CN108227243A - Automatically controlled THz wave regulation and control device of silicon substrate all dielectric type and preparation method thereof - Google Patents
Automatically controlled THz wave regulation and control device of silicon substrate all dielectric type and preparation method thereof Download PDFInfo
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Abstract
本发明提供一种硅基全介质型电控太赫兹波调控器件及其制备方法,包括双层圆柱形硅微米结构,高阻硅衬底、掺杂硅叉指电极、二氧化硅纳米氧化层以及二氧化钒薄膜,双层圆柱形硅微米结构位于高阻硅衬底的上侧,掺杂硅叉指电极、二氧化硅纳米氧化层、二氧化钒薄膜从上到下依次位于高阻硅衬底的下侧;本发明中选取半导体高阻硅材料作为主要介质材料,获取容易、成本低且半导体加工工艺成熟;这一器件具有很高的太赫兹波透射率以及极低的器件插损,同时具有大的工作带宽;通过在二氧化钒薄膜和掺杂硅叉指电极间引入氧化物绝缘层可有效抑制电流所产生的焦耳热,进而提高器件开关速度,可广泛应用于太赫兹波探测、太赫兹波成像等领域。
The invention provides a silicon-based all-dielectric electronically controlled terahertz wave control device and a preparation method thereof, including a double-layer cylindrical silicon micron structure, a high-resistance silicon substrate, doped silicon interdigitated electrodes, and a silicon dioxide nano-oxide layer And the vanadium dioxide film, the double-layer cylindrical silicon microstructure is located on the upper side of the high-resistance silicon substrate, the doped silicon interdigitated electrode, the silicon dioxide nano-oxide layer, and the vanadium dioxide film are located on the high-resistance silicon substrate from top to bottom. The underside of the substrate; the semiconductor high-resistance silicon material is selected as the main dielectric material in the present invention, which is easy to obtain, low in cost and mature in semiconductor processing technology; this device has very high terahertz wave transmittance and extremely low device insertion loss , and has a large working bandwidth; by introducing an oxide insulating layer between the vanadium dioxide film and the doped silicon interdigital electrode, the Joule heat generated by the current can be effectively suppressed, thereby increasing the switching speed of the device, which can be widely used in terahertz wave Detection, terahertz wave imaging and other fields.
Description
技术领域technical field
本发明属于太赫兹波应用技术领域,具体为一种硅基全介质型电控太赫兹波调控器件及其制备方法。The invention belongs to the technical field of terahertz wave applications, in particular to a silicon-based all-dielectric electrically controlled terahertz wave control device and a preparation method thereof.
背景技术Background technique
太赫兹波(terahertz wave)是其波段介于毫米波与红外波之间,其频率在0.1-10THz、波长为30μm-3mm范围内的电磁波波谱。具有独特的电磁特性,在电磁波谱中占据着重要位置。近年来太赫兹科学与技术得到迅猛发展,已经在无线通信、探测成像、电子对抗、安全检查、生物医学诊断和环境监测等领域发挥领先优势,具有非常重要的应用价值,对国民经济以及国防建设具有重大意义。在这些应用中,太赫兹成像与通信技术已受到越来越多的人关注,而太赫兹调控器是其系统中必不可少的关键部件,调控器件的优劣直接影响到整个系统的性能好坏。Terahertz wave (terahertz wave) is an electromagnetic wave spectrum whose waveband is between millimeter wave and infrared wave, its frequency is 0.1-10THz, and its wavelength is in the range of 30μm-3mm. It has unique electromagnetic properties and occupies an important position in the electromagnetic spectrum. In recent years, terahertz science and technology have developed rapidly, and have played a leading role in the fields of wireless communication, detection imaging, electronic countermeasures, security inspection, biomedical diagnosis and environmental monitoring, and have very important application value. has great significance. In these applications, terahertz imaging and communication technology has attracted more and more people's attention, and terahertz regulator is an indispensable key component in the system, and the quality of the control device directly affects the performance of the entire system Bad.
硅基太赫兹调控器因为能够与现有半导体工艺相兼容,因而受到广泛的关注,例如文献:Wen T,Zhang D,Wen Q,et al.Enhanced Optical Modulation Depth ofTerahertz Waves by Self‐Assembled Monolayer of Plasmonic Gold Nanoparticles[J].Advanced Optical Materials,2016,4.中提出了一种硅基光控太赫兹调控器,但是这些器件中,由于Si衬底的折射率较高,引起非常大的器件损耗,器件插损高达3-5dB,而且由于采用光控技术,与现有高集成度电子器件不相兼容。Silicon-based terahertz regulators have received extensive attention because they are compatible with existing semiconductor processes, such as literature: Wen T, Zhang D, Wen Q, et al. Enhanced Optical Modulation Depth of Terahertz Waves by Self‐Assembled Monolayer of Plasmonic Gold Nanoparticles[J].Advanced Optical Materials,2016,4. proposed a silicon-based optically controlled terahertz modulator, but in these devices, due to the high refractive index of the Si substrate, the device loss is very large, The insertion loss of the device is as high as 3-5dB, and due to the use of light control technology, it is not compatible with existing highly integrated electronic devices.
