CN108297506A - A kind of implosion guard for interior architecture partition - Google Patents
A kind of implosion guard for interior architecture partition Download PDFInfo
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- CN108297506A CN108297506A CN201810169535.XA CN201810169535A CN108297506A CN 108297506 A CN108297506 A CN 108297506A CN 201810169535 A CN201810169535 A CN 201810169535A CN 108297506 A CN108297506 A CN 108297506A
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- glass
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- implosion guard
- explosion
- interlayer
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The present invention relates to glass manufacturing areas, and in particular to a kind of implosion guard for interior architecture partition;Implosion guard is the double glazing being made of two pieces of glass substrates, and heat insulation coating is arranged in the inner wall of double glazing inside sandwich establishment, interlayer, and the ingredient of heat insulation coating is nano-stannic oxide, and the inside of interlayer is filled with explosion-proof filler.The component of explosion-proof filler includes:Acrylic resin, polyvinyl alcohol, butyraldehyde, polyisocyanate, plasticizer, ultra-violet absorber.Wherein, it is 150 165 DEG C of thermoplastic acrylic resin that acrylic resin, which selects softening point, and plasticizer selects dioctyl phthalate;Ultra-violet absorber selects 2 hydroxyl, 4 oxy-octyl benzophenone or septichen phenyl ester;The type implosion guard is fabricated through multiple tracks techniques such as overetch, plated film, conjunction piece, adhesive curing, filler injection and edge sealing processing.With good heat-insulating property and outstanding explosion-proof effect, and it can prevent glass fragment from splashing.
Description
Technical field
The present invention relates to glass manufacturing areas, and in particular to a kind of implosion guard for interior architecture partition.
Background technology
Many companies can ask Chevron Research Company (CRC) to be designed the working environment of company to improve the working efficiency of employee, thing
Real example is bright, the comfortable state of mind for contributing positively to improve employee of working environment, to promote the work incentive of employee.It is existing
Can space partition largely be carried out using glass material in Indoor Environmental Design, glass material can give people relative to solid wall
A kind of impression of light pleasure, isolation and sense of closure it is relatively weak, therefore working environment design in use it is more universal.
Currently, the glass that interior space partition uses is mainly tempered glass, the structural strength of this glass is high, shock resistance
Excellent performance, heat resistance are preferable.But the heat insulating effect of glass material is generally poor, in addition, either ordinary flat
Glass or tempered glass all have the risk of explosion under the influence of because of temperature change and force-bearing situation, although some are anti-
Quick-fried glass is added to fibrous material in glass, and disintegrating slag splashes after preventing glass self-explosion, reduces the harm of glass explosion, still
Glass is easy to still remain the problem of explosion when internal stress structure changes.
Invention content
For problems of the prior art, the present invention provides a kind of implosion guard for interior architecture partition,
The type implosion guard has good heat insulation effect, and can significantly reduce the risk of glass self-explosion, and safety is higher.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of implosion guard for interior architecture partition, which is the double-deck glass being made of two pieces of glass substrates
The thickness of glass, glass substrate is 1-1.2cm, and the thickness of double glazing inside sandwich establishment, interlayer is 2-4mm, the inner wall of interlayer
Heat insulation coating is set, explosion-proof filler is filled in interlayer.
Preferably, the ingredient of heat insulation coating is nano-stannic oxide, and coating layer thickness is 5-10 μm, and glass substrate is float glass process glass
Glass or tempered glass.
In the present invention, the component of explosion-proof filler includes according to mass fraction:80-95 parts of acrylic resin, polyvinyl alcohol 20-
25 parts, 25-28 parts of butyraldehyde, 7-10 parts of polyisocyanate, 6-9 parts of plasticizer, 2-3 parts of ultra-violet absorber.
It is further preferred that the component of explosion-proof filler includes according to mass fraction:87-91 parts of acrylic resin, polyethylene
22-23 parts of alcohol, 26-27 parts of butyraldehyde, 8-9 parts of polyisocyanate, 7-8 parts of plasticizer, 2.4-2.8 parts of ultra-violet absorber.
Preferably, it is 150-165 DEG C of thermoplastic acrylic resin that acrylic resin, which selects softening point, and plasticizer is selected adjacent
Dioctyl phthalate.
Preferably, ultra-violet absorber selects 2-hydroxy-4-n-octoxybenzophenone or septichen phenyl ester.
