CN108277499A - A kind of rust remover and preparation method thereof for mechanical equipment - Google Patents

A kind of rust remover and preparation method thereof for mechanical equipment Download PDF

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Publication number
CN108277499A
CN108277499A CN201810407191.1A CN201810407191A CN108277499A CN 108277499 A CN108277499 A CN 108277499A CN 201810407191 A CN201810407191 A CN 201810407191A CN 108277499 A CN108277499 A CN 108277499A
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China
Prior art keywords
parts
acid
rust remover
mechanical equipment
vegetable oil
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CN201810407191.1A
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Chinese (zh)
Inventor
何飞
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Hefei Bo Chuang Machinery Manufacturing Co Ltd
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Hefei Bo Chuang Machinery Manufacturing Co Ltd
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Priority to CN201810407191.1A priority Critical patent/CN108277499A/en
Publication of CN108277499A publication Critical patent/CN108277499A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds

Abstract

The rust remover and preparation method thereof that the present invention provides a kind of for mechanical equipment, the rust remover of the present invention has carried out modifications and adaptations to the formula of rust remover, and the ingredient of formula includes polyethylene glycol, cosolvent, anionic surfactant, oxalic acid, tannic acid powder, mannitol, organic acid, chlorination inorganic salts, antioxidant, vegetable oil.On the one hand the innovation of the present invention is to make rust remover different from general cleaning agent by the selection of ingredient and the reasonable preparation of amount, derusting effect is good, with strong points, environmental protection, small to human health damage.It is especially added to vegetable oil wherein, mechanical equipment can form layer protecting film on mechanical equipment surface, oxygen has been isolated, so as to avoid metal from being aoxidized, has played very effective, long-term protecting effect after rust remover derusts.