二氧化钒(VO2)是一种室温绝缘体-金属相变(MIT)材料,它在热、光或者电场驱动下发生从绝缘相到金属相的转变,其电导率一般可以有3到5个数量级的变化。在绝缘体相时,二氧化钒对太赫兹波具有优良的透明特性,吸收和反射损耗非常小;而处于金属相时,二氧化钒能够对太赫兹波产生很强的反射以及部分吸收。因此,利用二氧化钒薄膜的相变,可以实现对太赫兹波的幅度调控。然而,采用传统的热和光驱动方法,需要额外的热和光学装置,无法与目前主流的微电子系统相集成。而采用电驱动方式虽然解决了电子系统兼容性问题,但是所采用的金属电极对太赫兹波有强烈的反射作用,显著增加了器件插损。更重要的是,采用常规偏压加载方式驱动VO2相变,而导致二氧化钒材料中焦耳热的大量积累,由于热耗散过程慢,这限制了其调控速度通常不足1Hz。这些因素,限制了二氧化钒作为有效的太赫兹调控器的实际应用。Vanadium dioxide (VO 2 ) is a room temperature insulator-metal phase transition (MIT) material, which undergoes a transformation from an insulating phase to a metal phase driven by heat, light or an electric field, and its conductivity can generally range from 3 to 5 change in magnitude. In the insulator phase, vanadium dioxide has excellent transparency to terahertz waves, and the absorption and reflection losses are very small; while in the metal phase, vanadium dioxide can strongly reflect and partially absorb terahertz waves. Therefore, the amplitude regulation of terahertz waves can be achieved by using the phase transition of vanadium dioxide thin films. However, conventional thermal and optical actuation methods require additional thermal and optical devices, which cannot be integrated with current mainstream microelectronic systems. Although the electric drive method solves the compatibility problem of the electronic system, the metal electrode used has a strong reflection effect on the terahertz wave, which significantly increases the insertion loss of the device. More importantly, the use of conventional bias loading to drive the phase transition of VO2 leads to a large accumulation of Joule heat in the vanadium dioxide material, which limits its regulation speed to less than 1 Hz due to the slow heat dissipation process. These factors limit the practical application of vanadium dioxide as an effective terahertz regulator.
因此,研制一种能够与半导体工艺和现有高集成度电子系统相兼容的,并且具有较低的插损、大的调控深度以及高开关速率的太赫兹波调控器件是十分必须的,对于推动现有的太赫兹成像系统等实际应用系统发展具有重要价值。Therefore, it is necessary to develop a terahertz wave control device that is compatible with semiconductor processes and existing highly integrated electronic systems, and has low insertion loss, large control depth, and high switching rate. The development of practical application systems such as existing terahertz imaging systems is of great value.
发明内容Contents of the invention
本发明的目的在于提供一种硅基全介质型电控太赫兹波调控器件及其制备方法。The object of the present invention is to provide a silicon-based all-dielectric electrically controlled terahertz wave control device and a preparation method thereof.
为实现上述发明目的,本发明技术方案如下:In order to realize the foregoing invention object, the technical scheme of the present invention is as follows:
一种硅基全介质型电控太赫兹波调控器件,包括双层圆柱形硅微米结构、高阻硅衬底、掺杂硅叉指电极、二氧化硅纳米氧化层以及二氧化钒薄膜,其中双层圆柱形硅微米结构位于高阻硅衬底的上侧,掺杂硅叉指电极、二氧化硅纳米氧化层、二氧化钒薄膜从上到下依次位于高阻硅衬底的下侧,整个器件不含金属材料和金属结构;高阻硅衬底上侧的双层圆柱形硅微米结构层起到太赫兹波增透作用,高阻硅衬底下侧的二氧化钒薄膜结构层则起到太赫兹波幅度调控作用。A silicon-based all-dielectric electronically controlled terahertz wave control device, including a double-layer cylindrical silicon microstructure, a high-resistance silicon substrate, doped silicon interdigitated electrodes, a silicon dioxide nano-oxide layer and a vanadium dioxide film, wherein The double-layer cylindrical silicon microstructure is located on the upper side of the high-resistance silicon substrate, and the doped silicon interdigitated electrode, silicon dioxide nano-oxide layer, and vanadium dioxide film are located on the lower side of the high-resistance silicon substrate in sequence from top to bottom. The entire device does not contain metal materials and metal structures; the double-layer cylindrical silicon microstructure layer on the upper side of the high-resistance silicon substrate plays the role of terahertz wave anti-reflection, and the vanadium dioxide thin film structure layer on the lower side of the high-resistance silicon substrate acts To the regulation of the amplitude of terahertz waves.
作为优选方式,整个器件中的双层圆柱形硅微米结构、掺杂硅叉指电极、二氧化硅纳米氧化层均是由同一高阻硅衬底通过刻蚀、掺杂、氧化、光刻的标准半导体工艺加工而成。As a preferred method, the double-layer cylindrical silicon microstructure, doped silicon interdigitated electrodes, and silicon dioxide nano-oxide layer in the entire device are all made of the same high-resistance silicon substrate through etching, doping, oxidation, and photolithography. Processed by standard semiconductor process.
作为优选方式,所述双层圆柱形硅微米结构为按多排多列等间距排列的硅基双层圆柱周期阵列,双层圆柱包括上层的圆柱、上层圆柱下方同心设置的下层圆柱,上层圆柱的直径小于下层圆柱的直径,两层圆柱的直径均≤100微米,两层圆柱的总高度≤100微米。As a preferred mode, the double-layer cylindrical silicon microstructure is a periodic array of silicon-based double-layer cylinders arranged in multiple rows and columns at equal intervals. The double-layer cylinders include an upper cylinder, a lower cylinder concentrically arranged below the upper cylinder, and an upper cylinder. The diameter of the cylinder is smaller than the diameter of the lower cylinder, the diameters of the two cylinders are all ≤ 100 microns, and the total height of the two cylinders is ≤ 100 microns.
