CN108285635A - A kind of thermal insulation building material and preparation method thereof - Google Patents
A kind of thermal insulation building material and preparation method thereof Download PDFInfo
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- CN108285635A CN108285635A CN201810117363.1A CN201810117363A CN108285635A CN 108285635 A CN108285635 A CN 108285635A CN 201810117363 A CN201810117363 A CN 201810117363A CN 108285635 A CN108285635 A CN 108285635A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of thermal insulation building materials and preparation method thereof, are related to building material technical field, include the raw material of following parts by weight meter:24 parts of 15 20 parts of epoxy resin, 14 18 parts of phenolic resin, 16 21 parts of polyurethane, 6 12 parts of vermiculite, 8 15 parts of perlite, 7 15 parts of volcanic ash, 9 14 parts of asbestos, 15 18 parts of calcium silicates, 37 parts of prodan, 48 parts of nano aluminium oxide, 59 parts of nano silicon dioxide, 48 parts of liquid glass, 47 parts of ceramic fibre, 36 parts of zinc oxide, 24 parts of carbon black, 35 parts of fire retardant, 2.5 4.5 parts of antioxidant, 1.2 2.1 parts of antifoaming agent, 35 parts of optothermal stabilizer and curing agent;Thermal insulation building material thermal conductivity of the present invention is small, heat storage coefficient is big, with good heat preservation and insulation, and fire-retardant coefficient is high, and security performance is high, and cracking resistance, shock resistance and anti-aging property are good, service life is long, preparation method is simple, low in raw material price, has good market application prospect.
Description
Technical field
The present invention relates to building material technical fields, and in particular to a kind of thermal insulation building material and preparation method thereof.
Background technology
Building thermal insulation material is by taking measures to building external envelope structure, reducing architecture indoor heat and dissipated to outdoor
Hair, to keep architecture indoor temperature, building thermal insulation material is on building heat preservation to creating suitable indoor thermal environment and saving
The energy plays an important role.
In the prior art, external wall mostly uses the materials such as extruded polystyrene board, molding styrofoam, polyurethane foam board and ensures
The energy-saving heat preserving of wall, it is common in hot and cold alternation and rainwater, air etc. although this material has preferable heat-insulating property
Under effect, it is easy to that aging occurs, the service life is relatively low, and the flame retardant property of this material is not high enough, for this reason, it may be necessary to find one kind
Good heat insulating, cheap, the good thermal insulation material of flame retardant property.
Invention content
For problems of the prior art, the present invention provides a kind of thermal insulation building material and its preparation sides
Method, thermal insulation building material thermal conductivity of the present invention is small, and heat storage coefficient is big, has good heat preservation and insulation, and hinder
It is high to fire coefficient, security performance is high, and cracking resistance, shock resistance and anti-aging property are good, and service life is long, and preparation method is simple, raw material
It is cheap, there is good market application prospect.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of thermal insulation building material includes the raw material of following parts by weight meter:
15-20 parts of epoxy resin, 14-18 parts of phenolic resin, 16-21 parts of polyurethane, 6-12 parts of vermiculite, perlite 8-15
Part, 7-15 parts of volcanic ash, 9-14 parts of asbestos, 15-18 parts of calcium silicates, 3-7 parts of prodan, 4-8 parts of nano aluminium oxide, nanometer two
5-9 parts of silica, 4-8 parts of liquid glass, 4-7 parts of ceramic fibre, 3-6 parts of zinc oxide, 2-4 parts of carbon black, 3-5 parts of fire retardant,
2-4 parts of 2.5-4.5 parts of antioxidant, 1.2-2.1 parts of antifoaming agent, 3-5 parts of optothermal stabilizer and curing agent.
Preferably, include the raw material of following parts by weight meter:18 parts of epoxy resin, 17 parts of phenolic resin, 18 parts of polyurethane, leech
9 parts of stone, 12 parts of volcanic ash, 13 parts of asbestos, 16 parts of calcium silicates, 6 parts of prodan, 7 parts of nano aluminium oxide, is received 10 parts of perlite
6 parts of silica of rice, 6 parts of liquid glass, 5 parts of ceramic fibre, 4 parts of zinc oxide, 3 parts of carbon black, 3.5 parts of fire retardant, antioxidant
3 parts of 2.8 parts, 1.5 parts of antifoaming agent, 4.2 parts of optothermal stabilizer and curing agent.
