CN110216943A - A kind of fire-resistant composite panel and preparation method thereof - Google Patents

A kind of fire-resistant composite panel and preparation method thereof Download PDF

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Publication number
CN110216943A
CN110216943A CN201910580978.2A CN201910580978A CN110216943A CN 110216943 A CN110216943 A CN 110216943A CN 201910580978 A CN201910580978 A CN 201910580978A CN 110216943 A CN110216943 A CN 110216943A
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CN
China
Prior art keywords
layer
fire
resistant composite
composite panel
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910580978.2A
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Chinese (zh)
Inventor
谭家峻
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Guangdong Aluminium Industry Co Ltd
Original Assignee
Korea Guangdong Aluminium Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Guangdong Aluminium Industry Co Ltd filed Critical Korea Guangdong Aluminium Industry Co Ltd
Priority to CN201910580978.2A priority Critical patent/CN110216943A/en
Publication of CN110216943A publication Critical patent/CN110216943A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/061Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • B32B2037/1215Hot-melt adhesive
    • B32B2037/1223Hot-melt adhesive film-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7246Water vapor barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

Abstract

The invention discloses a kind of fire-resistant composite panels and preparation method thereof, belong to building decoration area.The fire-resistant composite panel includes core layer, and the upper and lower surface of the core layer is disposed with adhesive layer and metal layer, and the core layer is foamed glass plate, and the metal layer is sheet metal, and the adhesive layer is polymeric membrane.The embodiment of the present invention between the metal layer that two layers is sheet metal by being arranged the core layer that one layer is foamed glass plate, and foamed glass plate and sheet metal are bonded together by polymeric membrane, the fire protecting performance that composite plate can be greatly improved makes the fire-protection rating of composite plate reach A grades.In addition, since the thermal coefficient of foamed glass plate is low, water absorption rate is low and has certain sound absorption, therefore by selecting foamed glass plate as core layer, the anti-flammability of composite plate not only can be improved, but also the heat insulation property, waterproof and dampproof property and absorbing sound and lowering noise effect of composite plate can be improved.