作为优选方式,硅基双层圆柱形微米结构是通过半导体工艺从高阻硅衬底上直接加工而成,两者属于同一种高阻硅材料。As a preferred mode, the silicon-based double-layer cylindrical micron structure is directly processed from a high-resistance silicon substrate by semiconductor technology, and both belong to the same high-resistance silicon material.
作为优选方式,所述高阻硅衬底为本征或者高阻半导体Si材料,其电阻率≥3000Ω.cm,厚度在200μm~600μm之间。As a preferred manner, the high-resistance silicon substrate is an intrinsic or high-resistance semiconductor Si material with a resistivity ≥ 3000Ω.cm and a thickness between 200 μm and 600 μm.
作为优选方式,所述掺杂硅叉指电极是通过对高阻硅衬底进行选区掺杂形成的,其导电能力强弱通过控制掺杂浓度来调节,掺杂硅叉指电极的宽度在3μm-10μm之间,厚度在50nm到3μm之间。As a preferred mode, the doped silicon finger electrodes are formed by selectively doping the high-resistance silicon substrate, and its conductivity is adjusted by controlling the doping concentration. The width of the doped silicon finger electrodes is 3 μm Between -10μm and thickness between 50nm and 3μm.
作为优选方式,所述二氧化硅纳米氧化层是通过对高阻硅衬底以及掺杂硅叉指电极进行氧化而成,其厚度在50nm到100nm之间。As a preferred manner, the silicon dioxide nano-oxide layer is formed by oxidizing the high-resistance silicon substrate and doped silicon interdigital electrodes, and its thickness is between 50nm and 100nm.
作为优选方式,所述二氧化钒薄膜厚度为100nm-500nm,相变前后电阻率变化达到3个数量级以上,并且在金属相时的薄膜方阻≤50Ω/口。As a preferred mode, the thickness of the vanadium dioxide film is 100nm-500nm, the change of resistivity before and after the phase transition reaches more than 3 orders of magnitude, and the square resistance of the film in the metal phase is ≤50Ω/Ω.
作为优选方式,在超过450GHz的超宽带太赫兹频段范围内的器件插损≤1.5dB,器件调控深度达到76.5%以上,调控速度大于100Hz。As a preferred method, the insertion loss of the device in the ultra-broadband terahertz frequency range exceeding 450 GHz is ≤1.5 dB, the control depth of the device reaches more than 76.5%, and the control speed is greater than 100 Hz.
为实现上述发明目的,本发明还提供一种上述的硅基全介质型电控太赫兹波调控器件的制备方法,包括以下几个步骤:In order to achieve the purpose of the above invention, the present invention also provides a method for preparing the above-mentioned silicon-based all-dielectric electrically controlled terahertz wave control device, which includes the following steps:
步骤1、利用电磁仿真软件CST Microwave Studio,建立硅基双层圆柱形微结构单元3D模型,模型总厚度为500μm,设置好边界条件和求解器后,优化微结构中双层圆柱的半径r1,r2,圆柱柱高d1,d2,各双层圆柱之间的距离p,以获得最大的透射率和工作带宽;Step 1. Use the electromagnetic simulation software CST Microwave Studio to establish a 3D model of the silicon-based double-layer cylindrical microstructure unit. The total thickness of the model is 500 μm. After setting the boundary conditions and solver, optimize the radius r1 of the double-layer cylinder in the microstructure. r2, column height d1, d2, distance p between each double-layer column, to obtain maximum transmittance and working bandwidth;
步骤2、清洗半导体硅基片:首先将硅基片放入盛有丙酮的烧杯中超声清洗15min,然后再使用酒精超声清洗15min,最后使用去离子水超声清洗15min,清洗后的硅基片再氮气吹干,烘箱中干燥;Step 2. Clean the semiconductor silicon substrate: first put the silicon substrate into a beaker filled with acetone and ultrasonically clean it for 15 minutes, then use alcohol to ultrasonically clean it for 15 minutes, and finally use deionized water to ultrasonically clean it for 15 minutes. Blow dry with nitrogen, and dry in oven;
步骤3、根据设计好的微结构尺寸设计并加工掩膜板后,首先把硅基片放入热氧化炉,采用干氧氧化方法生长3μm厚的二氧化硅掩膜层,然后利用半导体光刻工艺和ICP蚀刻技术加工硅衬底,先制作底层大尺寸圆柱,再制作最上层小尺寸圆柱,形成双层阶梯型圆柱微结构;Step 3. After designing and processing the mask plate according to the designed microstructure size, first put the silicon substrate into a thermal oxidation furnace, and grow a 3μm thick silicon dioxide mask layer by dry oxygen oxidation method, and then use semiconductor photolithography to Process and ICP etching technology to process the silicon substrate, first make the bottom large-size cylinder, and then make the uppermost small-size cylinder to form a double-layer stepped cylinder microstructure;
步骤4、制备掺杂硅叉指电极:首先选用上步骤中生长的SiO2层做热扩散掺杂的阻挡层,其次利用电磁仿真软件CST Microwave Studio仿真,使得叉指电极对太赫兹波的透射无影响,得到优化后叉指电极线条和线条间隙都为7um,利用光刻技术在阻挡层上制作叉指电极的图形,再干法蚀刻阻挡层形成叉指电极的掺杂沟槽;再使用P作为热扩散源;在预扩散实验时全程通入1L/min氮气流下,用50min将炉内温度升高至850℃,并在此温度下送入基片;15min升至1000℃,在1000℃保持40min,然后在30min内降温至850℃,取出基片,最后使用BOE水浴方法去除掉剩余二氧化硅阻挡层;Step 4. Preparation of doped silicon interdigitated electrodes: firstly, the SiO 2 layer grown in the previous step is selected as the barrier layer for thermal diffusion doping, and secondly, the electromagnetic simulation software CST Microwave Studio is used for simulation to make the interdigitated electrodes transmit terahertz waves No effect, after optimization, the interdigital