Preferably, the fire retardant is silicone polymer and magnesium stearate according to mass ratio 2:1 mixing composition.
Preferably, the antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol esters and β-(3,5-
Di-tert-butyl-hydroxy phenyl) pentaerythritol ester is according to mass ratio 1:1 mixing composition.
Preferably, the antifoaming agent is one in silicone emulsion, dimethyl silicone polymer, the fatty acid ester compounded object of higher alcohols
Kind or several combinations.
Preferably, the optothermal stabilizer is O-hydroxyl-diphenyl ketone class and beta-diketone compounds according to mass ratio 3:2
Mixing composition.
Preferably, the curing agent is that one or more of polynary amine, anhydride and polyatomic phenol combine.
A kind of preparation method of above-mentioned thermal insulation building material is also disclosed in the present invention, specifically, including following step
Suddenly:
(1) each raw material is weighed according to the raw material weight number of thermal insulation building material
(2) vermiculite, perlite and volcanic ash are uniformly mixed, calcined under 800-1000 degrees Celsius 20-30 minutes to get
Mixture N1, it is spare;
(3) asbestos, calcium silicates, prodan, ceramic fibre and zinc oxide are sent into pulverizer, pulverized particles grain size is extremely
100-300 mesh is uniformly mixed to get mixture N2, spare;
(4) by epoxy resin, phenolic resin, polyurethane, nano aluminium oxide, nano silicon dioxide, liquid glass, mixing
Object N1 and mixture N2 is mixed, and is warming up to 60-90 degrees Celsius, with 1200-1500 revs/min stir 30-45 minutes to get
Mixture N3, it is spare;
(5) be added into mixture N3 the carbon blacks of above-mentioned parts by weight, fire retardant, antioxidant, antifoaming agent, optothermal stabilizer and
Curing agent, under 50-70 degrees Celsius, with 1500-2000 revs/min, stirring 50-70 minutes to get mixture N4, it is spare;
(6) it will be injected in mold in mixture N4, be then fed into hot press and be molded, molding temperature 150-170 takes the photograph
Family name's degree, clamp time 3-5 hours;It is dry after taking-up, it is cooled to room temperature to get to the thermal insulation building material.
The present invention has following advantageous effect:
(1) thermal insulation building material thermal conductivity of the present invention is small, and heat storage coefficient is big, has good heat-insulation and heat-preservation
Can, and fire-retardant coefficient is high, has a safety feature, cracking resistance, shock resistance and anti-aging property are good, and service life is long, preparation method
Simply, low in raw material price has good market application prospect;
(2) vermiculite is added in raw material of the present invention, vermiculite has the characteristics that thermal conductivity is small, is a kind of good heat-insulated material
Material, can increase the heat-proof quality and heat-insulating property of material;
(3) calcium silicates is added in raw material of the present invention, calcium silicates is a kind of safe heat-barrier material.With good thermal insulation separation
Hot property, and there is wearability, corrosion resistance and ageing resistance, the heat insulating ability of thermal insulation building material can be increased and make
Use the time;
(4) ceramic fibre is added in raw material of the present invention, ceramic fibre is a kind of fibrous light refractory material, has weight
The advantages that amount is light, high temperature resistant, thermal stability are good, thermal conductivity is low, specific heat is small and mechanical resistant shakes, can improve thermal insulation building
The heat insulating ability of material, anti-flammability and mechanical shock resistance;
(5) nano aluminium oxide is added in raw material of the present invention, nano aluminium oxide can improve thermal insulation building material
Flame retardant property improves materials'use safety;
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of thermal insulation building material includes the raw material of following parts by weight meter:
15 parts of epoxy resin, 14 parts of phenolic resin, 16 parts of polyurethane, 6 parts of vermiculite, 8 parts of perlite, 7 parts of volcanic ash, asbestos
9 parts, 15 parts of calcium silicates, 3 parts of prodan, 4 parts of nano aluminium oxide, 5 parts of nano silicon dioxide, 4 parts of liquid glass, ceramics it is fine
4 parts of dimension, 3 parts of zinc oxide, 2 parts of carbon black, 3 parts of fire retardant, 2.5 parts of antioxidant, 1.2 parts of antifoaming agent, 3 parts of optothermal stabilizer and solidification
2 parts of agent.
Fire retardant is silicone polymer and magnesium stearate according to mass ratio 2:1 mixing composition.
Antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol esters and β-(3,5- di-t-butyls -4-
Hydroxy phenyl) pentaerythritol ester is according to mass ratio 1:1 mixing composition.
Antifoaming agent is dimethyl silicone polymer.
Optothermal stabilizer is O-hydroxyl-diphenyl ketone class and beta-diketone compounds according to mass ratio 3:2 mixing compositions.
Curing agent is polynary amine.
A kind of preparation method of above-mentioned thermal insulation building material is also disclosed in the present embodiment, specifically, including it is following
Step:
(1) each raw material is weighed according to the raw material weight number of thermal insulation building material
(2) vermiculite, perlite and volcanic ash are uniformly mixed, 20 minutes is calcined under 800 degrees Celsius to get mixture
N1, it is spare;
(3) asbestos, calcium silicates, prodan, ceramic fibre and zinc oxide are sent into pulverizer, pulverized particles grain size is extremely
100 mesh are uniformly mixed to get mixture N2, spare;
(4) by epoxy resin, phenolic resin, polyurethane, nano aluminium oxide, nano silicon dioxide, liquid glass, mixing
Object N1 and mixture N2 is mixed, and is warming up to 60 degrees Celsius, standby with 1200 revs/min of stirrings 30 minutes to get mixture N3
With;
(5) be added into mixture N3 the carbon blacks of above-mentioned parts by weight, fire retardant, antioxidant, antifoaming agent, optothermal stabilizer and
Curing agent, at 50 c, with 1500 revs/min, stirring 50 minutes to get mixture N4, it is spare;
(6) it will be injected in mold in mixture N4, be then fed into hot press and be molded, 150 degrees Celsius of molding temperature,
Clamp time 3 hours;It is dry after taking-up, it is cooled to room temperature to get to the thermal insulation building material.
Embodiment 2
A kind of thermal insulation building material includes the raw material of following parts by weight meter:
20 parts of epoxy resin, 18 parts of phenolic resin, 21 parts of polyurethane, 12 parts of vermiculite, 5 parts of perlite, 15 parts of volcanic ash, stone
14 parts of cotton, 18 parts of calcium silicates, 7 parts of prodan, 8 parts of nano aluminium oxide, 9 parts of nano silicon dioxide, 8 parts of liquid glass, pottery
7 parts of porcelain fiber, 6 parts of zinc oxide, 4 parts of carbon black, 5 parts of fire retardant, 4.5 parts of antioxidant, 2.1 parts of antifoaming agent, 5 parts of optothermal stabilizer and
4 parts of curing agent.
Fire retardant is silicone polymer and magnesium stearate according to mass ratio 2:1 mixing composition.
Antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol esters and β-(3,5- di-t-butyls -4-
Hydroxy phenyl) pentaerythritol ester is according to mass ratio 1:1 mixing composition.
Antifoaming agent is the fatty acid ester compounded object of higher alcohols.
Optothermal stabilizer is O-hydroxyl-diphenyl ketone class and beta-diketone compounds according to mass ratio 3:2 mixing compositions.
Curing agent is polyatomic phenol.
A kind of preparation method of above-mentioned thermal insulation building material is also disclosed in the present embodiment, specifically, including it is following
Step:
(1) each raw material is weighed according to the raw material weight number of thermal insulation building material
(2) vermiculite, perlite and volcanic ash are uniformly mixed, 30 minutes is calcined under 1000 degrees Celsius to get mixture
N1, it is spare;
(3) asbestos, calcium silicates, prodan, ceramic fibre and zinc oxide are sent into pulverizer, pulverized particles grain size is extremely
300 mesh are uniformly mixed to get mixture N2, spare;
(4) by epoxy resin, phenolic resin, polyurethane, nano aluminium oxide, nano silicon dioxide, liquid glass, mixing
Object N1 and mixture N2 is mixed, and is warming up to 90 degrees Celsius, standby with 1500 revs/min of stirrings 45 minutes to get mixture N3
With;
(5) be added into mixture N3 the carbon blacks of above-mentioned parts by weight, fire retardant, antioxidant, antifoaming agent, optothermal stabilizer and
Curing agent, under 70 degrees Celsius, with 2000 revs/min, stirring 70 minutes to get mixture N4, it is spare;
(6) it will be injected in mold in mixture N4, be then fed into hot press and be molded, 170 degrees Celsius of molding temperature,
Clamp time 5 hours;It is dry after taking-up, it is cooled to room temperature to get to the thermal insulation building material.
