CN108207993A - A kind of Pesticidal combination and application containing fenbutatin oxide - Google Patents
A kind of Pesticidal combination and application containing fenbutatin oxide Download PDFInfo
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- CN108207993A CN108207993A CN201711474398.2A CN201711474398A CN108207993A CN 108207993 A CN108207993 A CN 108207993A CN 201711474398 A CN201711474398 A CN 201711474398A CN 108207993 A CN108207993 A CN 108207993A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
- A01N55/04—Tin
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Abstract
The invention discloses a kind of Pesticidal combinations containing fenbutatin oxide, are prepared by the component as follows in terms of mass percentage:30 80%A components, 10 25%B components and 10 60%C components;Wherein, component A is fenbutatin oxide, and B component is auxiliary agent, and component C is solvent or filler;The sum of said components mass percentage is 100%.The present invention also provides a kind of Pesticidal combination containing fenbutatin oxide in the application for preparing missible oil, suspending agent, aqueous emulsion, soluble concentrate, wettable powder or water-dispersible granules.The Pesticidal combination containing fenbutatin oxide of the present invention, the composition is prepared by fenbutatin oxide, auxiliary agent and solvent or filler, and the composition can be needed to configure according to difference as different dosage forms, reduces using and transportation cost, environmentally friendly, is readily transported and stores.
Description
Technical field
The present invention relates to pesticide medicine field more particularly to a kind of Pesticidal combinations and application containing fenbutatin oxide.
Background technology
Fenbutatin oxide inhibits the organotin acaricide of nerve fiber for temperature sensitive type.Structural formula is as follows:
Active compound is colorless crystalline powder, and active constituent content is up to 97%, 138-139 DEG C of fusing point, and vapour pressure is at 25 DEG C
6.7×10-6Pa.Water is insoluble in, is dissolved in acetone, is soluble in the organic solvents such as benzene, dichloromethane.To light and thermally stable, water energy is met
Be hydrolyzed, hydrolysate at room temperature can slowly (can be soon at 98 DEG C) be transformed into former compound again.In suitable condition
Lower storage is relatively stablized.To higher mammal low toxicity, to the aquatiles high poison such as fish, to birds, honeybee low toxicity, evil mite natural enemy is caught
It is safer to eat mite, carnivorism ladybug, Chrysopa etc..Acaricidal activity is higher, mainly plays action of contace poison, to young mite and into, deutonymph lethality
It is relatively strong, it is little to the lethality of mite ovum, there is the evil mite no interactions drug resistance of drug resistance to organophosphor, organochlorine insecticide.It can use
In fruit tree, tea tree, flowers and other crops, prevention citrus reticulata leaf spiders, citrus rust mite, apple tetranychus, pink tea rust mite, privet mite, chrysanthemum
Tetranychid, rose tetranychid etc..The existing pesticide including fenbutatin oxide is mainly solvent, solvent inconvenience transport, and inconvenient storage.
Invention content
For overcome the deficiencies in the prior art, one of the objects of the present invention is to provide a kind of Insecticidal combinations containing fenbutatin oxide
Object, the composition are prepared by fenbutatin oxide, auxiliary agent and solvent or filler, and the dosage form of the composition can be missible oil, suspend
Agent, aqueous emulsion, soluble concentrate, wettable powder or water-dispersible granules can be needed to configure according to difference as different dosage forms,
Use and transportation cost are reduced, it is environmentally friendly, it is readily transported and stores.
The second object of the present invention is that providing a kind of Pesticidal combination containing fenbutatin oxide is preparing missible oil, suspending agent, water
The application of emulsion, soluble concentrate, wettable powder or water-dispersible granules, various types are readily transported and store.
An object of the present invention adopts the following technical scheme that realization:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Component A 30-80%
B component 10-25%
Component C 10-60%;
Wherein, component A is fenbutatin oxide, and B component is auxiliary agent, and component C is solvent or filler;Said components mass percentage
The sum of be 100%.
Further, the auxiliary agent be emulsifier, it is dispersant, wetting agent, bleeding agent, pH conditioning agents, disintegrant, antifreeze
One or more of agent, preservative, antifoaming agent and thickener.
