CN107805429A - A kind of waterborne reflective heat-insulating building coating and apply its heat insulation decoration integrated plate - Google Patents

A kind of waterborne reflective heat-insulating building coating and apply its heat insulation decoration integrated plate Download PDF

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Publication number
CN107805429A
CN107805429A CN201710970383.9A CN201710970383A CN107805429A CN 107805429 A CN107805429 A CN 107805429A CN 201710970383 A CN201710970383 A CN 201710970383A CN 107805429 A CN107805429 A CN 107805429A
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China
Prior art keywords
heat
decoration integrated
integrated plate
coating
parts
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CN201710970383.9A
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Chinese (zh)
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CN107805429B (en
Inventor
吴银河
陈燕
汪斌
陈团
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XIAMEN KUCK COATING GROUP CO Ltd
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XIAMEN KUCK COATING GROUP CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/28Glass
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire

Abstract

The invention discloses a kind of waterborne reflective heat-insulating building coating, includes following raw material by mass fraction:10~15 parts of water, 50~60 parts of reflective insulation emulsion, 5~20 parts of rutile type titanium white, 1~5 part of heat reflection mill base, 8~10 parts of hollow glass micropearl, 5~8 parts of ceramic, 2.5~3.5 parts of auxiliary agent.The invention also discloses the heat insulation decoration integrated plate of application above-mentioned coating, include heat-insulation layer, tack coat, substrate layer and finish coat successively outward by interior, coating of the present invention has good reflective insulation effect, the heat insulation effect of heat insulation decoration integrated plate is largely improved, more efficiently realizes building energy conservation.

