CN108296150A - A kind of oil tank of transformer spraying technology - Google Patents

A kind of oil tank of transformer spraying technology Download PDF

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Publication number
CN108296150A
CN108296150A CN201710869986.XA CN201710869986A CN108296150A CN 108296150 A CN108296150 A CN 108296150A CN 201710869986 A CN201710869986 A CN 201710869986A CN 108296150 A CN108296150 A CN 108296150A
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CN
China
Prior art keywords
oil tank
paint film
spraying technology
technology according
acid anhydride
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710869986.XA
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Chinese (zh)
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CN108296150B (en
Inventor
刘立忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG JIANGSHAN POWER TRANSFORMER Co.,Ltd.
Original Assignee
Jiangshan Haiwei Technology Co Ltd
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Priority to CN201710869986.XA priority Critical patent/CN108296150B/en
Publication of CN108296150A publication Critical patent/CN108296150A/en
Application granted granted Critical
Publication of CN108296150B publication Critical patent/CN108296150B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/586No clear coat specified each layer being cured, at least partially, separately
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B05D7/26Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials synthetic lacquers or varnishes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09D179/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2518/00Other type of polymers
    • B05D2518/10Silicon-containing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2530/00Rubber or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of oil tank of transformer spraying technologies, include the following steps:Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process;Step 2. sprays first of paint film in the inner side and outer side of fuel tank;Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank;Second paint film is sprayed on elastic resin buffer layer after step 4. drying.

