CN103709906A - White ultraviolet curing finishing coat - Google Patents
White ultraviolet curing finishing coat Download PDFInfo
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- CN103709906A CN103709906A CN201410016805.5A CN201410016805A CN103709906A CN 103709906 A CN103709906 A CN 103709906A CN 201410016805 A CN201410016805 A CN 201410016805A CN 103709906 A CN103709906 A CN 103709906A
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- ultraviolet light
- finish paint
- white finish
- light polymerization
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Abstract
The invention discloses a white ultraviolet curing finishing coat which consists of the following components by weight percent: 50-70 percent of resin, 23-40 percent of an acrylate compound monomer, 4.5-9.5 percent of a photo-initiator and 0.3-3.0 percent of an aid, wherein the resin is a mixture consisting of epoxy acrylate and urethane acrylate; the acrylate compound monomer is one or a mixture of two of hydroxyethyl methylacrylate, tripropylene glycol diacrylate, 1,6-hexanediol diacrylate, dipropylene glycol diacrylate and trimethylolpropane triacrylate. The white ultraviolet curing finishing coat can be sprayed instead of the conventional solvent based coating, and has the advantages of high curing speed, high production efficiency, lower plate production cost, energy saving, carbon reduction and the like.
Description
Technical field
The present invention relates to a kind of ultraviolet light polymerization white finish paint that applies to floor, furniture, decorative sheet etc. to carry out application.
Background technology
The high light complete processing of current existing furniture and decorative sheet, needs through spraying, dry until operations such as polishings; Wherein spraying generally adopts traditional solvent borne polyurethane coating and nitro paint, and in those coating, the release of organic solvent pollutes the environment, and its time of drying is longer, need, through longer time operation and wait, cause the problems such as the wasting of resources.Above-mentioned these processes and factor have caused a large amount of wastings of resources and pollution, and the manufacturing cost that has greatly increased enterprise has also seriously restricted the production capacity of enterprise.
Afterwards, the exploitation of ultraviolet light polymerization white finish paint, had shortened the production time greatly, and its effect that can reduce the release of organic solvent and can reach carbon reduction.Current domestic white furniture, the decorative sheet market requirement are large, present explosive growth recent years, and the whitewash using as its upstream processing industry will have more wide market.But existing ultraviolet light polymerization white its rate of drying of finish paint and solidification effect are undesirable.
Summary of the invention
In order to overcome the defect of prior art, the present invention has developed a kind of novel ultraviolet light polymerization white finish paint, and it can be accelerated rate of drying and solidification effect is provided.
For solving above technical problem, the present invention takes following technical scheme: a kind of ultraviolet light polymerization white finish paint, and it is comprised of the component with following weight percentage: resin 50%～70%; Acrylic ester compound monomer 23%～40%; Pigment 3%～8%; Light trigger 4.5%～9.5%; And auxiliary agent 0.3%～3.0%, described resin is the mixture that epoxy acrylate and urethane acrylate form, it is characterized in that: described acrylic ester compound monomer is one or both the mixture in hydroxyethyl methylacrylate, tripropylene glycol diacrylate, 1,6 hexanediol diacrylate, propylene glycol diacrylate, Viscoat 295.
In addition, the present invention also provides following attached technical scheme:
Described acrylic ester compound monomer is comprised of the component with following two kinds of weight percentages: hydroxyethyl methylacrylate 1%～5% and tripropylene glycol diacrylate 25%～35%.
Described acrylic ester compound monomer is comprised of the component with following two kinds of weight percentages: hydroxyethyl methylacrylate 3%～8% and tripropylene glycol diacrylate 20%～30%.
The weight ratio of described epoxy acrylate and urethane acrylate can be arbitrary proportion, and preferred weight percentage is respectively: 40%～50% and 10%～20%.
The weight ratio of described epoxy acrylate and urethane acrylate can be arbitrary proportion, and preferred weight percentage is respectively: 35%～45% and 15%～25%.
Described light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2,4, the mixture of one or more in 6-trimethylbenzoyl-diphenyl phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-acetone.
Preferably; described light trigger is comprised of the component with following weight percentage: 1-hydroxy-cyclohexyl phenyl ketone 1.5%～3.5%, 2; 4,6 trimethylbenzoyl diphenyl phosphine oxides 1.5%～3.5%, 2-hydroxy-2-methyl-1-phenyl-acetone 0.5%～1.5%.
Another is preferred; described light trigger is comprised of the component with following weight percentage: 1-hydroxy-cyclohexyl phenyl ketone 2%～4%, 2; 4,6-trimethylbenzoyl-diphenyl phosphine oxide 2%～4%, 2-hydroxy-2-methyl-1-phenyl-acetone 0.5%～1.5%.
Described pigment is titanium dioxide.
