CN108276943A - A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive - Google Patents
A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive Download PDFInfo
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- CN108276943A CN108276943A CN201810084906.4A CN201810084906A CN108276943A CN 108276943 A CN108276943 A CN 108276943A CN 201810084906 A CN201810084906 A CN 201810084906A CN 108276943 A CN108276943 A CN 108276943A
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- Prior art keywords
- reaction kettle
- adhesive
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- added
- temperature
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of glass high intensity, the preparation method of high-temperature-resistant adhesive, method includes：Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 23 DEG C/min, and temperature is risen to 40 50 DEG C；Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed is 50 90r/min, and mixing time is 12 18min；By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 120 160r/min, mixing time is 3 8min, obtains adhesive.Adhesive prepared by this preparation method is applied on glassware, has preferable caking property with glassware, and adhesive strength is higher, high temperature resistant, is very suitable for the viscous application of glass mounting adhesive；And this preparation method is simple for process, process is few, mild condition, and manufacturing cost is low.
Description
Technical field
The present invention relates to adhesive technology field more particularly to a kind of glass high intensity, high-temperature-resistant adhesives
Preparation method.
Background technology
Glass, this physical development for possessing more than 5000 years history have greatly enriched our world to today, promote
The development of civilized society.Glass industry suffers from its developing history and rule, in 21 century as other industry
State, economic society is all-round developing, and Chinese glass industry equally achieves the achievement that the world attractes attention.
The promotion of glass is excellent, and glassware is widely used in all trades and professions, forms various types, example
Such as：What tempered glass, cellular glass, electro-conductive glass, devitrified glass, emulsion opal glass and hollow glass and glass were further processed
Mirror.
It is by punching, then bolt in many cases when it will connect with other objects since glass surface is smooth
Connection, can damage the overall integrity of glass in this way.There are also existing what is be fixedly connected by adhesive, still, existing preparation side
The shortcomings that there are intensity is low for adhesive prepared by method, non-refractory, and complex process.
Invention content
In view of this, the present invention provides a kind of glass high intensity, the preparation methods of high-temperature-resistant adhesive.
A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive, method include：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate be 2-3 DEG C/
Temperature is risen to 40-50 DEG C by min；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 50-90r/min,
Mixing time is 12-18min；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 120-160r/min, when stirring
Between be 3-8min, obtain adhesive.
Preferably, method includes：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate be 2-3 DEG C/
Temperature is risen to 43-47 DEG C by min；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 65-80r/min,
Mixing time is 14-17min；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 130-145r/min, when stirring
Between be 4-7min, obtain adhesive.
Preferably, method includes：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate be 2 DEG C/
Temperature is risen to 45 DEG C by min；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 72r/min is stirred
It is 15min to mix the time；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 138r/min, mixing time is
6min obtains adhesive.
Preferably, further include the epoxy resin for accurately weighing group component, acrylic resin, filler, silica sol, thickening
Agent, antioxidant and monohydric alcohol.
Preferably, further include that adhesive is subjected to 80-120 mesh sieves, packaging of then weighing.
Preferably, described adhesive crosses 85-105 mesh sieve, packaging of then weighing.
Preferably, the filler is at least one of carbon black, alumina powder, glass powder and flake asbestos.
Preferably, the tackifier are one kind in alicyclic petroleum resin, hydrogenated rosin resin and terpene resin.
Preferably, the antioxidant is 2,6- three-levels butyl -4- methylphenols or bis- (3,5- three-level butyl -4- hydroxyls
Phenyl) thioether.
Preferably, the monohydric alcohol is one kind in methanol, ethyl alcohol and propyl alcohol.
The present invention provides a kind of glass high intensity, the preparation method of high-temperature-resistant adhesive, prepared by this preparation method
Adhesive is applied on glassware, has preferable caking property with glassware, and adhesive strength is higher, high temperature resistant, non-
The often viscous application of suitable glass mounting adhesive；And this preparation method is simple for process, process is few, mild condition, and manufacturing cost is low.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are some of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to
The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " comprising " and "comprising" instruction
Described feature, entirety, step, operation, the presence of element and/or component, but one or more of the other feature, whole is not precluded
Body, step, operation, element, component and/or its presence or addition gathered.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is
Refer to any combinations and all possible combinations of one or more of associated item listed, and includes these combinations.
