CN108271778A - Agricultural agent, the application for including the product of the agricultural agent and the agricultural agent - Google Patents

Agricultural agent, the application for including the product of the agricultural agent and the agricultural agent Download PDF

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Publication number
CN108271778A
CN108271778A CN201810115624.6A CN201810115624A CN108271778A CN 108271778 A CN108271778 A CN 108271778A CN 201810115624 A CN201810115624 A CN 201810115624A CN 108271778 A CN108271778 A CN 108271778A
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China
Prior art keywords
agricultural agent
agricultural
agent
weight
parts
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CN201810115624.6A
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Chinese (zh)
Inventor
郑全
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Jiangxi Mai Ge Wei New Materials Co Ltd
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Jiangxi Mai Ge Wei New Materials Co Ltd
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Priority to CN201810115624.6A priority Critical patent/CN108271778A/en
Publication of CN108271778A publication Critical patent/CN108271778A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture

Abstract

The present invention relates to a kind of agricultural agent, include the application of the product of the agricultural agent and the agricultural agent, agricultural agent is mixture, and each component and content are in mixture:1~99 parts by weight of dimethyl silicone polymer, 1~50 parts by weight of polyether modified silicon oil, 1~50 parts by weight of surfactant, agricultural agent of the invention can use separately as insecticide and the good herbicide/insecticide/bactericides/plant growth regulator/foliar fertilizer of weeding/desinsection/sterilization/fruit retention/effect of increasing production can be made with other material mixings.The agricultural agent and product comprising the agricultural agent of the present invention is easy to use, prepares simple, and poisoning risk and environmentally safe will not be generated to crop, there is fabulous promotional value.

Description

Agricultural agent, the application for including the product of the agricultural agent and the agricultural agent
Technical field
The invention belongs to agriculture fields, and in particular to a kind of agricultural agent, comprising the product of the agricultural agent and this is agricultural The application of auxiliary agent.
Background technology
Early in 1865, i.e. the 6th year after first oil mining in the world, not emulsified kerosene was begun to for controlling Scale insect on mandarin tree processed, in the 1920s, lubricating oil adds emulsifier to start applied to mandarin tree and deciduous fruit tree, and at For the major pharmaceutical agent in orchard winter clear garden.70~eighties of 20th century, the narrow journey spray oil that slips of carbon 21- carbon 25 have been widely used for In the control of various pests.From the 1990s, agricultural spray oil begins to use highly refined white oil to do active ingredient, So that the safe class of agricultural spray oil reaches food-grade.Currently, spray oil obtained in many countries in the world it is wide General application is mainly used for controlling the pest on the crops such as vegetables, flowers, fruit tree and cotton and evil mite.
At present China registration mineral oils pesticide, such as machine oil, diesel oil, agricultural spray (mineral) oil list preparation and its It is no less than 500 kinds with the mixture preparation of chemical pesticide.Wherein, the product containing machine oil has 103 kinds, and the product containing diesel oil has 416 kinds, Agricultural spray oil has 5 kinds.Registration crop is related to the crops such as fruit tree, vegetables, cotton and grain, and Pesticidal products include desinsection (mite) Agent, fungicide and herbicide (as auxiliary agent), controlling object include crop pest, evil mite, disease and crop smothering etc..Registered In mineral oils pesticide, machine oil and diesel oil type pesticide are mainly produced by domestic pesticide producing enterprises registration, and raw material are from oil refining Factory or gas station;Spray oil registration enterprise is generally off-shore company, processes raw material as non-recycled paraffin class base oil.Due to original Material source is different, and product specification is different, drug effect, the residual degree to the safety of crop, in agricultural product and to environment Influence etc. have larger difference.
By being mixed with surfactant appropriate, can be made with automatic emulsifying performance agricultural oozes traditional mineral oil Saturating agent or insecticide, the effect for enhancing pesticide spray remove aphid or red spider etc. alternatively, it is also possible to directly use to kill Agricultural pests.But conventional mineral oil is usually by the molecular composition of 3 types, i.e. isoparaffin, cycloalkane and aromatic hydrocarbon group At.Aromatic hydrocarbon is unsaturated hydrocarbons, is the root for generating poisoning, certain polycyclic aromatic hydrocarbons (PAH)s and unsaturated hydrocarbons not only have carcinogenic work to people With also serious pollution environment.Each state is all limiting such product in application agriculturally, since the use of the product is to crops There are poisoning risks, therefore are only capable of applying on the preferable crop of the tolerances such as citrus, are of limited application.
Therefore, study it is a kind of it is environmentally protective, using it is easy, prepare simple and agricultural agent good applicability and have very Important meaning.
Invention content
The purpose of the invention is to overcome the problems, such as prior art mineral oil in fluid to crop phytotoxicity and environmental pollution, Provide it is a kind of it is environmentally protective, using it is easy, prepare simple and good applicability agricultural agent, and be directly applied to agriculture Industry field or with other product fit applications in agriculture field.
