CN108102339A - A kind of jacketed cable material and preparation method - Google Patents
A kind of jacketed cable material and preparation method Download PDFInfo
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- CN108102339A CN108102339A CN201611042913.5A CN201611042913A CN108102339A CN 108102339 A CN108102339 A CN 108102339A CN 201611042913 A CN201611042913 A CN 201611042913A CN 108102339 A CN108102339 A CN 108102339A
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- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
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- C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a kind of jacketed cable material, include the component of following parts by weight:10 18 parts of 55 85 parts of polyurethane elastomer, 58 parts of anticorrosive, 5 10 parts of maleic anhydride graft copolymer, 0.5 0.9 parts of halogen-free flame retardants, 37 parts of chlorinated paraffin, 13 parts of calcium stearate, 15 25 parts of antistatic agent, modified 10 15 parts of clay, 8 12 parts of methyl methacrylate, 10 20 parts of Halogen smoke suppressant, 0.1 0.3 parts, ultraviolet dose of antioxidant, 0.1 0.3 parts of absorbent and modified filler.In addition, the invention also discloses a kind of preparation methods of jacketed cable material.Using the embodiment of the present invention, corrosion resistance, chemical stability, flame retardant property, the antistatic performance of CABLE MATERIALS can be improved, more preferably meets the needs of different cables.
Description
Technical field
The present invention relates to cable technical field of polymer materials more particularly to a kind of jacketed cable material and preparation methods.
Background technology
With new energy technology, the development of robot field, the application range of cable is more and more wider, and technology requirement is also continuous
It improves.In the prior art, electric vehicle charging cable, wind energy cable and robot drag chain cable etc. using polyester type elastomer body as
Insulating sheath material, corrosion resistance, chemical stability, flame retardant property, the antistatic performance of the insulating sheath material etc. will
Ask not high.Therefore, it is necessary to develop such material of requirements at the higher level.
The content of the invention
A kind of jacketed cable material and system are provided it is an object of the invention to overcome the shortcomings of the prior art part
Preparation Method can improve corrosion resistance, chemical stability, flame retardant property, the antistatic performance of CABLE MATERIALS, more preferable to meet difference
The demand of cable.
The technical solution that the present invention is proposed with regard to above-mentioned technical problem is as follows:
On the one hand, the present invention provides a kind of jacketed cable material, includes the component of following parts by weight:Polyurethane elastomer 55-
85 parts, 5-8 parts of anticorrosive, 5-10 parts of maleic anhydride graft copolymer, 0.5-0.9 parts of halogen-free flame retardants, chlorinated paraffin 3-7
Part, 1-3 parts of calcium stearate, 15-25 parts of antistatic agent, modified 10-15 parts of clay, 8-12 parts of methyl methacrylate, Halogen suppression
10-18 parts of 10-20 parts of fumicants, 0.1-0.3 parts of absorbent of 0.1-0.3 parts, ultraviolet dose of antioxidant and modified filler.
Preferably, the polyurethane elastomer is polyester type elastomer body.
Preferably, the anticorrosive is modified chlorosulfonated polyethylene.
Preferably, the antistatic agent is carbon black (nanoscale).
Preferably, the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphate, ammonium polyphosphate
FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate.
Preferably, the antioxidant for stearic acid salt, organotin, magnesia, Irganox 1010 (Ciba),
At least one of Irganox 245 (Ciba).
Preferably, the ultra-violet absorber is at least one in Fisorb1268, benzophenone, benzotriazole
Kind.
Preferably, the modified filler is calcium sulfate crystal whiskers.
Preferably, the jacketed cable material further includes 0.15-0.3 parts of other processing aids, other described processing aids are
At least one of Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD).
On the other hand, the present invention provides a kind of preparation method of above-mentioned jacketed cable material, the preparation method is will be poly-
Urethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, calcium stearate, antistatic agent,
Modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and modified filler are according to above-mentioned heavy
Amount ratio be uniformly mixed, then vacuumize, heat, be granulated after obtain the jacketed cable material.
Preferably, the rotating speed of mixing is 1200-1600r/min, time 10-15min.
Preferably, the temperature of the hot melt is 160-180 DEG C, and the temperature of the granulation is 170-200 DEG C.
Preferably, the modified filler carries out drying and processing before combination, to remove the moisture in modified filler.
Preferably, the temperature of the drying is 80 DEG C.
Implement the embodiment of the present invention, have the advantages that:
Jacketed cable material provided in an embodiment of the present invention and preparation method can be suitable for electric vehicle charging cable, wind
Energy cable, industrial robot cable etc., have superior corrosion-resistant, chemical stability, low-smoke and flame retardant, antistatic performance.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention
It is described further.