Described auxiliary agent is comprised of the component with following weight percentage: dispersion agent 0.1%～1.0%, defoamer 0.1%～1.0% and flow agent 0.1%～1.0%.
The preparation method of described ultraviolet light polymerization white finish paint, it comprises the steps: first pigment to be become to mill base with a part of monomer and resin ground, then by after light trigger and a part of monomer stirring and dissolving, add successively again resin, remaining monomer, mill base and auxiliary agent, finally stir and within 30 minutes, obtain above described ultraviolet light polymerization white finish paint.
Owing to taking above technical scheme, the present invention compared with prior art tool has the following advantages: its ultraviolet light polymerization white finish paint is mainly by changing concrete component and the weight percent of existing traditional coating white finish paint, especially the different components of monomer and weight percent, make UV-light white finish paint of the present invention there is curing speed fast, the advantage that production efficiency is high, and also can reduce board materials production cost and environmental protection simultaneously, carbon reduction etc., thereby significantly reduce the wasting of resources and take into account the function of environment protection, reduce enterprise's manufacturing cost, improve enterprise's production capacity.
Embodiment
Forming various raw material of the present invention can directly buy from the market, or prepares by the means of prior art.Below in conjunction with preferred embodiment, technical solution of the present invention is further non-limitingly described in detail.
Embodiment mono-
According to the ultraviolet light polymerization white finish paint of the present embodiment, composition and weight percentage are in Table 1.
Table 1
The preparation method of the ultraviolet light polymerization white finish paint of the present embodiment comprises the steps: first pigment to be become to mill base with a part of monomer and resin ground, then by after light trigger and a part of monomer stirring and dissolving, add successively again resin, remaining monomer, mill base and auxiliary agent, finally stir and within 30 minutes, obtain above described ultraviolet light polymerization white finish paint.
Embodiment bis-
According to the ultraviolet light polymerization white finish paint of the present embodiment, composition and weight percentage are in Table 2.
Table 2
The preparation method of the ultraviolet light polymerization white finish paint of the present embodiment comprises the steps: first pigment to be become to mill base with a part of monomer and resin ground, then by after light trigger and a part of monomer stirring and dissolving, add successively again resin, remaining monomer, mill base and auxiliary agent, finally stir and within 30 minutes, obtain above described ultraviolet light polymerization white finish paint.
Comparative example one
According to the ultraviolet light polymerization white finish paint of this comparative example, composition and weight percentage are in Table 3.
Table 3
Comparative example two
According to the ultraviolet light polymerization white finish paint of this comparative example, composition and content are in Table 4.
Table 4
The performance test of the ultraviolet light polymerization white finish paint of each embodiment and comparative example, in Table 5.
Table 5
| Test event | Embodiment mono- | Embodiment bis- | Comparative example one | Comparative example two |
| Resistance to coin test | Success | Success | Failure | Failure |
| Adhere to test | ＞95 | ＞95 | ＞95 | ＞95 |
As can be seen from Table 5, the resistance to coin test of the adhesive agent of embodiment mono-and embodiment bis-is successful, and the resistance to coin test of comparative example one and comparative example two is failed, visible, the solidification effect of ultraviolet light polymerization of the present invention white finish paint is relatively good, and it adheres to test and can reach equally the sticking power per-cent that is greater than 95.
It is pointed out that above-mentioned preferred embodiment is only explanation technical conceive of the present invention and feature, its object is to allow person skilled in the art can understand content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences that spirit is done according to the present invention change or modify, within all should being encompassed in protection scope of the present invention.
Claims (10)
1. a ultraviolet light polymerization white finish paint, it is comprised of the component with following weight percentage: resin 50%～70%; Acrylic ester compound monomer 23%～40%; Pigment 3%～8%; Light trigger 4.5%～9.5%; And auxiliary agent 0.3%～3.0%, described resin is the mixture that epoxy acrylate and urethane acrylate form, it is characterized in that: described acrylic ester compound monomer is one or both the mixture in hydroxyethyl methylacrylate, tripropylene glycol diacrylate, 1,6 hexanediol diacrylate, propylene glycol diacrylate, Viscoat 295.
2. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: described acrylic ester compound monomer is comprised of the component with following two kinds of weight percentages: hydroxyethyl methylacrylate 1%～5% and tripropylene glycol diacrylate 25%～35%.
3. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: described acrylic ester compound monomer is comprised of the component with following two kinds of weight percentages: hydroxyethyl methylacrylate 3%～8% and tripropylene glycol diacrylate 20%～30%.
4. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: the weight percentage of described epoxy acrylate and urethane acrylate is respectively: 40%～50% and 10%～20%.
5. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: the weight percentage of described epoxy acrylate and urethane acrylate is respectively: 35%～45% and 15%～25%.
6. ultraviolet light polymerization according to claim 1 white finish paint; it is characterized in that: described light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2; the mixture of one or more in 4,6-trimethylbenzoyl-diphenyl phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-acetone.