In order to achieve the above object, the technical solution adopted by the present invention is:
A kind of agricultural agent is mixture, and each component and its content are as follows:
1~99 parts by weight of dimethyl silicone polymer;
1~50 parts by weight of polyether modified silicon oil;
1~50 parts by weight of surfactant;
The molecular formula of the dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, in formula, R1 With R2It is each independently selected from-H ,-OR3、-NH2、-R4NR5R6、-CH2CH2CH2OH and monovalent hydrocarbon, R3、R5And R6Respectively- H、-CH2CH2CH2OH or monovalent hydrocarbon, R4Value range for bivalent hydrocarbon radical, m is 1~1000;The knot of dimethyl silicone polymer Structure formula is as follows:
The molecular formula of the polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, formula In, the value range that the value range of x is 0~100, y is 0~100, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, R8 For-H ,-CH2CH2CH2The value range of OH or monovalent hydrocarbon, a or b are 0~100.
The agricultural agent of the present invention can mix spraying by bucket together with pesticide, reduce spray liquor surface tension, improve spraying Utilization rate increases Pesticide Infiltration ability, improves the final preventive effect of pesticide;The agricultural agent of the present invention is without in conventional mineral oil Aromatic hydrocarbon and carcinogen, no poisoning is pollution-free, is environmentally friendly product.
As preferred technical solution:
A kind of agricultural agent as described above, the surfactant are alkyl polyoxyethylene ether class surfactant, tool Body is AEO-3, AEO-4, AEO-5, AEO-7, NP-3, NP-4, NP-5, OP-3, OP-4, OP-5, DOW Chemical Tergitol 15-s-3, DOW Chemical Tergitol 15-s-5, DOW Chemical Tergitol 15-s-7, sand Suo Huagong Mutiso 13/30, Husky Suo Huagong Mutiso 13/50 or sand Suo Huagong Mutiso 13/60;The surfactant of the present invention is including but not limited to above-mentioned Surfactant only enumerates some preferred types here.
All monovalent hydrocarbons are each independently selected from-CH3,-CH=CH2With-CH2CH2CH3
The bivalent hydrocarbon radical is-CH2-;
The surface tension of the agricultural agent is 20~30mN/m, conventional mineral oil and the mixed surface of surfactant Tension is generally 30~50mN/m, higher than the surface tension of the agricultural agent of the present invention, leads to Pesticide Infiltration energy force difference, pesticide Final preventive effect effect is general.
The present invention also provides a kind of herbicides including agricultural agent as described above, phonetic by the agricultural agent and cigarette The grand suspending agent of sulphur mixes, a concentration of 40 grams per liter of nicosulfuron suspending agent before mixing, agricultural agent and cigarette phonetic sulphur when mixing The volume ratio of grand suspending agent is 1:2;
Spraying treatment is carried out to the cauline leaf of milpa monocotyledon weed after herbicide is mixed with water and measures strain after last medicine Preventive effect is 88.6~93.5%, and fresh weight preventive effect is 95.5~99.3% after last medicine, wherein monocotyledon weed is in 3~5 leaves Phase, corn were in for 5~6 leaf phases, and water consumption is 1 liter/mu, and herbicide dosage is 90 milliliters/mu.
The present invention also provides a kind of fungicide including agricultural agent as described above, by the agricultural agent with first just It is mixed up to Priori-Xtra 280SC, the volume ratio of agricultural agent and Syngenta Priori-Xtra 280SC is when mixing 2:1;
It is 53.6 to carry out bottom preventive effect after spraying treatment measures last medicine to the cauline leaf of soybean after fungicide is mixed with water ~58.5%, top preventive effect is 89.8~95.1% after last medicine, wherein soybean be in 1 monthly age, and water spray is 15 liters/mu, Fungicide dosage is 45 milliliters/acre.
The present invention also provides a kind of insecticides including agricultural agent as described above, by the agricultural agent and spiral shell mite Ester mixes, a concentration of 240 grams per liter of Envidor before mixing, and the volume ratio of agricultural agent and Envidor is 1 when mixing: 16.7;
After insecticide is mixed with water to the cauline leaf of sugar orange carry out spraying treatment measure 3 days preventive effects after medicine be 95.1~ 98.8%, 15 days preventive effects are 96.4~99.8% after medicine, and 30 days preventive effects are 97.6~99.9% after medicine, wherein water spray 100 Liter/mu, Envidor dosage are 20 milliliters/mu.
The present invention also provides a kind of plant growth regulator including agricultural agent as described above, agricultural helped by described Agent is mixed with gibberellin 920, and the volume ratio of agricultural agent and gibberellin 920 is 300 when mixing:1;
Sugar orange is thanked after plant growth regulator is mixed with water, 90% cauline leaf progress spraying treatment is spent to measure opposite guarantor Fruit rate increases to 52.2~57.3%, wherein water spray is 100 liters/mu, and plant growth regulator dosage is 1 milliliter/mu.