Description

A kind of fire-resistant composite panel and preparation method thereof
Technical field
The present invention relates to building decoration area, specifically a kind of fire-resistant composite panel and preparation method thereof.
Background technique
Composite plate is mainly made of core material, adhesive and metal three parts.Wherein, composite plate currently on the market Most of be widely used in various building decorations and daily necessity based on composited aluminum and plastic decking.However, existing Composited aluminum and plastic decking, since core material is plastic material, it is poor there are fire retardant performance the problems such as.Although by grinding for many years , there are a variety of flame-retardant polyethylene plastic products in the market in hair, but is limited by the polyethylene anti-flaming ability upper limit, made from The fire-protection rating of composited aluminum and plastic decking can only at most promote B grades, therefore be unable to satisfy domestic and international building fire protection A grades of requirement.
In addition, though have the core material by using inorganic material such as palm environmental protection boards as composite plate in the prior art, To improve the fire protecting performance of composite plate, but composite plate the problems such as there are thermal insulation property and poor anti-acoustic capabilities, therefore also need pair Existing composite plate improves.
Summary of the invention
The purpose of the present invention is to provide a kind of fire-resistant composite panels and preparation method thereof, to solve to mention in above-mentioned background technique Out the problem of.
To achieve the above object, the embodiment of the present invention provides the following technical solutions:
A kind of preparation method of fire-resistant composite panel comprising following steps:
Foamed glass plate is chosen as core layer;
It is respectively covered with one layer of polymeric membrane in the upper and lower surface of core layer, forms two-layer bonded layer;
Respectively be covered with one layer of sheet metal on surface of the two-layer bonded layer far from core layer, form two metal layers, obtain half at Product;
Under the conditions of 150-260 DEG C of temperature, semi-finished product obtained above are applied with the pressure of 0.5-0.8MPa, and keeps 1- 10min obtains fire-resistant composite panel.
The rate of closed hole of a kind of preferred embodiment used in the embodiment of the present invention, the foamed glass plate is greater than 75%.
Another kind preferred embodiment used in the embodiment of the present invention, the percent opening of the foamed glass plate are greater than 50%.
It is used in the embodiment of the present invention another kind preferred embodiment, the foamed glass plate with a thickness of 3-30mm.
Another kind preferred embodiment used in the embodiment of the present invention, the polymeric membrane are hot melt adhesive film.
It is used in the embodiment of the present invention another kind preferred embodiment, the polymeric membrane with a thickness of 0.06-0.15mm.
Another kind preferred embodiment used in the embodiment of the present invention, the sheet metal are aluminium alloy sheet.
It is used in the embodiment of the present invention another kind preferred embodiment, the sheet metal with a thickness of 0.1-0.6mm.
The embodiment of the present invention also provides a kind of fire-resistant composite panel, including core layer, the upper and lower surface of the core layer according to Secondary to be provided with adhesive layer and metal layer, the core layer is foamed glass plate, and the metal layer is sheet metal, described Adhesive layer is polymeric membrane;The fire-resistant composite panel is made by above-mentioned preparation method.
It is used in the embodiment of the present invention another kind preferred embodiment, at least one layer described in metal layer on be additionally provided with decorative layer, The decorative layer is paint coatings.
The above-mentioned technical proposal of the offer of the embodiment of the present invention has following technical effect that compared with the prior art
(1) embodiment of the present invention between the metal layer that two layers is sheet metal by being arranged the core material that one layer is foamed glass plate Layer, and be bonded together foamed glass plate and sheet metal by polymeric membrane, so as to greatly improve the fire prevention of composite plate Performance makes the fire-protection rating of composite plate reach A grades.
(2) since the thermal coefficient of foamed glass plate is low, water absorption rate is low and has certain sound absorption, therefore pass through selection The anti-flammability of composite plate not only can be improved as core layer in foamed glass plate, but also the thermal insulation separation of composite plate can be improved Hot, waterproof and dampproof property and absorbing sound and lowering noise effect.
(3) embodiment of the present invention, which also passes through, selects polymeric membrane as adhesive layer, can pass through pressure in hot conditions Fire-resistant composite panel is made in preparation method, the preparation method simple process, easy to operate, so as to realize continuity, extensive Production.
(4) embodiment of the present invention, which also passes through, selects aluminium alloy sheet as metal layer, in order to be applied on the metal layer Material spraying forms decorative layer, so that the dicoration of composite plate is improved, so as to meet different clients to color and dress The demand of decorations property.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram for fire-resistant composite panel that embodiment 1 provides.
Fig. 2 is a kind of structural schematic diagram for fire-resistant composite panel that embodiment 2 provides.
In figure: 1- core layer, 2- metal layer, 3- adhesive layer, 4- decorative layer.
Specific embodiment
Following specific embodiment is the tool made in conjunction with the attached drawing provided in this specification to the technical solution of the application Body, clearly description.Wherein, the attached drawing of specification is intended merely to for the technical solution of the application being presented more clear bright , the shape or size in actual production or use are not represented, and can not be using the label of attached drawing as related power The limitation that benefit requires.
In addition, the term used should make the understanding of broad sense, for the technology of this field in the description of the present application For personnel, the concrete meaning of term can be understood according to actual concrete condition.For example, term employed in the application " setting " and " being equipped with " can be defined as contact setting or not in contact with formula setting etc.;Used noun of locality term is With reference to the accompanying drawings or according to being subject to direction defined in actual conditions and common knowledge.