Embodiment one
The present invention provides a kind of jacketed cable material, includes the component of following parts by weight:55 parts of polyurethane elastomer, anticorrosion
5 parts of agent, 5 parts of maleic anhydride graft copolymer, 0.5 part of halogen-free flame retardants, 3 parts of chlorinated paraffin, 15 parts of antistatic agent, modified clay
10 parts, 8 parts of methyl methacrylate, 10 parts of Halogen smoke suppressant, 0.1 part, ultraviolet dose 0.1 part of absorbent of antioxidant, modification fill out
0 part of 10 parts of material and other processing aids.
Wherein, the polyurethane elastomer is polyester type elastomer body, and the anticorrosive is to be modified chlorosulfonated polyethylene, institute
Antistatic agent is stated as carbon black (nanoscale), the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphoric
Salt, ammonium polyphosphate FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate, and the antioxidant is stearic acid salt, has
At least one of machine tin, magnesia, Irganox 1010 (Ciba), Irganox245 (Ciba), the ultra-violet absorber
For at least one of Fisorb1268, benzophenone, benzotriazole, the modified filler is calcium sulfate crystal whiskers, described
Other processing aids are at least one in Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD)
Kind.
A kind of embodiment of the preparation method of above-mentioned jacketed cable material, the preparation method comprise the following steps:
(1) pre-process, modified filler is dried in an oven, remove the moisture in modified filler, wherein, oven temperature is
80℃;
(2) by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, hard
Resin acid calcium, antistatic agent are modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and change
Property filler is weighed according to above-mentioned weight ratio;
(3) in high-speed mixer, the material weighed is uniformly mixed with the rotating speed of 1200-1600r/min, time 10-
15min;
(4) vacuumize 3 it is small when, heated under the conditions of 160-180 DEG C, make double screw extruder in 170-200 DEG C of condition
Material is granulated, is packed after cooling, obtains Polyether-type thermoplastic polyurethane elastomer jacketed cable material.
Embodiment two
The present invention provides a kind of jacketed cable material, includes the component of following parts by weight:65 parts of polyurethane elastomer, anticorrosion
6 parts of agent, 6 parts of maleic anhydride graft copolymer, 0.6 part of halogen-free flame retardants, 4 parts of chlorinated paraffin, 18 parts of antistatic agent, modified clay
11 parts, it is 9 parts of methyl methacrylate, 13 parts of Halogen smoke suppressant, 0.15 part, ultraviolet dose 0.15 part of absorbent of antioxidant, modified
0.1 part of 12 parts of filler and other processing aids.
Wherein, the polyurethane elastomer is polyester type elastomer body, and the anticorrosive is to be modified chlorosulfonated polyethylene, institute
Antistatic agent is stated as carbon black (nanoscale), the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphoric
Salt, ammonium polyphosphate FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate, and the antioxidant is stearic acid salt, has
At least one of machine tin, magnesia, Irganox 1010 (Ciba), Irganox245 (Ciba), the ultra-violet absorber
For at least one of Fisorb1268, benzophenone, benzotriazole, the modified filler is calcium sulfate crystal whiskers, described
Other processing aids are at least one in Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD)
Kind.
A kind of embodiment of the preparation method of above-mentioned jacketed cable material, the preparation method comprise the following steps:
(1) pre-process, modified filler is dried in an oven, remove the moisture in modified filler, wherein, oven temperature is
80℃;
(2) by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, hard
Resin acid calcium, antistatic agent are modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and change
Property filler is weighed according to above-mentioned weight ratio;
(3) in high-speed mixer, the material weighed is uniformly mixed with the rotating speed of 1200-1600r/min, time 10-
15min;
(4) vacuumize 3 it is small when, heated under the conditions of 160-180 DEG C, make double screw extruder in 170-200 DEG C of condition
Material is granulated, is packed after cooling, obtains Polyether-type thermoplastic polyurethane elastomer jacketed cable material.
Embodiment three
The present invention provides a kind of jacketed cable material, includes the component of following parts by weight:75 parts of polyurethane elastomer, anticorrosion
7 parts of agent, 8 parts of maleic anhydride graft copolymer, 0.7 part of halogen-free flame retardants, 5 parts of chlorinated paraffin, 20 parts of antistatic agent, modified clay
13 parts, 10 parts of methyl methacrylate, 16 parts of Halogen smoke suppressant, 0.2 part, ultraviolet dose 0.2 part of absorbent of antioxidant, modification fill out
0.2 part of 14 parts of material and other processing aids.
