CN108283607A - A kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof - Google Patents
A kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof Download PDFInfo
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- CN108283607A CN108283607A CN201810059486.4A CN201810059486A CN108283607A CN 108283607 A CN108283607 A CN 108283607A CN 201810059486 A CN201810059486 A CN 201810059486A CN 108283607 A CN108283607 A CN 108283607A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/66—Enzymes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/676—Ascorbic acid, i.e. vitamin C
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
Abstract
The present invention relates to a kind of spinning liquid, spin nanometer facial mask and preparation method thereof, wherein, that is the spinning nanometer facial mask is different from traditional facial mask, it is a kind of invisible nanometer film of eyes to spin nanometer facial mask, it is prepared with raw materials such as collagen and/or the gelatin for having fine compatibility with skin, it is the non-woven fabrics that nano level silk is woven into, various skin cares, moisturizing ingredient can be carried, it is apparent naturally, have good gas permeability and moisture retention, it is flexible, feel good, no foreign body sensation, it is easy to use, belong to cosmetic product field.
Description
Technical field
The invention belongs to cosmetic product fields, and in particular to a kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof.
Background technology
With the raising of China's economic development and living standards of the people, demand of the people to skin-protection product is higher and higher, shape
At a large market.The many regional hazes in China are serious in recent years, and various germs and harmful substance are contained in haze, right
Skin lesion is serious.Northern China winter cold is dried, and northwest plateau area ultraviolet light is strong, serious to skin injury.Therefore,
Facial treatment mask is increasingly common as people, the product of quick skin care.Wherein, electrostatic spinning be it is a kind of it is advanced prepare it is organic high
The equipment of molecule nano material is originally raw material with various polymers, prepares nano level film, i.e., nano level silk
The non-woven fabrics being woven into, as industrial materials such as drug dispersant, catalyst carrier, nanofiltration membrane, haze environmental-friendfilm films.In recent years
Carry out electrostatic spinning technique and have been used for medical domain, prepares the high-end medical products such as artificial skin, periosteum, heart film, holder.Electrostatic
Spinning-drawing machine has been developed that easy desk-top and hand-held electric spinning machine, the former is such as telephone holder by improving in recent years
Machine size, the latter can take such as noggin, nanometer film are prepared in situ.However, existing facial treatment mask on the one hand can only
A night in inner use, cannot wear facial mask trip daytime, and effect is limited；The cold cream on another aspect daytime is with oiliness substrate
Main, gas permeability is bad, numerous Mies be badly in need of it is a kind of it is easy to use, moistening effect is high, haze and ultraviolet light, feels good
Facial mask good, daytime, trip can use.
Invention content
To solve the above problems, the present invention proposes that a kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof, described spin are received
Rice and flour film is different from traditional facial mask, that is, it is a kind of invisible nanometer film of eyes to spin nanometer facial mask, has fine parent with skin
It is prepared with raw materials such as the collagen of property and/or gelatin, is the non-woven fabrics that nano level silk is woven into, can carry various
Skin care, moisturizing ingredient, it is apparent naturally, have good gas permeability and moisture retention, it is flexible, feel good, no foreign body sensation makes
With conveniently.
The present invention is achieved by the following technical solutions：
A kind of spinning liquid, it is described spin liquid include mass fraction be 25%~40% macromolecule substrate and 40%~75% it is molten
Agent.
Further, the macromolecule substrate be collagen, gelatin, fibroin albumen and chitosan in any one or
It is arbitrary two or more；The macromolecule substrate must be that itself (such as fishskin gelatin) contains more moisture, have very well
Moisture-retaining capacity, have fine compatibility with skin and be easy to the polymer substance for being absorbed, water capable of being dissolved in, be easy to electrostatic spinning；
The polymer substance of substrate as nanometer facial mask cannot irritant smell, cannot have deeper color, it is preferably colourless,
There is preferable adhesion on the skin and has certain elasticity.
