CN108215358B - 一种太阳能电池背板及其制备方法 - Google Patents

一种太阳能电池背板及其制备方法 Download PDF

Info

Publication number
CN108215358B
CN108215358B CN201810002942.1A CN201810002942A CN108215358B CN 108215358 B CN108215358 B CN 108215358B CN 201810002942 A CN201810002942 A CN 201810002942A CN 108215358 B CN108215358 B CN 108215358B
Authority
CN
China
Prior art keywords
metal substrate
parts
fluororesin
rubber
eva
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201810002942.1A
Other languages
English (en)
Other versions
CN108215358A (zh
Inventor
张军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Yuanlian Technology Pioneer Park Management Co ltd
Original Assignee
Suzhou Yuanlian Technology Pioneer Park Management Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Yuanlian Technology Pioneer Park Management Co Ltd filed Critical Suzhou Yuanlian Technology Pioneer Park Management Co Ltd
Priority to CN201810002942.1A priority Critical patent/CN108215358B/zh
Publication of CN108215358A publication Critical patent/CN108215358A/zh
Application granted granted Critical
Publication of CN108215358B publication Critical patent/CN108215358B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/06—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H01L31/049—Protective back sheets
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/052—Cooling means directly associated or integrated with the PV cell, e.g. integrated Peltier elements for active cooling or heat sinks directly associated with the PV cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • B32B2038/166—Removing moisture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/06—Coating on the layer surface on metal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/302—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/31—Heat sealable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/12—Photovoltaic modules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Photovoltaic Devices (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

本发明提供一种太阳能电池背板及其制备方法。该太阳能电池背板的制备方法包括：1)在第一、第二、第三金属基板中分别形成多个过孔；2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理；3)依次层叠氟树脂外耐候层、第一金属基板、氟树脂‑橡胶复合层、第二金属基板、橡胶‑EVA复合层、第三金属基板以及EVA层；4)进行热压合处理，以得到所述太阳能电池背板。该方法制备的太阳能电池背板具有优异的密封性能、绝缘性能以及散热性能，进而可以提高相应太阳能电池组件的抗PID性能。

