CN108309819A - A kind of oil-in-water type suncream of high spf value and preparation method thereof - Google Patents
A kind of oil-in-water type suncream of high spf value and preparation method thereof Download PDFInfo
- Publication number
- CN108309819A CN108309819A CN201810413627.8A CN201810413627A CN108309819A CN 108309819 A CN108309819 A CN 108309819A CN 201810413627 A CN201810413627 A CN 201810413627A CN 108309819 A CN108309819 A CN 108309819A
- Authority
- CN
- China
- Prior art keywords
- polyglycereol
- suncream
- ethylhexyl
- minutes
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/496—Triazoles or their condensed derivatives, e.g. benzotriazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of oil-in-water type suncreams of high spf value, which is characterized in that includes the component of following mass percent：Styrene/acrylic (ester) analog copolymer 1 10%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.1 0.5%, polyalcohol 1 5%, EDETATE SODIUM 0.01 0.2%, thickener 0.1 0.5%, Phosphoric acid monohexadecyl ester potassium 0.1 0.5%, 6 distearate 1 5% of polyglycereol, 3 beeswax acid esters 0.1 1% of polyglycereol, moisturizing grease 0.01 10%, butylmethoxydibenzoylmethane 1 5%, ethylhexyl salicylate 1 5%, ethylhexyl methoxy cinnamate 1 10%, Homosalate 1 10%, ethylhexyl methoxy polyacrylonitrile 1 5%, butyl octanol salicylate 1 5%, benzotriazole base dodecyl p cresols 0.1 2%, water surplus.Have the function of good antiultraviolet, repair skin, delaying aging, and safety is good, salubrious non-greasy, it can anti-inflammation and sterilization, nourishes rough skin.
Description
Technical field
The present invention relates to cosmetic fields, and in particular to a kind of oil-in-water type suncream of high spf value and preparation method thereof.
Background technology
Summer is hot, and the ultraviolet light in sunlight is the main reason for causing skin blackening and aging.According to the difference of wavelength,
Ultraviolet light is divided into three kinds:UVA, UVB and UVC.UVA is a kind of longest ultraviolet light of wavelength, not by the ozone layer on atmosphere top
It absorbs, skin corium can be penetrated, can more go deep into skin than UVB, make skin tanning, and cause lipid and collagen impaired, draw
The light aging even cutaneum carcinoma for playing skin even more causes skin so UVA can not only excite pigment synthesis and make the colour of skin " blackening "
The main reason for skin " aging " and microgroove generate.UVB is ultraviolet B radiation, its reachable skin corium leads to skin sun burn,
Erythema, it is tanned phenomena such as, but major part UVB is absorbed by ozone layer, while can be by barriers such as glass, parasols, clothes.UVC meetings
It is almost absorbed by atmosphere, only few situation can go up us and run into.
In daily life, people can inevitably be exposed under ultraviolet light, so needing to protect skin using suncream
Shield.The suncream of different defence grades will be used by being directed to the ultraviolet light of varying strength.The defence index of suncream includes mainly：
PA (Preventive Effect) and SPF (Sun Protection Factor), PA is divided into the incremental PA of protection effect
+、PA++、PA+++；SPF refers to size of the sun-proof skin care product to UV protection ability, and SPF indexes are higher, given to skin
Protective capability it is stronger.
Invention content
The technical problem to be solved in the present invention is to provide a kind of oil-in-water type suncream of high spf value, have anti-well
Ultraviolet light, the effect for repairing skin, delaying aging, and safety is good, salubrious non-greasy, it can anti-inflammation and sterilization, nourishes rough skin.
