preparation of modified pitch A, the preparation of modified pitch B, the preparation of waterproof roll coating material and compound and etc. with tire sill, present invention incorporates two kinds of altered contents of BUTON rock asphalt modified pitch and SBS modified pitch, the two is all physical modification, the modified pitch being individually modified compared to SBS, the incorporation of BUTON rock asphalt can reduce production cost, improve the heat-resisting quantity and segregability of modified pitch, play the role of substituting part SBS modifier, pass through optimize technique formula in the present invention, determine the preferable content of BUTON rock asphalt modified pitch, not only obtain the more excellent performance of modification more independent than SBS, and also a save cost.
Description
Technical field
The present invention relates to building material fields, are related to a kind of preparation method of novel super-high performance basement waterproofing material.
Background technology
Basement roof engineering is an important component of building construction, and quality not only affects making for building
With the service life, and directly affect the normal life of user.Basement roof waterproof coiled material is that current China's basement roof is anti-
The Main of water.Waterproof coiled material has the advantages that light-weight, water resistance is good, and the flexibility of waterproof layer is good, adapts to one
Determine structural vibration and the swell-shrinking deformation of degree, therefore is widely used in basement roof waterproofing work.
With the development of China's economic, society steps up environmental protection, energy-efficient requirement, it is desirable to which the pitch of production will be with it
The advantages that efficient, at low cost, handling ease, performance are high, performance is easily-controllable obtains large-scale application in road construction.Although mesh
Application of the preceding modified pitch on road is more and more, but as rise in oil price causes SBS costs to increase, SBS is modified drip
Green high cost problem becomes the bottleneck for restricting its development.
China Patent Publication No. is that CN106245861A discloses a kind of polyethylene polypropylene fiber composite sheet, including from upper
Be disposed under and sand face layer, polyethylene polypropylene material layer, glass layer, mineral grain layer, tire base, POE plastic layers,
Nonwoven layer, self-adhering rubber waterproof layer and separating film layer.In this kind of waterproof roll, the setting of polyethylene polypropylene material layer increases
The tensile strength of waterproof roll, leakage resistance, deformation is adaptable, and the setting of POE plastic layers makes waterproof roll more flexible
And elasticity, there is good water-proof effect, good toughness can prevent the fracture of waterproof roll, improve the non-deformability of waterproof roll
Adaptability poor and to temperature change, while ensure that the water resistance of waterproof roll entirety.
China Patent Publication No. is that CN104859217A also discloses that a kind of ultralow temperature SBS modified asphalt waterproof coiled materials,
Including tire base, the upper and lower surface of the tire base is provided with hot melt or self-adhesive glue layer；The appearance of the hot melt or self-adhesive glue layer
Separation layer is provided on face.This kind of ultralow temperature SBS modified asphalt waterproof coiled material is reasonable for structure, and cohesive force is good, low temperature resistant good, material
It remains to that water proofing property, the cohesive force having had under low temperature is kept to be particularly suitable for cold district and winter waterproof construction at -50 DEG C.
Different altered contents and composite material has been respectively adopted inside in above two waterproof roll, although all obtaining
The waterproof roll that can be used, but the former uses a variety of composite layers, and corresponding binder is required between each composite layer,
To the more demanding of binder, and using lamination is susceptible to after long, the latter uses a large amount of SBS, of high cost, and
Anti-flammability is bad.
Invention content
Problem to be solved by this invention is to provide a kind of preparation method of novel super-high performance basement waterproofing material.
To achieve the goals above, the technical solution that the present invention takes is：A kind of novel super-high performance underground provided
The preparation method of room waterproof material, it is specific as follows：
A kind of preparation method of novel super-high performance basement waterproofing material, which is characterized in that specific as follows：
（1）Heated substrate pitch is subsequently added into a certain amount of BUTON rock asphalt, is stirred using mixing plant to 138-145 DEG C
1.8-2.2h makes to be uniformly distributed BUTON rock asphalt in matrix pitch, then the good modified pitch A of heating stirring is heated to 190-
195 DEG C, a certain amount of SBS is added, persistently stirs 1.2-1.8h so that is uniform-distribution with SBS in modified pitch A, is modified
Pitch B；
（2）A certain proportion of naphthenic oil, PP, fire-retardant compound material and antioxidant are sequentially added in modified pitch B, then are persistently stirred
Waterproof roll coating material is made in 3-4h；
（3）It selects non-to prolong die mould 180g/m2Polyester base is as tire sill, first in one thickness of surface smear of tire sill
The compound binding agent for being 0.2-0.6mm is spent as adhesive layer, then by step（2）In waterproof roll coating material obtained quickly apply
It is put on adhesive layer, after its cooled and solidified, you can obtain required waterproof material.