Description

一种太阳能电池背板及其制备方法
技术领域
本发明涉及太阳能电池技术领域，特别是涉及一种太阳能电池背板及其制备方法。
背景技术
晶体硅太阳能电池由于效率高、制造工艺成熟而得到广泛的应用。相应的晶体硅太阳能组件通常包括钢化玻璃、胶层、电池片层、胶层以及太阳能电池电池背板，太阳能电池背板位于太阳能电池组件的背面，对电池片起保护和支撑作用，具有可靠的绝缘性、阻水性、耐老化性。现有的太阳能电池背板通常分为两种：一种为涂胶复合式背板膜，在PET聚酯薄膜两面复合氟膜或者EVA胶膜，三层结构，常见的有TPT、TPE、KPK等结构。一种为涂覆背板膜，在PET聚酯薄膜两面涂覆氟树脂，经干燥固化成膜。
潜在电势诱导衰减(PotentialInducedDegradation，PID)是太阳能电池组件的一种特性，指在高温多湿环境下，高电压流经太阳能电池单元便会导致输出下降的现象。然而现有的太阳能电池背板的导热性能相对较差、密封性能相对较差，进而导致其不具备抗PID性能。如何提高太阳能电池背板的导热性能和密封性能，进而提高相应太阳能电池组件的抗PID性能，其引起了人们的广泛关注。
发明内容
本发明的目的是克服上述现有技术的不足，提供一种太阳能电池背板及其制备方法。
为实现上述目的，本发明提出的一种太阳能电池背板的制备方法，包括以下步骤：1)在第一金属基板、第二金属基板以及第三金属基板中分别形成多个过孔；2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理；3)在所述第一金属基板的下表面铺设氟树脂外耐候层，在所述第一金属基板的上表面铺设氟树脂-橡胶复合层，接着在所述氟树脂-橡胶复合层上铺设所述第二金属基板，接着在所述第二金属基板的上表面铺设橡胶-EVA复合层，接着在所述橡胶-EVA复合层上铺设所述第三金属基板，接着在所述第三金属基板的上表面铺设EVA层；4)进行热压合处理，使得所述氟树脂外耐候层、所述氟树脂-橡胶复合层、所述橡胶-EVA复合层以及所述EVA层各自的一部分进入与上述各层分别相邻的金属基板的各个过孔中，以得到所述太阳能电池背板。
作为优选的，所述步骤2)中的所述干燥处理的温度为70-120℃以及时间为50-90秒。
作为优选的，所述步骤4)中的热压合处理的具体工艺为：在100-120℃的温度下，以压力增加速率为每分钟增加1-3Kg/cm2的条件将压力增至15-20Kg/cm2，保持10-20分钟，接着以压力增加速率为每分钟增加4-6Kg/cm2的条件将压力增至40-50Kg/cm2，保持20-30分钟，接着以压力降低速率为4-6Kg/cm2的条件将压力降至15-20Kg/cm2，保持5-10分钟，接着以压力降低速率为1-2Kg/cm2的条件将压力降为0，然后在50-80℃的条件下固化70-100小时,最后冷却至室温。
作为优选的，所述氟树脂外耐候层包括：氟树脂100份，导热纳米颗粒10-20份，玻璃纤维5-10份。
作为优选的，所述氟树脂-橡胶复合层包括：氟树脂60-80份，橡胶60-80份；导热纳米颗粒20-30份；碳纤维10-20份。
作为优选的，所述橡胶-EVA复合层包括：橡胶50-70份，EVA40-60份，导热纳米颗粒10-20份；碳纤维10-15份。
作为优选的，所述EVA层包括：EVA100份，导热绝缘纳米颗粒10-20份，玻璃纤维10-15份。
作为优选的，所述第一、第二、第三金属基板中的多个过孔呈矩阵排列，过孔的直径为3-5毫米，相邻过孔之间的间距为5-10毫米。
本发明还提供了一种太阳能电池背板，所述太阳能电池背板为采用上述方法制备形成的。
本发明的太阳能电池背板包括三个金属基板，且每个金属基板中均具有多个过孔，且在每个金属基板的上下表面的树脂层通过过孔粘结在一起，各树脂层中均具有导热纳米颗粒，且通过优化过孔的直径和间距，提高树脂层与金属板之间的粘结性能，使得该太阳能电池背板具有优异的密封性能、绝缘性能以及散热性能，进而可以提高相应太阳能电池组件的抗PID性能，此外金属基板之间具有氟树脂-橡胶复合层以及所述橡胶-EVA复合层，使得该太阳能电池背板具有优异的抗震性能，有效减少相应太阳能电池组件由于碰撞导致损坏的几率。此外，本发明的制备方法与现有技术相比还具有如下有益效果：通过优化热压合处理工艺，压力采用先逐渐增加压力，并进行阶段性热压处理，然后再逐渐降低压力，使得在整个热压合过程中太阳能电池背板的受力更均匀，进而制备的太阳能电池背板的致密性更高、综合性能更优越，本发明的制备方法简单，易于工业生产。
附图说明
图1为本发明的太阳能电池背板的结构示意图。
图2为本发明的太阳能电池背板中的金属基板的俯视结构图。
具体实施方式
一种太阳能电池背板的制备方法，包括以下步骤：1)在第一金属基板、第二金属基板以及第三金属基板中分别形成多个过孔；2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理；3)在所述第一金属基板的下表面铺设氟树脂外耐候层，在所述第一金属基板的上表面铺设氟树脂-橡胶复合层，接着在所述氟树脂-橡胶复合层上铺设所述第二金属基板，接着在所述第二金属基板的上表面铺设橡胶-EVA复合层，接着在所述橡胶-EVA复合层上铺设所述第三金属基板，接着在所述第三金属基板的上表面铺设EVA层；4)进行热压合处理，使得所述氟树脂外耐候层、所述氟树脂-橡胶复合层、所述橡胶-EVA复合层以及所述EVA层各自的一部分进入与上述各层分别相邻的金属基板的各个过孔中，以得到所述太阳能电池背板。