The specific technical solution to solve the above problems is as follows：
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 1-10%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.1-1.5%, polyalcohol 1-
5%, EDETATE SODIUM 0.01-0.2%, thickener 0.1-0.5%, Phosphoric acid monohexadecyl ester potassium 0.1-0.5%, -6 distearyl of polyglycereol
Acid esters 1-5%, -3 beeswax acid esters 0.1-1% of polyglycereol, moisturizing grease 0.01-10%, butylmethoxydibenzoylmethane
1-5%, ethylhexyl salicylate 1-5%, ethylhexyl methoxy cinnamate 1-10%, Homosalate 1-10%, ethylhexyl
Methoxyl group polyacrylonitrile 1-5%, butyl octanol salicylate 1-5%, benzotriazole base dodecyl p- cresols 0.1-2%, water
Surplus.
Preferably, the polyalcohol is inositol, erythritol, glycerine, maltitol, mannitol, sorbierite, xylose
At least one of alcohol, butanediol, pentanediol and propylene glycol.
Preferably, the thickener be hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, xanthans it is mixed
It closes.
Preferably, the hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, the mass ratio of xanthans are
3：(1-2).
Preferably, the moisturizing grease is butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, polydimethylsiloxanes
The mixing of alkanol.
Preferably, the butanediol cocounut oil acid esters, the quality of lauric alcohol-caprylate/decylate, dimethiconol
The ratio between be 2:2:1.
Preferably, the suncream further includes the preservative of 0.1-0.3wt%, suitable pigment, suitable essence；It is described
Preservative is at least one of methyl hydroxybenzoate, Nipasol.
The present invention also provides a kind of preparation methods of the oil-in-water type suncream of high spf value, include the following steps：1) by benzene
In ethylene/acrylic acid (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then 5-10 points of high speed homogenization dispersion
Clock；2) it by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, polyalcohol and the advance mixing of remaining water, then throws
Enter to emulsify in pot, stir 10-30 minutes, fully adds EDETATE SODIUM, thickener, Phosphoric acid monohexadecyl ester potassium after swelling, heat up
To 75 DEG C；3) by -6 distearate of polyglycereol, -3 beeswax acid esters of polyglycereol, moisturizing grease, butyl methoxy dibenzoyl base
Methane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethylhexyl methoxy polyacrylonitrile, butyl
Octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, and 75 DEG C are warming up under stirring, and dissolving is complete, system
It is spare to obtain oil phase；4) oil phase is slowly pumped into emulsification pot, homogeneous 5-10 minutes, insulated and stirred 30 minutes；5) 45 DEG C are cooled to,
Preservative, pigment, essence is added, stirs evenly, homogeneous 1-3 minutes；It is cooled to room temperature, is discharged.
The present invention has the advantages that：
Ethylhexyl salicylate, ethylhexyl methoxy cinnamate and Homosalate of the present invention mainly absorb UVB wave bands
Ultraviolet light, to prevent skin turn to red because of sun burn；Butylmethoxydibenzoylmethane mainly absorbs the ultraviolet light of UVA wave bands, to
Prevent tanned and induced skin cancer；Benzotriazole base dodecyl p- cresols is effective broad spectrum UV absorbers, especially at it
Its ultra-violet absorber, which absorbs in the very weak regions 330-350nm, larger absorption, to make up the deficiency of other sun-screening agents.
In five kinds of sun-screening agents, ethylhexyl methoxy cinnamate is the fine solvent of other four kinds of sun-screening agents, they have association each other
With the effect of synergy, more stable efficient sun-proof result can be obtained, while improving butylmethoxydibenzoylmethane
Photostability；Butyl octanol salicylate is a kind of auxiliary agent that can improve spf value, compounds five kinds of sun-screening agents, further increases
Spf value gives the protection of skin bigger, while the addition of butyl octanol salicylate, it can be achieved that the up to SPF of SPF50
It is glossy that skin can also be reduced, especially compound ethylhexyl salicylate, further increase the salubrious sense of suncream.
Suncream of the present invention especially merges polyalcohol, thickener, moisturizing grease by reasonably combined so that the present invention
Suncream has the function of repairing skin, delaying aging well, and safety is good, salubrious non-greasy, can anti-inflammation and sterilization, taste
Support skin.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention will be made into one below
Step ground detailed description, embodiments of the present invention are not limited thereto, for not specifically specified technological parameter or condition, can refer to
Routine techniques carries out.