electrode lines and line gaps are both 7um, use photolithography technology to make interdigital electrode patterns on the barrier layer, and then dry etch the barrier layer to form interdigital electrode doping grooves; then use P is used as a thermal diffusion source; during the pre-diffusion experiment, under the nitrogen flow of 1L/min, the temperature in the furnace is raised to 850°C in 50 minutes, and the substrate is sent into the substrate at this temperature; it is raised to 1000°C in 15 minutes, Keep at ℃ for 40min, then cool down to 850℃ within 30min, take out the substrate, and finally use BOE water bath method to remove the remaining silicon dioxide barrier layer;
步骤5、制备二氧化硅绝缘层:采用干氧氧化的方式,致密性更好;在1L/min氮气流下用50min的时间将炉内的温度升至850℃,并在此温度下送入基片;继续升温,此时改通氧气,流量为1L/min,15min后升至1000℃,保持30min;然后开始降温,30min内使炉内温度降到850℃,取出基片,经测试制备的二氧化硅厚度为50nm;此步骤同时也为上步骤中预扩散后的再扩散,这样制备的掺杂硅叉指电极性能更好,测得电极方阻为4Ω/口;Step 5. Preparation of silicon dioxide insulating layer: dry oxygen oxidation method is adopted, and the density is better; the temperature in the furnace is raised to 850°C for 50 minutes under a nitrogen flow of 1L/min, and sent into the base at this temperature Continue to heat up, change to oxygen at this time, the flow rate is 1L/min, rise to 1000°C after 15min, and keep it for 30min; then start to cool down, let the temperature in the furnace drop to 850°C within 30min, take out the substrate, and prepare the The thickness of silicon dioxide is 50nm; this step is also the re-diffusion after pre-diffusion in the previous step, so that the performance of the doped silicon interdigitated electrode prepared in this way is better, and the measured electrode square resistance is 4Ω/Ω;
步骤6、制备二氧化钒薄膜:利用射频磁控溅射方法,由高纯金属钒靶材在磁控溅射系统参数:射频功率180w-220w、工作气压1Pa、氧氩流量比4%-6%、加热温度550℃的条件下,在二氧化硅绝缘层上沉积200nm的二氧化钒薄膜;Step 6. Preparation of vanadium dioxide thin film: using radio frequency magnetron sputtering method, high-purity metal vanadium target is used in magnetron sputtering system parameters: radio frequency power 180w-220w, working pressure 1Pa, oxygen-argon flow ratio 4%-6 %, under the condition of a heating temperature of 550°C, deposit a 200nm vanadium dioxide film on the silicon dioxide insulating layer;
步骤7、利用太赫兹时域光谱系统THz-TDS对器件的太赫兹透射性能进行测试,太赫兹波由双层圆柱形微结构一侧入射,器件所加电压由恒压源提供,正负极连接到叉指电极的两端,加到所需电压后,即刻记录THz-TDS系统数据。Step 7. Use the terahertz time-domain spectroscopy system THz-TDS to test the terahertz transmission performance of the device. The terahertz wave is incident on one side of the double-layer cylindrical microstructure, and the voltage applied to the device is provided by a constant voltage source. Connect to both ends of the interdigital electrodes, and record the THz-TDS system data immediately after the required voltage is applied.
该器件中硅基双层圆柱形微结构用于提高硅基二氧化钒型太赫兹调控器的调控深度以及克服原有调控器衬底对太赫兹波的插入损耗较大的问题。本发明的核心是采用半导体高阻硅材料做衬底,利用半导体光刻和ICP蚀刻技术对硅衬底进行处理,形成对太赫兹波起增加透射作用的表面微米结构,能够大幅提升太赫兹波透射幅度,在一定频段范围内其透射率达到85%以上;同时,在衬底另一面制作掺杂硅叉指电极,然后再制备氧化物绝缘层和二氧化钒核心调控纳米层。该全介质器件用以解决和现有微电子系统相兼容的问题,同时还可抑制器件产生焦耳热的问题。本发明实现的太赫兹调控器具有插入损耗低,工作带宽大,调控深度大,对入射太赫兹波方向极化不敏感等优点,可广泛应用在太赫兹成像和探测等系统中。The silicon-based double-layer cylindrical microstructure in the device is used to improve the control depth of the silicon-based vanadium dioxide type terahertz regulator and overcome the problem of large insertion loss of the original regulator substrate for terahertz waves. The core of the present invention is to use semiconductor high-resistance silicon material as the substrate, and use semiconductor photolithography and ICP etching technology to process the silicon substrate to form a surface microstructure that increases the transmission of terahertz waves, which can greatly improve the transmission of terahertz waves. The transmittance range is above 85% in a certain frequency range; at the same time, doped silicon interdigitated electrodes are fabricated on the other side of the substrate, and then an oxide insulating layer and a vanadium dioxide core control nanolayer are prepared. The all-dielectric device is used to solve the problem of being compatible with the existing microelectronic system, and at the same time suppress the problem of Joule heat generated by the device. The terahertz controller realized by the present invention has the advantages of low insertion loss, large working bandwidth, large regulation depth, and insensitivity to incident terahertz wave direction polarization, and can be widely used in terahertz imaging and detection systems.