其中，所述步骤2)中的所述干燥处理的温度为70-120℃以及时间为50-90秒。所述步骤4)中的热压合处理的具体工艺为：在100-120℃的温度下，以压力增加速率为每分钟增加1-3Kg/cm2的条件将压力增至15-20Kg/cm2，保持10-20分钟，接着以压力增加速率为每分钟增加4-6Kg/cm2的条件将压力增至40-50Kg/cm2，保持20-30分钟，接着以压力降低速率为4-6Kg/cm2的条件将压力降至15-20Kg/cm2，保持5-10分钟，接着以压力降低速率为1-2Kg/cm2的条件将压力降为0，然后在50-80℃的条件下固化70-100小时,最后冷却至室温。所述氟树脂外耐候层包括：氟树脂100份，导热纳米颗粒10-20份，玻璃纤维5-10份。所述氟树脂-橡胶复合层包括：氟树脂60-80份，橡胶60-80份；导热纳米颗粒20-30份；碳纤维10-20份。所述橡胶-EVA复合层包括：橡胶50-70份，EVA40-60份，导热纳米颗粒10-20份；碳纤维10-15份。所述EVA层包括：EVA100份，导热绝缘纳米颗粒10-20份，玻璃纤维10-15份。所述第一、第二、第三金属基板中的多个过孔呈矩阵排列，过孔的直径为3-5毫米，相邻过孔之间的间距为5-10毫米，所述第一、第二、第三金属基板的材质优选为铝或铜。
本发明还提供了一种太阳能电池背板，所述太阳能电池背板为采用上述方法制备形成的。如图1-2所示，所述太阳能电池背板包括氟树脂外耐候层1、第一金属基板2、氟树脂-橡胶复合层3、第二金属基板4、橡胶-EVA复合层5、第三金属基板6以及EVA层7，第一金属基板2、第二金属基板4以及第三金属基板6均具有多个过孔8，所述氟树脂外耐候层1、所述氟树脂-橡胶复合层3、所述橡胶-EVA复合层5以及所述EVA层7各自的一部分进入与上述各层分别相邻的金属基板的各个过孔8中，上述各树脂层在各过孔8中相互粘结在一起。
实施例1：
一种太阳能电池背板的制备方法，包括以下步骤：
1)在第一金属基板、第二金属基板以及第三金属基板中分别形成多个过孔，所述第一、第二、第三金属基板中的多个过孔呈矩阵排列，过孔的直径为4毫米，相邻过孔之间的间距为8毫米，所述所述第一、第二、第三金属基板的材质为铝；
2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理，所述干燥处理的温度为100℃以及时间为60秒；
3)在所述第一金属基板的下表面铺设氟树脂外耐候层，在所述第一金属基板的上表面铺设氟树脂-橡胶复合层，接着在所述氟树脂-橡胶复合层上铺设所述第二金属基板，接着在所述第二金属基板的上表面铺设橡胶-EVA复合层，接着在所述橡胶-EVA复合层上铺设所述第三金属基板，接着在所述第三金属基板的上表面铺设EVA层，其中，所述氟树脂外耐候层包括：氟树脂100份，导热纳米颗粒15份，玻璃纤维8份。所述氟树脂-橡胶复合层包括：氟树脂70份，橡胶70份；导热纳米颗粒25份；碳纤维15份。所述橡胶-EVA复合层包括：橡胶60份，EVA50份，导热纳米颗粒15份；碳纤维12份。所述EVA层包括：EVA100份，导热绝缘纳米颗粒15份，玻璃纤维12份；
4)进行热压合处理，热压合处理的具体工艺为：在110℃的温度下，以压力增加速率为每分钟增加2Kg/cm2的条件将压力增至18Kg/cm2，保持15分钟，接着以压力增加速率为每分钟增加5Kg/cm2的条件将压力增至48Kg/cm2，保持25分钟，接着以压力降低速率为5Kg/cm2的条件将压力降至18Kg/cm2，保持7分钟，接着以压力降低速率为2Kg/cm2的条件将压力降为0，然后在70℃的条件下固化80小时,最后冷却至室温，使得所述氟树脂外耐候层、所述氟树脂-橡胶复合层、所述橡胶-EVA复合层以及所述EVA层各自的一部分进入与上述各层分别相邻的金属基板的各个过孔中，上述各树脂层在各过孔中相互粘结在一起，以得到所述太阳能电池背板。
将上述方法制备的太阳能电池背板进行性能测试，结果表明，其与太阳能电池组件EVA胶层的剥离强度为150N/cm，水汽透过率为0.15g/m2*d，导热系数为19.58W/m*k。
实施例2：
一种太阳能电池背板的制备方法，包括以下步骤：
1)在第一金属基板、第二金属基板以及第三金属基板中分别形成多个过孔，所述第一、第二、第三金属基板中的多个过孔呈矩阵排列，过孔的直径为5毫米，相邻过孔之间的间距为5毫米，所述第一、第二、第三金属基板的材质为铜；
2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理，所述干燥处理的温度为80℃以及时间为80秒；
3)在所述第一金属基板的下表面铺设氟树脂外耐候层，在所述第一金属基板的上表面铺设氟树脂-橡胶复合层，接着在所述氟树脂-橡胶复合层上铺设所述第二金属基板，接着在所述第二金属基板的上表面铺设橡胶-EVA复合层，接着在所述橡胶-EVA复合层上铺设所述第三金属基板，接着在所述第三金属基板的上表面铺设EVA层，所述氟树脂外耐候层包括：氟树脂100份，导热纳米颗粒20份，玻璃纤维10份。所述氟树脂-橡胶复合层包括：氟树脂80份，橡胶60份；导热纳米颗粒30份；碳纤20份。所述橡胶-EVA复合层包括：橡胶50份，EVA60份，导热纳米颗粒18份；碳纤维15份。所述EVA层包括：EVA100份，导热绝缘纳米颗粒20份，玻璃纤维15份。；
4)进行热压合处理，热压合处理的具体工艺为：在100℃的温度下，以压力增加速率为每分钟增加1Kg/cm2的条件将压力增至15Kg/cm2，保持20分钟，接着以压力增加速率为每分钟增加6Kg/cm2的条件将压力增至50Kg/cm2，保持20分钟，接着以压力降低速率为4Kg/cm2的条件将压力降至15Kg/cm2，保持10分钟，接着以压力降低速率为2Kg/cm2的条件将压力降为0，然后在60℃的条件下固化90小时,最后冷却至室温，使得所述氟树脂外耐候层、所述氟树脂-橡胶复合层、所述橡胶-EVA复合层以及所述EVA层各自的一部分进入与上述各层分别相邻的金属基板的各个过孔中，上述各树脂层在各过孔中相互粘结在一起，以得到所述太阳能电池背板。
将上述方法制备的太阳能电池背板进行性能测试，结果表明，其与太阳能电池组件EVA胶层的剥离强度为145N/cm，水汽透过率为0.26g/m2*d，导热系数为25.62W/m*k。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (9)