Description

A kind of rust remover and preparation method thereof for mechanical equipment
Technical field
The invention belongs to rust remover technical fields, and in particular, to a kind of rust remover and its preparation for mechanical equipment Method.
Background technology
Mechanical equipment is often in contact with water equal solvent in use, in air under the action of get rusty easily, lead It causes mechanical equipment surface rusty stain contamination phenomenon serious, has seriously affected the performance and appearance of machinery, therefore, it is necessary to machinery The surface of equipment is derusted, and a kind of rust remover of excellent performance is essential.
Rust remover in the prior art for mechanical equipment derusting mostly uses greatly cleaning agent, and cleaning agent is directed to oil mostly Dirt, derusting effect is undesirable, also contains hazardous substance in some rust removers, endangers human health, specifically for removing for mechanical equipment Rust agent seldom relates to.
To solve the above-mentioned problems, research and development are a kind of can be to the carry out Rapid Cleaning environmental protection again of rusty stain, and can also be risen after cleaning Antirust agent to the effect for preventing to get rusty is imperative.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of rust remover for mechanical equipment and preparations Method.
It is described to be built using what microbial mineralization was handled according to a kind of rust remover for mechanical equipment provided by the invention Material material includes the raw material of following parts by weight:41-60 parts of polyethylene glycol, 2.3-3.6 parts of cosolvent, anionic surface activity 1.9-4.3 parts of agent, 4-18 parts of oxalic acid, 3-9 parts of tannic acid powder, 5-9 parts of mannitol, 9-13 parts of organic acid, 2-13 parts of chlorination inorganic salts, 13-15 parts of antioxidant, 4-11 parts of vegetable oil.
Preferably, the building material handled using microbial mineralization includes the raw material of following parts by weight:Poly- second 41-50 parts of glycol, 2.3-3.1 parts of cosolvent, 1.9-2.3 parts of anionic surfactant, 4-13 parts of oxalic acid, tannic acid powder 3-7 Part, 5-7 parts of mannitol, 9-11 parts of organic acid, 2-11 parts of chlorination inorganic salts, 13-14 parts of antioxidant, 6-11 parts of vegetable oil.
Preferably, the building material handled using microbial mineralization includes the raw material of following parts by weight:Poly- second It is 47 parts of glycol, 2.8 parts of cosolvent, 2.1 parts of anionic surfactant, 7 parts of oxalic acid, 4 parts of tannic acid powder, 6 parts of mannitol, organic 10 parts of acid, 5 parts of chlorination inorganic salts, 14 parts of antioxidant, 7 parts of vegetable oil.
Preferably, the organic acid is citric acid, tartaric acid, malic acid, chlorogenic acid, oxalic acid, benzoic acid, salicylic acid, coffee One or more of coffee acid.
Preferably, the chlorination inorganic salts are sodium chloride or potassium chloride.
Preferably, the vegetable oil is by following processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 70-80 DEG C of temperature condition and carry out reduction reaction, is gone back The mass ratio that feeds intake of oil solution after original, the vegetable oil and gallic acid is 10 ︰ 0.5-1.6;
(2)Neutralization reaction:The NaOH solution that mass concentration is 7-12% is added into the oil solution after reduction, in 50-60 DEG C Stirred at ambient temperature 20-30min is then allowed to stand layering, and water phase waste liquid is discharged, and obtains oil phase, and the NaOH of the addition is water-soluble The mass ratio of liquid and vegetable oil is 0.8-1.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 8-10% are added into oil phase, in 30-60 DEG C of stirred at ambient temperature Washing is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, and until the water phase separated is in neutrality, oil phase is de- through vacuum Water.
Preferably, described(3)The mass ratio that feeds intake of middle oil phase and NaCl aqueous solutions is 10 ︰ 1.
A kind of preparation method of rust remover for mechanical equipment, the method comprise the concrete steps that:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed equal It is heated to 45-50 DEG C after even, antioxidant is added while hot, continues to be heated to 70-80 DEG C of postcooling to room after keeping the temperature 10-20min Temperature;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 15-20min is kept the temperature at 40-60 DEG C, heat preservation 20-35min postcoolings are to room temperature after continuation is heated to 85-90 DEG C while stirring, i.e., It can.
Compared with prior art, the present invention has following advantageous effect:
1, a kind of rust remover for mechanical equipment provided by the invention, rust remover of the invention carry out the formula of rust remover The ingredient of modifications and adaptations, formula includes polyethylene glycol, cosolvent, anionic surfactant, oxalic acid, tannic acid powder, sweet dew Alcohol, organic acid, chlorination inorganic salts, antioxidant, vegetable oil.The innovation of the present invention be on the one hand by the selection of ingredient and The reasonable preparation of amount makes rust remover different from general cleaning agent, and derusting effect is good, with strong points, environmental protection, to human health damage It is small.It is especially added to vegetable oil wherein, mechanical equipment can form one layer after rust remover derusts on mechanical equipment surface Oxygen has been isolated in protective film, so as to avoid metal from being aoxidized, plays very effective, long-term protecting effect.
