CN108299724A - A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation - Google Patents
A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation Download PDFInfo
- Publication number
- CN108299724A CN108299724A CN201711494805.6A CN201711494805A CN108299724A CN 108299724 A CN108299724 A CN 108299724A CN 201711494805 A CN201711494805 A CN 201711494805A CN 108299724 A CN108299724 A CN 108299724A
- Authority
- CN
- China
- Prior art keywords
- parts
- crosslinking agent
- halogen
- polystyrene
- stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of CABLE MATERIALSs and preparation method thereof of high-strength anti-flaming insulation, include being prepared by the raw material of following parts by weight：40 parts of acrylic rubber ACM30,20 35 parts of tributyl citrate, 20 35 parts of linear low density polyethylene, 10 15 parts of polystyrene, 10 20 parts of high wear-resistant carbon black, 15 30 parts of calcined kaolin, 15 35 parts of MBS resins, 12 parts of hydroxymethyl starch.The present invention is added in combination antioxidant, lubricant, vulcanizing agent, crosslinking agent, halogen-free flame retardants, stabilizer and crosslinking agent using the proportioning of the above-mentioned raw materials such as acrylic rubber ACM, tributyl citrate, linear low density polyethylene, polystyrene, high wear-resistant carbon black, calcined kaolin, MBS resins, oleamide melamine pyrophosphate progress science and carries out reaction fusion, process of preparing is simple, prepared product has preferable fire protection flame retarding, insulation performance, is suitble to use in multiple fields.
Description
Technical field
The present invention relates to technical field of cable production, and in particular to a kind of CABLE MATERIALS of high-strength anti-flaming insulation and its preparation
Method.
Background technology
Currently, with the development of the social economy, electric wire dosage increases rapidly, it is also continuous to the quality requirement of cable
It improves, such as the cable used in the industries such as steel, metallurgy, electric power, chemical industry, oil, service life, anti-electromagnetism to cable
Requirement in terms of interference, pull resistance, shielding properties and high temperature resistant is all especially high, only meets the requirements, and could improve these
Safety when being manufactured in field.
Electric power is the energy using electric energy as power, and the invention and application of electric power have started second of industrialization climax, from
This science and technology changes people’s lives.In order to ensure the Electrical Safety of people, need on the electric equipment products surface for there are insulating requirements
Coat insulating materials.Insulating materials be for making device in the material electrically to insulate, that is, can prevent electric current by
Material.Its resistivity is very high, has good electrical insulation capability and high-temperature physical property, also has long shelf-life, moisture resistivity
The features such as good and fire-retardant.
Invention content
To solve the above problems, the present invention provides a kind of CABLE MATERIALSs and preparation method thereof of high-strength anti-flaming insulation.
To achieve the above object, the technical solution that the present invention takes is：
A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation, includes being prepared by the raw material of following parts by weight：Third
ACM30-40 parts of olefin(e) acid ester rubber, 20-35 parts of tributyl citrate, 20-35 parts of linear low density polyethylene, polystyrene 10-
15 parts, 10-20 parts of high wear-resistant carbon black, 15-30 parts of calcined kaolin, 15-35 parts of MBS resins, 1-2 parts of hydroxymethyl starch, trimerization
5-10 parts of pyrophosphate, 1-10 parts of nano-titanium dioxide, 1-5 parts of butyl rubber, 2-5 parts of hypo-aluminum orthophosphate, nanometer jade powder
5-10 parts, 10-30 parts of antioxidant, 10-20 parts of lubricant, 10-30 parts of vulcanizing agent, 10-20 parts of crosslinking agent, halogen-free flame retardants 15-
2-7 parts of 35 parts, 1-10 parts of stabilizer and crosslinking agent.
Further, the antioxidant is antioxidant 224, and the lubricant is oleamide, erucyl amide, polystyrene
One or more in wax, the vulcanizing agent is benzoyl peroxide, and the crosslinking agent is peroxy ketal, the halogen-free flame retardants
For phosphorus series non-halogen fire retardant, the stabilizer is magnesium stearate.