Wherein, the polyurethane elastomer is polyester type elastomer body, and the anticorrosive is to be modified chlorosulfonated polyethylene, institute
Antistatic agent is stated as carbon black (nanoscale), the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphoric
Salt, ammonium polyphosphate FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate, and the antioxidant is stearic acid salt, has
At least one of machine tin, magnesia, Irganox 1010 (Ciba), Irganox245 (Ciba), the ultra-violet absorber
For at least one of Fisorb1268, benzophenone, benzotriazole, the modified filler is calcium sulfate crystal whiskers, described
Other processing aids are at least one in Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD)
Kind.
A kind of embodiment of the preparation method of above-mentioned jacketed cable material, the preparation method comprise the following steps:
(1) pre-process, modified filler is dried in an oven, remove the moisture in modified filler, wherein, oven temperature is
80℃;
(2) by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, hard
Resin acid calcium, antistatic agent are modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and change
Property filler is weighed according to above-mentioned weight ratio;
(3) in high-speed mixer, the material weighed is uniformly mixed with the rotating speed of 1200-1600r/min, time 10-
15min;
(4) vacuumize 3 it is small when, heated under the conditions of 160-180 DEG C, make double screw extruder in 170-200 DEG C of condition
Material is granulated, is packed after cooling, obtains Polyether-type thermoplastic polyurethane elastomer jacketed cable material.
Example IV
The present invention provides a kind of jacketed cable material, includes the component of following parts by weight:80 parts of polyurethane elastomer, anticorrosion
7 parts of agent, 9 parts of maleic anhydride graft copolymer, 0.8 part of halogen-free flame retardants, 6 parts of chlorinated paraffin, 22 parts of antistatic agent, modified clay
14 parts, it is 11 parts of methyl methacrylate, 18 parts of Halogen smoke suppressant, 0.25 part, ultraviolet dose 0.25 part of absorbent of antioxidant, modified
0.25 part of 16 parts of filler and other processing aids.
Wherein, the polyurethane elastomer is polyester type elastomer body, and the anticorrosive is to be modified chlorosulfonated polyethylene, institute
Antistatic agent is stated as carbon black (nanoscale), the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphoric
Salt, ammonium polyphosphate FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate, and the antioxidant is stearic acid salt, has
At least one of machine tin, magnesia, Irganox 1010 (Ciba), Irganox245 (Ciba), the ultra-violet absorber
For at least one of Fisorb1268, benzophenone, benzotriazole, the modified filler is calcium sulfate crystal whiskers, described
Other processing aids are at least one in Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD)
Kind.
A kind of embodiment of the preparation method of above-mentioned jacketed cable material, the preparation method comprise the following steps:
(1) pre-process, modified filler is dried in an oven, remove the moisture in modified filler, wherein, oven temperature is
80℃;
(2) by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, hard
Resin acid calcium, antistatic agent are modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and change
Property filler is weighed according to above-mentioned weight ratio;
(3) in high-speed mixer, the material weighed is uniformly mixed with the rotating speed of 1200-1600r/min, time 10-
15min;
(4) vacuumize 3 it is small when, heated under the conditions of 160-180 DEG C, make double screw extruder in 170-200 DEG C of condition
Material is granulated, is packed after cooling, obtains Polyether-type thermoplastic polyurethane elastomer jacketed cable material.
Embodiment five
The present invention provides a kind of jacketed cable material, includes the component of following parts by weight:85 parts of polyurethane elastomer, anticorrosion
8 parts of agent, 10 parts of maleic anhydride graft copolymer, 0.9 part of halogen-free flame retardants, 7 parts of chlorinated paraffin, 25 parts of antistatic agent, modified pottery
15 parts of soil, 12 parts of methyl methacrylate, 20 parts of Halogen smoke suppressant, 0.3 part, ultraviolet dose 0.3 part of absorbent of antioxidant, modification
0.3 part of 18 parts of filler and other processing aids.
Wherein, the polyurethane elastomer is polyester type elastomer body, and the anticorrosive is to be modified chlorosulfonated polyethylene, institute
Antistatic agent is stated as carbon black (nanoscale), the non-halogen flame-proof smoke-restraining agent is 400A expansion type flame retardants, melamine pyrophosphoric
Salt, ammonium polyphosphate FH-422 type rings protect at least one of smoke suppressant, ammonium octamolybdate, and the antioxidant is stearic acid salt, has
At least one of machine tin, magnesia, Irganox 1010 (Ciba), Irganox245 (Ciba), the ultra-violet absorber
For at least one of Fisorb1268, benzophenone, benzotriazole, the modified filler is calcium sulfate crystal whiskers, described
Other processing aids are at least one in Tinuvin 328 (Ciba), pentaerythritol diphosphate, polycarbodiimide (PCD)
Kind.