The preparation method of explosion-proof filler is in the present invention:Acrylic resin is added in reaction kettle according to mass fraction,
Reactor temperature is improved to 170-175 DEG C to polyacrylate softening, then by polyvinyl alcohol, polyisocyanate and plasticizer
It is added in reaction kettle, is stirred with the rotating speed of 150-180r/min, react 25-30min, ultra-violet absorber is added to reaction
In kettle, continues to stir 10-15min, obtain required thermal insulation coatings.
The preparation method of implosion guard provided by the invention is as follows:
(1) prepare glass substrate, interlayer pit is formed on the surface of glass by etching method, it is then that glass cleaning is clean
After dry, by the glass after drying be sent to carry out coating chamber in processing form heat insulation coating.
(2) cut-parts are carried out to the glass substrate of two pieces of formation heat insulation coatings, the glass substrate after cut-parts is according to where pit
Face is placed in opposite directions to coincide, and places supporter in the family of two blocks of glass, is then sprayed in upper lower glass substrate pit edge position
Enter glass glue, while in the reserved arrangement injection-tube of glass substrate corner positions and exhaust tube, upper lower glass substrate is closed into piece
It is heating and curing in high-temperature cabinet afterwards.
(3) double glazing after piece cures will be closed to be cooled to room temperature, is then fed into injector, preheating double glazing is extremely
160-180 DEG C, explosion-proof filler is added in injector, the material feeding temperature of injector is 180-185 DEG C, is filled out explosion-proof by injector
Material is injected into from injection-tube in glass sandwich, is extracted out the air in interlayer by exhaust tube while injection so that explosion-proof to fill out
Material uniformly fills in interlayer, by double glazing cooled to room temperature after material feeding, finally consolidates injection-tube and exhaust tube
Weldering, and edge sealing is carried out to double glazing, obtain required implosion guard.
The present invention has following advantageous effect:
(1) the type implosion guard is double glazing, and interlayer is contained among glass, and explosion-proof filler is filled in interlayer, explosion-proof
Temperature buffer is carried out when the effect of filler and impact effect absorbs, because of the presence of explosion-proof filler, the outer shroud in implosion guard room
Under the situation that border temperature change is violent or temperature difference is larger, explosion-proof filler can allow temperature spread effectively to be buffered,
Simultaneously because the properties such as consistency and elasticity of explosion-proof filler are compared with glass and differed greatly, it is applied to the impact force of glass everywhere
It can effectively be absorbed by explosion-proof filler, to reduce glass because external impact or temperature change cause internal stress to change and oneself
Quick-fried possibility.In addition, even if skin glass is broken, explosion-proof filler can also bond glass fragment, prevent glass broken
Piece splashing causes secondary injury.
(2) it being further coated with heat preservation coating on the interlayer inner wall of the type implosion guard, thermal insulation coatings are Nano zinc dioxide impact-resistant,
The coating can significantly improve the heat-insulating property of glass, improve using effect of the implosion guard for interior architecture partition.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of implosion guard for interior architecture partition, which is the double-deck glass being made of two pieces of glass substrates
The thickness of glass, glass substrate is 1cm, and the thickness of double glazing inside sandwich establishment, interlayer is 2mm, and the inner wall setting of interlayer is protected
Warm coating, interlayer is interior to be filled with explosion-proof filler.The ingredient of heat insulation coating is nano-stannic oxide, and coating layer thickness is 5 μm, glass base
Plate is float glass.
The component of explosion-proof filler includes according to mass fraction:80 parts of acrylic resin, 20 parts of polyvinyl alcohol, 25 parts of butyraldehyde,
7 parts of polyisocyanate, 6 parts of plasticizer, 2 parts of ultra-violet absorber.Wherein, it is 150 DEG C of heat that acrylic resin, which selects softening point,
Plastic propene's acid resin, plasticizer select dioctyl phthalate;Ultra-violet absorber selects 2- hydroxyl -4- n-octyloxies two
Benzophenone.
The preparation method of explosion-proof filler is in the present embodiment:Acrylic resin is added to reaction kettle according to mass fraction
In, reactor temperature is improved to 170 DEG C to polyacrylate softening, then by polyvinyl alcohol, polyisocyanate and plasticizer
It is added in reaction kettle, is stirred with the rotating speed of 150r/min, react 25min, ultra-violet absorber is added in reaction kettle, after
Continuous stirring 10min, obtains required thermal insulation coatings.