Further, a kind of CABLE MATERIALS of high-strength anti-flaming insulation, includes being prepared by the raw material of following parts by weight：Third
ACM32-38 parts of olefin(e) acid ester rubber, 22-30 parts of tributyl citrate, 23-30 parts of linear low density polyethylene, polystyrene 12-
14 parts, 11-18 parts of high wear-resistant carbon black, 16-20 parts of calcined kaolin, 23-28 parts of MBS resins, 1-2 parts of hydroxymethyl starch, trimerization
6-9 parts of pyrophosphate, 3-7 parts of nano-titanium dioxide, 2-4 parts of butyl rubber, 3-5 parts of hypo-aluminum orthophosphate, nanometer jade powder 6-9
Part, 15-26 parts of antioxidant, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, 14-19 parts of crosslinking agent, 22-29 parts of halogen-free flame retardants,
3-6 parts of 3-9 parts of stabilizer and crosslinking agent.
Further, a kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation, includes the following steps：
S1, by 23-30 parts of linear low density polyethylene, 12-14 parts of polystyrene, 2-4 parts of butyl rubber, 3-5 parts of hypo-aluminum orthophosphate
It is uniform that mixing is carried out by mixing stove；Then 15-26 parts of antioxidant, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, crosslinking is added
3-6 parts of 14-19 parts of agent, 22-29 parts of halogen-free flame retardants, 3-9 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, ACM32-38 parts of acrylic rubber, 11-18 parts of high wear-resistant carbon black, 16-20 parts of calcined kaolin, methylol are formed sediment
1-2 parts of powder is calcined 2-4 hours at 400-600 DEG C, and 22-30 parts of the tributyl citrate of 3-4% is added, it is small to be ground 1-2
When, the hydrochloric acid solution of 12-15% is added, adjusting pH value is 4-5, is aged 10-15 hours, then adding citric acid tributyl adjusts grinding
Liquid pH is neutrality, and filtering dries and obtains filler powder；Melamine pyrophosphate 6-9 parts again, 3-7 parts of nano-titanium dioxide, receive
6-9 parts of jade powder of rice is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is uniformly dispersed, obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 110-140 DEG C of temperature, then
With, by being molded on cable extruding machine, obtain fire-resistant cable material together with metal core wire.
Further, a kind of CABLE MATERIALS of high-strength anti-flaming insulation, includes being prepared by the raw material of following parts by weight：Third
ACM35 parts of olefin(e) acid ester rubber, 25 parts of tributyl citrate, 27 parts of linear low density polyethylene, 13 parts of polystyrene, high abrasion charcoal
Black 16 parts, 18 parts of calcined kaolin, 25 parts of MBS resins, 1 part of hydroxymethyl starch, 7 parts of melamine pyrophosphate, nano-silica
Change 5 parts of titanium, 3 parts of butyl rubber, 7 parts of 4 part, nanometer jade powder of hypo-aluminum orthophosphate, 19 parts of antioxidant, 17 parts of lubricant, vulcanizing agent 16
Part, 17 parts of crosslinking agent, 26 parts of halogen-free flame retardants, 5 parts of stabilizer and 4 parts of crosslinking agent.
The present invention is resistance to using acrylic rubber ACM, tributyl citrate, linear low density polyethylene, polystyrene, height
Grind carbon black, calcined kaolin, MBS resins, oleamide melamine pyrophosphate, nano-titanium dioxide, butyl rubber, secondary phosphorus
The proportioning that the above-mentioned raw materials such as sour aluminium, nanometer jade powder carry out science is added in combination antioxidant, lubricant, vulcanizing agent, crosslinking agent, nothing
Halogen fire retardant, stabilizer and crosslinking agent carry out reaction fusion, and process of preparing is simple, and prepared product has preferable anti-
Fiery fire-retardant, insulation performance is suitble to use in multiple fields.
Specific implementation mode
In order to make objects and advantages of the present invention be more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention include include being prepared by the raw material of following parts by weight：ACM30-40 parts of acrylic rubber, lemon
Sour tributyl 20-35 parts, 20-35 parts of linear low density polyethylene, 10-15 parts of polystyrene, 10-20 parts of high wear-resistant carbon black, forge
Burn 15-30 parts of kaolin, 15-35 parts of MBS resins, 1-2 parts of hydroxymethyl starch, 5-10 parts of melamine pyrophosphate, nanometer two
1-10 parts of titanium oxide, 1-5 parts of butyl rubber, 2-5 parts of hypo-aluminum orthophosphate, 5-10 parts of nanometer jade powder, 10-30 parts of antioxidant, lubrication
10-20 parts of agent, 10-30 parts of vulcanizing agent, 10-20 parts of crosslinking agent, 15-35 parts of halogen-free flame retardants, 1-10 parts of stabilizer and crosslinking agent
2-7 parts.