The present invention also provides a kind of foliar fertilizers including agricultural agent as described above, by the agricultural agent and seaweed Fertilizer mixes, and the volume ratio of agricultural agent and alga fertilizer is 3.3 when mixing:1;
After foliar fertilizer is mixed with water to grape stem and leaf carry out spraying treatment measure for 6 times grape yield increasing be 22.5~ 26.9%, wherein water spray is 100 liters/mu, and foliar fertilizer dosage is 1000 milliliters/mu.
The present invention also provides a kind of application of agricultural agent as described above in control of insect, by the agricultural agent It is 93.6~99.9% to carry out 3 days preventive effects after spraying treatment measures medicine to sugar orange cauline leaf after being mixed with water, 30 days preventive effects after medicine It is 96.9~100%, wherein water spray is 100 liters/mu, and agricultural agent dosage is 330 milliliters/mu, 500 milliliters/mu or 1000 Milliliter/mu.To Crop securify when after the agricultural agent dilution of the present invention separately as insecticide, can be widely applied to fruit, The sensitive crops such as flowers effectively prevent the pests such as aphid and the red spider on sensitive crop, play the work of tradition spray mineral oil With, but will not crops be generated with poisoning and pollution is generated to environment.
Advantageous effect:
(1) a kind of agricultural agent of the invention, it is environmentally protective, it is easy to use, it prepares simply, there is fabulous promotional value.
(2) a kind of herbicide/insecticide/bactericides/plant growth regulator/blade face including agricultural agent of the invention Fertilizer, weeding/desinsection/sterilization/fruit retention/effect of increasing production is good, will not generate poisoning risk and environmentally safe to crop.
(3) application of a kind of agricultural agent of the invention in control of insect, can effectively prevent sensitive crop in the application On aphid and the pests such as red spider, play the role of tradition spray mineral oil, but will not crops be generated with poisoning and right Environment generates pollution.
Specific implementation mode
The invention will be further elucidated with reference to specific embodiments.It should be understood that these embodiments are merely to illustrate this hair It is bright rather than limit the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, art technology Personnel can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited Fixed range.
Embodiment 1
A kind of agricultural agent is mixture, and each component and content are as follows:
80 parts by weight of dimethyl silicone polymer;
1 parts by weight of polyether modified silicon oil;
50 parts by weight of AEO-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH3, R2For-OCH3, m 20;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein R7 For-CH2CH2CH2(OC2H4)aOR8, x 2, y 3, a 8, R8For-CH3
The surface tension for the agricultural agent prepared is 20mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 2
A kind of agricultural agent is mixture, and each component and content are as follows:
99 parts by weight of dimethyl silicone polymer;
1 parts by weight of polyether modified silicon oil;
1 parts by weight of AEO-4;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-H, R2For-CH3, m 1;
The molecular formula of polyether modified silicon oil is (CH3)3SiOSi(CH3)3
The surface tension for the agricultural agent prepared is 20.5mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 3
A kind of agricultural agent is mixture, and each component and content are as follows:
5 parts by weight of dimethyl silicone polymer;
48 parts by weight of polyether modified silicon oil;
2 parts by weight of AEO-5;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OH, R2For-CH=CH2, m 50;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 10, y 5, R7For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 23mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 4
A kind of agricultural agent is mixture, and each component and content are as follows:
10 parts by weight of dimethyl silicone polymer;
46 parts by weight of polyether modified silicon oil;
4 parts by weight of AEO-7;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OCH2CH2CH2OH, R2For-CH2CH2CH3, m 100;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)R7]yOSi(CH3)3, wherein y is 100, R7For- CH2CH2CH2(OC3H6)bOR8, b 50, R8For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 20mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 5
A kind of agricultural agent is mixture, and each component and content are as follows:
15 parts by weight of dimethyl silicone polymer;
45 parts by weight of polyether modified silicon oil;
6 parts by weight of NP-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OCH3, R2For-CH2CH2CH2OH, m 150;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 20, y 30, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 100, b 100, R8For-CH3
The surface tension for the agricultural agent prepared is 20.8mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 6
A kind of agricultural agent is mixture, and each component and content are as follows:
21 parts by weight of dimethyl silicone polymer;
43 parts by weight of polyether modified silicon oil;
7 parts by weight of NP-4;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OC=CH2, R2For-R4NR5R6, m 200, R4For-CH2, R5For-CH3, R6For-CH2CH2CH2OH;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 55, y 15, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 10, b 50, R8For-CH=CH2
The surface tension for the agricultural agent prepared is 23.1mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 7
A kind of agricultural agent is mixture, and each component and content are as follows:
25 parts by weight of dimethyl silicone polymer;
41 parts by weight of polyether modified silicon oil;
10 parts by weight of NP-5;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OCH2CH2CH3, R2For-R4NR5R6, m 300, R4For-CH2, R5For-CH=CH2, R6For-CH2CH2CH2OH;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]xOSi(CH3)3, wherein x is 100;
The surface tension for the agricultural agent prepared is 30mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 8