Preferably, BUTON rock asphalt in the preparation process of the waterproof roll coating material, SBS, naphthenic oil, PP, fire-retardant multiple
Close the proportioning of material and antioxidant（Mass fraction）For：40%-55%、20%-25%、10%-18%、10%-18%、3%-10%、1%-10%.
Preferably, BUTON rock asphalt in the preparation process of the waterproof roll coating material, SBS, naphthenic oil, PP, fire-retardant multiple
Close the proportioning of material and antioxidant（Mass fraction）For：45%、22%、10%、18%、3%、2%.
Preferably, the step（3）Middle compound binding agent includes mainly following parts by weight of component：Polyene irons resin 60-
2-8 parts of 65 parts, 15-25 parts of coupling molecule, 3-10 parts of polyethylene wax, 2-8 parts of white oil and zinc stearate.
Preferably, the compound binding agent specifically includes following parts by weight of component：Polyene irons 62 parts of resin, coupling molecule 18
Part, 7 parts of polyethylene wax, 5 parts of white oil and 5 parts of zinc stearate.
Preferably, it is 0.8-2.2mm's that the bottom surface of the tire sill is also bonded with a layer thickness by compound binding agent
Polyethylene polypropylene material layer.
Beneficial effects of the present invention：
（1）Present invention incorporates two kinds of altered contents of BUTON rock asphalt modified pitch and SBS modified pitch, and the two is all that physics changes
Property, compared to the modified pitch that SBS is individually modified, the incorporation of BUTON rock asphalt can reduce production cost, improve modified pitch
Heat-resisting quantity and segregability, play the role of substitute part SBS modifier, the present invention in pass through optimize technique formula, determine
The preferable content of BUTON rock asphalt modified pitch not only obtains the more excellent performance of modification more independent than SBS, but also saves
Cost；
（2）The addition of fire-retardant compound material in the present invention improves the overall flame performance of waterproof roll, can adapt to higher
Temperature environment, in addition, being also added into the special compound binding agent matched so that waterproof roll coating material can be with tire sill well
It is bonded together, reduces the lamination of deuterogenesis；
（3）The waterproof roll of the present invention, it is light-weight on the whole, water resistance is good, flexibility is good, non-deformability is strong；
（4）The present invention is also compounded with layer of polyethylene polypropylene fibre material layer in the bottom surface of tire sill, and it is anti-can to further increase it
Deformation and waterproof ability.
Specific implementation mode
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, the embodiment
It is only used for explaining the present invention, be not intended to limit the scope of the present invention..
Embodiment 1
A kind of preparation method of novel super-high performance basement waterproofing material, which is characterized in that specific as follows：
（1）Heated substrate pitch is subsequently added into a certain amount of BUTON rock asphalt to 138 DEG C, stirs 2.2h using mixing plant, makes
It is uniformly distributed BUTON rock asphalt in matrix pitch, then the good modified pitch A of heating stirring is heated to 190 DEG C, is added a certain amount of
SBS, persistently stir 1.8h so that be uniform-distribution with SBS in modified pitch A, obtain modified pitch B；
（2）A certain proportion of naphthenic oil, PP, fire-retardant compound material and antioxidant are sequentially added in modified pitch B, then are persistently stirred
Waterproof roll coating material is made in 4h；
（3）It selects non-to prolong die mould 180g/m2Polyester base is as tire sill, first in one thickness of surface smear of tire sill
The compound binding agent for being 0.2mm is spent as adhesive layer, then by step（2）In waterproof roll coating material rapid application obtained exist
On adhesive layer, after its cooled and solidified, you can obtain required waterproof material.
In the present embodiment, BUTON rock asphalt in the preparation process of the waterproof roll coating material, SBS, naphthenic oil, PP,
The proportioning of fire-retardant compound material and antioxidant（Mass fraction）For：40%、25%、10%、10%、10%、5%.
In the present embodiment, the step（3）Middle compound binding agent includes mainly following parts by weight of component：Polyene irons tree
2 parts of 60 parts of fat, 15 parts of coupling molecule, 3 parts of polyethylene wax, 2 parts of white oil and zinc stearate.
