CN108244770A - A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof - Google Patents
A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof Download PDFInfo
- Publication number
- CN108244770A CN108244770A CN201711281457.4A CN201711281457A CN108244770A CN 108244770 A CN108244770 A CN 108244770A CN 201711281457 A CN201711281457 A CN 201711281457A CN 108244770 A CN108244770 A CN 108244770A
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- China
- Prior art keywords
- parts
- resin
- button
- agent
- resistant
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B1/00—Buttons
- A44B1/02—Buttons characterised by their material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of Environment-friendlywear-resistant wear-resistant resin buttons, are made of the raw material of following parts by weight：44 52 parts of unsaturated polyester resin, 38 43 parts of Lauxite, 7 12 parts of photosensitive resin, adjacent 15 26 parts of benzene-type resin, 17 22 parts of metaphenylene resin, 8 10 parts of mill base, 9 13 parts of mica powder, 36 parts of accelerating agent, 58 parts of photosensitizer, 79 parts of antifoaming agent, 47 parts of levelling agent, 69 parts of curing agent.The present invention overcomes the drawbacks of prior art, and preparation method is simple, is added to adjacent benzene-type resin as primary raw material in the process of preparation, reduces the manufacture cost of button, and manufactured button is solid non-breakable, enhance the wear-resisting property of button；The present invention is recycled leftover pieces, effectively reduces the discharge of waste in resin button production process, decreases the dosage of resin, environmentally friendly degree higher.
Description
Technical field
The present invention relates to button production technical fields, and in particular to a kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof.
Background technology
Classify from material, button can be divided mainly into natural material button, resin button, metal button；Wherein natural material
Material button is subdivided into shell button, timber button, coconut husk button, fruit button etc.；Resin button can be subdivided into pearly-lustre knob again
Button, real color button, Manhattan button, rod flower button etc.；Metal button can then be subdivided into copper button, copper clad aluminum button, alloy knob
Button etc..
At present, resin button has that pattern is various, bright in colour, simulation quality is strong, the good, good physical performance of chemical-resistance etc.
Feature, and resin button handling ease, speed of production is fast, cheap, just because of these features, achieved resin button into
Dominance for present world's button industry.
Wherein unsaturated polyester resin button is classified from technique, can be divided into sheet material button and rod material button, wherein sheet material
Up to more than 70%, and in button industry, the technique for making sheet material button is the market share that button accounts for：Deployed resin falls
To after piece knob machine, sheet material is obtained after centrifugation, gel, sheet material is then washed into knob embryo by rushing embryo machine, knob embryo is using post-processing
Just obtain button.When rushing embryo, the connection position between knob embryo and knob embryo can form leftover pieces, and in button industry, unsaturation is poly-
The material that ester production of resins button has about 25-30% becomes this leftover pieces, then can generate about 5- again in process
10% waster, thereby results in the waste of resource, while these waste materials are more difficult to degrade in natural environment, meeting during discharge
Cause environmental pollution.
Invention content
The present invention is intended to provide a kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof.