2, a kind of rust remover for mechanical equipment provided by the invention, mechanical equipment rust remover of the invention, to machinery Equipment has very strong derusting effect, also has preferable surface protection performance, secondary antirust function is stronger after cleaning, abandons Damage or corrosion of the conventional clean agent to mechanical equipment surface have very strong practicability.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention Rather than it limits the scope of the invention.
Embodiment 1
A kind of rust remover for mechanical equipment provided in this embodiment, the building material handled using microbial mineralization Include the raw material of following parts by weight:60 parts of polyethylene glycol, 2.3 parts of cosolvent, 4.3 parts of anionic surfactant, oxalic acid 4 Part, 9 parts of tannic acid powder, 5 parts of mannitol, 13 parts of organic acid, 2 parts of chlorination inorganic salts, 15 parts of antioxidant, 4 parts of vegetable oil.
Preferably, the organic acid is citric acid, tartaric acid, malic acid, chlorogenic acid, oxalic acid, benzoic acid, bigcatkin willow One or more of acid, caffeic acid.
Preferably, the chlorination inorganic salts are sodium chloride or potassium chloride.
Preferably, the vegetable oil is by following processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 80 DEG C of temperature conditions and carry out reduction reaction, after obtaining reduction Oil solution, the mass ratio that feeds intake of the vegetable oil and gallic acid is 10 ︰ 1.6;
(2)Neutralization reaction:The NaOH solution that mass concentration is 12% is added into the oil solution after reduction, in 50 DEG C of environment temperature Degree is lower to stir 30min, is then allowed to stand layering, water phase waste liquid is discharged, obtain oil phase, the NaOH aqueous solutions and vegetable oil of the addition Mass ratio be 0.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 10% are added into oil phase, are washed in 30 DEG C of stirred at ambient temperature, It is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, until the water phase separated is in neutrality, oil phase is through vacuum dehydration It can.
Preferably, described(3)The mass ratio that feeds intake of middle oil phase and NaCl aqueous solutions is 10 ︰ 1.
A kind of preparation method of rust remover for mechanical equipment, the method comprise the concrete steps that:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed evenly After be heated to 50 DEG C and be added antioxidant while hot, continue to be heated to 80 DEG C of postcoolings to room temperature after keeping the temperature 10min;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 15min is kept the temperature at 60 DEG C, continuation keeps the temperature 20min postcoolings to room temperature after being heated to 90 DEG C while stirring, you can.
Embodiment 2
A kind of rust remover for mechanical equipment provided in this embodiment, the building material handled using microbial mineralization Include the raw material of following parts by weight:41 parts of polyethylene glycol, 3.1 parts of cosolvent, 1.9 parts of anionic surfactant, oxalic acid 13 parts, 3 parts of tannic acid powder, 7 parts of mannitol, 9 parts of organic acid, 11 parts of chlorination inorganic salts, 13 parts of antioxidant, 11 parts of vegetable oil.
Preferably, the organic acid is citric acid, tartaric acid, malic acid, chlorogenic acid, oxalic acid, benzoic acid, bigcatkin willow One or more of acid, caffeic acid.
Preferably, the chlorination inorganic salts are sodium chloride or potassium chloride.
Preferably, the vegetable oil is by following processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 70 DEG C of temperature conditions and carry out reduction reaction, after obtaining reduction Oil solution, the mass ratio that feeds intake of the vegetable oil and gallic acid is 10 ︰ 1.6;
(2)Neutralization reaction:The NaOH solution that mass concentration is 7% is added into the oil solution after reduction, in 60 DEG C of environment temperature Degree is lower to stir 20min, is then allowed to stand layering, water phase waste liquid is discharged, obtain oil phase, the NaOH aqueous solutions and vegetable oil of the addition Mass ratio be 1.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 10% are added into oil phase, are washed in 60 DEG C of stirred at ambient temperature, It is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, until the water phase separated is in neutrality, oil phase is through vacuum dehydration It can.
Preferably, described(3)The mass ratio that feeds intake of middle oil phase and NaCl aqueous solutions is 10 ︰ 1.
A kind of preparation method of rust remover for mechanical equipment, the method comprise the concrete steps that:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed evenly After be heated to 45 DEG C and be added antioxidant while hot, continue to be heated to 70 DEG C of postcoolings to room temperature after keeping the temperature 20min;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 0min is kept the temperature at 40 DEG C, continuation keeps the temperature 35min postcoolings to room temperature after being heated to 85 DEG C while stirring, you can.