Further, the solvent includes water, and water is the best cleaning agent of skin in nature, therefore using water as spinning liquid
Basic recipe, add a small amount of (or being not added with) perfume as secondary solvent.
Further, the water is deionized water, high purity water, distilled water, pure water or mineral water.
Further, the gelatin is fishskin gelatin；The fishskin gelatin is that collagen becomes in structure
Product after change has similar chemical composition with skin protein.The hydrophily of fishskin gelatin is strong, with the energy for forming jelly
Power, dissolved colloidal state and the gel state of gelatin can mutually convert, and filming performance is good, and side-chain radical reactivity is high, have both sexes electricity
The property of matter is solved, charge changes with the pH value of medium and changed.The finished product of fishskin gelatin is colourless or flaxen transparent sheet
Or particle.Gelatin can be dissolved in hot water, and water swelling softening can absorb the water of quite 5~10 times of its weight, forms gel after cooling
Shape object is the substrate for being suitble to do nanometer facial mask.
Further, the skin care for spinning liquid also comprising mass fraction for 1%~5% and moisturizing ingredient.
Further, the skin care and moisturizing ingredient are trehalose, glycerine, Hydrolyzed Collagen, sodium hyaluronate, aloe and day
In right moisturizing factor any one or it is arbitrary two or more.
Further, described spin in liquid also includes that mass fraction is little no more than 2% Cosmetic Ingredient and/or mass fraction
In 2% Cosmetic Ingredient.
Further, the Cosmetic Ingredient is in pearl powder, vitamin C, ursin, PORIA ALBA, brilliant white powder and flashlight powder
Any one or it is arbitrary two or more.
Further, the Cosmetic Ingredient is perfume and/or attar of rose.
Further, the perfume is lily lavender perfume, jessamine, cape jasmine flower perfume, rose perfume and osmanthus
In flower perfume any one or it is arbitrary two or more.
Further, the particular content that the fibroin albumen is produced is：Silk cocoon is cut off with scissors, silkworm chrysalis is removed, by silk cocoon
Shell into several layers of postposition 0.5% sodium bicarbonate aqueous solution (bath water ratio be 1：100) 30min is boiled in, removes silk surface silk gum,
So it is repeated twice.Then it is fully rinsed with deionized water, is finally dried.Degumming fibroin 10g is taken, with the LiBr of 9.5mol/L
It is made into a concentration of 10% solution, is stood overnight.Deionized water is added to dilute 5 times, filtering is subsequently poured into bag filter, then spend
Ionized water is continuously dialysed until the conductivity of the outer deionized water of bag filter is basically unchanged.
One kind spins nanometer facial mask, that is, the nanometer facial mask that spins is that use homogeneous includes mass fraction for 25%~40%
Macromolecule substrate and 40%~75% spinning liquid of solvent obtained after spinning on paper；
The fibre diameter for spinning nanometer facial mask is 200nm~400nm.
Further, the macromolecule substrate be collagen, gelatin, fibroin albumen and chitosan in any one or
It is arbitrary two or more.
Further, the solvent includes water, and water is the best cleaning agent of skin in nature, therefore using water as spinning liquid
Basic recipe, a small amount of (or being not added with) perfume can be added as secondary solvent.
Further, the water is deionized water, high purity water, distilled water, pure water or mineral water.
Further, described to spin in liquid also comprising 1%~5% skin care and moisturizing ingredient；Further enhance a nanometer facial mask
Skin care and moisture-retaining capacity.
Further, the skin care and moisturizing ingredient are any one in trehalose, aloe, papain and sodium hyaluronate
Kind or it is arbitrary two or more.
Further, described spin in liquid also includes that mass fraction is little no more than 2% Cosmetic Ingredient and/or mass fraction
In 2% Cosmetic Ingredient.
Further, the Cosmetic Ingredient be pearl powder, brilliant white powder and flashlight powder in any one or it is arbitrary two kinds or
Three kinds.
Further, the Cosmetic Ingredient is perfume and/or attar of rose.