The present invention provides following technical solution：
A kind of Environment-friendlywear-resistant wear-resistant resin button, is made of the raw material of following parts by weight：Unsaturated polyester resin 44-52
Part, 38-43 parts of Lauxite, 7-12 parts of photosensitive resin, adjacent 15-26 parts of benzene-type resin, 17-22 parts of metaphenylene resin, mill base 8-
10 parts, 9-13 parts of mica powder, 3-6 parts of accelerating agent, 5-8 parts of photosensitizer, 7-9 parts of antifoaming agent, 4-7 parts of levelling agent, curing agent 6-9
Part.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button, includes the following steps：
(1) by unsaturated polyester resin, Lauxite, photosensitive resin, adjacent benzene-type resin, metaphenylene resin, mill base, mica
After powder mixing, at a temperature of 200-300 DEG C, rubber cement is formed；
(2) above-mentioned uniformly mixed raw material is dispersed with stirring 10-20min, then adds in accelerating agent, photosensitizer, antifoaming agent
The viscosity that mixture is adjusted with levelling agent is 200-210Pas, the curing agent is eventually adding, using piece knob machine in rotating speed 60-
20-30min is centrifuged under the conditions of 100 turns/min, sheet material is made, the sheet material rushes embryo and obtain knob after gel solidification 30-50min
Embryo, the hardness of the knob embryo is A20-30；
(3) above-mentioned knob embryo is cured, cured solidification temperature is 75-85 DEG C, time 40-50min, the curing
The hardness of knob embryo afterwards is A70-80；
(4) button made of above-mentioned steps is put into water mill bucket, carries out polishing 10-15 hours, then the knob that will have been polished
Button cleans up, then using ultrasonic washing, organic cleaning solvent is added in supersonic wave cleaning machine, ultrasonic wave is carried out to it
Cleaning 30 minutes；Then surface Hardening Treatment is being carried out, button that is surface clean is clean and drying sprays dilute in dust-free workshop
Forced fluid after releasing is placed after ten minutes after spraying uniformly, is put into baking oven, is toasted 2-3 hours at 100 DEG C -120 DEG C, from
It is so cooled to room temperature up to the Environment-friendlywear-resistant wear-resistant resin button.
The photosensitive resin is selected from acrylate copolymer and urethane acrylate, the acrylate copolymer and polyurethane
The mass ratio of acrylate is 6：5.
The accelerating agent is cobalt naphthenate and/or cobalt iso-octoate, and the curing agent is methyl ethyl ketone peroxide.
The photosensitizer is selected from 1- hydroxy-cyclohexyl phenyl ketones, and the antifoaming agent is the defoaming of model Defom5700
Agent, the levelling agent are the levelling agent of model Levelol835.
The viscosity of mixture is 200-300Pas in the step (1).
Compared with prior art, the beneficial effects of the invention are as follows：The present invention overcomes the drawbacks of prior art, preparation method letter
It is single, adjacent benzene-type resin is added to as primary raw material in the process of preparation, reduces the manufacture cost of button, and manufactured knob
It is non-breakable to buckle reality, enhances the wear-resisting property of button；The present invention is recycled leftover pieces, effectively reduces resin
The discharge of waste in button production process decreases the dosage of resin, environmentally friendly degree higher.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, those of ordinary skill in the art's all other embodiments obtained without making creative work, all
Belong to the scope of protection of the invention.
A kind of 1 Environment-friendlywear-resistant wear-resistant resin button of embodiment, is made of the raw material of following parts by weight：Unsaturated polyester (UP) tree
44 parts of fat, 38 parts of Lauxite, 7 parts of photosensitive resin, adjacent 15 parts of benzene-type resin, 17 parts of metaphenylene resin, 8 parts of mill base, mica powder 9
Part, 3 parts of accelerating agent, 5 parts of photosensitizer, 7 parts of antifoaming agent, 4 parts of levelling agent, 6 parts of curing agent.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button, includes the following steps：
(1) by unsaturated polyester resin, Lauxite, photosensitive resin, adjacent benzene-type resin, metaphenylene resin, mill base, mica
After powder mixing, at a temperature of 200-300 DEG C, rubber cement is formed；
(2) above-mentioned uniformly mixed raw material is dispersed with stirring 10-20min, then adds in accelerating agent, photosensitizer, antifoaming agent
The viscosity that mixture is adjusted with levelling agent is 200-210Pas, the curing agent is eventually adding, using piece knob machine in rotating speed 60-
20-30min is centrifuged under the conditions of 100 turns/min, sheet material is made, the sheet material rushes embryo and obtain knob after gel solidification 30-50min
Embryo, the hardness of the knob embryo is A20-30；
(3) above-mentioned knob embryo is cured, cured solidification temperature is 75-85 DEG C, time 40-50min, the curing
The hardness of knob embryo afterwards is A70-80；
(4) button made of above-mentioned steps is put into water mill bucket, carries out polishing 10-15 hours, then the knob that will have been polished
Button cleans up, then using ultrasonic washing, organic cleaning solvent is added in supersonic wave cleaning machine, ultrasonic wave is carried out to it
Cleaning 30 minutes；Then surface Hardening Treatment is being carried out, button that is surface clean is clean and drying sprays dilute in dust-free workshop
Forced fluid after releasing is placed after ten minutes after spraying uniformly, is put into baking oven, is toasted 2-3 hours at 100 DEG C -120 DEG C, from
It is so cooled to room temperature up to the Environment-friendlywear-resistant wear-resistant resin button.