The antioxidant is antioxidant 224, and the lubricant is one in oleamide, erucyl amide, polystyrene wax
Kind or it is a variety of, the vulcanizing agent be benzoyl peroxide, the crosslinking agent be peroxy ketal, the halogen-free flame retardants be phosphorus system without
Halogen fire retardant, the stabilizer are magnesium stearate.
A kind of CABLE MATERIALS of high-strength anti-flaming insulation, includes being prepared by the raw material of following parts by weight：Acrylate rubber
ACM32-38 parts of glue, 22-30 parts of tributyl citrate, 23-30 parts of linear low density polyethylene, 12-14 parts of polystyrene, height are resistance to
Grind 11-18 parts of carbon black, 16-20 parts of calcined kaolin, 23-28 parts of MBS resins, 1-2 parts of hydroxymethyl starch, melamine pyrophosphoric
6-9 parts of salt, 3-7 parts of nano-titanium dioxide, 2-4 parts of butyl rubber, 3-5 parts of hypo-aluminum orthophosphate, 6-9 parts of nanometer jade powder, antioxidant
15-26 parts, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, 14-19 parts of crosslinking agent, 22-29 parts of halogen-free flame retardants, stabilizer 3-9
3-6 parts of part and crosslinking agent.
A kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation, includes the following steps：
S1, by 23-30 parts of linear low density polyethylene, 12-14 parts of polystyrene, 2-4 parts of butyl rubber, 3-5 parts of hypo-aluminum orthophosphate
It is uniform that mixing is carried out by mixing stove；Then 15-26 parts of antioxidant, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, crosslinking is added
3-6 parts of 14-19 parts of agent, 22-29 parts of halogen-free flame retardants, 3-9 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, ACM32-38 parts of acrylic rubber, 11-18 parts of high wear-resistant carbon black, 16-20 parts of calcined kaolin, methylol are formed sediment
1-2 parts of powder is calcined 2-4 hours at 400-600 DEG C, and 22-30 parts of the tributyl citrate of 3-4% is added, it is small to be ground 1-2
When, the hydrochloric acid solution of 12-15% is added, adjusting pH value is 4-5, is aged 10-15 hours, then adding citric acid tributyl adjusts grinding
Liquid pH is neutrality, and filtering dries and obtains filler powder；Melamine pyrophosphate 6-9 parts again, 3-7 parts of nano-titanium dioxide, receive
6-9 parts of jade powder of rice is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is uniformly dispersed, obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 110-140 DEG C of temperature, then
With, by being molded on cable extruding machine, obtain fire-resistant cable material together with metal core wire.
Embodiment 1：
A kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation, includes the following steps：
S1,26 parts of linear low density polyethylene, 13 parts of polystyrene, 3 parts of butyl rubber, 4 parts of hypo-aluminum orthophosphate are passed through into mixing stove
It is uniform to carry out mixing；Then 15 parts of antioxidant, 15 parts of lubricant, 15 parts of vulcanizing agent, 18 parts of crosslinking agent, halogen-free flame retardants 26 is added
5 parts of part, 6 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, by ACM33 parts of acrylic rubber, 13 parts of high wear-resistant carbon black, 15 parts of calcined kaolin, 2 parts of hydroxymethyl starch 430
It is calcined 3 hours at DEG C, 3% 25 parts of tributyl citrate is added, is ground 2 hours, 14% hydrochloric acid solution is added, adjust PH
Value is 4, is aged 15 hours, then adding citric acid tributyl adjusts lapping liquid pH as neutrality, and filtering, drying obtains filler powder；Again
8 parts of melamine pyrophosphate, 7 parts of 4 part, nanometer jade powder of nano-titanium dioxide are added in ultrasonic agitation dispersion machine, are carried out
Ultrasonic agitation is uniformly dispersed, and obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 130 DEG C of temperature, then with gold
Belong to core wire together by being molded on cable extruding machine, obtains fire-resistant cable material.
