CN108275878A - A kind of ceramic board bottom glaze and preparation method thereof greatly - Google Patents
A kind of ceramic board bottom glaze and preparation method thereof greatly Download PDFInfo
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- CN108275878A CN108275878A CN201810075729.3A CN201810075729A CN108275878A CN 108275878 A CN108275878 A CN 108275878A CN 201810075729 A CN201810075729 A CN 201810075729A CN 108275878 A CN108275878 A CN 108275878A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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Abstract
The invention discloses a kind of big board bottom glaze of ceramics, include following component according to the weight percentage of raw materials:Potassium feldspar 10~20%, albite 22~40%, nepheline 5~15%, mixing kaolin 20~30%, silica flour 5~15%, aluminium oxide 10~20%, medium temperature frit 5~10%, zirconium silicate 5~15%.The present invention is by adjusting raw material components and its proportioning, so that the ground-coat enamel is had excellent performance, adapt to the glaze spraying technological operation in production, simultaneously after high temperature firing, the defects of glaze is pin-free, recessed glaze, bubble, so that it is not only had the smooth natural advantage of natural big rock beam to showing for color and luster texture, but also do not lose the elegant of Ceramic Tiles, and assigns the big good soil resistance of plate of ceramics and resistance to chemical corrosion.Simple for process the invention also discloses the preparation method of the ground-coat enamel, technological parameter controllability is strong, and production efficiency is high, is suitable for large-scale industrial production.
Description
Technical field
The present invention relates to Ceramic Tiles field, more particularly to a kind of Ceramic Tiles ground-coat enamel.
Background technology
Ceramic big plate can be carried more than traditional ceramics brick as a new ceramics product with the characteristic of its super large-scale
The texel of horn of plenty, in conjunction with advanced technical merit, it can be achieved that excellent glaze quality.Ceramic big plate has decorative effect
Succinct air, stay seam less, avoid sheltering evil people and countenance evil practices, advantages, the accounting in high-end family product market such as paving of constructing is efficient
Have rate by continuous increase.
However, the big plate gauge lattice of ceramics break through conventional ceramic brick size, causes production difficulty to increase, should ensure production process
Stability, improve the quality of product again, this just needs glaze formula that can simultaneously coordinate with green body and kiln, reach stablize it is high
The effect of quality.The big plate of ceramics domestic at present is difficult to capture glaze technological difficulties, the glaze after product firing exist pin hole,
The mass defects such as recessed glaze, bubble, lead to that yield rate is low, production cost is high, to reduce economic benefit.
Invention content
It is an object of the invention in view of the above shortcomings of the prior art, provide a kind of big board bottom glaze of ceramics, provide simultaneously
The preparation method of the big board bottom glaze of the ceramics.
The technical solution used in the present invention is:A kind of big board bottom glaze of ceramics, includes such as according to the weight percentage of raw materials
Lower component:
As being further improved for said program, the potassium feldspar is K2O content accounts for 7~14% feldspar raw material, described
Albite is Na2O content accounts for 7~13% feldspar raw material, and the optimization of potassium feldspar and albite is selected and compounding, assigns the bottom
The good firing property of glaze, the ground-coat enamel profile pattern formed are high.
As being further improved for said program, the mixing kaolin is made a living the mixing of kaolin and calcined kaolin
Object, kaolin more raw than single selection or calcined kaolin have better adobe suitability, can effectively avoid out after high temperature firing
Existing pin-hole phenomena.The weight proportion of the preferably raw kaolin of the present invention and calcined kaolin is 1:3.
As being further improved for said program, the aluminium oxide is calcined alumina.
As being further improved for said program, Al by mass percentage in the nepheline2O3Content is 20~30%,
K2O content is 1~8%, Na2O content is 5~10%.Specifically, nepheline has both the advantages of two kinds of raw materials of potassium feldspar and albite,
It is compounded with potassium feldspar and albite three, not only can further improve the comprehensive performance of the ground-coat enamel, while can reduce raw material
Usage amount.
As being further improved for said program, SiO by mass percentage in the medium temperature frit2Content be 60~
75%, Al2O3Content is 2~10%.
Include following Main chemical component by mass percentage as being further improved for said program:
As being further improved for said program, the high temperature firing temperature of the ground-coat enamel is 1185~1215 DEG C.
A kind of preparation method of the big board bottom glaze of ceramics as described above comprising following processing step:
1) each component is put into glaze ball mill based on parts by weight of raw materials, addition accounts for total composition weight 30~40%
Water, in the river east tripolyphosphate that the sodium carboxymethylcellulose and 0.35~0.85% that account for total composition weight 0.15~0.45% is added
Sodium, ball milling mixing is uniform, and sieving obtains ball mill mixing;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains ground-coat enamel finished product.