从工作原理上讲:In terms of working principle:
本发明提出的双侧型器件,两个功能层分布于高阻硅衬底两侧,一侧起到太赫兹波增透的效果,另外一侧则起到太赫兹波透射调控的作用,这一新颖结构可以同时降低器件插损和实现大幅度快速调控。本发明结构中,衬底材料选用高阻硅材料是因为获取容易,成本低和成熟的半导体工艺特点。把硅表面蚀刻成特定三维立体结构,依据等效折射率模型使得硅衬底表层的折射率改变,在空气和硅衬底间形成渐变折射率结构组成增透构件,进而增加太赫兹波的透射幅度;同时本发明的调控器件采用掺杂硅叉指电极加载电压是为了兼容微电子系统工艺,并且降低常规金属电极导致的太赫兹波损耗;同时选用致密性良好的绝缘层抑制焦耳热的产生;该器件电极加载电压后产生电场控制二氧化钒薄膜从绝缘相变化到金属相,吸收入射的太赫兹波,从而达到调控太赫兹波的作用。In the double-sided device proposed by the present invention, two functional layers are distributed on both sides of the high-resistance silicon substrate, one side plays the role of terahertz wave anti-reflection, and the other side plays the role of terahertz wave transmission regulation. A novel structure can simultaneously reduce device insertion loss and realize large-scale and rapid regulation. In the structure of the present invention, the high-resistance silicon material is selected as the substrate material because of its easy acquisition, low cost and mature semiconductor process characteristics. Etch the silicon surface into a specific three-dimensional structure, change the refractive index of the surface layer of the silicon substrate according to the equivalent refractive index model, and form a graded refractive index structure between the air and the silicon substrate to form an anti-reflection component, thereby increasing the transmission of terahertz waves At the same time, the control device of the present invention uses doped silicon interdigitated electrodes to load the voltage in order to be compatible with the microelectronic system process, and to reduce the terahertz wave loss caused by conventional metal electrodes; at the same time, an insulating layer with good compactness is selected to suppress the generation of Joule heat ; After the electrode of the device is loaded with a voltage, an electric field is generated to control the transition of the vanadium dioxide film from an insulating phase to a metal phase, and absorb the incident terahertz wave, thereby achieving the function of regulating the terahertz wave.
综上所述,本发明的优点和效果有:In sum, advantage and effect of the present invention have:
本发明提供了一种硅基全介质型电控太赫兹波调控器件的设计理论和制备方案,是依据等效折射率渐变增透理论。本发明中选取半导体高阻硅材料作为衬底,获取容易、成本低且半导体加工工艺技术成熟;而且制备二氧化钒薄膜的技术也较成熟。其次这一器件大大提高了对太赫兹波的透射率,降低插损且具有大的工作带宽;而且在二氧化钒薄膜和掺杂硅叉指电极间引入氧化物绝缘层可以有效抑制电流所产生的焦耳热,进而提高器件调控速率,达到了本发明所述目的,可广泛应用于太赫兹波通信系统、太赫兹波探测、太赫兹波成像等领域。The invention provides a design theory and a preparation scheme of a silicon-based all-dielectric electronically controlled terahertz wave control device, which is based on the equivalent refractive index gradient anti-reflection theory. In the present invention, the semiconductor high-resistance silicon material is selected as the substrate, which is easy to obtain, low in cost, and the semiconductor processing technology is mature; moreover, the technology for preparing the vanadium dioxide thin film is relatively mature. Secondly, this device greatly improves the transmittance of terahertz waves, reduces insertion loss and has a large operating bandwidth; and the introduction of an oxide insulating layer between the vanadium dioxide film and the doped silicon interdigitated electrode can effectively suppress the current generation. Joule heat, and then improve the device control rate, to achieve the purpose of the present invention, can be widely used in terahertz wave communication systems, terahertz wave detection, terahertz wave imaging and other fields.
附图说明Description of drawings
图1是本发明硅基全介质型电控太赫兹波调控器件结构的三维示意图。Fig. 1 is a three-dimensional schematic diagram of the structure of the silicon-based all-dielectric electrically controlled terahertz wave regulating device of the present invention.
图2(a)是本发明硅基双层圆柱形微结构模型和裸硅片模型的仿真结果图。Fig. 2(a) is a simulation result diagram of a silicon-based double-layer cylindrical microstructure model and a bare silicon chip model of the present invention.
图2(b)是本发明硅基双层圆柱形微结构样品和裸硅片的实验测试结果图。Fig. 2(b) is a diagram of experimental test results of a silicon-based double-layer cylindrical microstructure sample and a bare silicon chip of the present invention.
图3(a)是本发明所使用的直接在二氧化硅绝缘层上制备的二氧化钒薄膜测试R-T热滞回线Fig. 3 (a) is the vanadium dioxide thin film test R-T thermal hysteresis loop that the present invention uses directly on the silicon dioxide insulating layer preparation
图3(b)是本发明所使用的直接在二氧化硅绝缘层上制备的二氧化钒薄膜测试的XRD图谱。Fig. 3(b) is the XRD spectrum of the vanadium dioxide thin film prepared directly on the silicon dioxide insulating layer used in the present invention.