Embodiment 1
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 1%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 1.5%, inositol 2%, red algae sugar
Alcohol 2%, EDETATE SODIUM 0.01%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.36%, xanthans
0.12%, Phosphoric acid monohexadecyl ester potassium 0.5%, -6 distearate 1% of polyglycereol, -3 beeswax acid esters 1% of polyglycereol, butanediol coconut palm
Oleate 1.2%, lauric alcohol-caprylate/decylate 1.2%, dimethiconol 0.6%, butylmethoxy hexichol first
Sulfonyl methane 5%, ethylhexyl salicylate 1%, ethylhexyl methoxy cinnamate 10%, Homosalate 1%, ethylhexyl first
Oxygroup polyacrylonitrile 5%, butyl octanol salicylate 1%, benzotriazole base dodecyl p- cresols 2%, water surplus.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 5 minutes；2) by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, inositol, erythritol and surplus
The remaining advance mixing of water stirs 30 minutes then in input emulsification pot, fully adds EDETATE SODIUM, acrylic acid hydroxyl second after swelling
Ester/sodium acryloyldimethyl taurate copolymers, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) by polyglycereol -6 two
Stearate, -3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethyl silicone polymer
Alcohol, butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl
Hexyl methoxyl group polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, under stirring
75 DEG C are warming up to, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 10 minutes, insulated and stirred
30 minutes；5) 45 DEG C are cooled to, discharging.
Embodiment 2
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 10%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.1%, glycerine 4%, maltose
Alcohol 1%, EDETATE SODIUM 0.2%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.18%, xanthans
0.12%, Phosphoric acid monohexadecyl ester potassium 0.1%, -6 distearate 5% of polyglycereol, -3 beeswax acid esters 0.1% of polyglycereol, butanediol
Cocounut oil acid esters 0.004%, lauric alcohol-caprylate/decylate 0.04%, dimethiconol 0.002%, butylmethoxy
Dibenzoyl methane 1%, ethylhexyl salicylate 5%, ethylhexyl methoxy cinnamate 1%, Homosalate 10%, ethyl
Hexyl methoxyl group polyacrylonitrile 1%, butyl octanol salicylate 5%, benzotriazole base dodecyl p- cresols 0.1%, more than water
Amount.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 10 minutes；2) by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, glycerine, maltitol and surplus
The remaining advance mixing of water stirs 10 minutes then in input emulsification pot, fully adds EDETATE SODIUM, acrylic acid hydroxyl second after swelling
Ester/sodium acryloyldimethyl taurate copolymers, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) by polyglycereol -6 two
Stearate, -3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethyl silicone polymer
Alcohol, butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl
Hexyl methoxyl group polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, under stirring
75 DEG C are warming up to, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 5 minutes, insulated and stirred
30 minutes；5) 45 DEG C are cooled to, discharging.
Embodiment 3
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 5%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.8%, mannitol 1%, sorbierite
2%, EDETATE SODIUM 0.1%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.24%, xanthans 0.08%,
Phosphoric acid monohexadecyl ester potassium 0.3%, -6 distearate 3% of polyglycereol, -3 beeswax acid esters 0.5% of polyglycereol, butanediol coconut oil
Ester 2.4%, lauric alcohol-caprylate/decylate 2.4%, dimethiconol 1.2%, butyl methoxy dibenzoyl base
Methane 3%, ethylhexyl salicylate 2.5%, ethylhexyl methoxy cinnamate 7.5%, Homosalate 9%, ethylhexyl first
Oxygroup polyacrylonitrile 3%, butyl octanol salicylate 4%, benzotriazole base dodecyl p- cresols 1%, water surplus.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 8 minutes；2) by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, mannitol, sorbierite and residue
The advance mixing of water, then input emulsification pot in, stir 20 minutes, fully swelling after add EDETATE SODIUM, hydroxy-ethyl acrylate/
Sodium acryloyldimethyl taurate copolymers, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) polyglycereol -6 two is hard
Resin acid ester, -3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethiconol,
Butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl hexyl
Ylmethoxy polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, are risen under stirring
For temperature to 75 DEG C, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 8 minutes, insulated and stirred 30
Minute；5) 45 DEG C are cooled to, discharging.