Description

A kind of waterborne reflective heat-insulating building coating and apply its heat insulation decoration integrated plate
Technical field
The present invention relates to building coating field, more particularly to a kind of waterborne reflective heat-insulating building coating, and apply the coating Heat insulation decoration integrated plate.
Background technology
Heat insulation decoration integrated plate wall insulation system can effectively improve external-wall exterior insulation performance, optimization indoor thermal environment, Reduce building and heating refrigeration Energy in use while energy-saving heat preserving engineering can be met to fire protecting performance and ornamental requirement;In recent years Come, already progressively instead of conventional outer wall outer heat preservation system.
Heat insulation decoration integrated plate wall insulation system by heat insulation decoration integrated plate, adhesive, Special anchor bolt, fixed fastener, Pointing and fluid sealant etc. form.Wherein heat insulation decoration integrated plate is the machine-shaping that is prefabricated in the factory, by decorative surface deck panels With warming plate, or the composite board formed with substrate bonding.The thermal conductivity factor of warming plate insulation material is building energy conservation The primary factor of design and select material, thermal conductivity factor are the intrinsic physical properties of insulation material, on the premise of selected insulation material, also Can be by increasing the thickness of insulation material further to improve warming plate insulation the effect of.In order to pursue higher energy-conservation Efficiency, the thickness of existing heat insulation decoration integrated plate warming plate is more and more thicker, has thus triggered the problem of new:
《JG/T 287-2013 heat insulating decorative board material for external thermal insulation system of external wall》Standard regulation, heat insulation decoration integrated plate Mass area ratio need≤30kg/ ㎡, increase insulation plate thickness, it is meant that the mass area ratio of heat insulation decoration integrated plate also increases Greatly, in order to meet standard regulation, by increasing insulation plate thickness to improve insulation effect be also limited;On the other hand, Mass area ratio increases, and is runed counter to the performance characteristics of heat insulation decoration integrated plate lightweight, can also increase the weight of building;In addition The overall coating of heat insulation decoration integrated plate is thicker, very big potential safety hazard be present to subsequent use user.
The content of the invention
For above-mentioned technical background problem, it is an object of the invention to provide a kind of waterborne reflective heat-insulating building coating and application Its heat insulation decoration integrated plate, so that on the premise of thickness is not increased, there is the effect of good insulation.
To achieve the above objectives, the invention discloses a kind of waterborne reflective heat-insulating building coating, by mass fraction include with Lower raw material:10~15 parts of water, 50~60 parts of reflective insulation emulsion, 5~20 parts of rutile type titanium white, heat reflection mill base 1~5 Part, 8~10 parts of hollow glass micropearl, 5~8 parts of ceramic, 2.5~3.5 parts of auxiliary agent.
Preferably, described reflective insulation emulsion is acrylic emulsion.Acrylic emulsion, more conventional emulsion have lower folding Rate is penetrated, increases the refringence of medium and titanium dioxide in coating, improves whole coating scattered power, therefore can be reflected more Solar radiation;Its unique UV-crosslinked technology provides excellent stain resistance in addition, after the higher pollution of holding too Sunlight reflectance value.
Preferably, the average grain diameter of described hollow glass micropearl is 40~50 μm.Hollow glass micropearl be isolation-type every Fuel factor filler, there is good effect of heat insulation.
Preferably, described ceramic is infrared radiation ceramic micro mist, emissivity >=0.9 of its 8~13.5 mu m waveband. Infrared radiation ceramic micro mist belongs to radiation type heat-insulation effect filler, and infrared radiation ceramic be able to will be absorbed in the form of heat emission To heat radiation fall, so as to reach insulative effectiveness.
The invention also discloses a kind of heat insulation decoration integrated plate, includes heat-insulation layer, tack coat, substrate layer successively outward by interior And finish coat, described finish coat are made up of seal coat coating, waterborne reflective heat-insulating building coating and finishing coat outward interior, Described seal coat coating is coated by seal coat to be formed, and described waterborne reflective heat-insulating building coating water-based is built by above-mentioned Build reflective heat-insulation paint to coat to be formed, described finishing coat is coated by finishing varnish to be formed.
Wherein, described seal coat is that one-component propylene permeates priming paint, aqueous polyurethane permeates priming paint, water-base epoxy oozes Reveal the exact details paint, water-based UV infiltration priming paint in one kind.It is used to improving attached between waterborne reflective heat-insulating building coating and substrate layer Put forth effort.