Embodiment 1
Referring to attached drawing 1, this embodiment offers a kind of fire-resistant composite panels and preparation method thereof, specifically, the fire-resistant composite panel packet Core layer 1 is included, the upper and lower surface of the core layer 1 is disposed with adhesive layer 3 and metal layer 2.
Wherein, the core layer 1 be foamed glass plate, foamed glass plate with a thickness of 3mm.The metal layer 2 is Sheet metal, sheet metal with a thickness of 0.1mm;In addition, aluminium alloy sheet specifically can be selected in sheet metal, but not limited to this. The adhesive layer 3 is polymeric membrane, and polymeric membrane is hot melt adhesive film in the prior art, with a thickness of 0.06mm.
By selecting foamed glass plate as inorganic core material, the fire protecting performance of composite plate can be not only greatly improved, is made multiple The fire-protection rating of plywood reaches A grades, but also heat insulating ability, waterproof and dampproof property and the noise reduction effect of composite plate can be improved.
Further, the foamed glass plate is the insulation foamed glass plate that rate of closed hole is greater than 75% in the prior art, thus It can be further improved the thermal insulation and heat insulating ability of composite plate.
In addition, the preparation method of the fire-resistant composite panel the following steps are included:
S1, the foamed glass plate with a thickness of 3mm is chosen as core layer 1;
S2, it is respectively covered with the polymeric membrane that a layer thickness is 0.06mm in the upper and lower surface of core layer 1, forms two-layer bonded layer 3;
S3, it is respectively covered with the sheet metal that a layer thickness is 0.1mm on two-layer bonded surface of the layer 3 far from core layer 1, forms two Layer metal layer 2, obtains semi-finished product;
S4, under the conditions of 150 DEG C of temperature, with press machine semi-finished product obtained above are applied with the pressure of 0.5MPa, and is kept 1min melts polymeric membrane, and sheet metal is bonded on foamed glass plate, so that above-mentioned fire-resistant composite panel can be obtained.
Embodiment 2
Referring to attached drawing 2, this embodiment offers a kind of fire-resistant composite panels and preparation method thereof, specifically, the fire-resistant composite panel packet Core layer 1 is included, the upper and lower surface of the core layer 1 is disposed with adhesive layer 3 and metal layer 2, wherein one layer of metal layer 2 On be additionally provided with decorative layer 4.
Wherein, the core layer 1 be foamed glass plate, foamed glass plate with a thickness of 30mm.The metal layer 2 is Sheet metal, sheet metal with a thickness of 0.6mm;In addition, aluminium alloy sheet specifically can be selected in sheet metal, but not limited to this. The adhesive layer 3 is polymeric membrane, and polymeric membrane is hot melt adhesive film in the prior art, with a thickness of 0.15mm.Described Decorative layer 4 is paint coatings, to improve the dicoration of composite plate.
By selecting foamed glass plate as inorganic core material, the fire protecting performance of composite plate can be not only greatly improved, is made multiple The fire-protection rating of plywood reaches A grades, but also heat insulating ability, waterproof and dampproof property and the noise reduction effect of composite plate can be improved.
Further, the foamed glass plate is the sound-absorbing foamed glass plate that percent opening is greater than 50% in the prior art, thus It can be further improved sound insulation, the noise reduction effect of composite plate.
In addition, the preparation method of the fire-resistant composite panel the following steps are included:
S1, the foamed glass plate with a thickness of 30mm is chosen as core layer 1;
S2, it is respectively covered with the polymeric membrane that a layer thickness is 0.15mm in the upper and lower surface of core layer 1, forms two-layer bonded layer 3;
S3, it is respectively covered with the sheet metal that a layer thickness is 0.6mm on two-layer bonded surface of the layer 3 far from core layer 1, forms two Layer metal layer 2, obtains semi-finished product;
S4, under the conditions of 260 DEG C of temperature, with press machine semi-finished product obtained above are applied with the pressure of 0.8MPa, and is kept 10min melts polymeric membrane, and sheet metal is bonded on foamed glass plate, so that above-mentioned fire-resistant composite panel can be obtained. In addition, sprayed on one layer of metal layer 2 of the fire-resistant composite panel with the coating with color, it can be on one layer of metal layer 2 Decorative layer 4 is formed, so as to play the role of decoration and protection.
In conclusion the embodiment of the present invention between two metal layers 2 by being arranged the core material that one layer is foamed glass plate Layer 1, can greatly improve the fire protecting performance of composite plate, the fire-protection rating of composite plate is made to reach A grades.In addition, due to foamed glass The thermal coefficient of plate is low, water absorption rate is low and has certain sound absorption, therefore by selecting foamed glass plate as core layer 1, The anti-flammability of composite plate not only can be improved, but also the heat insulation property, waterproof and dampproof property and suction of composite plate can be improved Sound noise reduction effect.
The embodiment of the present invention, which also passes through, selects polymeric membrane as adhesive layer 3, can pass through the system of pressure in hot conditions Fire-resistant composite panel is made in Preparation Method, the preparation method simple process, easy to operate, so as to realize continuity, large-scale Production.Select aluminium alloy sheet as metal layer 2 in addition, the embodiment of the present invention passes through, in order to carry out coating on metal layer 2 Spraying forms decorative layer 4, so that the dicoration of composite plate is improved, so as to meet different clients to color and decoration The demand of property.
It should be noted that above-described embodiment carries out specifically, clearly just for the technical solution and technical characteristic of the application The description of Chu.And to those skilled in the art, belong to the scheme or feature of the prior art or common knowledge, above It is not just described in detail in embodiment.
Certainly, the technical solution of the application is not limited solely to the above embodiments, and those skilled in the art should will illustrate As a whole, the technical solutions in the various embodiments may also be suitably combined for book, so as to form those skilled in the art The other embodiments that member is understood that.