A kind of agricultural agent is mixture, and each component and content are as follows:
32 parts by weight of dimethyl silicone polymer;
50 parts by weight of polyether modified silicon oil;
12 parts by weight of OP-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-NH2, R2For-R4NR5R6, m 400, R4For-CH2, R5For-CH2CH2CH3, R6For-CH2CH2CH2OH;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)R7]yOSi(CH3)3, wherein y is 50, R7For- CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 100, b 60, R8For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 21.1mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 9
A kind of agricultural agent is mixture, and each component and content are as follows:
38 parts by weight of dimethyl silicone polymer;
45 parts by weight of polyether modified silicon oil;
15 parts by weight of OP-4;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-R4NR5R6, R4For-CH2, R5For-H, R6For-CH3, m 500;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 30, y 10, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 100, b 60, R8For-CH2CH2CH3
The surface tension for the agricultural agent prepared is 22mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 10
A kind of agricultural agent is mixture, and each component and content are as follows:
43 parts by weight of dimethyl silicone polymer;
42 parts by weight of polyether modified silicon oil;
17 parts by weight of OP-5;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-R4NR5R6, m 600, R4For-CH2, R5For-CH2CH2CH2OH, R6For-H;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 42, y 96, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 15, b 88, R8For-H;
The surface tension for the agricultural agent prepared is 24mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 11
A kind of agricultural agent is mixture, and each component and content are as follows:
50 parts by weight of dimethyl silicone polymer;
37 parts by weight of polyether modified silicon oil;
19 parts by weight of DOW Chemical Tergitol 15-s-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-R4NR5R6, m 700, R4For-CH2, R5For-CH3, R6For-CH2CH2CH3
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 50, y 80, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 100, b 10, R8For-CH3
The surface tension for the agricultural agent prepared is 21.7mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 12
A kind of agricultural agent is mixture, and each component and content are as follows:
55 parts by weight of dimethyl silicone polymer;
36 parts by weight of polyether modified silicon oil;
21 parts by weight of DOW Chemical Tergitol 15-s-5;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-NH2, m 800, R4For-CH2, R5For-CH=CH2, R6For-H;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)R7]yOSi(CH3)3, wherein y is 66, R7For- CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 10, b 50, R8 are-CH=CH2
The surface tension for the agricultural agent prepared is 22.6mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 13
A kind of agricultural agent is mixture, and each component and content are as follows:
61 parts by weight of dimethyl silicone polymer;
33 parts by weight of polyether modified silicon oil;
23 parts by weight of DOW Chemical Tergitol 15-s-7;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-OH, m 900, R4For-CH2, R5For-CH2CH2CH3, R6For-CH2CH2CH2OH;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 20, y 75, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 20, b 60, R8For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 23mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 14
A kind of agricultural agent is mixture, and each component and content are as follows:
65 parts by weight of dimethyl silicone polymer;
36 parts by weight of polyether modified silicon oil;
Husky 13,/30 24 parts by weight of Suo Huagong Mutiso;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-OCH2CH2CH2OH, m 1000, R4For-CH2, R5For-H, R6For-H;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 80, y 10, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 60, b 20, R8For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 23mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 15
A kind of agricultural agent is mixture, and each component and content are as follows:
70 parts by weight of dimethyl silicone polymer;
35 parts by weight of polyether modified silicon oil;
Husky 13,/50 28 parts by weight of Suo Huagong Mutiso;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-R4NR5R6, R2For-O, m 150, R4For-CH2, R5For-CH2CH2CH2OH, R6For-CH2CH2CH2OH;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 40, y 75, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 89, b 91, R8For-CH3
The surface tension for the agricultural agent prepared is 24mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 16
A kind of agricultural agent is mixture, and each component and content are as follows:
76 parts by weight of dimethyl silicone polymer;
33 parts by weight of polyether modified silicon oil;
Husky 13,/60 29 parts by weight of Suo Huagong Mutiso;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH2CH2CH2OH, R2For-OC=CH2, m 350;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 25, y 64, R7For-CH2CH2CH2(OC3H6)bOR8, b 80, R8For-CH=CH2
The surface tension for the agricultural agent prepared is 22mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 17
A kind of agricultural agent is mixture, and each component and content are as follows:
81 parts by weight of dimethyl silicone polymer;
31 parts by weight of polyether modified silicon oil;
30 parts by weight of NP-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH3, R2For-OCH2CH2CH3, m 150;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 68, y 64, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 56, b 23, R8For-CH2CH2CH2OH;
The surface tension for the agricultural agent prepared is 23mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 18
A kind of agricultural agent is mixture, and each component and content are as follows:
86 parts by weight of dimethyl silicone polymer;
33 parts by weight of polyether modified silicon oil;