Embodiment 3
A kind of rust remover for mechanical equipment provided in this embodiment, the building material handled using microbial mineralization Include the raw material of following parts by weight:47 parts of polyethylene glycol, 2.8 parts of cosolvent, 2.1 parts of anionic surfactant, oxalic acid 7 Part, 4 parts of tannic acid powder, 6 parts of mannitol, 10 parts of organic acid, 5 parts of chlorination inorganic salts, 14 parts of antioxidant, 7 parts of vegetable oil.
Preferably, the organic acid is citric acid, tartaric acid, malic acid, chlorogenic acid, oxalic acid, benzoic acid, bigcatkin willow One or more of acid, caffeic acid.
Preferably, the chlorination inorganic salts are sodium chloride or potassium chloride.
Preferably, the vegetable oil is by following processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 80 DEG C of temperature conditions and carry out reduction reaction, after obtaining reduction Oil solution, the mass ratio that feeds intake of the vegetable oil and gallic acid is 10 ︰ 1.6;
(2)Neutralization reaction:The NaOH solution that mass concentration is 12% is added into the oil solution after reduction, in 60 DEG C of environment temperature Degree is lower to stir 30min, is then allowed to stand layering, water phase waste liquid is discharged, obtain oil phase, the NaOH aqueous solutions and vegetable oil of the addition Mass ratio be 1.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 10% are added into oil phase, are washed in 60 DEG C of stirred at ambient temperature, It is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, until the water phase separated is in neutrality, oil phase is through vacuum dehydration It can.
Preferably, described(3)The mass ratio that feeds intake of middle oil phase and NaCl aqueous solutions is 10 ︰ 1.
A kind of preparation method of rust remover for mechanical equipment, the method comprise the concrete steps that:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed evenly After be heated to 50 DEG C and be added antioxidant while hot, continue to be heated to 80 DEG C of postcoolings to room temperature after keeping the temperature 20min;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 20min is kept the temperature at 40 DEG C, continuation keeps the temperature 35min postcoolings to room temperature after being heated to 85 DEG C while stirring, you can.
Embodiment 4
A kind of rust remover for mechanical equipment provided in this embodiment, the building material handled using microbial mineralization Include the raw material of following parts by weight:41 parts of polyethylene glycol, 3.1 parts of cosolvent, 1.9 parts of anionic surfactant, oxalic acid 13 parts, 3 parts of tannic acid powder, 7 parts of mannitol, 9 parts of organic acid, 11 parts of chlorination inorganic salts, 13 parts of antioxidant, 11 parts of vegetable oil.
Preferably, the organic acid is citric acid, tartaric acid, malic acid, chlorogenic acid, oxalic acid, benzoic acid, bigcatkin willow One or more of acid, caffeic acid.
Preferably, the chlorination inorganic salts are sodium chloride or potassium chloride.
Preferably, the vegetable oil is by following processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 70 DEG C of temperature conditions and carry out reduction reaction, after obtaining reduction Oil solution, the mass ratio that feeds intake of the vegetable oil and gallic acid is 10 ︰ 1.6;
(2)Neutralization reaction:The NaOH solution that mass concentration is 7% is added into the oil solution after reduction, in 50 DEG C of environment temperature Degree is lower to stir 30min, is then allowed to stand layering, water phase waste liquid is discharged, obtain oil phase, the NaOH aqueous solutions and vegetable oil of the addition Mass ratio be 0.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 8% are added into oil phase, are washed in 30 DEG C of stirred at ambient temperature, It is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, until the water phase separated is in neutrality, oil phase is through vacuum dehydration It can.
Preferably, described(3)The mass ratio that feeds intake of middle oil phase and NaCl aqueous solutions is 10 ︰ 1.
A kind of preparation method of rust remover for mechanical equipment, the method comprise the concrete steps that:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed evenly After be heated to 45 DEG C and be added antioxidant while hot, continue to be heated to 70 DEG C of postcoolings to room temperature after keeping the temperature 20min;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 15min is kept the temperature at 60 DEG C, continuation keeps the temperature 20min postcoolings to room temperature after being heated to 90 DEG C while stirring, you can.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of rust remover for mechanical equipment, it is characterised in that:The building material handled using microbial mineralization Include the raw material of following parts by weight:41-60 parts of polyethylene glycol, 2.3-3.6 parts of cosolvent, anionic surfactant 1.9- 4.3 parts, it is 4-18 parts of oxalic acid, 3-9 parts of tannic acid powder, 5-9 parts of mannitol, 9-13 parts of organic acid, 2-13 parts of chlorination inorganic salts, anti-oxidant 13-15 parts of agent, 4-11 parts of vegetable oil.