Embodiment 3
A kind of thermal insulation building material includes the raw material of following parts by weight meter:
18 parts of epoxy resin, 17 parts of phenolic resin, 18 parts of polyurethane, 9 parts of vermiculite, 10 parts of perlite, 12 parts of volcanic ash, stone
13 parts of cotton, 16 parts of calcium silicates, 6 parts of prodan, 7 parts of nano aluminium oxide, 6 parts of nano silicon dioxide, 6 parts of liquid glass, pottery
5 parts of porcelain fiber, 4 parts of zinc oxide, 3 parts of carbon black, 3.5 parts of fire retardant, 2.8 parts of antioxidant, 1.5 parts of antifoaming agent, optothermal stabilizer 4.2
3 parts of part and curing agent.
Fire retardant is silicone polymer and magnesium stearate according to mass ratio 2:1 mixing composition.
Antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol esters and β-(3,5- di-t-butyls -4-
Hydroxy phenyl) pentaerythritol ester is according to mass ratio 1:1 mixing composition.
Antifoaming agent is silicone emulsion and dimethyl silicone polymer according to mass ratio 1:1 mixing composition.
Optothermal stabilizer is O-hydroxyl-diphenyl ketone class and beta-diketone compounds according to mass ratio 3:2 mixing compositions.
Curing agent is polynary amine and anhydride according to mass ratio 3:2 mixing compositions.
A kind of preparation method of above-mentioned thermal insulation building material is also disclosed in the present embodiment, specifically, including it is following
Step:
(1) each raw material is weighed according to the raw material weight number of thermal insulation building material
(2) vermiculite, perlite and volcanic ash are uniformly mixed, 25 minutes is calcined under 900 degrees Celsius to get mixture
N1, it is spare;
(3) asbestos, calcium silicates, prodan, ceramic fibre and zinc oxide are sent into pulverizer, pulverized particles grain size is extremely
200 mesh are uniformly mixed to get mixture N2, spare;
(4) by epoxy resin, phenolic resin, polyurethane, nano aluminium oxide, nano silicon dioxide, liquid glass, mixing
Object N1 and mixture N2 is mixed, and is warming up to 80 degrees Celsius, standby with 1400 revs/min of stirrings 40 minutes to get mixture N3
With;
(5) be added into mixture N3 the carbon blacks of above-mentioned parts by weight, fire retardant, antioxidant, antifoaming agent, optothermal stabilizer and
Curing agent, at 60 c, with 1700 revs/min, stirring 65 minutes to get mixture N4, it is spare;
(6) it will be injected in mold in mixture N4, be then fed into hot press and be molded, 165 degrees Celsius of molding temperature,
Clamp time 4.5 hours;It is dry after taking-up, it is cooled to room temperature to get to the thermal insulation building material.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of thermal insulation building material, which is characterized in that including following raw material by weight:Epoxy resin 15-20
Part, 14-18 parts of phenolic resin, 16-21 parts of polyurethane, 6-12 parts of vermiculite, 8-15 parts of perlite, 7-15 parts of volcanic ash, asbestos 9-
14 parts, 15-18 parts of calcium silicates, 3-7 parts of prodan, 4-8 parts of nano aluminium oxide, 5-9 parts of nano silicon dioxide, liquid glass
4-8 parts, 4-7 parts of ceramic fibre, 3-6 parts of zinc oxide, 2-4 parts of carbon black, 3-5 parts of fire retardant, 2.5-4.5 parts of antioxidant, antifoaming agent
2-4 parts of 1.2-2.1 parts, 3-5 parts of optothermal stabilizer and curing agent.
2. thermal insulation building material according to claim 1, which is characterized in that include the raw material of following parts by weight meter:
18 parts of epoxy resin, 17 parts of phenolic resin, 18 parts of polyurethane, 9 parts of vermiculite, 10 parts of perlite, 12 parts of volcanic ash, 13 parts of asbestos,
16 parts of calcium silicates, 6 parts of prodan, 7 parts of nano aluminium oxide, 6 parts of nano silicon dioxide, 6 parts of liquid glass, ceramic fibre 5
Part, 4 parts of zinc oxide, 3 parts of carbon black, 3.5 parts of fire retardant, 2.8 parts of antioxidant, 1.5 parts of antifoaming agent, 4.2 parts of optothermal stabilizer and solid
3 parts of agent.
3. thermal insulation building material according to claim 1, which is characterized in that the fire retardant be silicone polymer and
Magnesium stearate is according to mass ratio 2:1 mixing composition.