Embodiment 4
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 7%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.7%, xylitol 1%, EDTA bis-
Sodium 0.1%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.09%, xanthans 0.03%, cetanol phosphoric acid
Ester potassium 0.4%, -6 distearate 4% of polyglycereol, -3 beeswax acid esters 0.6% of polyglycereol, butanediol cocounut oil acid esters 0.6%, coconut palm
Oleyl alcohol-caprylate/decylate 0.6%, dimethiconol 0.3%, butylmethoxydibenzoylmethane 3%, water
Poplar acid ethylhexyl 2%, ethylhexyl methoxy cinnamate 8%, Homosalate 6%, ethylhexyl methoxy polyacrylonitrile
2%, butyl octanol salicylate 4%, benzotriazole base dodecyl p- cresols 0.9%, Nipasol 0.1%, appropriate pigment,
Appropriate essence, water surplus.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 5 minutes；2) hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, xylitol and remaining water is advance
Mixing stirs 15 minutes then in input emulsification pot, fully adds EDETATE SODIUM, hydroxy-ethyl acrylate/acryloyl after swelling
Dimethyltaurine sodium copolymer, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) by -6 distearate of polyglycereol,
- 3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethiconol, butyl first
Oxygroup dibenzoyl methane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl hexyl methoxy
Base polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, and 75 are warming up under stirring
DEG C, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 10 minutes, insulated and stirred 30 minutes；
5) 45 DEG C are cooled to, Nipasol, pigment, essence is added, stirs evenly, homogeneous 1-3 minutes；It is cooled to room temperature, is discharged.
Embodiment 5
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 2%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 1.3%, butanediol 3%, pentanediol
1%, EDETATE SODIUM 0.01-0.2%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.3%, xanthans
0.2%, Phosphoric acid monohexadecyl ester potassium 0.2%, -6 distearate 2% of polyglycereol, -3 beeswax acid esters 0.3% of polyglycereol, butanediol
Cocounut oil acid esters 2%, lauric alcohol-caprylate/decylate 2%, dimethiconol 1%, butyl methoxy dibenzoyl base
Methane 2.5%, ethylhexyl salicylate 4%, ethylhexyl methoxy cinnamate 6%, Homosalate 9%, ethyl hexyl methoxy
Base polyacrylonitrile 4%, butyl octanol salicylate 3%, benzotriazole base dodecyl p- cresols 1.5%, methyl hydroxybenzoate
0.2%, appropriate pigment, appropriate essence, water surplus.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 10 minutes；2) by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, butanediol, pentanediol and surplus
The remaining advance mixing of water stirs 25 minutes then in input emulsification pot, fully adds EDETATE SODIUM, acrylic acid hydroxyl second after swelling
Ester/sodium acryloyldimethyl taurate copolymers, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) by polyglycereol -6 two
Stearate, -3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethyl silicone polymer
Alcohol, butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl
Hexyl methoxyl group polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, under stirring
75 DEG C are warming up to, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 8 minutes, insulated and stirred
30 minutes；5) 45 DEG C are cooled to, methyl hydroxybenzoate, pigment, essence is added, stirs evenly, homogeneous 1-3 minutes；It is cooled to room temperature, is gone out
Material.
Embodiment 6
A kind of oil-in-water type suncream of high spf value, includes the component of following mass percent：Styrene/acrylic
(ester) analog copolymer 4%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.6%, propylene glycol 2%, EDTA bis-
Sodium 0.07%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.3%, xanthans 0.1%, cetanol phosphoric acid
Ester potassium 0.2%, -6 distearate 2% of polyglycereol, -3 beeswax acid esters 0.4% of polyglycereol, butanediol cocounut oil acid esters 4%, cocounut oil
Alcohol-caprylate/decylate 4%, dimethiconol 2%, butylmethoxydibenzoylmethane 4%, salicylic acid second
The own ester 3% of base, ethylhexyl methoxy cinnamate 3%, Homosalate 5%, ethylhexyl methoxy polyacrylonitrile 2%, butyl
Octanol salicylate 4%, benzotriazole base dodecyl p- cresols 0.6%, methyl hydroxybenzoate 0.1%, Nipasol 0.2%, color
Plain appropriate, appropriate essence, water surplus.