The photosensitive resin is selected from acrylate copolymer and urethane acrylate, the acrylate copolymer and polyurethane
The mass ratio of acrylate is 6：5.
The accelerating agent is cobalt naphthenate and/or cobalt iso-octoate, and the curing agent is methyl ethyl ketone peroxide.
The photosensitizer is selected from 1- hydroxy-cyclohexyl phenyl ketones, and the antifoaming agent is the defoaming of model Defom5700
Agent, the levelling agent are the levelling agent of model Levelol835.
The viscosity of mixture is 200-300Pas in the step (1).
A kind of 2 Environment-friendlywear-resistant wear-resistant resin button of embodiment, is made of the raw material of following parts by weight：Unsaturated polyester (UP) tree
52 parts of fat, 43 parts of Lauxite, 12 parts of photosensitive resin, adjacent 26 parts of benzene-type resin, 22 parts of metaphenylene resin, 10 parts of mill base, mica
13 parts of powder, 6 parts of accelerating agent, 8 parts of photosensitizer, 9 parts of antifoaming agent, 7 parts of levelling agent, 9 parts of curing agent.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button, includes the following steps：
(1) by unsaturated polyester resin, Lauxite, photosensitive resin, adjacent benzene-type resin, metaphenylene resin, mill base, mica
After powder mixing, at a temperature of 200-300 DEG C, rubber cement is formed；
(2) above-mentioned uniformly mixed raw material is dispersed with stirring 10-20min, then adds in accelerating agent, photosensitizer, antifoaming agent
The viscosity that mixture is adjusted with levelling agent is 200-210Pas, the curing agent is eventually adding, using piece knob machine in rotating speed 60-
20-30min is centrifuged under the conditions of 100 turns/min, sheet material is made, the sheet material rushes embryo and obtain knob after gel solidification 30-50min
Embryo, the hardness of the knob embryo is A20-30；
(3) above-mentioned knob embryo is cured, cured solidification temperature is 75-85 DEG C, time 40-50min, the curing
The hardness of knob embryo afterwards is A70-80；
(4) button made of above-mentioned steps is put into water mill bucket, carries out polishing 10-15 hours, then the knob that will have been polished
Button cleans up, then using ultrasonic washing, organic cleaning solvent is added in supersonic wave cleaning machine, ultrasonic wave is carried out to it
Cleaning 30 minutes；Then surface Hardening Treatment is being carried out, button that is surface clean is clean and drying sprays dilute in dust-free workshop
Forced fluid after releasing is placed after ten minutes after spraying uniformly, is put into baking oven, is toasted 2-3 hours at 100 DEG C -120 DEG C, from
It is so cooled to room temperature up to the Environment-friendlywear-resistant wear-resistant resin button.
The photosensitive resin is selected from acrylate copolymer and urethane acrylate, the acrylate copolymer and polyurethane
The mass ratio of acrylate is 6：5.
The accelerating agent is cobalt naphthenate and/or cobalt iso-octoate, and the curing agent is methyl ethyl ketone peroxide.
The photosensitizer is selected from 1- hydroxy-cyclohexyl phenyl ketones, and the antifoaming agent is the defoaming of model Defom5700
Agent, the levelling agent are the levelling agent of model Levelol835.
The viscosity of mixture is 200-300Pas in the step (1).