Further, the perfume is lily lavender perfume, jessamine, cape jasmine flower perfume, rose perfume and osmanthus
In flower perfume any one or it is arbitrary two or more.
Further, the spinning liquid is after determining macromolecule substrate and solvent, described to spin the dense of substrate and solvent in liquid
Degree is a very crucial factor；When macromolecule substrate is gelatin, solvent is water, the gelatin of preparation spin liquid concentration have compared with
There is droplet spot it is, in general, that concentration is too low in wide allowable range, cannot be at silk；Concentration is relatively low, and silk is thicker, structure pine
It dissipates；It is increased with concentration, the diameter of silk first reduces, then increases；There are solid globules in excessive concentration；Concentration is appropriate, formed uniformly,
Fine and close, smooth nanometer film；It is also related with the molecular weight of polymer substance to spin liquid concentration, if the average molecular weight of polymer substance
Height, concentration can be lower；If average molecular weight is low, concentration wants higher；The gelatin spin the concentration of liquid also with gelatin sheet
The water content of body is related.
Further, that is, the nanometer facial mask that spins has good moisture retention and gas permeability, and appearance in trip naturally, can make
With long-time plays skin care, moisturizing, anti-haze, and effect is more preferable.
Further, that is, the nanometer facial mask that spins can at any time be prepared by user, and the production is simple and convenient, can be used as dailyization
Cosmetic uses, and apparent ease can be washed away at night with warm water, without any side effect, not generate any waste.
Further, it is described spin nanometer facial mask can according to the hobby of user, add various skin cares, moisturizing and treatment at
Point, for the demand of different crowd, series of products are developed, reach specific effect.
Further, that is, the substrate for spinning nanometer facial mask and skin care therein and therapeutic component are all with nano level scale
In the presence of can directly be absorbed by the skin, if trehalose has the good function of preventing cell dehydration and moisturizing, have excellent holding thin
The characteristic of born of the same parents' vigor prevents the generation of Skin Cell dehydration and keratinization under the environment such as high temperature, high and cold, dry, intensive ultraviolet；
Papain can dissolve the scurf of keratinization, play the effect of better skin care and treatment.
Further, that is, the nanometer facial mask that spins is blocked in the harmful substance in haze except skin, plays good
Anti- haze effect, protects the health of user.
Further, that is, various beauty and Cosmetic Ingredient can also be added by spinning in nanometer facial mask, substitute various cosmetics, side
Just user uses, and reduces the spending of user.
Further, that is, the moisture preserving time for spinning nanometer facial mask is not less than 4h.
Further, that is, the moisture preserving time for spinning nanometer facial mask is not less than 6h.
A kind of preparation method for spinning nanometer facial mask, the method include macromolecule substrate and solvent by using homogeneous
Spinning liquid the i.e. spinning nanometer facial mask is obtained after spinning on wafer.
Further, the preparation method is as follows：
Step 1, the preparation of liquid is spun：After the macromolecule substrate and solvent are mixed 10h is stirred at 60 DEG C~80 DEG C of constant temperature
More than, until the macromolecule substrate and the solvent are uniformly mixed, at this point, the spinning liquid is made；
Step 2, that is, the preparation of nanometer facial mask is spun：The spinning liquid obtained in step 1 is placed in electrostatic spinning machine, is arranged
The parameter of the electrostatic spinning machine includes system temperature, spins flow velocity, receives distance and voltage, with the electricity of the electrostatic spinning machine
Spinning pipette tips uniform 8~12min of spinning on wafer or human skin spins nanometer facial mask to get to described.
Further, macromolecule substrate described in step 1 and the solvent be added after mixing skin care and moisturizing ingredient,
In Cosmetic Ingredient and Cosmetic Ingredient any one or it is two or three arbitrary, continue stirring until the skin care and moisturizing ingredient
It is uniformly mixed with the macromolecule substrate and the solvent.
Further, the mass fraction ranging from 25%~40% of the macromolecule substrate.