The preparation method of the implosion guard of the present embodiment is as follows:
(1) prepare glass substrate, interlayer pit is formed on the surface of glass by etching method, it is then that glass cleaning is clean
After dry, by the glass after drying be sent to carry out coating chamber in processing form heat insulation coating.
(2) cut-parts are carried out to the glass substrate of two pieces of formation heat insulation coatings, the glass substrate after cut-parts is according to where pit
Face is placed in opposite directions to coincide, and places supporter in the family of two blocks of glass, is then sprayed in upper lower glass substrate pit edge position
Enter glass glue, while in the reserved arrangement injection-tube of glass substrate corner positions and exhaust tube, upper lower glass substrate is closed into piece
It is heating and curing in high-temperature cabinet afterwards.
(3) double glazing after piece cures will be closed to be cooled to room temperature, is then fed into injector, preheating double glazing is extremely
160 DEG C, it is added explosion-proof filler in injector, the material feeding temperature of injector is 180 DEG C, by injector by explosion-proof filler from injection
Pipe is injected into glass sandwich, is extracted out the air in interlayer by exhaust tube while injection so that explosion-proof filler uniformly fills
It is full of in interlayer, by double glazing cooled to room temperature after material feeding, finally welds injection-tube and exhaust tube admittedly, and to double
Layer glass carries out edge sealing, obtains required implosion guard.
Embodiment 2
A kind of implosion guard for interior architecture partition, which is the double-deck glass being made of two pieces of glass substrates
The thickness of glass, glass substrate is 1.2cm, and the thickness of double glazing inside sandwich establishment, interlayer is 4mm, and the inner wall of interlayer is arranged
Heat insulation coating, interlayer is interior to be filled with explosion-proof filler.The ingredient of heat insulation coating is nano-stannic oxide, and coating layer thickness is 10 μm, glass
Glass substrate is tempered glass.
The component of explosion-proof filler includes according to mass fraction:95 parts of acrylic resin, 25 parts of polyvinyl alcohol, 28 parts of butyraldehyde,
10 parts of polyisocyanate, 9 parts of plasticizer, 3 parts of ultra-violet absorber.Wherein, it is 165 DEG C of heat that acrylic resin, which selects softening point,
Plastic propene's acid resin, plasticizer select dioctyl phthalate;Ultra-violet absorber selects septichen phenyl ester.
The preparation method of explosion-proof filler is in the present embodiment:Acrylic resin is added to reaction kettle according to mass fraction
In, reactor temperature is improved to 175 DEG C to polyacrylate softening, then by polyvinyl alcohol, polyisocyanate and plasticizer
It is added in reaction kettle, is stirred with the rotating speed of 180r/min, react 30min, ultra-violet absorber is added in reaction kettle, after
Continuous stirring 15min, obtains required thermal insulation coatings.
The preparation method of implosion guard provided in this embodiment is as follows:
(1) prepare glass substrate, interlayer pit is formed on the surface of glass by etching method, it is then that glass cleaning is clean
After dry, by the glass after drying be sent to carry out coating chamber in processing form heat insulation coating.
(2) cut-parts are carried out to the glass substrate of two pieces of formation heat insulation coatings, the glass substrate after cut-parts is according to where pit
Face is placed in opposite directions to coincide, and places supporter in the family of two blocks of glass, is then sprayed in upper lower glass substrate pit edge position
Enter glass glue, while in the reserved arrangement injection-tube of glass substrate corner positions and exhaust tube, upper lower glass substrate is closed into piece
It is heating and curing in high-temperature cabinet afterwards.
(3) double glazing after piece cures will be closed to be cooled to room temperature, is then fed into injector, preheating double glazing is extremely
180 DEG C, it is added explosion-proof filler in injector, the material feeding temperature of injector is 185 DEG C, by injector by explosion-proof filler from injection
Pipe is injected into glass sandwich, is extracted out the air in interlayer by exhaust tube while injection so that explosion-proof filler uniformly fills
It is full of in interlayer, by double glazing cooled to room temperature after material feeding, finally welds injection-tube and exhaust tube admittedly, and to double
Layer glass carries out edge sealing, obtains required implosion guard.