In the following, in conjunction with specific embodiments, adhesive is specifically described：
Embodiment 1
The high intensity of glass, high-temperature-resistant adhesive, by mass fraction, its material component includes：
Preparation method is：
The accurate epoxy resin for weighing group component, acrylic resin, carbon black, silica sol, alicyclic petroleum resin, 2,6-
Three-level butyl -4- methylphenols and methanol；
Epoxy resin and methanol are added into reaction kettle, reaction kettle is heated, heating rate is 3 DEG C/min,
Temperature is risen to 40 DEG C；
Acrylic resin and carbon black are added into reaction kettle, turn on agitator, mixing speed 90r/min, are stirred
Time is 12min；
It, will stirring speed in 6- three-level butyl -4- methylphenol reaction kettles by silica sol, alicyclic petroleum resin and 2
Degree is adjusted to 160r/min, and mixing time 3min obtains adhesive；
Adhesive is subjected to 120 mesh sieves, packaging of then weighing.
Embodiment 2
The high intensity of glass, high-temperature-resistant adhesive, by mass fraction, its material component includes：
Preparation method is：
It is the accurate epoxy resin for weighing group component, acrylic resin, alumina powder, silica sol, hydrogenated rosin resin, double
(3,5- three-level butyl -4- hydroxy phenyls) thioether and ethyl alcohol；
Epoxy resin and ethyl alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 3 DEG C/min,
Temperature is risen to 47 DEG C；
Acrylic resin and alumina powder are added into reaction kettle, turn on agitator, mixing speed 80r/min,
Mixing time is 14min；
By in silica sol, hydrogenated rosin resin and bis- (3,5- three-level butyl -4- hydroxy phenyls) thioether reactant kettles, incite somebody to action
Mixing speed is adjusted to 145r/min, and mixing time 7min obtains adhesive；
Adhesive is subjected to 85 mesh sieves, packaging of then weighing.
Embodiment 3
The high intensity of glass, high-temperature-resistant adhesive, by mass fraction, its material component includes：
Preparation method is：
The accurate epoxy resin for weighing group component, acrylic resin, glass powder, silica sol, terpene resin, 2,6- three-levels
Butyl -4- methylphenols and propyl alcohol；
Epoxy resin and propyl alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2 DEG C/min,
Temperature is risen to 50 DEG C；
Acrylic resin and glass powder are added into reaction kettle, turn on agitator, mixing speed 50r/min is stirred
It is 18min to mix the time；
By silica sol, terpene resin and 2, in 6- three-level butyl -4- methylphenol reaction kettles, mixing speed is adjusted to
120r/min, mixing time 8min, obtains adhesive；
Adhesive is subjected to 80 mesh sieves, packaging of then weighing.
Embodiment 4
The high intensity of glass, high-temperature-resistant adhesive, by mass fraction, its material component includes：
Preparation method is：
It is the accurate epoxy resin for weighing group component, acrylic resin, flake asbestos, silica sol, alicyclic petroleum resin, double
(3,5- three-level butyl -4- hydroxy phenyls) thioether and propyl alcohol；
Epoxy resin and propyl alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2 DEG C/min,
Temperature is risen to 43 DEG C；
Acrylic resin and flake asbestos are added into reaction kettle, turn on agitator, mixing speed 65r/min is stirred
It is 17min to mix the time；
By in silica sol, alicyclic petroleum resin and bis- (3,5- three-level butyl -4- hydroxy phenyls) thioether reactant kettles,
Mixing speed is adjusted to 130r/min, mixing time 4min obtains adhesive；
Adhesive is subjected to 105 mesh sieves, packaging of then weighing.
Embodiment 5
The high intensity of glass, high-temperature-resistant adhesive, by mass fraction, its material component includes：
Preparation method is：
Accurate epoxy resin, acrylic resin, alumina powder, flake asbestos, silica sol, the hydrogenated rosin for weighing group component
Resin, 2,6- three-levels butyl -4- methylphenols and ethyl alcohol；
Epoxy resin and ethyl alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2 DEG C/min,
Temperature is risen to 45 DEG C；
Acrylic resin and alumina powder, flake asbestos are added into reaction kettle, turn on agitator, mixing speed is
72r/min, mixing time 15min；
By silica sol, hydrogenated rosin resin and 2, in 6- three-level butyl -4- methylphenol reaction kettles, by mixing speed
It is adjusted to 138r/min, mixing time 6min obtains adhesive；
Adhesive is subjected to 90 mesh sieves, packaging of then weighing.