A kind of embodiment of the preparation method of above-mentioned jacketed cable material, the preparation method comprise the following steps:
(1) pre-process, modified filler is dried in an oven, remove the moisture in modified filler, wherein, oven temperature is
80℃;
(2) by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, hard
Resin acid calcium, antistatic agent are modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and change
Property filler is weighed according to above-mentioned weight ratio;
(3) in high-speed mixer, the material weighed is uniformly mixed with the rotating speed of 1200-1600r/min, time 10-
15min;
(4) vacuumize 3 it is small when, heated under the conditions of 160-180 DEG C, make double screw extruder in 170-200 DEG C of condition
Material is granulated, is packed after cooling, obtains Polyether-type thermoplastic polyurethane elastomer jacketed cable material.
The test result of each performance of the jacketed cable material of embodiment one, two, three, four and five is as shown in table 1, from table 1
Test result understand, the jacketed cable material for preparing of the present invention, the jacketed cable material tool especially prepared by embodiment three and four
There are superior corrosion-resistant, chemical stability, low-smoke and flame retardant, antistatic performance, can more preferably meet the needs of different cables.
Table 1
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should
Understand, technical scheme can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And scope.
Claims (10)
1. a kind of jacketed cable material, which is characterized in that include the component of following parts by weight:55-85 parts of polyurethane elastomer, anti-corrosion
Lose 5-8 parts of agent, 5-10 parts of maleic anhydride graft copolymer, 0.5-0.9 parts of halogen-free flame retardants, 3-7 parts of chlorinated paraffin, calcium stearate
1-3 parts, 15-25 parts of antistatic agent, modified 10-15 parts of clay, 8-12 parts of methyl methacrylate, 10-20 parts of Halogen smoke suppressant,
10-18 parts of 0.1-0.3 parts of absorbent of 0.1-0.3 parts, ultraviolet dose of antioxidant and modified filler.
2. jacketed cable material as described in claim 1, which is characterized in that the anticorrosive is modified chlorosulfonated polyethylene.
3. jacketed cable material as described in claim 1, which is characterized in that the antistatic agent is carbon black.
4. jacketed cable material as described in claim 1, which is characterized in that the non-halogen flame-proof smoke-restraining agent hinders for 400A intumescents
Fire at least one of agent, melamine pyrophosphate, ammonium polyphosphate FH-422 type rings guarantor smoke suppressant, ammonium octamolybdate.
5. jacketed cable material as described in claim 1, which is characterized in that the antioxidant is stearic acid salt, organotin, oxygen
Change at least one of magnesium, Irganox 1010, Irganox 245.
6. jacketed cable material as described in claim 1, which is characterized in that the ultra-violet absorber is Fisorb1268, two
At least one of Benzophenone class, benzotriazole.
7. jacketed cable material as described in claim 1, which is characterized in that the modified filler is calcium sulfate crystal whiskers.
8. jacketed cable material as described in any one of claim 1 to 7, which is characterized in that the jacketed cable material further includes it
His 0.15-0.3 parts of processing aid, other described processing aids are Tinuvin 328, pentaerythritol diphosphate, poly- carbonization two
At least one of imines.
A kind of 9. preparation method of jacketed cable material as described in any one of claim 1 to 7, which is characterized in that the preparation
Method is by polyurethane elastomer, anticorrosive, maleic anhydride graft copolymer, halogen-free flame retardants, chlorinated paraffin, stearic acid
Calcium, antistatic agent, modified clay, methyl methacrylate, Halogen smoke suppressant, antioxidant, ultraviolet dose of absorbent and modification are filled out
Material be uniformly mixed according to weight ratio as described in claim 1, then vacuumize, heat, be granulated after obtain the sheath
CABLE MATERIALS.
10. the preparation method of jacketed cable material according to claim 9, which is characterized in that the temperature of the hot melt is
160-180 DEG C, the temperature of the granulation is 170-200 DEG C.
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CN201611042913.5A CN108102339A (en) | 2016-11-24 | 2016-11-24 | A kind of jacketed cable material and preparation method |
PCT/CN2017/111508 WO2018095274A1 (en) | 2016-11-24 | 2017-11-17 | Sheathed electrical-cable material and method for fabricating same |
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CN112679940A (en) * | 2020-12-17 | 2021-04-20 | 东莞市稳畅电子制品有限公司 | Antistatic TPU electric wire and preparation method thereof |
CN113470872A (en) * | 2021-06-25 | 2021-10-01 | 广西桂潮电缆投资有限公司 | Anti-corrosion cable for mine |
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