Specifically, the water being added in step 1) be not easy it is excessive or very few, to avoid because adding dilutional hyponatremia to keep ballstone buoyancy big,
Cause ball mill mixing to go out ball fineness big, the ball glaze time need to be increased, increase electric energy loss, or avoids that water is very few to make mixed material because adding
It is difficult to be slurried, it is impossible to be used in production, to cause material loss;The restriction of aging time in step 2), can make raw material components it
Between fully react, be evenly distributed, while the bubble inside ball mill mixing is discharged, occurs bubble when to avoid subsequent high temperature from being burnt into
Phenomenon.
As being further improved for said program, gained ball mill mixing fineness described in step 1) is via hole diameter 0.045mm
For screen over-size after sieve sieving in 0.5~1.0% range, control moisture is 34~36%, and flow velocity is 60~80s, than
Weight is 1.85~2.15g/ml.Specifically, the present invention further limits ball mill mixing technological parameter, can make final gained bottom
Glaze final product quality controllability is strong.
As being further improved for said program, gained ground-coat enamel finish fineness is via hole diameter 0.045mm sieves in step 2)
Screen over-size after sieving is in 0.2~0.5% range, and control moisture is 40~52%, and flow velocity is 20~30s, and proportion is
1.50~1.65g/ml.Specifically, the present invention further limits ground-coat enamel finished product technological parameter, can make the bottom after high temperature firing
Glaze has excellent mechanical property.
The beneficial effects of the invention are as follows:
The present invention is by adjusting raw material components and its proportioning so that the ground-coat enamel is had excellent performance, and adapts to the glaze spraying in production
The defects of technological operation, while after high temperature firing, glaze is pin-free, recessed glaze, bubble, it is made both to have showing for color and luster texture
The smooth natural advantage of standby natural big rock beam, and the elegant of Ceramic Tiles is not lost, and assign the big plate of ceramics good soil resistance
And resistance to chemical corrosion.
Preparation method of the present invention is simple for process, and technological parameter controllability is strong, and production efficiency is high, is suitable for heavy industrialization
Production.
Specific implementation mode
The present invention is specifically described with reference to embodiment, in order to technical field personnel to the present invention
Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this
The limitation of invention protection domain, fields person skilled in the art, the non-intrinsically safe that the present invention is made according to foregoing invention content
The modifications and adaptations of property, should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified, are
Commercial product;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of big board bottom glaze of ceramics, high temperature firing temperature is 1185~1215 DEG C, includes according to the weight percentage of raw materials
Following component:
Wherein, the potassium feldspar is K2O content accounts for 7% feldspar raw material;The albite is Na2O content accounts for 13% length
Stone raw material;The mixing kaolin make a living kaolin and calcined kaolin with weight proportion for 1:The mixture of 3 compositions;The rosy clouds
Al by mass percentage in stone2O3Content is 20%, K2O content is 8%, Na2O content is 5%;It is pressed in the medium temperature frit
Mass percent meter SiO2Content is 60%, Al2O3Content is 10%;The ground-coat enamel includes following mainization by mass percentage
Learn component:22% Al2O3, 65% SiO2, 0.01% Fe2O3, 0.9% CaO, 0.1% MgO, 0.99% K2O、
1% Na2O, 0.6% TiO2, 5.4% ZrO2, 4% burning lose.
Preparation method:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 30% is added,
In the river east sodium tripolyphosphate that the sodium carboxymethylcellulose and 0.35% that account for total composition weight 0.45% is added, ball milling mixing is equal
Even, sieving obtains ball mill mixing, controls the screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves in 0.5~1.0% model
In enclosing, control moisture is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains 1 ground-coat enamel finished product of embodiment,
The screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves is controlled in 0.2~0.5% range, control moisture is
40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
Embodiment 2
A kind of big board bottom glaze of ceramics, high temperature firing temperature is 1185~1215 DEG C, includes according to the weight percentage of raw materials
Following component:
Wherein, the potassium feldspar is K2O content accounts for 14% feldspar raw material;The albite is Na2O content accounts for 7% length
Stone raw material;The mixing kaolin make a living kaolin and calcined kaolin with weight proportion for 1:The mixture of 3 compositions;The rosy clouds
Al by mass percentage in stone2O3Content is 30%, K2O content is 1%, Na2O content is 10%;It is pressed in the medium temperature frit
Mass percent meter SiO2Content is 75%, Al2O3Content is 2%;The ground-coat enamel includes following primary chemical by mass percentage
Component:29.25% Al2O3, 50% SiO2, 0.45% Fe2O3, 0.1% CaO, 0.1% MgO, 0.5% K2O、
1% Na2O, 0.6% TiO2, 10% ZrO2, 8% burning lose.