Wherein, the finishing varnish is aqueous double-component polyurethane finishing varnish.Aqueous double-component polyurethane finishing varnish With many-sided excellent properties, using aqueous double-component polyurethane finishing varnish can be lifted the more excellent weatherability of Bulk coat, Stain resistance, ensure that coating persistently keeps long-acting sun luminous reflectance.
Wherein, heat-insulation layer material is in XPS plate, EPS sheet, PU cystosepiment, PF cystosepiments, rock wool belt, thermosetting molded plate It is a kind of.
Preferably, described tack coat is no-solvent polyurethane structure glue.
Preferably, the material of described substrate layer is fiber reinforcement asbestos-free calcium silicate board.It is main realize bending resistance, anti-folding, The functions such as shock resistance.
The beneficial effects of the present invention are:
1st, coating of the present invention is environment-friendly products, no APE0, formaldehydeless, low smell, low VOC.
2nd, low thermal conductivity factor can be obtained containing hollow glass micropearl in coating of the present invention, height can be obtained containing ceramic Hemispherical emissivity, raw material rutile type titanium white and heat reflection mill base can obtain high sun luminous reflectance and near-infrared reflection Than using the lower reflective insulation emulsion of refractive index, increasing the refringence of medium and titanium dioxide, improving whole coating Scattered power;Above-mentioned several raw material effect Synergistics so that waterborne reflective heat-insulating building coating of the present invention has good insulation Heat-insulated efficiency.
3rd, by waterborne reflective heat-insulating building coating of the present invention, optimal effect is obtained applied to heat insulation decoration integrated plate finish coat Fruit:(1) thick apply of waterborne reflective heat-insulating building coating can more play insulation effect than scumbling, with exterior wall scene elevation construction side Formula is different, and the finish coat of heat insulation decoration integrated plate is plane construction, it is easier to realizes thick apply;Millwork metaplasia production. art, more Advantageously ensure that the homogeneity of waterborne reflective heat-insulating building coating coating thickness;
(2) if not changing the thickness of heat insulation decoration integrated plate, using waterborne reflective heat-insulating building coating as insulation and decoration one The facing layer material of body plate, it can further lift the energy-saving effect of heat insulation decoration integrated plate;
(3) same energy-saving design is reached, the finish coat using waterborne reflective heat-insulating building coating as heat insulation decoration integrated plate Material, by the characteristic of the reflection heat of reflective heat-insulation paint itself, trap heat and radiations heat energy, make heat insulation decoration integrated plate Reach more preferable energy-conservation, while the thickness of warming plate can be reduced to a certain extent, reduce heat insulation decoration integrated plate unit area Quality while solve coating structure potential safety hazard;
(4) raw material reflective insulation emulsion is used, its glass transition temperature is moderate, is applied with the waterborne reflective heat-insulating building of its preparation After expecting drying and forming-film, film has impact resistance and pliability concurrently, as heat insulation decoration integrated plate facing layer material, will not cause and hold While carrying the deformation such as the panel generation warpage of finish coat, it can meet that heat insulation decoration integrated plate has very high adhesive force to coating Requirement.
4th, heat insulation decoration integrated plate of the present invention has excellent coating structure:Heat-insulation layer provides trap heat, fire prevention effect; Substrate layer provides bending resistance, resistance to compression, shock resistance effect;Gathered between heat-insulation layer and substrate layer by non-solvent foamed type macromolecule polyurethane Bonding adhesive force between the offer layer by layer of compound structure glue;By the attachment between seal coat offer layer by layer between finish coat and substrate layer Power;Reflective heat-insulation paint finish coat provides higher sun luminous reflectance, has preferable reflective insulation performance;Finishing coat provides Excellent weatherability, stain resistance, ensure that facing coating has permanent heat reflection ratio.
Brief description of the drawings
Fig. 1 is the structural representation of heat insulation decoration integrated plate of the present invention.
Fig. 2 is the heat insulation decoration integrated plate contrast test schematic diagram of heat insulation decoration integrated plate of the present invention and common facing.
Primary symbols explanation:
1st, heat-insulation layer, 2:Tack coat, 3:Substrate layer, 4:Finish coat, 41:Seal coat coating, 42:Aqueous architectural reflection every Hot coating, 43:Finishing coat, 5:Heat insulation decoration integrated plate, 6:The heat insulation decoration integrated plate of common facing, 7:Without paper thermograph Instrument.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to invent into Row is further described.
Embodiment one~tetra-
The invention discloses a kind of waterborne reflective heat-insulating building coating, and (propylene yogurt is selected by water, reflective insulation emulsion Liquid), rutile type titanium white, heat reflection mill base, hollow glass micropearl, ceramic (selecting infrared radiation ceramic micro mist), help Agent is prepared by the mass fraction material composition of table 1.