Embodiment 3
A kind of implosion guard for interior architecture partition, which is the double-deck glass being made of two pieces of glass substrates
The thickness of glass, glass substrate is 1.1cm, and the thickness of double glazing inside sandwich establishment, interlayer is 3mm, and the inner wall of interlayer is arranged
Heat insulation coating, interlayer is interior to be filled with explosion-proof filler.The ingredient of heat insulation coating is nano-stannic oxide, and coating layer thickness is 8 μm, glass
Substrate is tempered glass.
The component of explosion-proof filler includes according to mass fraction:90 parts of acrylic resin, 23 parts of polyvinyl alcohol, 26 parts of butyraldehyde,
8 parts of polyisocyanate, 7 parts of plasticizer, 2.5 parts of ultra-violet absorber.Wherein, it is 160 DEG C that acrylic resin, which selects softening point,
Thermoplastic acrylic resin, plasticizer select dioctyl phthalate;Ultra-violet absorber selects 2- hydroxyl -4- n-octyloxies
Benzophenone.
The preparation method of explosion-proof filler is in the present embodiment:Acrylic resin is added to reaction kettle according to mass fraction
In, reactor temperature is improved to 173 DEG C to polyacrylate softening, then by polyvinyl alcohol, polyisocyanate and plasticizer
It is added in reaction kettle, is stirred with the rotating speed of 165r/min, react 28min, ultra-violet absorber is added in reaction kettle, after
Continuous stirring 13min, obtains required thermal insulation coatings.
The preparation method of implosion guard provided in this embodiment is as follows:
(1) prepare glass substrate, interlayer pit is formed on the surface of glass by etching method, it is then that glass cleaning is clean
After dry, by the glass after drying be sent to carry out coating chamber in processing form heat insulation coating.
(2) cut-parts are carried out to the glass substrate of two pieces of formation heat insulation coatings, the glass substrate after cut-parts is according to where pit
Face is placed in opposite directions to coincide, and places supporter in the family of two blocks of glass, is then sprayed in upper lower glass substrate pit edge position
Enter glass glue, while in the reserved arrangement injection-tube of glass substrate corner positions and exhaust tube, upper lower glass substrate is closed into piece
It is heating and curing in high-temperature cabinet afterwards.
(3) double glazing after piece cures will be closed to be cooled to room temperature, is then fed into injector, preheating double glazing is extremely
170 DEG C, it is added explosion-proof filler in injector, the material feeding temperature of injector is 183 DEG C, by injector by explosion-proof filler from injection
Pipe is injected into glass sandwich, is extracted out the air in interlayer by exhaust tube while injection so that explosion-proof filler uniformly fills
It is full of in interlayer, by double glazing cooled to room temperature after material feeding, finally welds injection-tube and exhaust tube admittedly, and to double
Layer glass carries out edge sealing, obtains required implosion guard.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of implosion guard for interior architecture partition, it is characterised in that:The implosion guard is by two pieces of glass substrates
The thickness of the double glazing of composition, glass substrate is 1-1.2cm, and the thickness of double glazing inside sandwich establishment, interlayer is 2-
Heat insulation coating is arranged in the inner wall of 4mm, interlayer, and explosion-proof filler is filled in interlayer.
2. a kind of implosion guard for interior architecture partition according to claim 1, it is characterised in that:The heat preservation applies
The ingredient of layer is nano-stannic oxide, and coating layer thickness is 5-10 μm, and glass substrate is float glass or tempered glass.
3. a kind of implosion guard for interior architecture partition according to claim 1, it is characterised in that:It is described explosion-proof to fill out
The component of material includes according to mass fraction:80-95 parts of acrylic resin, 20-25 parts of polyvinyl alcohol, 25-28 parts of butyraldehyde, poly- isocyanide
7-10 parts of acid esters, 6-9 parts of plasticizer, 2-3 parts of ultra-violet absorber.
4. a kind of implosion guard for interior architecture partition according to claim 3, it is characterised in that:It is described explosion-proof to fill out
The component of material includes according to mass fraction:87-91 parts of acrylic resin, 22-23 parts of polyvinyl alcohol, 26-27 parts of butyraldehyde, poly- isocyanide
8-9 parts of acid esters, 7-8 parts of plasticizer, 2.4-2.8 parts of ultra-violet absorber.