Preparation method:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 35% is added,
In the river east sodium tripolyphosphate that the sodium carboxymethylcellulose and 0.65% that account for total composition weight 0.3% is added, ball milling mixing is uniform,
Sieving, obtains ball mill mixing, controls the screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves in 0.5~1.0% range
Interior, control moisture is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains 2 ground-coat enamel finished product of embodiment,
The screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves is controlled in 0.2~0.5% range, control moisture is
40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
Embodiment 3
A kind of big board bottom glaze of ceramics, high temperature firing temperature is 1185~1215 DEG C, includes according to the weight percentage of raw materials
Following component:
Wherein, the potassium feldspar is K2O content accounts for 10% feldspar raw material;The albite is Na2O content accounts for 10%
Feldspar raw material;The mixing kaolin make a living kaolin and calcined kaolin with weight proportion for 1:The mixture of 3 compositions;It is described
Al by mass percentage in nepheline2O3Content is 25%, K2O content is 4%, Na2O content is 8%;In the medium temperature frit
SiO by mass percentage2Content is 70%, Al2O3Content is 8%;The ground-coat enamel includes following mainization by mass percentage
Learn component:25% Al2O3, 55% SiO2, 0.2% Fe2O3, 0.7% CaO, 0.4% MgO, 1.5% K2O, 8%
Na2O, 0.3% TiO2, 4% ZrO2, 4.9% burning lose.
Preparation method:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 38% is added,
In the river east sodium tripolyphosphate that the sodium carboxymethylcellulose and 0.6% that account for total composition weight 0.3% is added, ball milling mixing is uniform,
Sieving, obtains ball mill mixing, controls the screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves in 0.5~1.0% range
Interior, control moisture is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains 3 ground-coat enamel finished product of embodiment,
The screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves is controlled in 0.2~0.5% range, control moisture is
40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
Embodiment 4
A kind of big board bottom glaze of ceramics, high temperature firing temperature is 1185~1215 DEG C, includes according to the weight percentage of raw materials
Following component:
Wherein, the potassium feldspar is K2O content accounts for 12% feldspar raw material;The albite is Na2O content accounts for 8% length
Stone raw material;The mixing kaolin make a living kaolin and calcined kaolin with weight proportion for 1:The mixture of 3 compositions;The rosy clouds
Al by mass percentage in stone2O3Content is 22%, K2O content is 3%, Na2O content is 7%;It is pressed in the medium temperature frit
Mass percent meter SiO2Content is 70%, Al2O3Content is 9%;The ground-coat enamel includes following primary chemical by mass percentage
Component:28% Al2O3, 52% SiO2, 0.4% Fe2O3, 0.7% CaO, 0.2% MgO, 0.5% K2O, 4%
Na2O, 0.5% TiO2, 10% ZrO2, 4% burning lose.
Preparation method:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 32% is added,
In the river east sodium tripolyphosphate that the sodium carboxymethylcellulose and 0.75% that account for total composition weight 0.42% is added, ball milling mixing is equal
Even, sieving obtains ball mill mixing, controls the screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves in 0.5~1.0% model
In enclosing, control moisture is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains 4 ground-coat enamel finished product of embodiment,
The screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves is controlled in 0.2~0.5% range, control moisture is
40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
Embodiment 5
A kind of big board bottom glaze of ceramics, high temperature firing temperature is 1185~1215 DEG C, includes according to the weight percentage of raw materials
Following component:
Wherein, the potassium feldspar is K2O content accounts for 7~14% feldspar raw material;The albite is Na2O content accounts for 12%
Feldspar raw material;The mixing kaolin make a living kaolin and calcined kaolin with weight proportion for 1:The mixture of 3 compositions;Institute
State in nepheline Al by mass percentage2O3Content is 20%, K2O content is 8%, Na2O content is 10%;It states in medium temperature frit
SiO by mass percentage2Content is 60%, Al2O3Content is 3%;The ground-coat enamel includes following mainization by mass percentage
Learn component:30% Al2O3, 50% SiO2, 0.05% Fe2O3, 0.15% CaO, 0.2% MgO, 1.8% K2O、
4% Na2O, 0.1% TiO2, 10% ZrO2, 4% burning lose.