Husky 13,/50 32 parts by weight of Suo Huagong Mutiso;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH=CH2, R2For-H, m 450;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)R7]yOSi(CH3)3, wherein y is 58, R7For- CH2CH2CH2(OC2H4)aOR8, a 100, R8For-CH=CH2
The surface tension for the agricultural agent prepared is 30mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 19
A kind of agricultural agent is mixture, and each component and content are as follows:
90 parts by weight of dimethyl silicone polymer;
29 parts by weight of polyether modified silicon oil;
34 parts by weight of AEO-4;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH2CH2CH3, R2For-CH2CH2CH2OH, m 150;
The molecular formula of polyether modified silicon oil is (CH3)3SiOSi(CH3)3
The surface tension for the agricultural agent prepared is 20mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 20
A kind of agricultural agent is mixture, and each component and content are as follows:
93 parts by weight of dimethyl silicone polymer;
25 parts by weight of polyether modified silicon oil;
40 parts by weight of OP-3;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-NH2, R2For-NH2, m 550;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 80, y 16, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 94, b 51, R8For-H;
The surface tension for the agricultural agent prepared is 25.6mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 21
A kind of agricultural agent is mixture, and each component and content are as follows:
95 parts by weight of dimethyl silicone polymer;
20 parts by weight of polyether modified silicon oil;
42 parts by weight of DOW Chemical Tergitol 15-s-7;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-CH=CH2, R2For-CH=CH2, m 650;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 40, y 75, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 35, b 38, R8For-CH2CH2CH3
The surface tension for the agricultural agent prepared is 22mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 22
A kind of agricultural agent is mixture, and each component and content are as follows:
97 parts by weight of dimethyl silicone polymer;
16 parts by weight of polyether modified silicon oil;
Husky 13,/30 45 parts by weight of Suo Huagong Mutiso;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OC=CH2, R2For-OC=CH2, m 750;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 50, y 90, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, a 100, b 100, R8For-CH3
The surface tension for the agricultural agent prepared is 28.6mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 23
A kind of agricultural agent is mixture, and each component and content are as follows:
98 parts by weight of dimethyl silicone polymer;
11 parts by weight of polyether modified silicon oil;
48 parts by weight of AEO-7;
Wherein, the molecular formula of dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, wherein R1 For-OH, R2For-OH, m 850;
The molecular formula of polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, wherein x is 20, y 30, R7For-CH2CH2CH2(OC2H4)aOR8, a 60, R8For-H;
The surface tension for the agricultural agent prepared is 29.3mN/m, and penetrating power is strong, and final preventive effect effect is good.
Embodiment 24
A kind of includes the herbicide of the agricultural agent prepared by embodiment 1, by agricultural agent and nicosulfuron suspending agent By 1:2 volume ratio mixes, a concentration of 40 grams per liter of nicosulfuron suspending agent before mixing.
Spraying treatment is carried out to the cauline leaf of milpa monocotyledon weed after herbicide is mixed with water, measures strain after last medicine Preventive effect is 91.5%, and fresh weight preventive effect is 97.2% after last medicine, wherein monocotyledon weed was in for 3 leaf phases, and corn was in for 6 leaf phases, Water consumption is 1 liter/mu, and herbicide dosage is 90 milliliters/mu.
Comparative example 1
Substantially with embodiment 24, the difference is that the agricultural agent being added is emulsified mineral oil (trade name EnSpray 99) strain preventive effect is 73.5% after finally measuring last medicine, and fresh weight preventive effect is 77.1% after last medicine, by embodiment 24 and comparative example 1 comparison is as can be seen that the agricultural agent of the present invention is more advantageous to relative to existing agricultural agent and improves nicosulfuron suspending agent Herbicidal effect.
Embodiment 25
A kind of includes the herbicide of the agricultural agent prepared by embodiment 10, by agricultural agent and nicosulfuron suspending agent By 1:2 volume ratio mixes, a concentration of 40 grams per liter of nicosulfuron suspending agent before mixing.
Spraying treatment is carried out to the cauline leaf of milpa monocotyledon weed after herbicide is mixed with water, measures strain after last medicine Preventive effect is 88.6%, and fresh weight preventive effect is 99.3% after last medicine, wherein monocotyledon weed was in for 5 leaf phases, and corn was in for 5 leaf phases, Water consumption is 1 liter/mu, and herbicide dosage is 90 milliliters/mu.
Embodiment 26
A kind of includes the herbicide of the agricultural agent prepared by embodiment 20, by agricultural agent and nicosulfuron suspending agent By 1:2 volume ratio mixes, a concentration of 40 grams per liter of nicosulfuron suspending agent before mixing.
Spraying treatment is carried out to the cauline leaf of milpa monocotyledon weed after herbicide is mixed with water, measures strain after last medicine Preventive effect is 93.5%, and fresh weight preventive effect is 95.5% after last medicine, wherein monocotyledon weed was in for 4 leaf phases, and corn was in for 5 leaf phases, Water consumption is 1 liter/mu, and herbicide dosage is 90 milliliters/mu.
Embodiment 27
A kind of includes the fungicide of the agricultural agent prepared by embodiment 5, by agricultural agent and Syngenta Priori- Xtra 280SC press 2:1 volume ratio mixes.
Carrying out bottom preventive effect after spraying treatment measures last medicine to the cauline leaf of soybean after fungicide is mixed with water is 55.6%, top preventive effect is 92.2% after last medicine, wherein soybean be in 1 monthly age, and water spray is 15 liters/mu, fungicide use Amount is 45 milliliters/acre.