1.一种太阳能电池背板的制备方法，其特征在于：包括以下步骤：
1)在第一金属基板、第二金属基板以及第三金属基板中分别形成多个过孔；
2)在所述第一、第二、第三金属基板的各自的上表面和下表面分别涂刷粘结剂，并进行干燥处理；
3)在所述第一金属基板的下表面铺设氟树脂外耐候层，在所述第一金属基板的上表面铺设氟树脂-橡胶复合层，接着在所述氟树脂-橡胶复合层上铺设所述第二金属基板，接着在所述第二金属基板的上表面铺设橡胶-EVA复合层，接着在所述橡胶-EVA复合层上铺设所述第三金属基板，接着在所述第三金属基板的上表面铺设EVA层；
4)进行热压合处理，使得所述氟树脂外耐候层、所述氟树脂-橡胶复合层、所述橡胶-EVA复合层以及所述EVA层各自的一部分进入与上述各层分别相邻的金属基板的各个过孔中，以得到所述太阳能电池背板。
2.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述步骤2)中的所述干燥处理的温度为70-120℃以及时间为50-90秒。
3.根据权利要求2所述的太阳能电池背板的制备方法，其特征在于：所述步骤4)中的热压合处理的具体工艺为：在100-120℃的温度下，以压力增加速率为每分钟增加1-3Kg/cm2的条件将压力增至15-20Kg/cm2，保持10-20分钟，接着以压力增加速率为每分钟增加4-6Kg/cm2的条件将压力增至40-50Kg/cm2，保持20-30分钟，接着以压力降低速率为4-6Kg/cm2的条件将压力降至15-20Kg/cm2，保持5-10分钟，接着以压力降低速率为1-2Kg/cm2的条件将压力降为0，然后在50-80℃的条件下固化70-100小时,最后冷却至室温。
4.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述氟树脂外耐候层包括：氟树脂100份，导热纳米颗粒10-20份，玻璃纤维5-10份。
5.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述氟树脂-橡胶复合层包括：氟树脂60-80份，橡胶60-80份；导热纳米颗粒20-30份；碳纤维10-20份。
6.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述橡胶-EVA复合层包括：橡胶50-70份，EVA40-60份，导热纳米颗粒10-20份；碳纤维10-15份。
7.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述EVA层包括：EVA100份，导热绝缘纳米颗粒10-20份，玻璃纤维10-15份。
8.根据权利要求1所述的太阳能电池背板的制备方法，其特征在于：所述第一、第二、第三金属基板中的多个过孔呈矩阵排列，过孔的直径为3-5毫米，相邻过孔之间的间距为5-10毫米。
9.一种太阳能电池背板，其特征在于，采用权利要求1-8任一项所述的方法制备形成的。
CN201810002942.1A 2018-01-02 2018-01-02 一种太阳能电池背板及其制备方法 Expired - Fee Related CN108215358B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810002942.1A CN108215358B (zh) 2018-01-02 2018-01-02 一种太阳能电池背板及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810002942.1A CN108215358B (zh) 2018-01-02 2018-01-02 一种太阳能电池背板及其制备方法