Embodiment 2：
A kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation, includes the following steps：
S1,30 parts of linear low density polyethylene, 14 parts of polystyrene, 4 parts of butyl rubber, 5 parts of hypo-aluminum orthophosphate are passed through into mixing stove
It is uniform to carry out mixing；Then 26 parts of antioxidant, 18 parts of lubricant, 24 parts of vulcanizing agent, 19 parts of crosslinking agent, halogen-free flame retardants 29 is added
6 parts of part, 9 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, by ACM38 parts of acrylic rubber, 18 parts of high wear-resistant carbon black, 20 parts of calcined kaolin, 2 parts of hydroxymethyl starch 600
It is calcined 4 hours at DEG C, 4% 30 parts of tributyl citrate is added, is ground 2 hours, 15% hydrochloric acid solution is added, adjust PH
Value is 5, is aged 15 hours, then adding citric acid tributyl adjusts lapping liquid pH as neutrality, and filtering, drying obtains filler powder；Again
9 parts of melamine pyrophosphate, 9 parts of 7 part, nanometer jade powder of nano-titanium dioxide are added in ultrasonic agitation dispersion machine, are carried out
Ultrasonic agitation is uniformly dispersed, and obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 140 DEG C of temperature, then with gold
Belong to core wire together by being molded on cable extruding machine, obtains fire-resistant cable material.
Embodiment 3：
A kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation, includes the following steps：
S1,23 parts of linear low density polyethylene, 12 parts of polystyrene, 2 parts of butyl rubber, 5 parts of hypo-aluminum orthophosphate are passed through into mixing stove
It is uniform to carry out mixing；Then 15 parts of antioxidant, 14 parts of lubricant, 13 parts of vulcanizing agent, 14 parts of crosslinking agent, halogen-free flame retardants 22 is added
3 parts of part, 3 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, by ACM32 parts of acrylic rubber, 11 parts of high wear-resistant carbon black, 16 parts of calcined kaolin, 1 part of hydroxymethyl starch 400
It is calcined 2 hours at DEG C, 3% 22 parts of tributyl citrate is added, is ground 1 hour, 12% hydrochloric acid solution is added, adjust PH
Value is 4, is aged 10 hours, then adding citric acid tributyl adjusts lapping liquid pH as neutrality, and filtering, drying obtains filler powder；Again
6 parts of melamine pyrophosphate, 6 parts of 3 part, nanometer jade powder of nano-titanium dioxide are added in ultrasonic agitation dispersion machine, are carried out
Ultrasonic agitation is uniformly dispersed, and obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 110 DEG C of temperature, then with gold
Belong to core wire together by being molded on cable extruding machine, obtains fire-resistant cable material.
The present invention is resistance to using acrylic rubber ACM, tributyl citrate, linear low density polyethylene, polystyrene, height
Grind carbon black, calcined kaolin, MBS resins, oleamide melamine pyrophosphate, nano-titanium dioxide, butyl rubber, secondary phosphorus
The proportioning that the above-mentioned raw materials such as sour aluminium, nanometer jade powder carry out science is added in combination antioxidant, lubricant, vulcanizing agent, crosslinking agent, nothing
Halogen fire retardant, stabilizer and crosslinking agent carry out reaction fusion, and process of preparing is simple, and prepared product has preferable anti-
Fiery fire-retardant, insulation performance is suitble to use in multiple fields.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of CABLE MATERIALS of high-strength anti-flaming insulation, which is characterized in that include being prepared by the raw material of following parts by weight：Third
ACM30-40 parts of olefin(e) acid ester rubber, 20-35 parts of tributyl citrate, 20-35 parts of linear low density polyethylene, polystyrene 10-
15 parts, 10-20 parts of high wear-resistant carbon black, 15-30 parts of calcined kaolin, 15-35 parts of MBS resins, 1-2 parts of hydroxymethyl starch, trimerization
5-10 parts of pyrophosphate, 1-10 parts of nano-titanium dioxide, 1-5 parts of butyl rubber, 2-5 parts of hypo-aluminum orthophosphate, nanometer jade powder
5-10 parts, 10-30 parts of antioxidant, 10-20 parts of lubricant, 10-30 parts of vulcanizing agent, 10-20 parts of crosslinking agent, halogen-free flame retardants 15-
2-7 parts of 35 parts, 1-10 parts of stabilizer and crosslinking agent.