In addition, the bottom surface of the tire sill is also bonded with the polyethylene that a layer thickness is 0.8mm by compound binding agent
Polypropylene fibre material layer.
Embodiment 2
A kind of preparation method of novel super-high performance basement waterproofing material, which is characterized in that specific as follows：
（1）Heated substrate pitch is subsequently added into a certain amount of BUTON rock asphalt to 140 DEG C, stirs 2.0h using mixing plant, makes
It is uniformly distributed BUTON rock asphalt in matrix pitch, then the good modified pitch A of heating stirring is heated to 192 DEG C, is added a certain amount of
SBS, persistently stir 1.5h so that be uniform-distribution with SBS in modified pitch A, obtain modified pitch B；
（2）A certain proportion of naphthenic oil, PP, fire-retardant compound material and antioxidant are sequentially added in modified pitch B, then are persistently stirred
Waterproof roll coating material is made in 3h；
（3）It selects non-to prolong die mould 180g/m2Polyester base is as tire sill, first in one thickness of surface smear of tire sill
The compound binding agent for being 0.5mm is spent as adhesive layer, then by step（2）In waterproof roll coating material rapid application obtained exist
On adhesive layer, after its cooled and solidified, you can obtain required waterproof material.
In the present embodiment, BUTON rock asphalt in the preparation process of the waterproof roll coating material, SBS, naphthenic oil, PP,
The proportioning of fire-retardant compound material and antioxidant（Mass fraction）For：45%、22%、10%、18%、3%、2%.
In the present embodiment, the step（3）Middle compound binding agent includes mainly following parts by weight of component：Polyene irons tree
5 parts of 62 parts of fat, 18 parts of coupling molecule, 7 parts of polyethylene wax, 5 parts of white oil and zinc stearate.
In addition, the bottom surface of the tire sill is also bonded with the polyethylene that a layer thickness is 2.0mm by compound binding agent
Polypropylene fibre material layer.
Embodiment 3
A kind of preparation method of novel super-high performance basement waterproofing material, which is characterized in that specific as follows：
（1）Heated substrate pitch is subsequently added into a certain amount of BUTON rock asphalt to 145 DEG C, stirs 1.8h using mixing plant, makes
It is uniformly distributed BUTON rock asphalt in matrix pitch, then the good modified pitch A of heating stirring is heated to 195 DEG C, is added a certain amount of
SBS, persistently stir 1.2h so that be uniform-distribution with SBS in modified pitch A, obtain modified pitch B；
（2）A certain proportion of naphthenic oil, PP, fire-retardant compound material and antioxidant are sequentially added in modified pitch B, then are persistently stirred
Waterproof roll coating material is made in 4h；
（3）It selects non-to prolong die mould 180g/m2Polyester base is as tire sill, first in one thickness of surface smear of tire sill
The compound binding agent for being 0.6mm is spent as adhesive layer, then by step（2）In waterproof roll coating material rapid application obtained exist
On adhesive layer, after its cooled and solidified, you can obtain required waterproof material.
In the present embodiment, BUTON rock asphalt in the preparation process of the waterproof roll coating material, SBS, naphthenic oil, PP,
The proportioning of fire-retardant compound material and antioxidant（Mass fraction）For：55%、20%、10%、10%、4%、6%.
In the present embodiment, the step（3）Middle compound binding agent includes mainly following parts by weight of component：Polyene irons tree
8 parts of 65 parts of fat, 25 parts of coupling molecule, 10 parts of polyethylene wax, 8 parts of white oil and zinc stearate.
In addition, the bottom surface of the tire sill is also bonded with the polyethylene that a layer thickness is 2.2mm by compound binding agent
Polypropylene fibre material layer.
The performance test results are as follows：
Obviously present invention specific implementation is not subject to the restrictions described above, as long as using methodology and the technical side of the present invention
Case carry out various unsubstantialities improvement, or it is not improved by the present invention design and technical solution directly apply to other fields
It closes, within protection scope of the present invention.