Further, the emulsifier is alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, glycerine fatty acid polyoxy
Vinethene, phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil ethylene oxide adduct, alkane
Base phenol polyethenoxy ether formaldehyde condensation products, alkyl phenol polyoxyethylene ether phosphate, phenethyl phenol polyethenoxy ether phosphate, 12
One or more of alkyl benzene calcium sulfonate and neopelex;The dispersant is polycarboxylate, lignin
Sulfonate, alkyl phenol polyoxyethylene ether, APES formaldehyde condensation products sulfat, alkylnaphthalene sulfonate, alkylbenzene
One or both of sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether and aliphatic acid polyethenoxy ether
More than.
Further, the wetting agent is neopelex, dodecyl sodium naphthalene sulfonate, dodecyl phenyl-hydrogen-sulfate
Sodium, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonate and gleditsia sinensis
One or more of powder;The bleeding agent is sulfated castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfide
Acid esters sodium, sodium secondary alkyl sulfonate, secondary alkyl sulphate sodium, Negel, succinic acid alkyl ester sulfonate sodium, Igepon T, ammonia
One or both of base sodium sulfonate, fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyethers and phosphate compounds
More than.
Further, the pH adjusting agent for citric acid, lactic acid, tartaric acid, malic acid, metatartaric acid, phosphoric acid, acetic acid,
Hydrochloric acid, hexanedioic acid, fumaric acid, sodium hydroxide, potassium carbonate, sodium carbonate, sodium citrate, potassium citrate, sodium sesquicarbonate and lemon
One or more of sour sodium;The disintegrant is bentonite, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate, lemon
One or more of acid and aluminium chloride.
Further, the preservative is benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate, fumaric acid two
One or more of methyl esters and benzoisothiazolinone;The antifreezing agent for ethylene glycol, propylene glycol, glycerine or urea and
The one or more of sodium chloride.
Further, the antifoaming agent for silicone oil, organosilicon ketone, C8-C10 fatty alcohols, C8-C20 saturated fatty acids and
One or more of C8-C20 polyunsaturated fatty acid esters;The thickener is carboxymethyl cellulose, carboxyethyl cellulose, first
One or both of base cellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, xanthans and polyvinyl alcohol aluminum magnesium silicate with
On.
Further, the filler is talcum powder, kaolin, clay, diatomite, White Carbon black, attapulgite, starch, sulphur
One or more of sour sodium, sodium metasilicate, ammonium sulfate, sodium bicarbonate, bentonite, ammonium chloride and precipitated calcium carbonate.
Further, the solvent is methanol, ethyl alcohol, isobutanol, ethyl acetate, sec-Butyl Acetate, oleic acid potassium ester, mineral
Oil, soybean oil, dimethylformamide, dimethylacetylamide, dimethyl carbonate, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, ring are
One or more of ketone, toluene, dimethylbenzene, solvent naphtha, chloroform and deionized water.
The second object of the present invention adopts the following technical scheme that realization:
It is a kind of to prepare missible oil, suspending agent, aqueous emulsion, soluble concentrate, wettable using the Pesticidal combination containing fenbutatin oxide
Application in the pesticidal preparations of pulvis or water-dispersible granules.
Compared with prior art, the beneficial effects of the present invention are:
(1) Pesticidal combination containing fenbutatin oxide of the invention, the composition is by fenbutatin oxide, auxiliary agent and solvent or filler system
It is standby to form, it can be needed to configure according to difference as different dosage forms, reduce using and transportation cost, it is environmentally friendly, convenient for fortune
Defeated and storage;
(2) dosage form of the Pesticidal combination containing fenbutatin oxide of the invention can be missible oil, suspending agent, aqueous emulsion, can solution
Agent, wettable powder or water-dispersible granules are readily transported and store.
Specific embodiment
In the following, with reference to specific embodiment, the present invention is described further, it should be noted that is do not collided
Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Component A 30-80%
B component 10-25%
Component C 10-60%;
Wherein, component A is fenbutatin oxide, and B component is auxiliary agent, and component C is solvent or filler;Said components mass percentage
The sum of be 100%.