Publications (2)

Publication Number Publication Date
CN108215358A CN108215358A (zh) 2018-06-29
CN108215358B true CN108215358B (zh) 2019-12-06

Family

ID=62645106

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810002942.1A Expired - Fee Related CN108215358B (zh) 2018-01-02 2018-01-02 一种太阳能电池背板及其制备方法

Country Status (1)

Country Link
CN (1) CN108215358B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2026972B1 (en) * 2020-11-25 2022-07-04 Atlas Technologies Holding Bv Solar panel with a composite laminate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550770A (zh) * 2018-11-23 2019-04-02 浙江晶科能源有限公司 一种报废光伏背板无害化处理的方法和装置

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6081017A (en) * 1998-05-28 2000-06-27 Samsung Electronics Co., Ltd. Self-biased solar cell and module adopting the same
CN202434552U (zh) * 2011-12-16 2012-09-12 新高电子材料（中山）有限公司 用耐候性高导热率涂层制作的太阳能背板及太阳能电池板
WO2013182954A2 (en) * 2012-06-05 2013-12-12 Ebfoil S.R.L. Encapsulating layer adapted to be applied to back-sheets for photovoltaic modules including back-contact cells
CN103972315B (zh) * 2013-01-25 2017-07-04 纳幕尔杜邦公司 集成式背板、背接触式光生伏打模块及其生产方法
CN204189809U (zh) * 2014-11-28 2015-03-04 明冠新材料股份有限公司 一种高散热耐污型太阳能电池背板

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2026972B1 (en) * 2020-11-25 2022-07-04 Atlas Technologies Holding Bv Solar panel with a composite laminate

Also Published As

Publication number Publication date
CN108215358A (zh) 2018-06-29

Similar Documents

Publication Publication Date Title
CN108022989B (zh) 一种双面玻璃光伏建材构件及其制备方法
US20090272436A1 (en) Non-glass photovoltaic module and methods for manufacture
WO2013086814A1 (zh) 耐候、高导热涂层和散热太阳能背板及高效太阳能电池板
CN108215358B (zh) 一种太阳能电池背板及其制备方法
CN113013297A (zh) 一种无栅线异质结电池组件的制备方法
CN103560164A (zh) 一种含氟散热型太阳能电池背板
JP2016187061A (ja) 薄膜系太陽電池モジュール、及び薄膜系太陽電池モジュールの製造方法
US20240178334A1 (en) Method for manufacturing photovoltaic module and photovoltaic module
WO2014153997A1 (zh) 太阳能电池背板及太阳能电池组件
CN108183146A (zh) 一种散热型光伏背板及其制备方法
CN107968131B (zh) 太阳能电池背板、其制备方法和含有其的太阳能电池组件
WO2021212804A1 (zh) 金属基复合背板、生产方法及装置及光伏瓦
CN1950954A (zh) 光伏系统及其制造方法
CN104347741A (zh) 一种柔性透光光伏组件及其制备方法
CN102738280A (zh) 一种太阳能电池背膜
JP2012079838A (ja) 太陽電池モジュールとその製造方法
JP2002111014A (ja) 太陽光発電プラスチックモジュール
CN202434552U (zh) 用耐候性高导热率涂层制作的太阳能背板及太阳能电池板
CN104409547A (zh) 一种散热型太阳能电池背板结构及其制备方法
TWI599059B (zh) 弧彎透光組件、其用途及其製作方法
JP5652911B2 (ja) 太陽電池モジュールの製造方法
EP2474043B1 (en) Solar battery assembly and method for forming the same
JPH04116987A (ja) 太陽電池モジュールの製造方法
CN112646339A (zh) 一种抗力学冲击的封装胶膜、制备工艺及光伏组件
CN201523014U (zh) 太阳能光伏电池绝缘背板

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20191114

Address after: 215131 no.959, Jiayuan Road, Yuanhe street, Xiangcheng District, Suzhou City, Jiangsu Province

Applicant after: Suzhou Yuanlian Technology Pioneer Park Management Co.,Ltd.

Address before: No. 1701 Binhe Road, Suzhou High-tech Zone, Suzhou City, Jiangsu Province

Applicant before: SUZHOU BAOLAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd.

GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20191206