Claims (6)
1. a kind of preparation method of novel super-high performance basement waterproofing material, which is characterized in that specific as follows：
（1）Heated substrate pitch is subsequently added into a certain amount of BUTON rock asphalt, is stirred using mixing plant to 138-145 DEG C
1.8-2.2h makes to be uniformly distributed BUTON rock asphalt in matrix pitch, then the good modified pitch A of heating stirring is heated to 190-
195 DEG C, a certain amount of SBS is added, persistently stirs 1.2-1.8h so that is uniform-distribution with SBS in modified pitch A, is modified
Pitch B；
（2）A certain proportion of naphthenic oil, PP, fire-retardant compound material and antioxidant are sequentially added in modified pitch B, then are persistently stirred
Waterproof roll coating material is made in 3-4h；
（3）It selects non-to prolong die mould 180g/m2Polyester base is as tire sill, first in one thickness of surface smear of tire sill
The compound binding agent for being 0.2-0.6mm is spent as adhesive layer, then by step（2）In waterproof roll coating material obtained quickly apply
It is put on adhesive layer, after its cooled and solidified, you can obtain required waterproof material.
2. a kind of preparation method of novel super-high performance basement waterproofing material according to claim 1, feature exist
In BUTON rock asphalt, SBS, naphthenic oil, PP, fire-retardant compound material and antioxidant in the preparation process of the waterproof roll coating material
Proportioning（Mass fraction）For：40%-55%、20%-25%、10%-18%、10%-18%、3%-10%、1%-10%.
3. a kind of preparation method of novel super-high performance basement waterproofing material according to claim 2, feature exist
In BUTON rock asphalt, SBS, naphthenic oil, PP, fire-retardant compound material and antioxidant in the preparation process of the waterproof roll coating material
Proportioning（Mass fraction）For：45%、22%、10%、18%、3%、2%.
4. a kind of preparation method of novel super-high performance basement waterproofing material according to claim 1, feature exist
In the step（3）Middle compound binding agent includes mainly following parts by weight of component：Polyene irons 60-65 parts of resin, coupling molecule
2-8 parts of 15-25 parts, 3-10 parts of polyethylene wax, 2-8 parts of white oil and zinc stearate.
5. a kind of preparation method of novel super-high performance basement waterproofing material according to claim 4, feature exist
In the compound binding agent specifically includes following parts by weight of component：Polyene irons 62 parts of resin, 18 parts of coupling molecule, polyethylene wax 7
5 parts of part, 5 parts of white oil and zinc stearate.
6. a kind of preparation method of novel super-high performance basement waterproofing material according to claim 1, feature exist
In the bottom surface of the tire sill is also bonded with the polyethylene polypropylene material that a layer thickness is 0.8-2.2mm by compound binding agent
The bed of material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810030250.8A CN108314967A (en) | 2018-01-12 | 2018-01-12 | A kind of preparation method of novel super-high performance basement waterproofing material |
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| CN201810030250.8A CN108314967A (en) | 2018-01-12 | 2018-01-12 | A kind of preparation method of novel super-high performance basement waterproofing material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113444470A (en) * | 2021-07-16 | 2021-09-28 | 安徽省奥佳建材有限公司 | Self-adhesive waterproof coiled material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104553130A (en) * | 2015-01-23 | 2015-04-29 | 唐山东方雨虹防水技术有限责任公司 | Fusible high-performance elastomer modified asphalt waterproof roll |
| CN105419358A (en) * | 2015-12-21 | 2016-03-23 | 潍坊市宏源防水材料有限公司 | High-elongation bituminous waterproof sheet material and preparation method thereof |
| CN106009728A (en) * | 2016-06-21 | 2016-10-12 | 沈阳建筑大学 | Buton rock-modified asphalt waterproof rolling material coating material and technological method thereof |
| CN106279949A (en) * | 2016-08-17 | 2017-01-04 | 山东安之源防水材料有限公司 | A kind of polyethylene polypropylene macromolecule composite flame-proof waterproof roll |
-
2018
- 2018-01-12 CN CN201810030250.8A patent/CN108314967A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104553130A (en) * | 2015-01-23 | 2015-04-29 | 唐山东方雨虹防水技术有限责任公司 | Fusible high-performance elastomer modified asphalt waterproof roll |
| CN105419358A (en) * | 2015-12-21 | 2016-03-23 | 潍坊市宏源防水材料有限公司 | High-elongation bituminous waterproof sheet material and preparation method thereof |
| CN106009728A (en) * | 2016-06-21 | 2016-10-12 | 沈阳建筑大学 | Buton rock-modified asphalt waterproof rolling material coating material and technological method thereof |
| CN106279949A (en) * | 2016-08-17 | 2017-01-04 | 山东安之源防水材料有限公司 | A kind of polyethylene polypropylene macromolecule composite flame-proof waterproof roll |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113444470A (en) * | 2021-07-16 | 2021-09-28 | 安徽省奥佳建材有限公司 | Self-adhesive waterproof coiled material |
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