Spraying technology for transformer oil tank
Technical Field
The invention relates to a spraying technology of a transformer oil tank.
Background
The oil tank is the shell of the transformer, the iron core and the winding are arranged in the oil tank and filled with transformer oil, and the iron core and the winding are immersed in the oil. The transformer oil plays the role of insulation and heat dissipation. The large transformer generally comprises two oil tanks, wherein one oil tank is a main body oil tank; one is an on-load voltage-adjusting oil tank, and a tap switch is arranged in the on-load voltage-adjusting oil tank. This is because the tap changer may generate an arc during operation, which may deteriorate the insulating property of oil if frequent operations are performed, and thus a separate tank is provided to place the tap changer separately.
The common transformer oil tank has 3 basic types, namely a tank type oil tank, a bell jar type oil tank and a sealed type oil tank according to the capacity of the oil tank.
CN102962187A discloses a painting process for a transformer oil tank and parts thereof, which comprises the following steps: firstly, blending paint; secondly, filtering the paint by using a 120-180-mesh sand screen after the paint is prepared; step three, painting is carried out; and fourthly, drying after the paint is coated.
CN106064139A discloses a surface coating process of a transformer oil tank, which comprises the following steps: 1) pre-degreasing the oil tank, the combined variable door plate and the workpiece with more oil stains on the surface; 2) oil and rust removal: a workpiece with light surface oil stain is directly put into a tank for normal temperature treatment; 3) first washing: operating at normal temperature, and swinging the workpiece left and right, front and back and up and down under liquid; 4) and (3) second water washing: operating at normal temperature, and swinging the workpiece left and right, front and back and up and down under liquid; 5) phosphorization; 6) soaking and washing with hot water: the temperature of the bath solution is not less than 70 ℃, and the time is 1-2 min; 7) drying; 8) coating a primer: spraying primer on the inner wall and the outer wall of the box body; 9) coating a middle layer paint: spraying middle layer paint on the inner wall and the outer wall of the box body; 10) coating finish paint: and spraying finish paint on the inner wall and the outer wall of the box body.
The main disadvantage of the existing paint film sprayed on the transformer oil tank is that the paint film is easy to fall off and crack, so that the tank body of the oil tank is rusted, and meanwhile, no measures are taken for preventing collision possibly generated in daily use.
Disclosure of Invention
The purpose of the invention is: the spraying technology for the transformer oil tank is characterized by comprising the following steps:
step 1, cleaning, phosphorizing and drying the oil tank to be sprayed.
And 2, spraying a first paint film on the inner side and the outer side of the oil tank.
And 3, after drying, spraying an elastic resin buffer layer on the first paint film of the oil tank.
And 4, spraying a second paint film on the elastic resin buffer layer after drying.
The first paint film is chlorinated rubber micaceous iron paint.
The preparation method of the elastic resin buffer layer comprises the following steps: according to the weight portion, pyromellitic dianhydride and diphenyl ether diamine are dissolved in dimethylformamide, 1, 2-bis (trimethylsiloxy) cyclobutene and 1, 1-dimethylsiloxane-11-crown ether-4 are added, the temperature is raised to 125-140 ℃, the reaction lasts for 3-8h, and after the reaction is finished, glutathione sepharose and calcium carbonate are added into the product, thus obtaining the elastic resin buffer layer.
The second paint film adopts epoxy resin paint.
The mass consumption of the diphenyl ether diamine is 60-75% of pyromellitic dianhydride.
The mass consumption of the 1, 2-bis (trimethylsiloxy) cyclobutene is 1.5-4.5% of pyromellitic dianhydride.
The mass consumption of the 1, 1-dimethyl sila-11-crown-4 is 1-3% of pyromellitic dianhydride.
The mass consumption of the glutathione sepharose gel is 1-3% of pyromellitic dianhydride.
The mass consumption of the calcium carbonate is 4-8% of that of the pyromellitic dianhydride.
The pyromellitic dianhydride is a product sold in the market, such as a product produced by Zhengzhou Jex chemical products Co., Ltd; the diphenyl ether diamine is a product sold in the market, such as a product produced by Shanghai Rong Biotechnology Limited; the 1, 2-bis (trimethylsiloxy) cyclobutene is a commercial product, such as a product produced by Hangzhou high chemical engineering company; the 1, 1-dimethyl sila-11-crown-4 is a commercial product, such as a product produced by Beijing Wai Ruike chemical company; glutathione sepharose is a commercially available product, such as a product produced by Xian blue Xiao Tech Co.