Further, the mass fraction of the solvent ranging from 40%~75%.
Further, the macromolecule substrate be collagen, gelatin, fibroin albumen and chitosan in any one or
It is arbitrary two or more.
Further, macromolecule substrate described in step 1 and the solvent be added after mixing mass fraction be 1%~
5% skin care and moisturizing ingredient continue stirring until the skin care and moisturizing ingredient and the macromolecule substrate and the solvent
It is uniformly mixed.
Further, the macromolecule substrate be collagen, gelatin, fibroin albumen and chitosan in any one or
It is arbitrary two or more.
Further, the solvent includes water, and water is the best cleaning agent of skin in nature, therefore using water as spinning liquid
Basic recipe, a small amount of (or being not added with) perfume can be added as secondary solvent.
Further, the water is deionized water, high purity water, distilled water, pure water or mineral water.
Further, the skin care and moisturizing ingredient are any one in trehalose, aloe, papain and sodium hyaluronate
Kind or it is arbitrary two or more.
Further, macromolecule substrate described in step 1 and the solvent are added mass fraction and are not more than after mixing
2% Cosmetic Ingredient and/or mass fraction is not more than 2% Cosmetic Ingredient.
Further, the Cosmetic Ingredient be pearl powder, brilliant white powder and flashlight powder in any one or it is arbitrary two kinds or
Three kinds.
Further, the Cosmetic Ingredient is perfume and/or attar of rose.
Further, the perfume is lily lavender perfume, jessamine, cape jasmine flower perfume, rose perfume and osmanthus
In flower perfume any one or it is arbitrary two or more.
Further, the time of spinning described in step 2 is best in 5~10min, and the time is too short, described to spin nanometer face
Certain thickness is not achieved in film, and the time is too long, i.e. the spinning nanometer facial mask is excessively fine and close.
Further, system temperature described in step 2 is 25 DEG C~40 DEG C.
Further, it is 0.1 to 0.3ml/h that flow velocity is spun described in step 2.
Further, described in step 2 receive distance be the electrostatic spinning rifle at a distance from the wafer, it is described to connect
It is 5~8cm to receive distance.
Further, voltage described in step 2 is 8kv~20kv.
The present invention has following advantageous effects：
(1) the nanometer facial mask that spins of the invention has good moisture retention and gas permeability, and appearance in trip naturally, can make
With long-time plays skin care, moisturizing, anti-haze, and effect is more preferable.
(2) the nanometer facial mask that spins of the invention can at any time be prepared by user, and the production is simple and convenient, can be used as daily makeup
Product use, and apparent ease can be washed away at night with warm water, without any side effect, not generate any waste.
(3) it is of the invention spin nanometer facial mask can according to the hobby of user, add various skin cares, moisturizing and treatment at
Point, for the demand of different crowd, series of products are developed, reach specific effect.
(4) substrate for spinning nanometer facial mask of the invention and skin care therein and therapeutic component are all deposited with nano level scale
It can directly be absorbed by the skin, if trehalose has the good function of preventing cell dehydration and moisturizing, there is excellent holding cell
The characteristic of vigor prevents the generation of Skin Cell dehydration and keratinization under the environment such as high temperature, high and cold, dry, intensive ultraviolet；Wood
Melon protease can dissolve the scurf of keratinization, play the effect of better skin care and treatment.
(5) the nanometer facial mask that spins of the invention is blocked in the harmful substance in haze except skin, plays good anti-
Haze effect protects the health of user.
(6) various beauty and Cosmetic Ingredient can also be added in i.e. spinning nanometer facial mask of the invention, substitutes various cosmetics,
It is user-friendly, reduce the spending of user.
Description of the drawings
Fig. 1 is scanning electron microscopy (SEM) figure of the gelatin nanometer facial mask in the embodiment of the present invention 1.
Fig. 2 is gelatin+trehalose nanometer facial mask scanning electron microscopy (SEM) figure in the embodiment of the present invention 2.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to the accompanying drawings and embodiments, right
The present invention is explained in further detail.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, and
It is not used in the restriction present invention.