Description

A kind of oil tank of transformer spraying technology
Technical field
The present invention relates to a kind of oil tank of transformer spraying technologies.
Background technology
Fuel tank is the shell of transformer, built-in iron core and winding and is full of transformer oil, and iron core and winding is made to be immersed in oil. Transformer oil plays insulation and cooling effect.For high-power transformer generally there are two fuel tank, one is ontology fuel tank;One is to have load to wither Pressure oil case, on-load voltage regulation fuel tank is interior to be equipped with tap switch.This is because tap switch will produce electric arc in operation, if into Row frequent operation will make the decreasing insulating of oil, therefore it is individually placed by tap switch to set an individual fuel tank.
Common oil tank of transformer presses the size of its capacity, there is 3 kinds of box fuel tank, bell type tank and sealed fuel tank bases This pattern.
CN102962187A discloses the enamelling process of a kind of oil tank of transformer and its parts, includes the following steps:The One step, the allotment first painted;Second step, after paint deployment is good, with the sand net filtration of 120~180 mesh;Third walks, and carries out Japanning;4th step, is painted with after paint, is dried.
CN106064139A discloses a kind of external coating technique of oil tank of transformer, includes the following steps:1)To oil Case, combination become fuel tank, combination becomes door-plate and surface and oil contaminant compared with the pre- ungrease treatment of the advanced row of multi-work piece;2)Degreasing and rust removal:Surface oil Dirt directly enters slot compared with light industry part and carries out room temperature processing;3)First of washing:Normal-temperature operation, workpiece control under liquid, are front and back, upper and lower It swings;4)Second is washed:Normal-temperature operation, workpiece control under liquid, are front and back, swinging up and down;5)Phosphatization;6)Hot water embathes:Slot Liquid temperature is not less than 70 DEG C, 1~2 min of time;7)Drying;8)Coating prime lacquer:In the inner and outer wall spray-applied primer of babinet;9) Application intermediate layer paint:Intermediate layer paint is sprayed in the inner and outer wall of babinet;10)Coating finish:In the inner and outer wall spray-coating surface of babinet Paint.
Existing oil tank of transformer sprays paint film, primary disadvantage is that easy to produce fall off, slight crack, to make tank body of oil tank There is the phenomenon that corrosion, while the measure without preventing issuable collision in routine use.
Invention content
The purpose of the present invention is:There is provided a kind of oil tank of transformer spraying technology, it is characterised in that following steps:
Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process.
Step 2. sprays first of paint film in the inner side and outer side of fuel tank.
Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank.
Second paint film is sprayed on elastic resin buffer layer after step 4. drying.
First of paint film is using chlorinated rubber cloud iron paint.
The elastic resin buffer layer preparation method is:By weight, by pyromellitic acid anhydride, diphenyldiamine It is dissolved in dimethylformamide, bis- (trimethylsiloxy group) cyclobutanes of 1,2- is added, 1,1- crown ether -4 dimethyl sila -11- rise Temperature reacts 3-8h, is added Glutathione Sepharose into product after reaction to 125-140 DEG C, calcium carbonate to get to Elastic resin buffer layer.
The second paint film is using epoxy coating.
The diphenyldiamine, quality dosage are the 60-75% of pyromellitic acid anhydride.
Bis- (trimethylsiloxy group) cyclobutanes of 1, the 2-, quality dosage are the 1.5- of pyromellitic acid anhydride 4.5%。
Crown ether -4 1,1- dimethyl sila -11-, quality dosage are the 1-3% of pyromellitic acid anhydride.
The Glutathione Sepharose, quality dosage are the 1-3% of pyromellitic acid anhydride.
The calcium carbonate, quality dosage are the 4-8% of pyromellitic acid anhydride.
The pyromellitic acid anhydride is commercial product, the production produced such as Zhengzhou Brian Jacks chemical products Co., Ltd Product;The diphenyldiamine is commercial product, the product produced such as Shanghai Rong Chuan Bioisystech Co., Ltd;The 1,2- Bis- (trimethylsiloxy group) cyclobutanes are commercial product, the product produced such as Hangzhou Pin Gao Chemical Co., Ltd.s;The 1,1- Dimethyl sila -11- crown ethers -4 are commercial product, the product produced such as Beijing Chemical Co., Ltd. of Hua Weirui sections;Glutathione Ago-Gel is commercial product, the product produced such as Xi'an Lanxiao Sci-Tech Co., Ltd..
The product of the present invention has the advantages that:
Elastic resin buffer layer of the present invention has good elasticity, ductility, adherence, is touched in fuel tank paint film When hitting, the energy of collision can be buffered, sticks together inside and outside twice paint film, protection fuel tank paint film is damaged smaller;Elasticity tree Fat has excellent dielectric property, and dielectric constant is small, is suitable as the use of oil tank of transformer paint film;Elastic resin layer contains carbonic acid Calcium, surface is more concave-convex, convenient for being connected even closer with inside and outside twice paint film.
Specific implementation mode
Following instance is only to further illustrate the present invention, and is not limitation the scope of protection of the invention.
Embodiment 1
Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process.
Step 2. sprays first of chlorinated rubber cloud iron paint film in the inner side and outer side of fuel tank.
Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank.
Second epoxy resin paint film is sprayed on elastic resin buffer layer after step 4. drying.
The elastic resin buffer layer preparation method is:In a kettle, addition pyromellitic acid anhydride 100Kg, two The phenylate diamines dimethyl sila -11- crown ether -42Kg of 67.5Kg, 1,2- bis- (trimethylsiloxy group) cyclobutane 3Kg, 1,1-, heating To 132 DEG C, react 5.5h, after reaction into product be added Glutathione Sepharose 2Kg, calcium carbonate 6Kg to get to Elastic resin buffer layer.
Embodiment 2
Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process.
Step 2. sprays first of chlorinated rubber cloud iron paint film in the inner side and outer side of fuel tank.
Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank.
Second epoxy resin paint film is sprayed on elastic resin buffer layer after step 4. drying.
The elastic resin buffer layer preparation method is:In a kettle, addition pyromellitic acid anhydride 100Kg, two The phenylate diamines dimethyl sila -11- crown ether -41Kg of 60Kg, 1,2- bis- (trimethylsiloxy group) cyclobutane 1.5Kg, 1,1-, heating To 125 DEG C, 3h is reacted, Glutathione Sepharose 1Kg is added into product after reaction, calcium carbonate 4Kg is to get to bullet Property resin buffer layer.
Embodiment 3
Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process.
Step 2. sprays first of chlorinated rubber cloud iron paint film in the inner side and outer side of fuel tank.
Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank.
Second epoxy resin paint film is sprayed on elastic resin buffer layer after step 4. drying.
The elastic resin buffer layer preparation method is:In a kettle, addition pyromellitic acid anhydride 100Kg, two The phenylate diamines dimethyl sila -11- crown ether -43Kg of 75Kg, 1,2- bis- (trimethylsiloxy group) cyclobutane 4.5Kg, 1,1-, heating To 140 DEG C, 8h is reacted, Glutathione Sepharose 3Kg is added into product after reaction, calcium carbonate 8Kg is to get to bullet Property resin buffer layer.
Comparative example 1
Bis- (trimethylsiloxy group) cyclobutanes of 1,2- are added without in elastic resin, other conditions are the same as embodiment 1.
Comparative example 2
Crown ether -4 1,1- dimethyl sila -11- are added without in elastic resin, other conditions are the same as embodiment 1.
Comparative example 3
Glutathione Sepharose is added without in elastic resin, other conditions are the same as embodiment 1.
Embodiment 4
The dielectric constant for the elastic resin that inspection embodiment 1-3 and comparative example 1-3 is produced respectively, and testing elastic resin Elongation percentage.
The dielectric constant for the elastic resin that 1 embodiment 1-3 of table and comparative example 1-3 is produced.