图4是本发明所述硅基全介质型电控太赫兹波调控器件的实际测试时域谱。Fig. 4 is an actual test time-domain spectrum of the silicon-based all-dielectric electronically controlled terahertz wave control device of the present invention.
图5是本发明所述硅基全介质型电控太赫兹波调控器件的实际测试太赫兹波透射率拟合图。Fig. 5 is a fitting diagram of the actual test terahertz wave transmittance of the silicon-based all-dielectric electrically controlled terahertz wave control device of the present invention.
图6是本发明所述硅基全介质型电控太赫兹波调控器件的实际测试太赫兹波最大调控深度拟合图。Fig. 6 is a fitting diagram of the actual test terahertz wave maximum control depth of the silicon-based all-dielectric electrically controlled terahertz wave control device of the present invention.
其中,1为双层圆柱形硅微米结构,2为高阻硅衬底,3为掺杂硅叉指电极,4为二氧化硅纳米氧化层,5为二氧化钒薄膜,6为入射太赫兹波。Among them, 1 is a double-layer cylindrical silicon microstructure, 2 is a high-resistance silicon substrate, 3 is a doped silicon interdigitated electrode, 4 is a silicon dioxide nano-oxide layer, 5 is a vanadium dioxide film, and 6 is an incident terahertz Wave.
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。Embodiments of the present invention are described below through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented or applied through other different specific implementation modes, and various modifications or changes can be made to the details in this specification based on different viewpoints and applications without departing from the spirit of the present invention.
一种硅基全介质型电控太赫兹波调控器件,包括双层圆柱形硅微米结构1,高阻硅衬底2、掺杂硅叉指电极3、二氧化硅纳米氧化层4以及二氧化钒薄膜5,其中双层圆柱形硅微米结构1位于高阻硅衬底2的上侧,掺杂硅叉指电极3、二氧化硅纳米氧化层4、二氧化钒薄膜5从上到下依次位于高阻硅衬底2的下侧,整个器件不含金属材料和金属结构;高阻硅衬底2上侧的双层圆柱形硅微米结构层起到太赫兹波增透作用,高阻硅衬底2下侧的二氧化钒薄膜5结构层则起到太赫兹波幅度调控作用。A silicon-based all-dielectric electronically controlled terahertz wave control device, including a double-layer cylindrical silicon microstructure 1, a high-resistance silicon substrate 2, a doped silicon interdigitated electrode 3, a silicon dioxide nano-oxide layer 4, and a silicon dioxide Vanadium thin film 5, wherein double-layer cylindrical silicon microstructure 1 is located on the upper side of high resistance silicon substrate 2, doped silicon interdigitated electrode 3, silicon dioxide nano-oxide layer 4, and vanadium dioxide thin film 5 are sequentially arranged from top to bottom Located on the lower side of the high-resistance silicon substrate 2, the entire device does not contain metal materials and metal structures; the double-layer cylindrical silicon microstructure layer on the upper side of the high-resistance silicon substrate 2 plays the role of terahertz wave anti-reflection, and the high-resistance silicon The structural layer of the vanadium dioxide thin film 5 on the underside of the substrate 2 plays a role in regulating the amplitude of the terahertz wave.
整个器件中的双层圆柱形硅微米结构1、掺杂硅叉指电极3、二氧化硅纳米氧化层4均是由同一高阻硅衬底2通过刻蚀、掺杂、氧化、光刻的标准半导体工艺加工而成。The double-layer cylindrical silicon microstructure 1, doped silicon interdigitated electrodes 3, and silicon dioxide nano-oxide layer 4 in the entire device are all made of the same high-resistance silicon substrate 2 through etching, doping, oxidation, and photolithography. Processed by standard semiconductor process.
所述双层圆柱形硅微米结构1为按多排多列等间距排列的硅基双层圆柱周期阵列,双层圆柱包括上层的圆柱、上层圆柱下方同心设置的下层圆柱,上层圆柱的直径小于下层圆柱的直径,两层圆柱的直径均≤100微米,两层圆柱的总高度≤100微米。The double-layer cylindrical silicon microstructure 1 is a periodic array of silicon-based double-layer cylinders arranged at equal intervals in multiple rows and columns. The double-layer cylinder includes an upper cylinder and a lower cylinder concentrically arranged below the upper cylinder. The diameter of the upper cylinder is less than The diameter of the lower cylinder, the diameters of the two layers of cylinders are all ≤ 100 microns, and the total height of the two layers of cylinders is ≤ 100 microns.
硅基双层圆柱形微米结构1是通过半导体工艺从高阻硅衬底2上直接加工而成,两者属于同一种高阻硅材料。The silicon-based double-layer cylindrical microstructure 1 is directly processed from a high-resistance silicon substrate 2 by semiconductor technology, and both belong to the same high-resistance silicon material.
所述高阻硅衬底2为本征或者高阻半导体Si材料,其电阻率≥3000Ω.cm,厚度在200μm~600μm之间。The high-resistance silicon substrate 2 is an intrinsic or high-resistance semiconductor Si material with a resistivity ≥ 3000Ω.cm and a thickness between 200 μm and 600 μm.
所述掺杂硅叉指电极3是通过对高阻硅衬底2进行选区掺杂形成的,其导电能力强弱通过控制掺杂浓度来调节,掺杂硅叉指电极3的宽度在3μm-10μm之间,厚度在50nm到3μm之间。.The doped silicon interdigital electrode 3 is formed by selectively doping the high-resistance silicon substrate 2, and its conductivity is adjusted by controlling the doping concentration. The width of the doped silicon interdigital electrode 3 is between 3 μm- Between 10μm and thickness between 50nm and 3μm. .