As the mode that further carries out, auxiliary agent is emulsifier, dispersant, wetting agent, bleeding agent, pH adjusting agent, disintegration
One or more of agent, antifreezing agent, preservative, antifoaming agent and thickener.
As the mode that further carries out, emulsifier is alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, glyceride
Fat acid polyoxyethylene ether, phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, castor oil ethylene oxide add
Into object, APES formaldehyde condensation product, alkyl phenol polyoxyethylene ether phosphate, phenethyl phenol polyethenoxy ether phosphoric acid
One or more of ester, calcium dodecyl benzene sulfonate and neopelex;Dispersant is polycarboxylate, wooden
Plain sulfonate, alkyl phenol polyoxyethylene ether, APES formaldehyde condensation products sulfat, alkylnaphthalene sulfonate, alkyl
One kind in benzene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether and aliphatic acid polyethenoxy ether or two
Kind or more.
As the mode that further carries out, wetting agent is neopelex, dodecyl sodium naphthalene sulfonate, dodecane
Base phenyl-hydrogen-sulfate sodium, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonic acid
One or more of salt and spaonin powder;Bleeding agent is sulfated castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkane
Base sodium sulfovinate, sodium secondary alkyl sulfonate, secondary alkyl sulphate sodium, Negel, succinic acid alkyl ester sulfonate sodium, pancreas add drift
T, one kind in sulfamic acid sodium, fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyethers and phosphate compounds or
It is two or more.
As the mode that further carries out, pH adjusting agent is citric acid, lactic acid, tartaric acid, malic acid, metatartaric acid, phosphorus
Acid, acetic acid, hydrochloric acid, hexanedioic acid, fumaric acid, sodium hydroxide, potassium carbonate, sodium carbonate, sodium citrate, potassium citrate, bicarbonate three
One or more of sodium and sodium dihydrogen citrate;Disintegrant for bentonite, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate,
One or more of citric acid and aluminium chloride.
As the mode that further carries out, preservative is benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate,
One or more of dimethyl fumarate and benzoisothiazolinone;Antifreezing agent is ethylene glycol, propylene glycol, glycerine or urine
The one or more of element and sodium chloride.
As the mode that further carries out, antifoaming agent is silicone oil, organosilicon ketone, C8-C10 fatty alcohols, C8-C20 saturations
One or more of aliphatic acid and C8-C20 polyunsaturated fatty acid esters;Thickener is carboxymethyl cellulose, carboxyethylcellulose
Element, methylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, xanthans and one kind in polyvinyl alcohol aluminum magnesium silicate or
It is two or more.
As the mode that further carries out, filler is talcum powder, kaolin, clay, diatomite, White Carbon black, attapulgite,
One or both of starch, sodium sulphate, sodium metasilicate, ammonium sulfate, sodium bicarbonate, bentonite, ammonium chloride and precipitated calcium carbonate with
On.
As the mode that further carries out, solvent is methanol, ethyl alcohol, isobutanol, ethyl acetate, sec-Butyl Acetate, oleic acid
Potassium ester, mineral oil, soybean oil, dimethylformamide, dimethylacetylamide, dimethyl carbonate, dimethyl sulfoxide (DMSO), N- methylpyrroles
One or more of alkanone, cyclohexanone, toluene, dimethylbenzene, solvent naphtha, chloroform and deionized water.
The above-mentioned Pesticidal combination containing fenbutatin oxide, which can be applicable to, prepares missible oil, suspending agent, aqueous emulsion, soluble concentrate, wettable
In the pesticidal preparations of property pulvis or water-dispersible granules.
Missible oil is one kind of pesticidal preparations, it be by the dissolving of the active ingredient of higher concentration in a solvent, add emulsifier and
Into liquid.
Suspending agent refers to the preparation being dispersed in solid pesticide active compound with less than 4 microns of particle in water.
Aqueous emulsion is to disperse liquid or the liquid pesticidal active compound being mixed to prepare with solvent with 0.5-1.5 microns of droplet
Preparation in water.
Soluble concentrate refers to, to being in that the pesticide original medicine of slightly soluble state is equipped with a large amount of Hydrophilic polar solvents in water, be aided with
Obtained a kind of formulations of pesticide that can be dissolved in water in use after cosolvent and emulsifier.