On the contrary, the present invention covers any replacement done in the spirit and scope of the present invention being defined by the claims, repaiies
Change, equivalent method and scheme.Further, in order to make the public have a better understanding the present invention, below to the thin of the present invention
It is detailed to describe some specific detail sections in section description.Part without these details for a person skilled in the art
Description can also understand the present invention completely.
Embodiment 1
The present embodiment provides a kind of preparation method for spinning nanometer facial mask, the method includes high score by using homogeneous
The spinning liquid of sub- substrate and water obtains the i.e. spinning nanometer facial mask on wafer after spinning.
The preparation method is as follows：
(1) selection of liquid raw material is spun：Select gelatin made of collagen as macromolecule substrate, wet concentration remove from
Sub- water；
(2) preparation of liquid is spun：The gelatin and the deionized water are pressed 1:2 mass ratio is placed in 50ml volumetric flasks and mixes
12h is stirred at 60 DEG C~80 DEG C of constant temperature after conjunction, until the gelatin and the deionized water are uniformly mixed, then adds deionized water fixed
Hold, the spinning liquid that gelatin mass fraction is 33.3% is made；
(3) electric spinning machine parameter setting：It is 8cm that system temperature, which is 35 DEG C, spinning flow velocity is 0.2ml/h, receives distance, voltage
For 8kv.
(4) preparation of nanometer facial mask is spun：The spinning liquid obtained in step 1 is placed in electrostatic spinning machine, with described
The Electrospun pipette tips of electrostatic spinning machine uniform 8~12min of spinning on wafer spins nanometer facial mask to get to described.
Nanometer facial mask is spun described in being prepared and carries out moisturizing test, obtains its moisture preserving time in 4h or more.
Nanometer facial mask will be spun made from preparation method according to the present embodiment observes nanometer under a scanning electron microscope
The structure of film, as shown in Figure 1, gained gelatin nanometer facial mask (nano non-woven fabric) has uniform, smooth, porous microscopic appearance, it is fine
Diameter is tieed up between 200nm to 400nm.
Embodiment 2
The present embodiment it is a kind of i.e. spin nanometer facial mask preparation method it is substantially the same manner as Example 1, only unlike：
(2) in when preparing the spinnings liquid, when the gelatin and the deionized water after mixing, addition matter 2~3 is dripped extra large
The sweet osmanthus perfume of algae sugar and 2~3 drops, and continue stirring until all the components are uniformly mixed.
Nanometer facial mask is spun described in being prepared and carries out moisturizing test, obtains its moisture preserving time in 6h or more.
Nanometer facial mask will be spun made from preparation method according to the present embodiment observes nanometer under a scanning electron microscope
The structure of film, as shown in Fig. 2, gained gelatin nanometer facial mask (nano non-woven fabric) has uniform, smooth, porous microscopic appearance, it is fine
Dimension diameter has oval protrusion between 200nm to 400nm, on nanofiber, wherein including the ingredient of trehalose.
Embodiment 3
The present embodiment it is a kind of i.e. spin nanometer facial mask preparation method it is substantially the same manner as Example 1, only unlike：
(2) preparation process of spinning liquid is in：
1. the gelatin and the deionized water are pressed 1:2 mass ratio is placed in 50ml volumetric flasks 60 DEG C of constant temperature after mixing
12h is stirred at~80 DEG C, until the gelatin and the deionized water are uniformly mixed, adds 3% trehalose of matter and 1% fragrance of osmanthus
Water, and continue stirring until all the components are uniformly mixed；At this point, the gelatin solution that mass fraction is 16.0% is made；
2. silk cocoon is cut off with scissors, silkworm chrysalis is removed, by silk cocoon stripping at the sodium bicarbonate aqueous solution (bath of several layers of postposition 0.5%
Water ratio is 1：100) 30min is boiled in, is removed silk surface silk gum, is so repeated twice.Then it is fully rinsed with deionized water,
Finally dry.Degumming fibroin 10g is taken, a concentration of 10% solution is made into the LiBr of 9.5mol/L, is stood overnight.Add from
Sub- water dilutes 5 times, and filtering is subsequently poured into bag filter, then is continuously dialysed up to deionized water outside bag filter with deionized water
Until conductivity is basically unchanged；
3. weighing natural silk 8g, institute's gelatine solution in being dissolved in 1. is settled to 50mL to get to gelatin fibroin albumen
Spin liquid.