The product of the invention has the following beneficial effects:
the elastic resin buffer layer has good elasticity, ductility and adhesiveness, can buffer collision energy when a paint film of an oil tank is collided, adheres an inner paint film and an outer paint film, and protects the paint film of the oil tank from being damaged slightly; the elastic resin has excellent dielectric property and small dielectric constant, and is suitable for being used as a paint film of a transformer oil tank; the elastic resin layer contains calcium carbonate, the surface is relatively concave-convex, and the elastic resin layer is conveniently connected with the inner paint film and the outer paint film more tightly.
Detailed Description
The following examples are intended to further illustrate the present invention and are not intended to limit the scope of the invention.
Example 1
Step 1, cleaning, phosphorizing and drying the oil tank to be sprayed.
And 2, spraying a first chlorinated rubber micaceous iron paint film on the inner side and the outer side of the oil tank.
And 3, after drying, spraying an elastic resin buffer layer on the first paint film of the oil tank.
And 4, spraying a second epoxy resin paint film on the elastic resin buffer layer after drying.
The preparation method of the elastic resin buffer layer comprises the following steps: adding 100Kg of pyromellitic dianhydride, 67.5Kg of diphenyl ether diamine, 3Kg of 1, 2-bis (trimethylsiloxy) cyclobutene and 42Kg of 1, 1-dimethylsiloxane-11-crown ether into a reaction kettle, heating to 132 ℃, reacting for 5.5 hours, and adding 2Kg of glutathione sepharose and 6Kg of calcium carbonate into a product after the reaction is finished to obtain the elastic resin buffer layer.
Example 2
Step 1, cleaning, phosphorizing and drying the oil tank to be sprayed.
And 2, spraying a first chlorinated rubber micaceous iron paint film on the inner side and the outer side of the oil tank.
And 3, after drying, spraying an elastic resin buffer layer on the first paint film of the oil tank.
And 4, spraying a second epoxy resin paint film on the elastic resin buffer layer after drying.
The preparation method of the elastic resin buffer layer comprises the following steps: adding 100Kg of pyromellitic dianhydride, 60Kg of diphenyl ether diamine, 1.5Kg of 1, 2-bis (trimethylsiloxy) cyclobutene and 41Kg of 1, 1-dimethylsiloxane-11-crown ether into a reaction kettle, heating to 125 ℃, reacting for 3 hours, and adding 1Kg of glutathione sepharose and 4Kg of calcium carbonate into a product after the reaction is finished to obtain the elastic resin buffer layer.
Example 3
Step 1, cleaning, phosphorizing and drying the oil tank to be sprayed.
And 2, spraying a first chlorinated rubber micaceous iron paint film on the inner side and the outer side of the oil tank.
And 3, after drying, spraying an elastic resin buffer layer on the first paint film of the oil tank.
And 4, spraying a second epoxy resin paint film on the elastic resin buffer layer after drying.
The preparation method of the elastic resin buffer layer comprises the following steps: adding 100Kg of pyromellitic dianhydride, 75Kg of diphenyl ether diamine, 4.5Kg of 1, 2-bis (trimethylsiloxy) cyclobutene and 43Kg of 1, 1-dimethylsiloxa-11-crown ether into a reaction kettle, heating to 140 ℃, reacting for 8 hours, and adding 3Kg of glutathione sepharose and 8Kg of calcium carbonate into a product after the reaction is finished to obtain the elastic resin buffer layer.
Comparative example 1
The elastomeric resin was prepared without adding 1, 2-bis (trimethylsiloxy) cyclobutene under the same conditions as in example 1.
Comparative example 2
The same procedure as in example 1 was repeated except that 1, 1-dimethylsiloxa-11-crown-4 was not added to the elastomeric resin.
Comparative example 3
Glutathione sepharose was not added to the elastic resin and the other conditions were the same as in example 1.
Example 4
The dielectric constants of the elastic resins produced in examples 1 to 3 and comparative examples 1 to 3 were examined, respectively, and the elongation of the elastic resin was examined.
TABLE 1 dielectric constants of the elastic resins produced in examples 1 to 3 and comparative examples 1 to 3.