Wettable powder is the powderous preparations for being dispersed among being formed stable suspension in water.
Water-dispersible granules are also known as dry suspending agent or grain shape wettable powder, once it into the water, can be disintegrated, divide quickly
It dissipates, forms the granular preparation of the solid-liquid dispersing system of higher suspension.
It is specific embodiment of the present invention below, used raw material, equipment etc. remove special limit in the following embodiments
It can be obtained outside fixed by buying pattern.
Embodiment 1:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, is crushed through airslide disintegrating mill, obtaining 70% fenbutatin oxide can
Wet powder.
Embodiment 2
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, after airslide disintegrating mill crushes, granulating and drying obtains
60% fenbutatin oxide water-dispersible granules.
Embodiment 3:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, after airslide disintegrating mill crushes, granulating and drying obtains
70% fenbutatin oxide water-dispersible granules.
Embodiment 4:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, through being sanded, obtains 50% fenbutatin oxide suspending agent.
Embodiment 5:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, clipped sand milling obtains 40% fenbutatin oxide suspending agent.
Embodiment 6:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:It after each component is dissolved by proportioning, is uniformly mixed, obtains 50% fenbutatin oxide missible oil.
Embodiment 7:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:It after each component is dissolved by proportioning, is uniformly mixed, obtains 40% fenbutatin oxide missible oil.
Embodiment 8:
A kind of Pesticidal combination containing fenbutatin oxide is prepared by the component as follows in terms of mass percentage:
Preparation method is:Each component is uniformly mixed by proportioning, it is dispersible to obtain 30% fenbutatin oxide for clipped sand milling
Oil-suspending agent.
Comparative example 1:
1 difference from Example 1 of comparative example is that the fenbutatin oxide content of comparative example 1 is 20%, and kaolin content is
65%.
Comparative example 2:
2 difference from Example 1 of comparative example is that the fenbutatin oxide content of comparative example 2 is 90%, dioctyl succinate
Sodium sulfonate is 2%, and kaolin content is 3%.
Effect assessment and performance detection
Experiment name:The Pesticidal combination prevention citrus blister mite field of fenbutatin oxide can the test of pesticide effectiveness
1. trial crops:Phase tangerine
2. controlling object:Blister mite (Phyllocoptruta oleivora)
3. environmental condition:One citrus arboretum of chrysanthemum town Gu Tang villages is experimental field located at, soil cultivation level is medium, plaster field soil
Matter, fertility is preferable, and irrigation and drainage are convenient, and field management routinely carries out, and does not spray other insecticidal/acaricidal agents.It is citrus nutrition during experiment
In growth period, grow more uniform consistent, citrus blister mite quantity is medium during dispenser.
4. application method and water consumption:It is measured in explosive barrel with measuring pipette respectively by processing requirement, adds in a small amount of water and stir
It is even, it adds after remaining water is sufficiently stirred and pours into sharp agriculture HD400 types and gnaw in day with fog;Using conventional spray-on process, spray one by one,
Every plant of spraying liquid 2L, even spraying pay attention to spraying vacuum side of blade and fruit in citrus complete stool.
5. computational methods:
6. statistical methods for experiment
The statistical analysis of test data is carried out using DPSV7.05 softwares, is compared with Deng Kenshi duncan's new multiple range methods (DMRT)
The difference degree of effect between each processing.