The preparation method of above-described embodiment, includes the following steps：
1) by styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed
Homogenous disperse 5 minutes；2) hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, propylene glycol and remaining water is advance
Mixing stirs 30 minutes then in input emulsification pot, fully adds EDETATE SODIUM, hydroxy-ethyl acrylate/acryloyl after swelling
Dimethyltaurine sodium copolymer, xanthans, Phosphoric acid monohexadecyl ester potassium, are warming up to 75 DEG C；3) by -6 distearate of polyglycereol,
- 3 beeswax acid esters of polyglycereol, butanediol cocounut oil acid esters, lauric alcohol-caprylate/decylate, dimethiconol, butyl first
Oxygroup dibenzoyl methane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethyl hexyl methoxy
Base polyacrylonitrile, butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, and 75 are warming up under stirring
DEG C, dissolving is complete, and it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 10 minutes, insulated and stirred 30 minutes；
5) 45 DEG C are cooled to, methyl hydroxybenzoate, Nipasol, pigment, essence is added, stirs evenly, homogeneous 1-3 minutes；Room temperature is cooled to,
Discharging.
Comparative example 1
The difference is that, butylmethoxydibenzoylmethane is not added with embodiment 3.
Comparative example 2
The difference is that, ethylhexyl salicylate is not added with embodiment 3.
Comparative example 3
The difference is that, ethylhexyl methoxy cinnamate is not added with embodiment 3.
Comparative example 4
The difference is that, Homosalate is not added with embodiment 3.
Comparative example 5
The difference is that, butyl octanol salicylate is not added with embodiment 3.
Comparative example 6
The difference is that, benzotriazole base dodecyl p- cresols is not added with embodiment 3.
It is the spf value test of embodiment 1-6, comparative example 1-6 suncreams below：Test method be according to《Cosmetics health
Specification》Four (one) sun care preparations SPF (spf value) of Ministry of Health of the People's Republic of China's in January, 2007 Part V is surveyed
Determine method (page 283) to test, subject totally 20 people, wherein male 5 people, 15 people of female, the age between 18-45 Sui, measurement
As a result meet detection method requirement, suncream spf value result is seen below：
Table 1:Spf value is tested
| Spf value | |
| Embodiment 1 | 47 |
| Embodiment 2 | 47 |
| Embodiment 3 | 47 |
| Embodiment 4 | 48 |
| Embodiment 5 | 50 |
| Embodiment 6 | 49 |
| Comparative example 1 | 30 |
| Degree ratio 2 | 31 |
| Comparative example 3 | 30 |
| Comparative example 4 | 32 |
| Comparative example 5 | 33 |
| Comparative example 6 | 32 |
Spf value test result, which shows embodiment product, higher SPF.Pass through embodiment 1-6 and comparative example 1-
6 comparisons are it is found that butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Hu Moliu
Ester, butyl octanol salicylate, benzotriazole base dodecyl p- cresols be the key that suncream obtain higher SPF at
Point, and butylmethoxydibenzoylmethane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, fourth
The effect of suncream is just apparent when base octanol salicylate, benzotriazole base dodecyl p- cresols share, and embodies collaboration and increases
The effect of effect.
It randomly selects 140 people to try out embodiment 1-6, comparative example 1-6, every morning using once, uses 1 altogether
Month.Result on trial is counted, every using effect total score is 5 points：5 points are best result, indicate fine；4 points are preferable；3 points is can
Receive；2 points are bad；1 point is that cannot receive.It is every average below, as shown in table 2：
Table 2
Can be obtained by upper table, suncream of the invention have it is good using salubrious sense, skin nourishment degree, anti-inflammatory effects,
Skin effects, desalination microgroove effect are repaired, comparative example product is much better than.