Nanometer facial mask will be spun made from preparation method according to the present embodiment observes nanometer under a scanning electron microscope
The structure of film, gained gelatin nanometer facial mask (nano non-woven fabric) have uniform, smooth, porous microscopic appearance, fibre diameter to exist
There is oval protrusion between 200nm to 400nm, on nanofiber, wherein including the ingredient of trehalose.
Claims (10)
1. a kind of spinning liquid, which is characterized in that the liquid that spins includes the macromolecule substrate and 40% that mass fraction is 25%~40%
~75% solvent.
2. a kind of spinning liquid according to claim 1, which is characterized in that the macromolecule substrate is collagen, gelatin, silk
In fibroin and chitosan any one or it is arbitrary two or more.
3. a kind of spinning liquid according to claim 1, which is characterized in that the solvent includes water.
4. a kind of spinning liquid according to claim 1, which is characterized in that the spinning liquid also includes that mass fraction is 1%~5%
Skin care and moisturizing ingredient.
5. a kind of spinning liquid according to claim 1, which is characterized in that the spinning liquid also includes that mass fraction is not more than 2%
Cosmetic Ingredient and/or mass fraction be not more than 2% Cosmetic Ingredient.
6. one kind spinning nanometer facial mask, which is characterized in that the nanometer facial mask that spins is using such as any one of Claims 1 to 5
What the spinning liquid obtained on paper after spinning；
The fibre diameter for spinning nanometer facial mask is 200nm~400nm.
7. a kind of preparation method for spinning nanometer facial mask according to claim 6, which is characterized in that the method is by adopting
The i.e. spinning nanometer facial mask is obtained after spinning on wafer with the spinning liquid comprising macromolecule substrate and solvent of homogeneous.
8. a kind of preparation method for spinning nanometer facial mask according to claim 7, which is characterized in that the preparation method tool
Steps are as follows for body：
Step 1, the preparation of liquid is spun：10h or more is stirred at 60 DEG C~80 DEG C of constant temperature after the macromolecule substrate and solvent are mixed,
Until the macromolecule substrate and the solvent are uniformly mixed, at this point, the spinning liquid is made；
Step 2, that is, the preparation of nanometer facial mask is spun：The spinning liquid obtained in step 1 is placed in electric spinning machine, setting electric spinning machine is joined
Number includes system temperature, spins flow velocity, receives distance and voltage, with the pipette tips of the electrostatic spinning rifle of the electric spinning machine in wafer
Or uniform 8~12min of spinning spins nanometer facial mask to get to described on human skin.
9. a kind of preparation method for spinning nanometer facial mask according to claim 8, which is characterized in that high described in step 1
Any one in skin care and moisturizing ingredient, Cosmetic Ingredient and Cosmetic Ingredient is added in molecule substrate and the solvent after mixing
Or arbitrary two or three, continue stirring until the skin care and moisturizing ingredient are mixed with the macromolecule substrate and the solvent
Uniformly.
10. a kind of preparation method for spinning nanometer facial mask according to claim 8, which is characterized in that body described in step 2
Be temperature be 25 DEG C~40 DEG C；
It is 0.1 to 0.3ml/h that flow velocity is spun described in step 2；
It is the electrostatic spinning rifle with the wafer at a distance from that distance is received described in step 2, receptions apart from be 5~
8cm；
Voltage described in step 2 is 8kv~20kv.
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