Claims (9)

1. the present invention relates to a kind of oil tank of transformer spraying technologies, it is characterised in that following steps:
Step 1. cleans the fuel tank that sprays of needs, phosphatization, drying process;
Step 2. sprays first of paint film in the inner side and outer side of fuel tank;
Step 3. after drying, sprays one layer of elastic resin buffer layer on first of paint film of fuel tank;
Second paint film is sprayed on elastic resin buffer layer after step 4. drying.
2. a kind of oil tank of transformer spraying technology according to claim 1, it is characterised in that:First of paint film is adopted It is chlorinated rubber cloud iron paint.
3. a kind of oil tank of transformer spraying technology according to claim 1, it is characterised in that:The elastic resin buffering Layer preparation method be:By weight, by pyromellitic acid anhydride, diphenyldiamine is dissolved in dimethylformamide, is added 1, Bis- (trimethylsiloxy group) cyclobutanes of 2-, 1,1- crown ether -4 dimethyl sila -11- are warming up to 125-140 DEG C, react 3-8h, instead It is added Glutathione Sepharose after should terminating into product, calcium carbonate is to get to elastic resin buffer layer.
4. a kind of oil tank of transformer spraying technology according to claim 1, it is characterised in that:The second paint film is adopted It is epoxy coating.
5. a kind of oil tank of transformer spraying technology according to claim 3, it is characterised in that:The diphenyldiamine, Its quality dosage is the 60-75% of pyromellitic acid anhydride.
6. a kind of oil tank of transformer spraying technology according to claim 3, it is characterised in that:Bis- (the front threes of the 1,2- Base siloxy) cyclobutane, quality dosage is the 1.5-4.5% of pyromellitic acid anhydride.
7. a kind of oil tank of transformer spraying technology according to claim 3, it is characterised in that:The 1,1- dimethyl-silicons Miscellaneous crown ether-4-11-, quality dosage are the 1-3% of pyromellitic acid anhydride.
8. a kind of oil tank of transformer spraying technology according to claim 3, it is characterised in that:The glutathione-agarose Sugared gel, quality dosage are the 1-3% of pyromellitic acid anhydride.
9. a kind of oil tank of transformer spraying technology according to claim 3, it is characterised in that:The calcium carbonate, matter Measure the 4-8% that dosage is pyromellitic acid anhydride.
CN201710869986.XA 2017-09-23 2017-09-23 Spraying technology for transformer oil tank Active CN108296150B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710869986.XA CN108296150B (en) 2017-09-23 2017-09-23 Spraying technology for transformer oil tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710869986.XA CN108296150B (en) 2017-09-23 2017-09-23 Spraying technology for transformer oil tank

Publications (2)

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CN108296150A true CN108296150A (en) 2018-07-20
CN108296150B CN108296150B (en) 2020-08-25

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102962187A (en) * 2012-12-17 2013-03-13 江苏亨特集团华特电气有限公司 Transformer oil tank and painting technique for parts thereof
CN105140013A (en) * 2015-09-23 2015-12-09 江苏宏源电气有限责任公司 Paint spraying process for corrugated oil tank of oil-immersed transformer
CN106064139A (en) * 2016-04-27 2016-11-02 南通盛洋电气有限公司 A kind of external coating technique of oil tank of transformer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102962187A (en) * 2012-12-17 2013-03-13 江苏亨特集团华特电气有限公司 Transformer oil tank and painting technique for parts thereof
CN105140013A (en) * 2015-09-23 2015-12-09 江苏宏源电气有限责任公司 Paint spraying process for corrugated oil tank of oil-immersed transformer
CN106064139A (en) * 2016-04-27 2016-11-02 南通盛洋电气有限公司 A kind of external coating technique of oil tank of transformer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李敏风等: "变压器油箱涂装设计一例", 《腐蚀与防护》 *

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PB01 Publication
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SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
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Effective date of registration: 20221025

Address after: No. 1 Xinggong Road, Jiangdong District, Jiangshan Economic Development Zone, Quzhou City, Zhejiang Province 324123

Patentee after: ZHEJIANG JIANGSHAN POWER TRANSFORMER Co.,Ltd.

Address before: 324100 3 building, 24 West Ring Road, Jiangshan City, Quzhou, Zhejiang.

Patentee before: JIANGSHAN HAIWEI TECHNOLOGY Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A Spraying Technology for Transformer Oil Tank

Granted publication date: 20200825

Pledgee: Zhejiang Jiangshan rural commercial bank Limited by Share Ltd.

Pledgor: ZHEJIANG JIANGSHAN POWER TRANSFORMER Co.,Ltd.

Registration number: Y2024980017429