The above described is only a preferred embodiment of the present invention, limitation in any form not is done to the present invention, therefore
All contents without departing from technical solution of the present invention, it is made to the above embodiment according to the technical essence of the invention any simply to repair
Change, equivalent variations and modification, in the range of still falling within technical solution of the present invention.
Claims (8)
1. a kind of oil-in-water type suncream of high spf value, which is characterized in that include the component of following mass percent：Styrene/
It is acrylic acid (ester) analog copolymer 1-10%, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.1-0.5%, more
First alcohol 1-5%, EDETATE SODIUM 0.01-0.2%, thickener 0.1-0.5%, Phosphoric acid monohexadecyl ester potassium 0.1-0.5%, polyglycereol -6
Distearate 1-5%, -3 beeswax acid esters 0.1-1% of polyglycereol, moisturizing grease 0.01-10%, butyl methoxy dibenzoyl
Methylmethane 1-5%, ethylhexyl salicylate 1-5%, ethylhexyl methoxy cinnamate 1-10%, Homosalate 1-10%, second
Base hexyl methoxyl group polyacrylonitrile 1-5%, butyl octanol salicylate 1-5%, benzotriazole base dodecyl p- cresols 0.1-
2%, water surplus.
2. suncream according to claim 1, which is characterized in that the polyalcohol be inositol, erythritol, glycerine,
At least one of maltitol, mannitol, sorbierite, xylitol, butanediol, pentanediol and propylene glycol.
3. suncream according to claim 1, which is characterized in that the thickener is hydroxy-ethyl acrylate/acryloyl two
The mixing of N-methyltaurine sodium copolymer, xanthans.
4. suncream according to claim 3, which is characterized in that the hydroxy-ethyl acrylate/acryloyldimethyl ox sulphur
Sour sodium copolymer, xanthans mass ratio be 3：(1-2).
5. suncream according to claim 1, which is characterized in that the moisturizing grease is butanediol cocounut oil acid esters, cocounut oil
The mixing of alcohol-caprylate/decylate, dimethiconol.
6. suncream according to claim 5, which is characterized in that the butanediol cocounut oil acid esters, lauric alcohol-caprylate/
Decylate, dimethiconol mass ratio be 2:2:1.
7. suncream according to claim 1, which is characterized in that the suncream further includes the anti-corrosion of 0.1-0.3wt%
Agent, suitable pigment, suitable essence；The preservative is at least one of methyl hydroxybenzoate, Nipasol.
8. a kind of method preparing claim 1-6 any one of them suncreams, which is characterized in that include the following steps：1)
By in styrene/acrylic (ester) analog copolymer and part water input emulsification pot, 55 DEG C are warming up to, then high speed homogenization disperses 5-
10 minutes；2) by hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, polyalcohol and the advance mixing of remaining water, so
It afterwards in input emulsification pot, stirs 10-30 minutes, fully adds EDETATE SODIUM, thickener, Phosphoric acid monohexadecyl ester potassium after swelling,
It is warming up to 75 DEG C；3) by -6 distearate of polyglycereol, -3 beeswax acid esters of polyglycereol, moisturizing grease, butylmethoxy hexichol first
Sulfonyl methane, ethylhexyl salicylate, ethylhexyl methoxy cinnamate, Homosalate, ethylhexyl methoxy polyacrylonitrile,
Butyl octanol salicylate, benzotriazole base dodecyl p- cresols put into oil phase pot, and 75 DEG C are warming up under stirring, has been dissolved
Entirely, it is spare that oil phase is made；4) oil phase is slowly pumped into emulsification pot, homogeneous 5-10 minutes, insulated and stirred 30 minutes；5) it cools to