Claims (10)

1. a kind of preparation method of fire-resistant composite panel, which comprises the following steps:
Foamed glass plate is chosen as core layer (1);
It is respectively covered with one layer of polymeric membrane in the upper and lower surface of core layer (1), forms two-layer bonded layer (3);
It is respectively covered with one layer of sheet metal on the surface of two-layer bonded layer (3) far from core layer (1), is formed two metal layers (2), Obtain semi-finished product;
Under the conditions of 150-260 DEG C of temperature, semi-finished product obtained above are applied with the pressure of 0.5-0.8MPa, and keeps 1- 10min obtains fire-resistant composite panel.
2. a kind of preparation method of fire-resistant composite panel according to claim 1, which is characterized in that the foamed glass plate Rate of closed hole be greater than 75%.
3. a kind of preparation method of fire-resistant composite panel according to claim 1, which is characterized in that the foamed glass plate Percent opening be greater than 50%.
4. a kind of preparation method of fire-resistant composite panel according to claim 2 or 3, which is characterized in that the foamed glass Plate with a thickness of 3-30mm.
5. a kind of preparation method of fire-resistant composite panel according to claim 1, which is characterized in that the polymeric membrane is Hot melt adhesive film.
6. a kind of preparation method of fire-resistant composite panel according to claim 5, which is characterized in that the thickness of the polymeric membrane Degree is 0.06-0.15mm.
7. a kind of preparation method of fire-resistant composite panel according to claim 1, which is characterized in that the sheet metal is Aluminium alloy sheet.
8. a kind of preparation method of fire-resistant composite panel according to claim 7, which is characterized in that the thickness of the sheet metal Degree is 0.1-0.6mm.
9. the upper and lower surface of a kind of fire-resistant composite panel, including core layer (1), the core layer (1) is disposed with adhesive layer (3) and metal layer (2), which is characterized in that the core layer (1) is foamed glass plate, and the metal layer (2) is metal foil Plate, the adhesive layer (3) are polymeric membrane;The fire-resistant composite panel passes through as of any of claims 1-8 Preparation method is made.
10. a kind of fire-resistant composite panel according to claim 9, which is characterized in that on metal layer (2) described at least one layer It is additionally provided with decorative layer (4), the decorative layer (4) is paint coatings.
CN201910580978.2A 2019-06-29 2019-06-29 A kind of fire-resistant composite panel and preparation method thereof Pending CN110216943A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910580978.2A CN110216943A (en) 2019-06-29 2019-06-29 A kind of fire-resistant composite panel and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910580978.2A CN110216943A (en) 2019-06-29 2019-06-29 A kind of fire-resistant composite panel and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110216943A true CN110216943A (en) 2019-09-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111535536A (en) * 2020-05-13 2020-08-14 福州索科特材料科技有限公司 Metal foamed ceramic fireproof composite board
CN111746084A (en) * 2020-07-01 2020-10-09 广东高丽铝业有限公司 Preparation method of PVC aerogel co-agent foaming board

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111535536A (en) * 2020-05-13 2020-08-14 福州索科特材料科技有限公司 Metal foamed ceramic fireproof composite board
CN111746084A (en) * 2020-07-01 2020-10-09 广东高丽铝业有限公司 Preparation method of PVC aerogel co-agent foaming board

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