Pharmacodynamic results are as shown in the table:
1 embodiment 1-8 of table and comparative example 1-2 pharmacodynamic results
Note:With Duncan, newly multiple differential method is test, and has difference not significantly (small letter between same letter person expression processing in table
Female p=0.05, capitalization p=0.01)
7. result and analysis
70% fenbutatin oxide wettable powder that the Pesticidal combination of the fenbutatin oxide of embodiment 1-8 is applied respectively, 60% benzene fourth
Tin water-dispersible granules, 70% fenbutatin oxide water-dispersible granules, 50% fenbutatin oxide suspending agent, 40% fenbutatin oxide suspending agent, 50%
Fenbutatin oxide missible oil, 40% fenbutatin oxide missible oil and the dispersible oil-suspending agent of 30% fenbutatin oxide, can be with by field control effectiveness test result
Find out, the application of the Pesticidal combination of the fenbutatin oxide of embodiment 1-8 can effectively preventive effect, and respectively handle for 28 days after medicine
Preventive effect shows excellent lasting effect, and entirely during experiment, does not find to apply trial drug to for trying still above 96%
The blade of crop, fruit and plant generate any poisoning, also do not find that it generates harmful effect to ambient enviroment.Comparative example 1-2
Effect be worse than the effect of embodiment 1-8, this illustrates that the effect of the Pesticidal combination of the fenbutatin oxide of the present invention is by specific
Component and proportioning synergy obtain, fenbutatin oxide too high levels or too low or lack wherein certain component and cannot reach corresponding
Effect.This illustrate the present invention the Pesticidal combination containing fenbutatin oxide no matter be applied to missible oil, suspending agent, aqueous emulsion, soluble concentrate,
In the pesticidal preparations of wettable powder or water-dispersible granules, the parasitosis such as citrus blister mite can be prevented, quick-acting is preferable, holds
Effect property is excellent.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed range.
Claims (10)
1. a kind of Pesticidal combination containing fenbutatin oxide, which is characterized in that it is by the component system as follows in terms of mass percentage
It is standby to form:
Component A 30-80%
B component 10-25%
Component C 10-60%;
Wherein, component A is fenbutatin oxide, and B component is auxiliary agent, and component C is solvent or filler;The sum of said components mass percentage
It is 100%.
2. the Pesticidal combination containing fenbutatin oxide as described in claim 1, which is characterized in that the auxiliary agent is emulsifier, dispersion
One or both of agent, wetting agent, bleeding agent, pH adjusting agent, disintegrant, antifreezing agent, preservative, antifoaming agent and thickener with
On.
3. the Pesticidal combination containing fenbutatin oxide as claimed in claim 2, which is characterized in that the emulsifier is alkyl phenol polyoxy
Vinethene, fatty alcohol polyoxyethylene ether, glycerine fatty acid polyoxyethylene ether, phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxy
Ethylene polyethenoxy ether, castor oil ethylene oxide adduct, APES formaldehyde condensation product, alkylphenol-polyethenoxy
One kind in ether phosphate, phenethyl phenol polyethenoxy ether phosphate, calcium dodecyl benzene sulfonate and neopelex
It is or two or more;The dispersant is polycarboxylate, lignosulfonates, alkyl phenol polyoxyethylene ether, alkylphenol-polyethenoxy
Ether formaldehyde condensation products sulfate, alkylnaphthalene sulfonate, alkylbenzenesulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, fatty amine polyoxy
One or more of vinethene and aliphatic acid polyethenoxy ether.
4. the Pesticidal combination containing fenbutatin oxide as claimed in claim 2, which is characterized in that the wetting agent is detergent alkylate
Sodium sulfonate, dodecyl sodium naphthalene sulfonate, sodium dodecyl benzene sulfonate, potassium oleate, enuatrol, dioctyl sodium sulfosuccinate, two
One or more of sodium butylnaphthalenesulfonate, alkyl polyoxyethylene ether sulfonate and spaonin powder;The bleeding agent is sulfuric acid
Change castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, sodium secondary alkyl sulfonate, secondary alkyl sulphate sodium, alkane
Base sodium naphthalene sulfonate, succinic acid alkyl ester sulfonate sodium, Igepon T, sulfamic acid sodium, fatty alcohol polyoxyethylene ether, alkyl phenol polyoxy
One or more of vinethene, polyethers and phosphate compounds.
5. the Pesticidal combination containing fenbutatin oxide as claimed in claim 2, which is characterized in that the pH adjusting agent for citric acid,
Lactic acid, tartaric acid, malic acid, metatartaric acid, phosphoric acid, acetic acid, hydrochloric acid, hexanedioic acid, fumaric acid, sodium hydroxide, potassium carbonate, carbonic acid
One or more of sodium, sodium citrate, potassium citrate, sodium sesquicarbonate and sodium dihydrogen citrate;The disintegrant is swollen
Moisten one or more of soil, urea, sodium bicarbonate, ammonium sulfate, sodium carbonate, citric acid and aluminium chloride.