7. ultraviolet light polymerization according to claim 6 white finish paint; it is characterized in that: described light trigger is comprised of the component with following weight percentage: 1-hydroxy-cyclohexyl phenyl ketone 1.5%～3.5%, 2; 4,6-trimethylbenzoyl-diphenyl phosphine oxide 1.5%～3.5%, 2-hydroxy-2-methyl-1-phenyl-acetone 0.5%～1.5%.
8. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: described pigment is titanium dioxide.
9. ultraviolet light polymerization white finish paint according to claim 1, is characterized in that: described auxiliary agent is comprised of the component with following weight percentage: dispersion agent 0.1%～1.0%, defoamer 0.1%～1.0% and flow agent 0.1%～1.0%.
10. according to the preparation method of the ultraviolet light polymerization white finish paint described in claim 1 to 10 any one, it comprises the steps: first pigment to be become to mill base with a part of monomer and resin ground, then by after light trigger and a part of monomer stirring and dissolving, add successively again resin, remaining monomer, mill base and auxiliary agent, finally stir and within 30 minutes, obtain above described ultraviolet light polymerization white finish paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410016805.5A CN103709906B (en) | 2014-01-15 | 2014-01-15 | Ultraviolet light polymerization white finish paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410016805.5A CN103709906B (en) | 2014-01-15 | 2014-01-15 | Ultraviolet light polymerization white finish paint |
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| Publication Number | Publication Date |
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| CN103709906A true CN103709906A (en) | 2014-04-09 |
| CN103709906B CN103709906B (en) | 2016-08-24 |
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| CN201410016805.5A Active CN103709906B (en) | 2014-01-15 | 2014-01-15 | Ultraviolet light polymerization white finish paint |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073165A (en) * | 2014-06-26 | 2014-10-01 | 林创举 | UV (ultraviolet) paint capable of being quickly dried from inside to outside |
| CN104497849A (en) * | 2015-01-07 | 2015-04-08 | 东周化学工业（昆山）有限公司 | Ultraviolet curing non-slip elastic floor paint and method |
| CN105199515A (en) * | 2015-10-27 | 2015-12-30 | 惠州圣源恒工艺品有限公司 | Porcelain imitation coating and spraying method thereof |
| CN106010144A (en) * | 2016-06-20 | 2016-10-12 | 上海飞凯光电材料股份有限公司 | UV-LED-curing optical fiber coating resin and preparing method and application thereof |
| CN108165139A (en) * | 2018-02-02 | 2018-06-15 | 东周化学工业（昆山）有限公司 | A kind of ultraviolet cured vacuum spraying coating |
| CN108342106A (en) * | 2018-03-16 | 2018-07-31 | 广州市精合致新材料科技有限公司 | A kind of decoration thin aluminium photocuring white coating and its preparation and application method |
| CN111876003A (en) * | 2020-03-02 | 2020-11-03 | 杨建波 | Additive for decoration material and decoration material thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073165A (en) * | 2014-06-26 | 2014-10-01 | 林创举 | UV (ultraviolet) paint capable of being quickly dried from inside to outside |
| CN104073165B (en) * | 2014-06-26 | 2016-05-04 | 广东葫芦堡文化科技股份有限公司 | One is rapid-curing cutback UV paint from inside to outside |
| CN104497849A (en) * | 2015-01-07 | 2015-04-08 | 东周化学工业（昆山）有限公司 | Ultraviolet curing non-slip elastic floor paint and method |
| CN105199515A (en) * | 2015-10-27 | 2015-12-30 | 惠州圣源恒工艺品有限公司 | Porcelain imitation coating and spraying method thereof |
| CN105199515B (en) * | 2015-10-27 | 2017-11-14 | 惠州圣源恒工艺品有限公司 | A kind of imitation porcelain coating and its spraying method |
| CN106010144A (en) * | 2016-06-20 | 2016-10-12 | 上海飞凯光电材料股份有限公司 | UV-LED-curing optical fiber coating resin and preparing method and application thereof |
| CN106010144B (en) * | 2016-06-20 | 2019-04-23 | 上海飞凯光电材料股份有限公司 | A kind of UV-LED solidification optical fiber coated with resins and its preparation method and application |
| CN108165139A (en) * | 2018-02-02 | 2018-06-15 | 东周化学工业（昆山）有限公司 | A kind of ultraviolet cured vacuum spraying coating |
| CN108342106A (en) * | 2018-03-16 | 2018-07-31 | 广州市精合致新材料科技有限公司 | A kind of decoration thin aluminium photocuring white coating and its preparation and application method |
| CN111876003A (en) * | 2020-03-02 | 2020-11-03 | 杨建波 | Additive for decoration material and decoration material thereof |
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| Publication number | Publication date |
|---|---|
| CN103709906B (en) | 2016-08-24 |
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