Embodiment 28
A kind of includes the fungicide of the agricultural agent prepared by embodiment 7, by agricultural agent and Syngenta Priori- Xtra 280SC press 2:1 volume ratio mixes.
Carrying out bottom preventive effect after spraying treatment measures last medicine to the cauline leaf of soybean after fungicide is mixed with water is 53.6%, top preventive effect is 95.1% after last medicine, wherein soybean be in 1 monthly age, and water spray is 15 liters/mu, fungicide use Amount is 45 milliliters/acre.
Embodiment 29
A kind of includes the fungicide of the agricultural agent prepared by embodiment 8, by agricultural agent and Syngenta Priori- Xtra 280SC press 2:1 volume ratio mixes.
Carrying out bottom preventive effect after spraying treatment measures last medicine to the cauline leaf of soybean after fungicide is mixed with water is 58.5%, top preventive effect is 89.8% after last medicine, wherein soybean be in 1 monthly age, and water spray is 15 liters/mu, fungicide use Amount is 45 milliliters/acre.
Comparative example 2
Substantially with embodiment 27~29, the difference is that the agricultural agent being added is emulsified mineral oil (trade name EnSpray 99), strain preventive effect is 25.3% after finally measuring last medicine, and fresh weight preventive effect is 54.5% after last medicine, by embodiment 27~29 agricultural agents that can be seen that the present invention with the comparison of comparative example 2 are more advantageous to raising relative to existing agricultural agent The bactericidal effect of Syngenta Priori-Xtra 280SC.
Embodiment 30
A kind of includes the insecticide of the agricultural agent prepared by embodiment 12, and 1 is pressed by agricultural agent and Envidor:16.7 Volume ratio mix, mix before Envidor a concentration of 240 grams per liter.
It is 97.8% to carry out 3 days preventive effects after spraying treatment measures medicine to the cauline leaf of sugar orange after insecticide is mixed with water, 15 days preventive effects are 98.8% after medicine, and 30 days preventive effects are 99.5% after medicine, wherein water spray is 100 liters/mu, and Envidor dosage is 20 milliliters/mu.
Embodiment 31
A kind of includes the insecticide of the agricultural agent prepared by embodiment 10, and 1 is pressed by agricultural agent and Envidor:16.7 Volume ratio mix, mix before Envidor a concentration of 240 grams per liter.
It is 95.1% to carry out 3 days preventive effects after spraying treatment measures medicine to the cauline leaf of sugar orange after insecticide is mixed with water, 15 days preventive effects are 99.8% after medicine, and 30 days preventive effects are 97.6% after medicine, wherein water spray is 100 liters/mu, and Envidor dosage is 20 milliliters/mu.
Embodiment 32
A kind of includes the insecticide of the agricultural agent prepared by embodiment 21, and 1 is pressed by agricultural agent and Envidor:16.7 Volume ratio mix, mix before Envidor a concentration of 240 grams per liter.
It is 98.8% to carry out 3 days preventive effects after spraying treatment measures medicine to the cauline leaf of sugar orange after insecticide is mixed with water, 15 days preventive effects are 96.4% after medicine, and 30 days preventive effects are 99.9% after medicine, wherein water spray is 100 liters/mu, and Envidor dosage is 20 milliliters/mu.
Comparative example 3
Substantially with embodiment 30~32, the difference is that the agricultural agent being added is emulsified mineral oil (trade name EnSpray 99), 3 days preventive effects are 52.3% after finally measuring medicine, and 15 days preventive effects are 78.6% after medicine, and 30 days preventive effects are after medicine 90.3%, by the comparison of embodiment 30~32 and comparative example 3 as can be seen that the agricultural agent of the present invention agricultural is helped relative to existing Agent is more advantageous to the insecticidal effect for improving Envidor.
Embodiment 33
A kind of includes the plant growth regulator of the agricultural agent prepared by embodiment 12, by agricultural agent and gibberellin 920 press 300:1 volume ratio mixes.
Sugar orange is thanked after plant growth regulator is mixed with water, 90% cauline leaf progress spraying treatment is spent to measure opposite guarantor Fruit rate increases to 54.3%, wherein water spray is 100 liters/mu, and plant growth regulator dosage is 1 milliliter/mu.
Embodiment 34
A kind of includes the plant growth regulator of the agricultural agent prepared by embodiment 17, by agricultural agent and gibberellin 920 press 300:1 volume ratio mixes.
Sugar orange is thanked after plant growth regulator is mixed with water, 90% cauline leaf progress spraying treatment is spent to measure opposite guarantor Fruit rate increases to 52.2%, wherein water spray is 100 liters/mu, and plant growth regulator dosage is 1 milliliter/mu.
Embodiment 35
A kind of includes the plant growth regulator of the agricultural agent prepared by embodiment 19, by agricultural agent and gibberellin 920 press 300:1 volume ratio mixes.
Sugar orange is thanked after plant growth regulator is mixed with water, 90% cauline leaf progress spraying treatment is spent to measure opposite guarantor Fruit rate increases to 57.3%, wherein water spray is 100 liters/mu, and plant growth regulator dosage is 1 milliliter/mu.