6. the Pesticidal combination containing fenbutatin oxide as claimed in claim 2, which is characterized in that the preservative is benzoic acid, benzene
One or more of sodium formate, sorbic acid, potassium sorbate, calcium propionate, dimethyl fumarate and benzoisothiazolinone;
One or more of the antifreezing agent for ethylene glycol, propylene glycol, glycerine or urea and sodium chloride.
7. the Pesticidal combination containing fenbutatin oxide as claimed in claim 2, which is characterized in that the antifoaming agent is silicone oil, organic
One or more of silicone, C8-C10 fatty alcohols, C8-C20 saturated fatty acids and C8-C20 polyunsaturated fatty acid esters;Institute
Thickener is stated as carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, Huang
One or more of virgin rubber and polyvinyl alcohol aluminum magnesium silicate.
8. the Pesticidal combination containing fenbutatin oxide as described in claim 1, which is characterized in that the filler is talcum powder, kaolinite
Soil, clay, diatomite, White Carbon black, attapulgite, starch, sodium sulphate, sodium metasilicate, ammonium sulfate, sodium bicarbonate, bentonite, chlorination
One or more of ammonium and precipitated calcium carbonate.
9. the Pesticidal combination containing fenbutatin oxide as described in claim 1, which is characterized in that the solvent is methanol, ethyl alcohol, different
Butanol, ethyl acetate, sec-Butyl Acetate, oleic acid potassium ester, mineral oil, soybean oil, dimethylformamide, dimethylacetylamide, carbon
In dimethyl phthalate, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, cyclohexanone, toluene, dimethylbenzene, solvent naphtha, chloroform and deionized water
One or more.
10. a kind of preparing missible oil, suspending using according to Pesticidal combination of the claim 1-9 any one of them containing fenbutatin oxide
Agent, aqueous emulsion, soluble concentrate, wettable powder or water-dispersible granules pesticidal preparations in application.
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0057035A2 (en) * | 1981-01-28 | 1982-08-04 | Shell Internationale Researchmaatschappij B.V. | Liquid biocidal formulation, a process for preparing such a formulation, and the use of such a formulation |
CN101167474A (en) * | 2007-12-06 | 2008-04-30 | 张少武 | Fenbutatin oxide water dispersible granule and preparation method thereof |
CN101790978A (en) * | 2009-12-02 | 2010-08-04 | 深圳诺普信农化股份有限公司 | Pesticide emulsion in water and preparation method thereof |
CN101984808A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Microemulsion preparation taking rosin-based vegetable oil as solvent and preparation method thereof |
CN101984810A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Aqueous emulsion preparation using rosin-based vegetable oil as solvent and preparation method thereof |
CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
CN101984807A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Missible oil preparation using turpentine-based vegetable oil as solvent and preparation method thereof |
CN102301996A (en) * | 2011-09-20 | 2012-01-04 | 汕头市大千高新科技研究中心有限公司 | Water emulsion pesticide system and preparation method thereof |
-
2017
- 2017-12-29 CN CN201711474398.2A patent/CN108207993A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0057035A2 (en) * | 1981-01-28 | 1982-08-04 | Shell Internationale Researchmaatschappij B.V. | Liquid biocidal formulation, a process for preparing such a formulation, and the use of such a formulation |
CN101167474A (en) * | 2007-12-06 | 2008-04-30 | 张少武 | Fenbutatin oxide water dispersible granule and preparation method thereof |
CN101790978A (en) * | 2009-12-02 | 2010-08-04 | 深圳诺普信农化股份有限公司 | Pesticide emulsion in water and preparation method thereof |
CN101984808A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Microemulsion preparation taking rosin-based vegetable oil as solvent and preparation method thereof |
CN101984810A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Aqueous emulsion preparation using rosin-based vegetable oil as solvent and preparation method thereof |
CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
CN101984807A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Missible oil preparation using turpentine-based vegetable oil as solvent and preparation method thereof |
CN102301996A (en) * | 2011-09-20 | 2012-01-04 | 汕头市大千高新科技研究中心有限公司 | Water emulsion pesticide system and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
刘新等: "《农药安全使用技术》", 30 September 2014, 福建科学技术出版社 * |
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