2. a kind of CABLE MATERIALS of high-strength anti-flaming insulation according to claim 1, which is characterized in that the antioxidant is anti-
Oxygen agent 224, the lubricant are one or more in oleamide, erucyl amide, polystyrene wax, and the vulcanizing agent was
Benzoyl Oxide, the crosslinking agent are peroxy ketal, and the halogen-free flame retardants is phosphorus series non-halogen fire retardant, and the stabilizer is hard
Fatty acid magnesium.
3. a kind of CABLE MATERIALS of high-strength anti-flaming insulation according to claim 1, which is characterized in that including by following weight
The raw material of part is prepared：ACM32-38 parts of acrylic rubber, 22-30 parts of tributyl citrate, linear low density polyethylene
23-30 parts, 12-14 parts of polystyrene, 11-18 parts of high wear-resistant carbon black, 16-20 parts of calcined kaolin, 23-28 parts of MBS resins, hydroxyl
1-2 parts of methyl starch, 6-9 parts of melamine pyrophosphate, 3-7 parts of nano-titanium dioxide, 2-4 parts of butyl rubber, hypo-aluminum orthophosphate
3-5 parts, 6-9 parts of nanometer jade powder, 15-26 parts of antioxidant, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, crosslinking agent 14-19
Part, 22-29 parts of halogen-free flame retardants, 3-9 parts of stabilizer and 3-6 parts of crosslinking agent.
4. a kind of preparation method of the CABLE MATERIALS of high-strength anti-flaming insulation according to claim 1, which is characterized in that including
Following steps：
S1, by 23-30 parts of linear low density polyethylene, 12-14 parts of polystyrene, 2-4 parts of butyl rubber, 3-5 parts of hypo-aluminum orthophosphate
It is uniform that mixing is carried out by mixing stove；Then 15-26 parts of antioxidant, 14-18 parts of lubricant, 13-24 parts of vulcanizing agent, crosslinking is added
3-6 parts of 14-19 parts of agent, 22-29 parts of halogen-free flame retardants, 3-9 parts of stabilizer and crosslinking agent mixings uniformly obtain mixture；
S2, ACM32-38 parts of acrylic rubber, 11-18 parts of high wear-resistant carbon black, 16-20 parts of calcined kaolin, methylol are formed sediment
1-2 parts of powder is calcined 2-4 hours at 400-600 DEG C, and 22-30 parts of the tributyl citrate of 3-4% is added, it is small to be ground 1-2
When, the hydrochloric acid solution of 12-15% is added, adjusting pH value is 4-5, is aged 10-15 hours, then adding citric acid tributyl adjusts grinding
Liquid pH is neutrality, and filtering dries and obtains filler powder；Melamine pyrophosphate 6-9 parts again, 3-7 parts of nano-titanium dioxide, receive
6-9 parts of jade powder of rice is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is uniformly dispersed, obtains mixed material；
S3, by obtained by step S1 mixture and step S2 obtain material and first carry out extruding pelletization at 110-140 DEG C of temperature, then
With, by being molded on cable extruding machine, obtain fire-resistant cable material together with metal core wire.