5. a kind of implosion guard for interior architecture partition according to claim 3, it is characterised in that:The acrylic acid
It is 150-165 DEG C of thermoplastic acrylic resin that resin, which selects softening point, and plasticizer selects dioctyl phthalate.
6. a kind of implosion guard for interior architecture partition according to claim 3, it is characterised in that:The ultraviolet light
Absorbent selects 2-hydroxy-4-n-octoxybenzophenone or septichen phenyl ester.
7. a kind of implosion guard for interior architecture partition according to claim 3, it is characterised in that:It is described explosion-proof to fill out
The preparation method of material is:Acrylic resin is added in reaction kettle according to mass fraction, improves reactor temperature to 170-
175 DEG C soften to polyacrylate, then polyvinyl alcohol, polyisocyanate and plasticizer are added in reaction kettle, with 150-
The rotating speed of 180r/min stirs, and reacts 25-30min, ultra-violet absorber is added in reaction kettle, continues to stir 10-
15min obtains required thermal insulation coatings.
8. a kind of implosion guard for interior architecture partition according to claim 1-7 any one, it is characterised in that:
The preparation method of the implosion guard is as follows:
(1)Prepare glass substrate, interlayer pit is formed on the surface of glass by etching method, then totally dries glass cleaning afterwards
It is dry, the glass after drying is sent to processing in progress coating chamber and forms heat insulation coating;
(2)Cut-parts are carried out to the glass substrate of two pieces of formation heat insulation coatings, the glass substrate after cut-parts is according to face phase where pit
It coincide to placement, places supporter in the family of two blocks of glass, then spray into glass in upper lower glass substrate pit edge position
Glass adhesive, while in the reserved arrangement injection-tube of glass substrate corner positions and exhaust tube, by upper lower glass substrate close after piece
It is heating and curing in high-temperature cabinet;
(3)The double glazing after piece cures will be closed to be cooled to room temperature, be then fed into injector, preheating double glazing to 160-
180 DEG C, be added explosion-proof filler in injector, the material feeding temperature of injector is 180-185 DEG C, by injector by explosion-proof filler from
Injection-tube is injected into glass sandwich, is extracted out the air in interlayer by exhaust tube while injection so that explosion-proof filler is equal
It is even to fill in interlayer, by double glazing cooled to room temperature after material feeding, finally injection-tube and exhaust tube are welded admittedly, and
Edge sealing is carried out to double glazing, obtains required implosion guard.
Priority Applications (1)
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CN201810169535.XA CN108297506A (en) | 2018-03-01 | 2018-03-01 | A kind of implosion guard for interior architecture partition |
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CN201810169535.XA CN108297506A (en) | 2018-03-01 | 2018-03-01 | A kind of implosion guard for interior architecture partition |
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CN108297506A true CN108297506A (en) | 2018-07-20 |
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CN201810169535.XA Withdrawn CN108297506A (en) | 2018-03-01 | 2018-03-01 | A kind of implosion guard for interior architecture partition |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104960277A (en) * | 2015-06-08 | 2015-10-07 | 湖南省华京粉体材料有限公司 | Thermal-insulating heat-preserving laminated safety glass and manufacturing method thereof |
CN106285336A (en) * | 2015-05-18 | 2017-01-04 | 深圳市雅丹幕墙工程有限公司 | The recycling structure of building glass |
CN106746755A (en) * | 2016-12-30 | 2017-05-31 | 青岛亨达玻璃科技有限公司 | A kind of preparation method and its usage of vacuum glass |
CN107244817A (en) * | 2017-06-08 | 2017-10-13 | 何志铭 | A kind of doubling glass and preparation method thereof |
-
2018
- 2018-03-01 CN CN201810169535.XA patent/CN108297506A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106285336A (en) * | 2015-05-18 | 2017-01-04 | 深圳市雅丹幕墙工程有限公司 | The recycling structure of building glass |
CN104960277A (en) * | 2015-06-08 | 2015-10-07 | 湖南省华京粉体材料有限公司 | Thermal-insulating heat-preserving laminated safety glass and manufacturing method thereof |
CN106746755A (en) * | 2016-12-30 | 2017-05-31 | 青岛亨达玻璃科技有限公司 | A kind of preparation method and its usage of vacuum glass |
CN107244817A (en) * | 2017-06-08 | 2017-10-13 | 何志铭 | A kind of doubling glass and preparation method thereof |
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