所述二氧化硅纳米氧化层4是通过对高阻硅衬底2以及掺杂硅叉指电极3进行氧化而成,其厚度在50nm到100nm之间。The silicon dioxide nano-oxide layer 4 is formed by oxidizing the high-resistance silicon substrate 2 and the doped silicon interdigital electrodes 3, and its thickness is between 50nm and 100nm.
所述二氧化钒薄膜5厚度为100nm-500nm,相变前后电阻率变化达到3个数量级以上,并且在金属相时的薄膜方阻≤50Ω/口。The thickness of the vanadium dioxide thin film 5 is 100nm-500nm, the change of resistivity before and after the phase transition reaches more than 3 orders of magnitude, and the square resistance of the thin film in the metal phase is ≤50Ω/μm.
在超过450GHz的超宽带太赫兹频段范围内的器件插损≤1.5dB,器件调控深度达到76.5%以上,调控速度大于100Hz。In the ultra-broadband terahertz frequency range exceeding 450GHz, the insertion loss of the device is ≤1.5dB, the control depth of the device reaches more than 76.5%, and the control speed is greater than 100Hz.
上述的硅基全介质型电控太赫兹波调控器件的制备方法,包括以下几个步骤:The preparation method of the above-mentioned silicon-based all-dielectric electrically controlled terahertz wave control device includes the following steps:
步骤1、利用电磁仿真软件CST Microwave Studio,建立硅基双层圆柱形微结构单元3D模型,模型总厚度为500μm,设置好边界条件和求解器后,优化微结构中双层圆柱的半径r1,r2,圆柱柱高d1,d2,各双层圆柱之间的距离p,以获得最大的透射率和工作带宽;Step 1. Use the electromagnetic simulation software CST Microwave Studio to establish a 3D model of the silicon-based double-layer cylindrical microstructure unit. The total thickness of the model is 500 μm. After setting the boundary conditions and solver, optimize the radius r1 of the double-layer cylinder in the microstructure. r2, column height d1, d2, distance p between each double-layer column, to obtain maximum transmittance and working bandwidth;
步骤2、清洗半导体硅基片:首先将硅基片放入盛有丙酮的烧杯中超声清洗15min,然后再使用酒精超声清洗15min,最后使用去离子水超声清洗15min,清洗后的硅基片再氮气吹干,烘箱中干燥;Step 2. Clean the semiconductor silicon substrate: first put the silicon substrate into a beaker filled with acetone and ultrasonically clean it for 15 minutes, then use alcohol to ultrasonically clean it for 15 minutes, and finally use deionized water to ultrasonically clean it for 15 minutes. Blow dry with nitrogen, and dry in oven;
步骤3、根据设计好的微结构尺寸设计并加工掩膜板后,首先把硅基片放入热氧化炉,采用干氧氧化方法生长3μm厚的二氧化硅掩膜层,然后利用半导体光刻工艺和ICP蚀刻技术加工硅衬底,先制作底层大尺寸圆柱,再制作最上层小尺寸圆柱,形成双层阶梯型圆柱微结构;Step 3. After designing and processing the mask plate according to the designed microstructure size, first put the silicon substrate into a thermal oxidation furnace, and grow a 3μm thick silicon dioxide mask layer by dry oxygen oxidation method, and then use semiconductor photolithography to Process and ICP etching technology to process the silicon substrate, first make the bottom large-size cylinder, and then make the uppermost small-size cylinder to form a double-layer stepped cylinder microstructure;
步骤4、制备掺杂硅叉指电极:首先选用上步骤中生长的SiO2层做热扩散掺杂的阻挡层,其次利用电磁仿真软件CST Microwave Studio仿真,使得叉指电极对太赫兹波的透射无影响,得到优化后叉指电极线条和线条间隙都为7um,利用光刻技术在阻挡层上制作叉指电极的图形,再干法蚀刻阻挡层形成叉指电极的掺杂沟槽;再使用P作为热扩散源;在预扩散实验时全程通入1L/min氮气流下,用50min将炉内温度升高至850℃,并在此温度下送入基片;15min升至1000℃,在1000℃保持40min,然后在30min内降温至850℃,取出基片,最后使用BOE水浴方法去除掉剩余二氧化硅阻挡层;Step 4. Preparation of doped silicon interdigitated electrodes: firstly, the SiO 2 layer grown in the previous step is selected as the barrier layer for thermal diffusion doping, and secondly, the electromagnetic simulation software CST Microwave Studio is used for simulation to make the interdigitated electrodes transmit terahertz waves No effect, after optimization, the interdigital electrode lines and line gaps are both 7um, use photolithography technology to make interdigital electrode patterns on the barrier layer, and then dry etch the barrier layer to form interdigital electrode doping grooves; then use P is used as a thermal diffusion source; during the pre-diffusion experiment, under the nitrogen flow of 1L/min, the temperature in the furnace is raised to 850°C in 50 minutes, and the substrate is sent into the substrate at this temperature; it is raised to 1000°C in 15 minutes, Keep at ℃ for 40min, then cool down to 850℃ within 30min, take out the substrate, and finally use BOE water bath method to remove the remaining silicon dioxide barrier layer;