Comparative example 4
Substantially with embodiment 33~35, the difference is that the agricultural agent being added is emulsified mineral oil (trade name EnSpray 99), it finally measures opposite fruit retention rate and increases to 40.4%, embodiment 33~35 and the comparison of comparative example 4 can be seen that The agricultural agent of the present invention is more advantageous to the plant growth regulating effect for improving gibberellin 920 relative to existing agricultural agent.
Embodiment 36
A kind of includes the foliar fertilizer of the agricultural agent prepared by embodiment 1, and 3.3 are pressed by agricultural agent and alga fertilizer:1 Volume ratio mixes.
Grape stem and leaf is carried out spraying treatment to measure grape yield increasing being 24% after plant growth regulator is mixed with water, In, water spray is 100 liters/mu, and foliar fertilizer dosage is 1000 milliliters/mu.
Embodiment 37
A kind of includes the foliar fertilizer of the agricultural agent prepared by embodiment 2, and 3.3 are pressed by agricultural agent and alga fertilizer:1 Volume ratio mixes.
Grape stem and leaf is carried out spraying treatment to measure grape yield increasing being 22.5% after plant growth regulator is mixed with water, Wherein, water spray is 100 liters/mu, and foliar fertilizer dosage is 1000 milliliters/mu.
Embodiment 38
A kind of includes the foliar fertilizer of the agricultural agent prepared by embodiment 3, and 3.3 are pressed by agricultural agent and alga fertilizer:1 Volume ratio mixes.
Grape stem and leaf is carried out spraying treatment to measure grape yield increasing being 26.9% after plant growth regulator is mixed with water, Wherein, water spray is 100 liters/mu, and foliar fertilizer dosage is 1000 milliliters/mu.
Comparative example 5
Substantially with embodiment 36~38, the difference is that the agricultural agent being added is emulsified mineral oil (trade name EnSpray 99), it finally measures opposite fruit retention rate and increases to 18%, by embodiment 36~38 and the comparison of comparative example 5 as can be seen that originally The agricultural agent of invention is more advantageous to the effect of increasing production for improving alga fertilizer relative to existing agricultural agent.
Embodiment 39
It includes answering in the pests such as aphid and red spider that a kind of agricultural agent by prepared by embodiment 1, which is used individually in prevention, With it is 93.6% to carry out 3 days preventive effects after spraying treatment measures medicine to sugar orange cauline leaf after mixing agricultural agent with water, 30 after medicine Its preventive effect is 96.9%, wherein water spray is 100 liters/mu, and agricultural agent dosage is 330 milliliters/mu, and preventive effect effect is good and right Any damage is not caused in sugar orange blade face.
Embodiment 40
It includes answering in the pests such as aphid and red spider that a kind of agricultural agent by prepared by embodiment 5, which is used individually in prevention, With it is 97.8% to carry out 3 days preventive effects after spraying treatment measures medicine to sugar orange cauline leaf after mixing agricultural agent with water, 30 after medicine Its preventive effect is 99.9%, wherein water spray is 100 liters/mu, and agricultural agent dosage is 500 milliliters/mu, and preventive effect effect is good and right Any damage is not caused in sugar orange blade face.
Embodiment 41
It includes in the pests such as aphid and red spider that a kind of agricultural agent by prepared by embodiment 22, which is used individually in prevention, Using it is 99.9% to carry out 3 days preventive effects after spraying treatment measures medicine to sugar orange cauline leaf after mixing agricultural agent with water, after medicine 30 days preventive effects are 100%, wherein water spray is 100 liters/mu, and agricultural agent dosage is 1000 milliliters/mu.Preventive effect effect it is good and Any damage is not caused to sugar orange blade face.
Comparative example 6
Substantially with embodiment 40, the difference is that the agricultural agent being added is green grain husk, 3 days preventive effects are after finally measuring medicine 93.5%, 30 days preventive effects are 98.8% after medicine, by embodiment 40 and the comparison of comparative example 6 as can be seen that the agricultural agent of the present invention It is more advantageous to raising pest controling effect relative to existing agricultural agent.

Claims (8)

1. a kind of agricultural agent, it is characterized in that:For mixture, each component and its content are as follows:
1~99 parts by weight of dimethyl silicone polymer;
1~50 parts by weight of polyether modified silicon oil;
1~50 parts by weight of surfactant;
The molecular formula of the dimethyl silicone polymer is R1-(CH3)2SiO[(CH3)2SiO]m(CH3)2Si-R2, in formula, R1With R2Respectively From independently selected from-H ,-OR3、-NH2、-R4NR5R6、-CH2CH2CH2OH and monovalent hydrocarbon, R3、R5And R6Respectively-H ,- CH2CH2CH2OH or monovalent hydrocarbon, R4Value range for bivalent hydrocarbon radical, m is 1~1000;
The molecular formula of the polyether modified silicon oil is (CH3)3Si[OSi(CH3)2]x[OSi(CH3)R7]yOSi(CH3)3, in formula, x's The value range that value range is 0~100, y is 0~100, R7For-CH2CH2CH2(OC2H4)a(OC3H6)bOR8, R8For-H ,- CH2CH2CH2The value range of OH or monovalent hydrocarbon, a or b are 0~100.