45 DEG C, preservative, pigment, essence is added, stirs evenly, homogeneous 1-3 minutes；It is cooled to room temperature, is discharged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810413627.8A CN108309819A (en) | 2018-04-29 | 2018-04-29 | A kind of oil-in-water type suncream of high spf value and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810413627.8A CN108309819A (en) | 2018-04-29 | 2018-04-29 | A kind of oil-in-water type suncream of high spf value and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108309819A true CN108309819A (en) | 2018-07-24 |
Family
ID=62896472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810413627.8A Withdrawn CN108309819A (en) | 2018-04-29 | 2018-04-29 | A kind of oil-in-water type suncream of high spf value and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108309819A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077974A (en) * | 2018-08-27 | 2018-12-25 | 天津市康婷生物工程有限公司 | One kind having the anti-sweat type all band sunlight screening skin-protecting product of waterproof |
| CN109199954A (en) * | 2018-10-25 | 2019-01-15 | 广州睿森生物科技有限公司 | A kind of isolation ultra light sun block lotion and preparation method thereof |
| CN111714389A (en) * | 2020-07-28 | 2020-09-29 | 广州美兮生物科技有限公司 | Compound sunscreen agent, sunscreen cosmetic and preparation method thereof |
-
2018
- 2018-04-29 CN CN201810413627.8A patent/CN108309819A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077974A (en) * | 2018-08-27 | 2018-12-25 | 天津市康婷生物工程有限公司 | One kind having the anti-sweat type all band sunlight screening skin-protecting product of waterproof |
| CN109199954A (en) * | 2018-10-25 | 2019-01-15 | 广州睿森生物科技有限公司 | A kind of isolation ultra light sun block lotion and preparation method thereof |
| CN111714389A (en) * | 2020-07-28 | 2020-09-29 | 广州美兮生物科技有限公司 | Compound sunscreen agent, sunscreen cosmetic and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105434188B (en) | Suncream and its preparation method | |
| CN107233220B (en) | Alcohol-based sunscreen oil and preparation method thereof | |
| CN107625660A (en) | A kind of transparent sun-proof oleogel and preparation method thereof | |
| CN108309819A (en) | A kind of oil-in-water type suncream of high spf value and preparation method thereof | |
| CN102327196A (en) | Sun-proof BB (Blemish Balm) cream and preparation method thereof | |
| BR9917231B1 (en) | Sunscreen composition. | |
| CN103006519A (en) | Natural plant sun-screening agent as well as preparation method and application of natural plant sun-screening agent | |
| CN110075007A (en) | With waterproof, the oil-in-water sunscreen product for improving skin elasticity and preparation method thereof | |
| CN105997642B (en) | A kind of skin boudoir honey frost and preparation method thereof | |
| CN109077974B (en) | Waterproof and sweat-resistant all-band sunscreen skin care product | |
| KR20110056253A (en) | Cosmetic composition containing inorganic powder | |
| CN109199954A (en) | A kind of isolation ultra light sun block lotion and preparation method thereof | |
| CN107625654A (en) | A kind of efficiently water-in-oil type sunscreen and preparation method thereof | |
| CN103083203A (en) | Sunscreen composition and preparation method thereof | |
| KR101250074B1 (en) | UV protecting cosmetic composite with no emulsifiers | |
| CN110025548A (en) | A kind of natural plant sun composition and preparation method thereof | |
| CN114042002A (en) | Mild and full-green sun block capable of remarkably increasing SPF (specific pathogen free) and preparation method thereof | |
| JPS62234012A (en) | Anti-suntan cosmetic | |
| CN116966117A (en) | Sun-screening composition and preparation method and application thereof | |
| KR102122720B1 (en) | Cosmetic Composition for UV and Bule-light Protection | |
| CN101161231A (en) | Ocean medicine hairdressing sun cream containing shuck powder | |
| CN106109256B (en) | CC frost | |
| CN109316395A (en) | A kind of fullerene suncream | |
| CN106983685A (en) | A kind of suntan lotion and preparation method thereof | |
| CN108210401A (en) | A kind of sun-proof synergistic compound and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180724 |