步骤5、制备二氧化硅绝缘层:采用干氧氧化的方式,致密性更好;在1L/min氮气流下用50min的时间将炉内的温度升至850℃,并在此温度下送入基片;继续升温,此时改通氧气,流量为1L/min,15min后升至1000℃,保持30min;然后开始降温,30min内使炉内温度降到850℃,取出基片,经测试制备的二氧化硅厚度为50nm;此步骤同时也为上步骤中预扩散后的再扩散,这样制备的掺杂硅叉指电极性能更好,测得电极方阻为4Ω/口;Step 5. Preparation of silicon dioxide insulating layer: dry oxygen oxidation method is adopted, and the density is better; the temperature in the furnace is raised to 850°C for 50 minutes under a nitrogen flow of 1L/min, and sent into the base at this temperature Continue to heat up, change to oxygen at this time, the flow rate is 1L/min, rise to 1000°C after 15min, and keep it for 30min; then start to cool down, let the temperature in the furnace drop to 850°C within 30min, take out the substrate, and prepare the The thickness of silicon dioxide is 50nm; this step is also the re-diffusion after pre-diffusion in the previous step, so that the performance of the doped silicon interdigitated electrode prepared in this way is better, and the measured electrode square resistance is 4Ω/Ω;
步骤6、制备二氧化钒薄膜:利用射频磁控溅射方法,由高纯金属钒靶材在磁控溅射系统参数:射频功率180w-220w、工作气压1Pa、氧氩流量比4%-6%、加热温度550℃的条件下,在二氧化硅绝缘层上沉积200nm的二氧化钒薄膜;Step 6. Preparation of vanadium dioxide thin film: using radio frequency magnetron sputtering method, high-purity metal vanadium target is used in magnetron sputtering system parameters: radio frequency power 180w-220w, working pressure 1Pa, oxygen-argon flow ratio 4%-6 %, under the condition of a heating temperature of 550°C, deposit a 200nm vanadium dioxide film on the silicon dioxide insulating layer;
步骤7、利用太赫兹时域光谱系统THz-TDS对器件的太赫兹透射性能进行测试,太赫兹波由双层圆柱形微结构一侧入射,器件所加电压由恒压源提供,正负极连接到叉指电极的两端,加到所需电压后,即刻记录THz-TDS系统数据。Step 7. Use the terahertz time-domain spectroscopy system THz-TDS to test the terahertz transmission performance of the device. The terahertz wave is incident on one side of the double-layer cylindrical microstructure, and the voltage applied to the device is provided by a constant voltage source. Connect to both ends of the interdigital electrodes, and record the THz-TDS system data immediately after the required voltage is applied.
相关测试结果如下:The relevant test results are as follows:
图2(b)是本发明的具体实施方式所设计的硅基双层圆柱形微米结构实际测试透射率结果图,可看出在一定频带内该结构透射率达到85%以上,相比于同参数高阻裸硅片增大了15%以上,与图2(a)仿真数据对比可以看出达到了设计预期。Fig. 2 (b) is the actual test transmittance result figure of the silicon-based double-layer cylindrical microstructure designed in the specific embodiment of the present invention, it can be seen that the transmittance of this structure reaches more than 85% in a certain frequency band, compared with the same The parameter high-resistance bare silicon chip has increased by more than 15%. Compared with the simulation data in Figure 2(a), it can be seen that the design expectation has been achieved.
图3是本发明的具体实施方式所制备的二氧化钒薄膜随温度变化的方阻变化曲线和XRD,表明该薄膜在70℃附近发生相变,薄膜方阻变化超过3个数量级;XRD图谱显示薄膜单晶取向良好。Fig. 3 is the square resistance change curve and XRD of the vanadium dioxide thin film prepared according to the specific embodiment of the present invention as the temperature changes, showing that the film undergoes a phase transition near 70°C, and the thin film square resistance changes more than 3 orders of magnitude; the XRD pattern shows The single crystal orientation of the thin film is good.
对本发明所述调控器成品测试出的THz-TDS时域图谱4,再进行数据处理得到图5器件透射率拟合图和图6器件最大调控深度拟合图。从本发明的最终成品实际测试结果分析,可以看到在不加载电压的情况下,二氧化钒薄膜、SiO2绝缘层和制作的掺杂硅叉指电极对太赫兹波无插入损耗;随着加载电压的增大,太赫兹波的透射率不断降低,当电压加到3.5V,二氧化钒薄膜从绝缘相完全相变成金属相后,器件对太赫兹波的透射率下降到20%左右,通过计算得出整个器件的调控深度可达到76.5%以上,表明本发明所提供的太赫兹调控器具有低插入损耗和非常高的调控深度。The THz-TDS time-domain spectrum 4 tested by the finished controller of the present invention is then processed to obtain the fitting diagram of the transmittance of the device in Figure 5 and the fitting diagram of the maximum control depth of the device in Figure 6 . From the analysis of the actual test results of the final product of the present invention, it can be seen that under the condition of no applied voltage, the vanadium dioxide film, the SiO2 insulating layer and the fabricated doped silicon interdigitated electrodes have no insertion loss for the terahertz wave; As the applied voltage increases, the transmittance of the terahertz wave decreases continuously. When the voltage is increased to 3.5V, the vanadium dioxide film completely transforms from the insulating phase to the metal phase, and the transmittance of the device to the terahertz wave drops to about 20%. , it is calculated that the control depth of the whole device can reach more than 76.5%, indicating that the terahertz regulator provided by the present invention has low insertion loss and very high control depth.
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments only illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those skilled in the art without departing from the spirit and technical ideas disclosed in the present invention shall still be covered by the claims of the present invention.
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