4. thermal insulation building material according to claim 1, which is characterized in that the antioxidant is β-(3,5- bis- uncles
Butyl -4- hydroxy phenyls) propionic acid octadecanol ester and β-(3,5- di-tert-butyl-hydroxy phenyls) pentaerythritol ester be according to quality
Than 1:1 mixing composition.
5. thermal insulation building material according to claim 1, which is characterized in that the antifoaming agent is silicone emulsion, gathers
One or more of fatty acid ester compounded object of dimethyl siloxane, higher alcohols combines.
6. thermal insulation building material according to claim 1, which is characterized in that the optothermal stabilizer is adjacent hydroxyl two
Benzophenone class and beta-diketone compounds are according to mass ratio 3:2 mixing compositions.
7. thermal insulation building material according to claim 1, which is characterized in that the curing agent is polynary amine, acid
One or more of anhydride and polyatomic phenol combine.
8. a kind of preparation method of such as claim 1-7 any one of them thermal insulation building materials, which is characterized in that including
Following steps:
(1) each raw material is weighed according to the raw material weight number of thermal insulation building material
(2) vermiculite, perlite and volcanic ash are uniformly mixed, 20-30 minutes is calcined under 800-1000 degrees Celsius to get mixing
Object N1, it is spare;
(3) asbestos, calcium silicates, prodan, ceramic fibre and zinc oxide are sent into pulverizer, pulverized particles grain size to 100-
300 mesh are uniformly mixed to get mixture N2, spare;
(4) by epoxy resin, phenolic resin, polyurethane, nano aluminium oxide, nano silicon dioxide, liquid glass, mixture N1
It is mixed with mixture N2, is warming up to 60-90 degrees Celsius, 30-45 minutes are stirred to get mixing with 1200-1500 revs/min
Object N3, it is spare;
(5) carbon black, fire retardant, antioxidant, antifoaming agent, optothermal stabilizer and the solidification of above-mentioned parts by weight are added into mixture N3
Agent, under 50-70 degrees Celsius, with 1500-2000 revs/min, stirring 50-70 minutes to get mixture N4, it is spare;
(6) it will be injected in mold in mixture N4, be then fed into hot press and be molded, 150-170 degrees Celsius of molding temperature,
Clamp time 3-5 hours;It is dry after taking-up, it is cooled to room temperature to get to the thermal insulation building material.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109054636A (en) * | 2018-07-28 | 2018-12-21 | 南京钰博科信新材料有限公司 | A kind of insulation coating material and preparation method thereof |
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CN107177273A (en) * | 2017-04-28 | 2017-09-19 | 黄河科技学院 | A kind of heat-isolating flame retardant material and preparation method thereof |
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CN107265920A (en) * | 2017-06-20 | 2017-10-20 | 合肥尚涵装饰工程有限公司 | A kind of construction material of fire-proof and thermal-insulation and preparation method thereof |
CN107417172A (en) * | 2017-06-22 | 2017-12-01 | 合肥月煌新型装饰材料有限公司 | A kind of thermal insultion heat insulating board for building and preparation method thereof |
CN107500707A (en) * | 2017-09-27 | 2017-12-22 | 马鞍山松鹤信息科技有限公司 | A kind of building panel insulation material and its preparation technology |
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CN107177273A (en) * | 2017-04-28 | 2017-09-19 | 黄河科技学院 | A kind of heat-isolating flame retardant material and preparation method thereof |
CN107244835A (en) * | 2017-06-13 | 2017-10-13 | 合肥大麦灯箱器材有限公司 | A kind of construction material and preparation method thereof |
CN107265920A (en) * | 2017-06-20 | 2017-10-20 | 合肥尚涵装饰工程有限公司 | A kind of construction material of fire-proof and thermal-insulation and preparation method thereof |
CN107417172A (en) * | 2017-06-22 | 2017-12-01 | 合肥月煌新型装饰材料有限公司 | A kind of thermal insultion heat insulating board for building and preparation method thereof |
CN107500707A (en) * | 2017-09-27 | 2017-12-22 | 马鞍山松鹤信息科技有限公司 | A kind of building panel insulation material and its preparation technology |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN109054636A (en) * | 2018-07-28 | 2018-12-21 | 南京钰博科信新材料有限公司 | A kind of insulation coating material and preparation method thereof |
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Application publication date: 20180717 |