2. a kind of agricultural agent according to claim 1, which is characterized in that the surfactant is alkyl polyoxyethylene Ether surfactant, specially AEO-3, AEO-4, AEO-5, AEO-7, NP-3, NP-4, NP-5, O-P3, OP-4, OP-5, pottery Family name's chemistry Tergitol 15-s-3, DOW Chemical Tergitol 15-s-5, DOW Chemical Tergitol 15-s-7, Sha Suohua Work Mutiso 13/30, sand Suo Huagong Mutiso 13/50 or sand Suo Huagong Mutiso 13/60;
All monovalent hydrocarbons are each independently selected from-CH3,-CH=CH2With-CH2CH2CH3
The bivalent hydrocarbon radical is-CH2-;
The surface tension of the agricultural agent is 20~30mN/m.
3. include the herbicide of agricultural agent as claimed in claim 1 or 2, it is characterized in that:It is phonetic by the agricultural agent and cigarette The grand suspending agent of sulphur mixes, a concentration of 40 grams per liter of nicosulfuron suspending agent before mixing, agricultural agent and cigarette phonetic sulphur when mixing The volume ratio of grand suspending agent is 1:2;
Spraying treatment is carried out to the cauline leaf of milpa monocotyledon weed after herbicide is mixed with water and measures strain preventive effect after last medicine It is 88.6~93.5%, fresh weight preventive effect is 95.5~99.3% after last medicine, wherein monocotyledon weed was in for 3~5 leaf phases, beautiful Rice was in for 5~6 leaf phases, and water consumption is 1 liter/mu, and herbicide dosage is 90 milliliters/mu.
4. include the fungicide of agricultural agent as claimed in claim 1 or 2, it is characterized in that:Just by the agricultural agent and elder generation It is mixed up to 280 SC of Priori-Xtra, the volume ratio of agricultural agent and 280 SC of Syngenta Priori-Xtra when mixing It is 2:1;
After fungicide is mixed with water to the cauline leaf of soybean carry out spraying treatment measure bottom preventive effect after last medicine be 53.6~ 58.5%, top preventive effect is 89.8~95.1% after last medicine, wherein soybean be in 1 monthly age, and water spray is 15 liters/mu, is killed Microbial inoculum dosage is 45 milliliters/acre.
5. include the insecticide of agricultural agent as claimed in claim 1 or 2, it is characterized in that:By the agricultural agent and spiral shell mite Ester mixes, a concentration of 240 grams per liter of Envidor before mixing, and the volume ratio of agricultural agent and Envidor is 1 when mixing: 16.7;
After insecticide is mixed with water to the cauline leaf of sugar orange carry out spraying treatment measure 3 days preventive effects after medicine be 95.1~ 98.8%, 15 days preventive effects are 96.4~99.8% after medicine, and 30 days preventive effects are 97.6~99.9% after medicine, wherein water spray 100 Liter/mu, Envidor dosage are 20 milliliters/mu.
6. include the plant growth regulator of agricultural agent as claimed in claim 1 or 2, it is characterized in that:It agricultural is helped by described Agent is mixed with gibberellin 920, and the volume ratio of agricultural agent and gibberellin 920 is 300 when mixing:1;
Sugar orange is thanked after plant growth regulator is mixed with water, 90% cauline leaf progress spraying treatment is spent to measure opposite fruit retention rate Increase to 52.2~57.3%, wherein water spray is 100 liters/mu, and plant growth regulator dosage is 1 milliliter/mu.
7. include the foliar fertilizer of agricultural agent as claimed in claim 1 or 2, it is characterized in that:By the agricultural agent and seaweed Fertilizer mixes, and the volume ratio of agricultural agent and alga fertilizer is 3.3 when mixing:1;
Grape stem and leaf is carried out spraying treatment to measure grape yield increasing for 6 times being 22.5~26.9% after foliar fertilizer is mixed with water, In, water spray is 100 liters/mu, and foliar fertilizer dosage is 1000 milliliters/mu.
8. application of the agricultural agent as claimed in claim 1 or 2 in control of insect, it is characterized in that:By the agricultural agent It is 93.6~99.9% to carry out 3 days preventive effects after spraying treatment measures medicine to sugar orange cauline leaf after being mixed with water, 30 days preventive effects after medicine It is 96.9~100%, wherein water spray is 100 liters/mu, and agricultural agent dosage is 330 milliliters/mu, 500 milliliters/mu or 1000 Milliliter/mu.
CN201810115624.6A 2018-02-06 2018-02-06 Agricultural agent, the application for including the product of the agricultural agent and the agricultural agent Pending CN108271778A (en)

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CN201810115624.6A CN108271778A (en) 2018-02-06 2018-02-06 Agricultural agent, the application for including the product of the agricultural agent and the agricultural agent

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