Preparation method:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 40% is added,
In the river east sodium tripolyphosphate that the sodium carboxymethylcellulose and 0.35% that account for total composition weight 0.45% is added, ball milling mixing is equal
Even, sieving obtains ball mill mixing, controls the screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves in 0.5~1.0% model
In enclosing, control moisture is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains 5 ground-coat enamel finished product of embodiment,
The screen over-size after its fineness is sieved for via hole diameter 0.045mm sieves is controlled in 0.2~0.5% range, control moisture is
40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
Embodiment 6:Performance detection
By ground-coat enamel finished product difference charity made from above-described embodiment 1~5 on ceramic big plate green compact, and in 1195 DEG C of high temperature
Firing, then correlated performance detection is carried out, testing result is as shown in table 1 below.
The every correlated performance detection of table 1
Above-described embodiment is the preferred embodiment of the present invention, it is all with similar technique of the invention and made by equivalence changes,
The protection category of the present invention should all be belonged to.
Claims (10)
1. a kind of big board bottom glaze of ceramics, which is characterized in that include following component according to the weight percentage of raw materials:
2. the big board bottom glaze of a kind of ceramics according to claim 1, it is characterised in that:The mixing kaolin is made a living kaolin
With the mixture of calcined kaolin.
3. the big board bottom glaze of a kind of ceramics according to claim 1, it is characterised in that:The aluminium oxide is calcined alumina.
4. the big board bottom glaze of a kind of ceramics according to claim 1, it is characterised in that:In the nepheline by mass percentage
Al2O3Content is 20~30%, K2O content is 1~8%, Na2O content is 5~10%.
5. the big board bottom glaze of a kind of ceramics according to claim 1, it is characterised in that:Quality percentage is pressed in the medium temperature frit
Than counting SiO2Content is 60~75%, Al2O3Content is 2~10%.
6. the big board bottom glaze of a kind of ceramics according to claim 1, which is characterized in that include following main by mass percentage
Want chemical constituent:
7. the big board bottom glaze of a kind of ceramics according to claim 1, it is characterised in that:The high temperature firing temperature of the ground-coat enamel is
1185~1215 DEG C.
8. a kind of preparation method of the big board bottom glaze of such as claim 1~7 any one of them ceramics, which is characterized in that including such as
Lower processing step:
1) each component is put into glaze ball mill based on parts by weight of raw materials, the water for accounting for total composition weight 30~40% is added,
The sodium carboxymethylcellulose of total composition weight 0.15~0.45% and 0.35~0.85% river east sodium tripolyphosphate are accounted in addition,
Ball milling mixing is uniform, and sieving obtains ball mill mixing;
2) by ball mill mixing obtained by step 1) as in pond it is aging for 24 hours more than, sieving removal of impurities obtains ground-coat enamel finished product.
9. a kind of preparation method of the big board bottom glaze of ceramics according to claim 8, it is characterised in that:Institute described in step 1)
The screen over-size after ball mill mixing fineness is sieved for via hole diameter 0.045mm sieves is obtained in 0.5~1.0% range, control moisture contains
Amount is 34~36%, and flow velocity is 60~80s, and proportion is 1.85~2.15g/ml.
10. a kind of preparation method of the big board bottom glaze of ceramics according to claim 8, it is characterised in that:Gained in step 2)
Ground-coat enamel finish fineness be via hole diameter 0.045mm sieves sieving after screen over-size in 0.2~0.5% range, control moisture
It is 40~52%, flow velocity is 20~30s, and proportion is 1.50~1.65g/ml.
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CN111943723A (en) * | 2020-07-30 | 2020-11-17 | 佛山欧神诺陶瓷有限公司 | Ceramic glaze with silk texture, preparation method and ceramic rock plate using ceramic glaze |
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CN112159206A (en) * | 2020-09-29 | 2021-01-01 | 姜霁洋 | Ceramic hand mold for producing nitrile rubber gloves and PVC gloves and preparation method thereof |
CN112209618A (en) * | 2020-09-29 | 2021-01-12 | 广东金牌陶瓷有限公司 | Velvet ceramic rock plate and preparation method thereof |
CN113548798A (en) * | 2021-06-30 | 2021-10-26 | 蒙娜丽莎集团股份有限公司 | Ultra-flat-bottom glaze and application thereof in ceramic tiles |
CN113548798B (en) * | 2021-06-30 | 2023-08-11 | 蒙娜丽莎集团股份有限公司 | Ultra-flat-bottom glaze and application thereof in ceramic tiles |
CN113620603A (en) * | 2021-09-07 | 2021-11-09 | 广东东唯新材料有限公司 | Metal glaze rock plate ground coat and preparation method thereof |
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Application publication date: 20180713 |