2. a kind of rust remover for mechanical equipment according to claim 1, it is characterised in that:Described utilizes microorganism The building material of mineralising processing includes the raw material of following parts by weight:41-50 parts of polyethylene glycol, 2.3-3.1 parts of cosolvent, it is cloudy from 1.9-2.3 parts of subtype surfactant, 4-13 parts of oxalic acid, 3-7 parts of tannic acid powder, 5-7 parts of mannitol, 9-11 parts of organic acid, chlorination 2-11 parts of inorganic salts, 13-14 parts of antioxidant, 6-11 parts of vegetable oil.
3. a kind of rust remover for mechanical equipment according to claim 1, it is characterised in that:Described utilizes microorganism The building material of mineralising processing includes the raw material of following parts by weight:47 parts of polyethylene glycol, 2.8 parts of cosolvent, anionic table 2.1 parts of face activating agent, 7 parts of oxalic acid, 4 parts of tannic acid powder, 6 parts of mannitol, 10 parts of organic acid, 5 parts of chlorination inorganic salts, antioxidant 14 Part, 7 parts of vegetable oil.
4. a kind of rust remover for mechanical equipment according to claim 1, it is characterised in that:The organic acid is lemon Acid, tartaric acid, one or more of malic acid, chlorogenic acid, oxalic acid, benzoic acid, salicylic acid, caffeic acid.
5. a kind of rust remover for mechanical equipment according to claim 1, it is characterised in that:The chlorination inorganic salts are Sodium chloride or potassium chloride.
6. a kind of rust remover for mechanical equipment according to claim 1, it is characterised in that:The vegetable oil is by such as Lower processing:
(1)Reduction reaction:Vegetable oil and gallic acid are blended under 70-80 DEG C of temperature condition and carry out reduction reaction, is gone back The mass ratio that feeds intake of oil solution after original, the vegetable oil and gallic acid is 10 ︰ 0.5-1.6;
Neutralization reaction:The NaOH solution that mass concentration is 7-12% is added into the oil solution after reduction, in 50-60 DEG C of environment At a temperature of stir 20-30min, be then allowed to stand layering, water phase waste liquid be discharged, obtain oil phase, the NaOH aqueous solutions of the addition with The mass ratio of vegetable oil is 0.8-1.8 ︰ 10;
(3)Purifying:The NaCl aqueous solutions that mass concentration is 8-10% are added into oil phase, in 30-60 DEG C of stirred at ambient temperature Washing is then centrifuged for separating oil reservoir, repeats above-mentioned washing process, and until the water phase separated is in neutrality, oil phase is de- through vacuum Water.
7. a kind of rust remover for mechanical equipment according to claim 6, it is characterised in that:It is described(3)Middle oil phase with The mass ratio that feeds intake of NaCl aqueous solutions is 10 ︰ 1.
8. a kind of preparation method of rust remover for mechanical equipment according to claim 1, it is characterised in that:The system Preparation Method includes the following steps:
(1)The polyethylene glycol of required weight, cosolvent, anionic surfactant, oxalic acid, tannic acid powder are mixed evenly After be heated to 45-50 DEG C and be added antioxidant while hot, continue to be heated to 70-80 DEG C of postcooling to room temperature after keeping the temperature 10-20min;
(2)The desired amount of mannitol, organic acid, chlorination inorganic salts, vegetable oil are added into above-mentioned solvent after cooling, is heated to 15-20min is kept the temperature at 40-60 DEG C, heat preservation 20-35min postcoolings are to room temperature after continuation is heated to 85-90 DEG C while stirring, i.e., It can.
CN201810407191.1A 2018-05-02 2018-05-02 A kind of rust remover and preparation method thereof for mechanical equipment Pending CN108277499A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108677205A (en) * 2018-07-25 2018-10-19 泾县狸宣文化用品有限公司 A kind of preparation method and application method of Deruster for metal
CN109112559A (en) * 2018-09-03 2019-01-01 合肥久新不锈钢厨具有限公司 A kind of hardware tool rust remover and its preparation and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289820A (en) * 2013-07-01 2013-09-11 扬州大学 Method for reducing peroxide in plant oil
CN104233358A (en) * 2014-09-10 2014-12-24 句容金猴机械研究所有限公司 Rust remover for mechanical equipment and preparation method of rust remover
CN104674243A (en) * 2015-03-19 2015-06-03 张新贞 Rust remover and using method, preparation method and additives of rust remover
CN106635279A (en) * 2016-09-19 2017-05-10 铜陵日科电子有限责任公司 Anti-rusting and scale-inhibiting transformer vegetable insulating oil and preparation method thereof
CN106757061A (en) * 2016-12-07 2017-05-31 青岛巨能管道设备有限公司 A kind of new rust remover

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289820A (en) * 2013-07-01 2013-09-11 扬州大学 Method for reducing peroxide in plant oil
CN104233358A (en) * 2014-09-10 2014-12-24 句容金猴机械研究所有限公司 Rust remover for mechanical equipment and preparation method of rust remover
CN104674243A (en) * 2015-03-19 2015-06-03 张新贞 Rust remover and using method, preparation method and additives of rust remover
CN106635279A (en) * 2016-09-19 2017-05-10 铜陵日科电子有限责任公司 Anti-rusting and scale-inhibiting transformer vegetable insulating oil and preparation method thereof
CN106757061A (en) * 2016-12-07 2017-05-31 青岛巨能管道设备有限公司 A kind of new rust remover

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108677205A (en) * 2018-07-25 2018-10-19 泾县狸宣文化用品有限公司 A kind of preparation method and application method of Deruster for metal
CN109112559A (en) * 2018-09-03 2019-01-01 合肥久新不锈钢厨具有限公司 A kind of hardware tool rust remover and its preparation and application

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