Adhesive prepared by the preparation method of embodiment 1-5, be applied between glass and glass or glass with
Between other metallic plates, at a temperature of 50 DEG C, 150 DEG C, 250 DEG C and 350 DEG C, respectively test adhesive tensile strength and
Shear strength, test result is as follows：
According to table as can be seen that the adhesive that embodiment 1 to 5 is produced, with the raising of temperature, intensity is constantly existing
Decline, this may be the rising with temperature, and polymer segment is moved in adhesive, and rigidity declines.But although by force
Degree declines, and still, fall is smaller, is fully able to meet the needs of glassware at high temperature；Because in strength test,
Its open position is typically all and glassware position, it is possible to think to be defect point at adhesive and glassware gluing,
Reach such intensity, also illustrates that the compatibility of adhesive and glass is preferable, and this preparation method is simple for process, process is few, item
Part is mild, and manufacturing cost is low.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained
It states, above example is merely used to help understand the method and its core concept of the present invention；Meanwhile for the general skill of this field
Art personnel, according to the thought of the present invention, there will be changes in the specific implementation manner and application range, in conclusion this
Description should not be construed as limiting the invention.
Claims (10)
1. a kind of glass high intensity, the preparation method of high-temperature-resistant adhesive, which is characterized in that method includes：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2-3 DEG C/min,
Temperature is risen to 40-50 DEG C；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 50-90r/min, are stirred
Time is 12-18min；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 120-160r/min, mixing time is
3-8min obtains adhesive.
2. preparation method according to claim 1, which is characterized in that method includes：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2-3 DEG C/min,
Temperature is risen to 43-47 DEG C；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 65-80r/min, are stirred
Time is 14-17min；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 130-145r/min, mixing time is
4-7min obtains adhesive.
3. preparation method according to claim 1, which is characterized in that method includes：
Epoxy resin and monohydric alcohol are added into reaction kettle, reaction kettle is heated, heating rate is 2 DEG C/min, will
Temperature rises to 45 DEG C；
Acrylic resin and filler are added into reaction kettle, turn on agitator, mixing speed 72r/min, when stirring
Between be 15min；
By in silica sol, tackifier and antioxidant reaction kettle, mixing speed is adjusted to 138r/min, mixing time is
6min obtains adhesive.
4. according to any preparation methods of claim 1-3, it is characterised in that：It further include the epoxy for accurately weighing group component
Resin, acrylic resin, filler, silica sol, tackifier, antioxidant and monohydric alcohol.
5. according to any preparation methods of claim 1-3, it is characterised in that：Further include that adhesive is subjected to 80-120 mesh
It is sieved through sieve, packaging of then weighing.
6. preparation method according to claim 5, it is characterised in that：Described adhesive crosses 85-105 mesh sieve, then weighs
Packaging.
7. according to any preparation methods of claim 1-3, it is characterised in that：The filler be carbon black, alumina powder,
At least one of glass powder and flake asbestos.
8. according to any preparation methods of claim 1-3, it is characterised in that：The tackifier are alicyclic petroleum tree
One kind in fat, hydrogenated rosin resin and terpene resin.
9. according to any preparation methods of claim 1-3, it is characterised in that：The antioxidant is 2,6- three-levels butyl-
4- methylphenols or bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers.
10. according to any preparation methods of claim 1-3, it is characterised in that：The monohydric alcohol be methanol, ethyl alcohol and
One kind in propyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810084906.4A CN108276943A (en) | 2018-01-29 | 2018-01-29 | A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810084906.4A CN108276943A (en) | 2018-01-29 | 2018-01-29 | A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108276943A true CN108276943A (en) | 2018-07-13 |
Family
ID=62805580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810084906.4A Pending CN108276943A (en) | 2018-01-29 | 2018-01-29 | A kind of glass high intensity, the preparation method of high-temperature-resistant adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN108276943A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102703009A (en) * | 2012-07-05 | 2012-10-03 | 黑龙江省科学院石油化学研究院 | Preparation method of nano silicon dioxide/polyacrylate modified epoxy resin adhesive |
| CN103351831A (en) * | 2013-06-27 | 2013-10-16 | 衢州市东凯胶业有限公司 | Plastic binder and preparation method thereof |
| CN106189876A (en) * | 2016-07-08 | 2016-12-07 | 姚华鹏 | Antimicrobial form PUR |
-
2018
- 2018-01-29 CN CN201810084906.4A patent/CN108276943A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102703009A (en) * | 2012-07-05 | 2012-10-03 | 黑龙江省科学院石油化学研究院 | Preparation method of nano silicon dioxide/polyacrylate modified epoxy resin adhesive |
| CN103351831A (en) * | 2013-06-27 | 2013-10-16 | 衢州市东凯胶业有限公司 | Plastic binder and preparation method thereof |
| CN106189876A (en) * | 2016-07-08 | 2016-12-07 | 姚华鹏 | Antimicrobial form PUR |
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