A kind of 3 Environment-friendlywear-resistant wear-resistant resin button of embodiment, is made of the raw material of following parts by weight：Unsaturated polyester (UP) tree
48 parts of fat, 41 parts of Lauxite, 10 parts of photosensitive resin, adjacent 18 parts of benzene-type resin, 19 parts of metaphenylene resin, 9 parts of mill base, mica powder
11 parts, 5 parts of accelerating agent, 6 parts of photosensitizer, 8 parts of antifoaming agent, 6 parts of levelling agent, 7 parts of curing agent.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button, includes the following steps：
(1) by unsaturated polyester resin, Lauxite, photosensitive resin, adjacent benzene-type resin, metaphenylene resin, mill base, mica
After powder mixing, at a temperature of 200-300 DEG C, rubber cement is formed；
(2) above-mentioned uniformly mixed raw material is dispersed with stirring 10-20min, then adds in accelerating agent, photosensitizer, antifoaming agent
The viscosity that mixture is adjusted with levelling agent is 200-210Pas, the curing agent is eventually adding, using piece knob machine in rotating speed 60-
20-30min is centrifuged under the conditions of 100 turns/min, sheet material is made, the sheet material rushes embryo and obtain knob after gel solidification 30-50min
Embryo, the hardness of the knob embryo is A20-30；
(3) above-mentioned knob embryo is cured, cured solidification temperature is 75-85 DEG C, time 40-50min, the curing
The hardness of knob embryo afterwards is A70-80；
(4) button made of above-mentioned steps is put into water mill bucket, carries out polishing 10-15 hours, then the knob that will have been polished
Button cleans up, then using ultrasonic washing, organic cleaning solvent is added in supersonic wave cleaning machine, ultrasonic wave is carried out to it
Cleaning 30 minutes；Then surface Hardening Treatment is being carried out, button that is surface clean is clean and drying sprays dilute in dust-free workshop
Forced fluid after releasing is placed after ten minutes after spraying uniformly, is put into baking oven, is toasted 2-3 hours at 100 DEG C -120 DEG C, from
It is so cooled to room temperature up to the Environment-friendlywear-resistant wear-resistant resin button.
The photosensitive resin is selected from acrylate copolymer and urethane acrylate, the acrylate copolymer and polyurethane
The mass ratio of acrylate is 6：5.
The accelerating agent is cobalt naphthenate and/or cobalt iso-octoate, and the curing agent is methyl ethyl ketone peroxide.
The photosensitizer is selected from 1- hydroxy-cyclohexyl phenyl ketones, and the antifoaming agent is the defoaming of model Defom5700
Agent, the levelling agent are the levelling agent of model Levelol835.
The viscosity of mixture is 200-300Pas in the step (1).
It is obvious to a person skilled in the art that the present invention is not limited to the details of the exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than it is described illustrate to limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.In addition, it should be understood that although this specification is described in terms of embodiments, but it is not each
Embodiment is only comprising an independent technical solution, and this description of the specification is merely for the sake of clarity, this field
Technical staff should consider the specification as a whole, and the technical solutions in each embodiment can also be properly combined, form this
The other embodiment that field technology personnel are appreciated that.
Claims (6)
1. a kind of Environment-friendlywear-resistant wear-resistant resin button, which is characterized in that its raw material by following parts by weight forms：Unsaturated polyester (UP)
44-52 parts of resin, 38-43 parts of Lauxite, 7-12 parts of photosensitive resin, adjacent 15-26 parts of benzene-type resin, metaphenylene resin 17-22
Part, is consolidated 8-10 parts of mill base, 9-13 parts of mica powder, 3-6 parts of accelerating agent, 5-8 parts of photosensitizer, 7-9 parts of antifoaming agent, 4-7 parts of levelling agent
6-9 parts of agent.