The waterborne reflective heat-insulating building coating material composition table of table 1.
The average grain diameter of hollow glass micropearl is 40~50 μm, and Main Ingredients and Appearance is borosilicate matter;Structure hollow, have hard Shell, in shell be N2Or CO2Inert gas, wall thickness are the 10-20% of its diameter;Thermal conductivity factor is 0.043W/mK, resistance to compression Intensity about 3.4MPa, effective density 0.2g/cm3
Infrared radiation ceramic micro mist, emissivity >=0.9 of its 8~13.5 mu m waveband.
Heat reflection mill base is by coating technology, mill base is had infrared external reflection effect, with heat reflection color paste toning, can make The waterborne reflective heat-insulating building coating has higher sun luminous reflectance and near-infrared reflection ratio under different lightness.
Embodiment five
As shown in figure 1, present embodiment discloses a kind of heat insulation decoration integrated plate, by the interior heat-insulation layer 1, viscous of including successively outward Tie layer 2, substrate layer 3 and finish coat 4.Finish coat 4 is by interior outward by seal coat coating 41, waterborne reflective heat-insulating building coating 42 Formed with finishing coat 43.The seal coat coating 41 of finish coat 4 is coated by seal coat to be formed, waterborne reflective heat-insulating building coating 42 are coated by the waterborne reflective heat-insulating building coating of embodiment 1~4 and are formed, and finishing coat 43 is coated by finishing varnish to be formed.Each layer Material selection it is as shown in table 2.
The material selection of the heat insulation decoration integrated plate of table 2.
The material that the present embodiment is specifically selected is as follows:
Heat-insulation layer 1 is thermosetting molded plate, thickness 60mm, density 35kg/m3, compressive strength 0.20MPa, tensile strength 0.15MPa, thermal conductivity factor (25 DEG C) 0.038W/ (m.k).
Tack coat 2 is non-solvent foamed type macromolecule polyurethane polymer architecture glue, pull strength 6MPa, frothing percentage 40~ 80%, operable time after mixing >=25min/25 DEG C.
Substrate layer 3 is fiber reinforcement asbestos-free calcium silicate board, thickness 8mm, dry density 1.4g/cm3, rupture strength 16MPa, Moisture content 9%.Frost resistance is through 25 Frozen-thawed cycled crack-frees, layering, the dry rupture strength >=16MPa of gas, and the water rupture strength of satisfying >= 13MPa, fire-protection rating are not less than A2 levels.
Seal coat is that water-base epoxy permeates priming paint.Waterborne reflective heat-insulating building coating 42 is that the raw material of embodiment one is prepared into Arrive.Finishing varnish is aqueous double-component polyurethane finishing varnish.
Heat insulation decoration integrated plate made from the present embodiment is detected, specific experimental test mode and equipment:
1st, testing standard:Tested according to standard JG/T 235-2014, JG/T 287-2013.
2nd, instrument source:Hualong Detector Co., Ltd., Shanghai's WDW-50C universal testing machines.
Xiamen grace Lay automates Science and Technology Ltd. ELR-90 without paper moisture recorder
3rd, auxiliary test methods:Censorship detects.
Spatial volume is spliced into as 1m using heat insulation decoration integrated plate made from above-described embodiment3Casing is experimental subjects, is surveyed Its main physico-mechanical performance is tried, as a result as shown in table 3.
The heat insulating decorative board decorative cover performance test table of table 3
As shown in Fig. 2 the heat insulation decoration integrated plate 6 of heat insulation decoration integrated plate 5 and the common facing of the present invention is carried out pair Than test, in the case where shining upon, the testing time is from 8:00 to 18:00, using the coating table without paper moisture recorder 7 to two groups of plates Face temperature and cavity inside temperature are tested, as a result as shown in table 4.
Table 4 is of the invention with the heat insulation decoration integrated plate contrast test of common facing
Test point The temperature difference
Coated Surface Temperature test point A, B 3~5 DEG C of the temperature difference
Cavity inside temperature test point C, D 4~6 DEG C of the temperature difference
From table 3, table 4 as can be seen that reflective insulation performance indications of the present invention meet《JG/T 235-2014 building reflection every Hot coating》The regulation of standard, show that waterborne reflective heat-insulating building coating of the present invention is used for heat insulation decoration integrated plate and has thermal insulation separation Hot merit is imitated, and is used as the material of heat insulation decoration integrated plate finish coat, effectively can further be realized building energy conservation.
To sum up, on the premise of identical insulation effect is reached, heat insulation decoration integrated plate facing coating using reflection every Hot coating can suitably reduce insulation layer thickness, can substantially reduce the unit mass of whole coating, solve because weight issue produces Potential safety hazard, there is application value.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, the change or replacement that can readily occur in, It should all be included within the scope of the present invention.