5. a kind of CABLE MATERIALS of high-strength anti-flaming insulation according to claim 1, which is characterized in that including by following weight
The raw material of part is prepared：ACM35 parts of acrylic rubber, 27 parts of linear low density polyethylene, is gathered at 25 parts of tributyl citrate
13 parts of styrene, 16 parts of high wear-resistant carbon black, 18 parts of calcined kaolin, 25 parts of MBS resins, 1 part of hydroxymethyl starch, melamine are burnt
7 parts of phosphate, 5 parts of nano-titanium dioxide, 3 parts of butyl rubber, 7 parts of 4 part, nanometer jade powder of hypo-aluminum orthophosphate, 19 parts of antioxidant, profit
4 parts of 17 parts of lubrication prescription, 16 parts of vulcanizing agent, 17 parts of crosslinking agent, 26 parts of halogen-free flame retardants, 5 parts of stabilizer and crosslinking agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711494805.6A CN108299724A (en) | 2017-12-31 | 2017-12-31 | A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711494805.6A CN108299724A (en) | 2017-12-31 | 2017-12-31 | A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108299724A true CN108299724A (en) | 2018-07-20 |
Family
ID=62868269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711494805.6A Pending CN108299724A (en) | 2017-12-31 | 2017-12-31 | A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108299724A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928448A (en) * | 2010-08-16 | 2010-12-29 | 中国科学技术大学 | Nano composite flame-retardant reinforced polyester engineering plastic and preparation method thereof |
| CN103509235A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Environment-friendly polyethylene cable material and preparation method thereof |
| CN104086923A (en) * | 2014-07-24 | 2014-10-08 | 芜湖君禾电线电缆有限公司 | Antiflaming plastic for cable and preparation method of plastic |
| CN105419199A (en) * | 2016-01-21 | 2016-03-23 | 长园电子（东莞）有限公司 | Diesel-resistant flame-retardant heat-shrink tube and preparation method thereof |
-
2017
- 2017-12-31 CN CN201711494805.6A patent/CN108299724A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928448A (en) * | 2010-08-16 | 2010-12-29 | 中国科学技术大学 | Nano composite flame-retardant reinforced polyester engineering plastic and preparation method thereof |
| CN103509235A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Environment-friendly polyethylene cable material and preparation method thereof |
| CN104086923A (en) * | 2014-07-24 | 2014-10-08 | 芜湖君禾电线电缆有限公司 | Antiflaming plastic for cable and preparation method of plastic |
| CN105419199A (en) * | 2016-01-21 | 2016-03-23 | 长园电子（东莞）有限公司 | Diesel-resistant flame-retardant heat-shrink tube and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103756121B (en) | A kind of heatproof oil-resistant low-smoke halogen-free flame-retardant cross-linking radiation composite polyolefine material and preparation method thereof | |
| CN103450544A (en) | Low-smoke, halogen-free and flame-retardant irradiation crosslinking polyolefin composite material and preparation method thereof | |
| CN102702629B (en) | Flame-retardant heat-resistant wear-resistant radiation cross-linking chlorinated polyethylene rubber and preparation method thereof | |
| CN107903496B (en) | Flame-retardant polypropylene material with low odor and needle flame performance and preparation method thereof | |
| CN110240760A (en) | A kind of flame-resistant insulation ethylene propylene diene rubber hose compositions and preparation method thereof | |
| CN102838803A (en) | Silicon rubber insulation and heat resisting control cable material and preparation method thereof | |
| CN107868436A (en) | A kind of building CABLE MATERIALS of high-performance refractory fire resisting and preparation method thereof | |
| CN107652622A (en) | A kind of high-strength anti-flaming cable for building and preparation method thereof | |
| CN104910447A (en) | Flame-retardant rubber | |
| CN103928172B (en) | Fire retardant crosslinked polyethylene insulated power cable | |
| CN108299724A (en) | A kind of CABLE MATERIALS and preparation method thereof of high-strength anti-flaming insulation | |
| CA2834812A1 (en) | Polymer composition for electrical devices | |
| CN102161804B (en) | -R type polrvinyl chloride wire and cable insulation material | |
| CN102276935B (en) | Parallel flexible cord for heater and preparation method thereof | |
| CN107652596A (en) | A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof | |
| CN107903516A (en) | A kind of electronic engineering cable elastomer sheathing material and preparation method thereof | |
| CN106279897A (en) | A kind of heat-shrink tube and preparation method thereof | |
| CN104558758A (en) | Preparation method of flame-retardant cable protective layer | |
| CN103881196A (en) | Polyethylene material modified by red-phosphorus flame-retardant master batch and preparation method of the material | |
| EP3785281B1 (en) | Flame retardant electrical cable | |
| CN103739956B (en) | Electrical equipment Flame retardant polypropylene special material and preparation method thereof | |
| CN108102339A (en) | A kind of jacketed cable material and preparation method | |
| CN106009543A (en) | Power insulation flame-retardant cable and preparation method thereof | |
| CN105419091A (en) | Flame-retardant cable and production process thereof | |
| KR20160099271A (en) | Environmental friendly non-toxic flame retardant high density polyethylene compound for extrusion sheath of ultra high-voltage cable and a method of manufacturing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180720 |
|
| RJ01 | Rejection of invention patent application after publication |