2. a kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button as described in claim 1, which is characterized in that including following step
Suddenly：
(1) unsaturated polyester resin, Lauxite, photosensitive resin, adjacent benzene-type resin, metaphenylene resin, mill base, mica powder are mixed
After conjunction, at a temperature of 200-300 DEG C, rubber cement is formed；
(2) above-mentioned uniformly mixed raw material is dispersed with stirring 10-20min, then adds in accelerating agent, photosensitizer, antifoaming agent and stream
The viscosity that flat agent adjusts mixture is 200-210Pas, the curing agent is eventually adding, using piece knob machine in rotating speed 60-100
Turn/min under the conditions of centrifuge 20-30min, sheet material is made, the sheet material rushes embryo and obtains knob embryo after gel solidification 30-50min,
The hardness of the knob embryo is A20-30；
(3) above-mentioned knob embryo is cured, cured solidification temperature is 75-85 DEG C, time 40-50min, after the curing
The hardness of knob embryo is A70-80；
(4) button made of above-mentioned steps is put into water mill bucket, carries out polishing 10-15 hours, then the button polished is clear
Wash clean, then using ultrasonic washing, organic cleaning solvent is added in supersonic wave cleaning machine, ultrasonic cleaning is carried out to it
30 minutes；Then surface Hardening Treatment is being carried out, surface clean is the clean and button dried is after dust-free workshop spraying dilution
Forced fluid, spray uniformly after place after ten minutes, be put into baking oven, toasted 2-3 hours at 100 DEG C -120 DEG C, it is naturally cold
But to room temperature up to the Environment-friendlywear-resistant wear-resistant resin button.
3. a kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button according to claim 1 or 2, it is characterised in that：The light
Quick resin is selected from the quality of acrylate copolymer and urethane acrylate, the acrylate copolymer and urethane acrylate
Than being 6：5.
4. a kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button according to claim 1 or 2, it is characterised in that：The rush
It is cobalt naphthenate and/or cobalt iso-octoate into agent, the curing agent is methyl ethyl ketone peroxide.
5. a kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button according to claim 1 or 2, it is characterised in that：The light
Quick dose is selected from 1- hydroxy-cyclohexyl phenyl ketones, and the antifoaming agent is the antifoaming agent of model Defom5700, and the levelling agent is
The levelling agent of model Levelol835.
6. a kind of preparation method of Environment-friendlywear-resistant wear-resistant resin button according to claim 1 or 2, it is characterised in that：The step
Suddenly the viscosity of mixture is 200-300Pas in (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711281457.4A CN108244770A (en) | 2017-12-07 | 2017-12-07 | A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711281457.4A CN108244770A (en) | 2017-12-07 | 2017-12-07 | A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof |
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| CN108244770A true CN108244770A (en) | 2018-07-06 |
Family
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|---|---|---|---|
| CN201711281457.4A Pending CN108244770A (en) | 2017-12-07 | 2017-12-07 | A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135318A (en) * | 2018-07-20 | 2019-01-04 | 金永福 | A kind of resin button and its preparation process |
| CN110760173A (en) * | 2019-11-05 | 2020-02-07 | 深圳联达钮扣有限公司 | Novel hot-pressing antique button and corresponding manufacturing method and manufacturing equipment |
| CN114262510A (en) * | 2022-01-17 | 2022-04-01 | 浙江飞素服饰有限公司 | Environment-friendly grain resin button and preparation method thereof |
| CN114369374A (en) * | 2020-10-15 | 2022-04-19 | 义丰行有限公司 | Regenerated environment-friendly fruit button blank, regenerated environment-friendly fruit button, various fashion accessories and ornaments |
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| CN107141746A (en) * | 2017-05-23 | 2017-09-08 | 浙江伟星实业发展股份有限公司 | A kind of high impact resins button and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135318A (en) * | 2018-07-20 | 2019-01-04 | 金永福 | A kind of resin button and its preparation process |
| CN110760173A (en) * | 2019-11-05 | 2020-02-07 | 深圳联达钮扣有限公司 | Novel hot-pressing antique button and corresponding manufacturing method and manufacturing equipment |
| CN114369374A (en) * | 2020-10-15 | 2022-04-19 | 义丰行有限公司 | Regenerated environment-friendly fruit button blank, regenerated environment-friendly fruit button, various fashion accessories and ornaments |
| CN114262510A (en) * | 2022-01-17 | 2022-04-01 | 浙江飞素服饰有限公司 | Environment-friendly grain resin button and preparation method thereof |
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Application publication date: 20180706 |