Claims (10)

1. a kind of waterborne reflective heat-insulating building coating, it is characterised in that include following raw material by mass fraction:10~15 parts of water, 50~60 parts of reflective insulation emulsion, 5~20 parts of rutile type titanium white, 1~5 part of heat reflection mill base, hollow glass micropearl 8~10 Part, 5~8 parts of ceramic, 2.5~3.5 parts of auxiliary agent.
2. waterborne reflective heat-insulating building coating as claimed in claim 1, it is characterised in that described reflective insulation emulsion is third Olefin(e) acid emulsion.
3. waterborne reflective heat-insulating building coating as claimed in claim 1, it is characterised in that described hollow glass micropearl is put down Equal particle diameter is 40~50 μm.
4. waterborne reflective heat-insulating building coating as claimed in claim 1, it is characterised in that described ceramic is infrared spoke Ceramic is penetrated, the emissivity of its 8~13.5 mu m waveband0.9。
A kind of 5. heat insulation decoration integrated plate, it is characterised in that:Include heat-insulation layer, tack coat, substrate layer and decorations successively outward by interior Surface layer, described finish coat is made up of seal coat coating, waterborne reflective heat-insulating building coating and finishing coat outward interior, described Seal coat coating coated and formed by seal coat, described waterborne reflective heat-insulating building coating is any by Claims 1 to 4 Waterborne reflective heat-insulating building coating described in is coated to be formed, and described finishing coat is coated by finishing varnish to be formed.
6. heat insulation decoration integrated plate as claimed in claim 5, it is characterised in that:Described seal coat is that one-component propylene oozes Revealing the exact details, paint, aqueous polyurethane permeate priming paint, water-base epoxy permeates priming paint, one kind in water-based UV infiltration priming paint.
7. heat insulation decoration integrated plate as claimed in claim 5, it is characterised in that:The finishing varnish is the poly- ammonia of aqueous double-component Ester finishing varnish.
8. heat insulation decoration integrated plate as claimed in claim 5, it is characterised in that:Described heat-insulation layer material is XPS plate, EPS One kind in plate, PU cystosepiment, PF cystosepiments, rock wool belt, thermosetting molded plate.
9. heat insulation decoration integrated plate as claimed in claim 5, it is characterised in that:Described tack coat is no-solvent polyurethane knot Structure glue.
10. heat insulation decoration integrated plate as claimed in claim 5, it is characterised in that:The material of described substrate layer increases for fiber Strong asbestos-free calcium silicate board.
CN201710970383.9A 2017-10-18 2017-10-18 Water-based building reflective heat-insulating coating and heat-insulating decorative integrated board applying same Active CN107805429B (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN108909120A (en) * 2018-08-25 2018-11-30 广东高丽铝业有限公司 A kind of reflective insulation foam polyvinyl chloride composite plate
CN108943958A (en) * 2018-08-25 2018-12-07 广东高丽铝业有限公司 A kind of polyvinyl chloride silica co-extrusion foaming composite metal plate
CN109517459A (en) * 2018-11-20 2019-03-26 四川华邦保和涂料有限公司 A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint
CN112248571A (en) * 2020-10-21 2021-01-22 汇克涂料(湖南)有限公司 Fireproof heat-preservation reflection heat-insulation wall heat-preservation composite board and preparation method thereof
CN113737531A (en) * 2021-09-26 2021-12-03 深圳市联星服装辅料有限公司 Impregnation liquid, waterborne polyurethane impregnation polyester cord and preparation method thereof
CN115387556A (en) * 2022-08-30 2022-11-25 金彩螺新材料科技有限公司 Energy-saving and heat-insulating architectural decoration system for outer wall

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CN104675042A (en) * 2014-12-26 2015-06-03 高俊丽 Manufacturing method of vacuum thermal-insulation and decoration integrated board
CN106010029A (en) * 2016-07-05 2016-10-12 阳泉市澳丽丝科技涂料有限公司 Water-based outer wall heat insulation and preservation coating and preparation method thereof
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CN101481583A (en) * 2008-01-08 2009-07-15 北京航空航天大学 Aqueous contamination resistant heat reflection phase change insulating paint and its preparing process
CN104212286A (en) * 2014-08-26 2014-12-17 中国建筑股份有限公司 Gray solar reflective cooling coating and preparation method thereof
CN104675042A (en) * 2014-12-26 2015-06-03 高俊丽 Manufacturing method of vacuum thermal-insulation and decoration integrated board
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108909120A (en) * 2018-08-25 2018-11-30 广东高丽铝业有限公司 A kind of reflective insulation foam polyvinyl chloride composite plate
CN108943958A (en) * 2018-08-25 2018-12-07 广东高丽铝业有限公司 A kind of polyvinyl chloride silica co-extrusion foaming composite metal plate
CN109517459A (en) * 2018-11-20 2019-03-26 四川华邦保和涂料有限公司 A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint
CN112248571A (en) * 2020-10-21 2021-01-22 汇克涂料(湖南)有限公司 Fireproof heat-preservation reflection heat-insulation wall heat-preservation composite board and preparation method thereof
CN113737531A (en) * 2021-09-26 2021-12-03 深圳市联星服装辅料有限公司 Impregnation liquid, waterborne polyurethane impregnation polyester cord and preparation method thereof
CN113737531B (en) * 2021-09-26 2023-10-20 深圳市联星服装辅料有限公司 Dipping liquid, aqueous polyurethane dipping polyester rope and preparation method thereof
CN115387556A (en) * 2022-08-30 2022-11-25 金彩螺新材料科技有限公司 Energy-saving and heat-insulating architectural decoration system for outer wall
CN115387556B (en) * 2022-08-30 2023-10-13 金彩螺新材料科技有限公司 Energy-saving heat-insulating building decoration system for outer wall

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