CN108194844A - A kind of deep ultraviolet light source of electron-beam excitation fluorescent powder - Google Patents

A kind of deep ultraviolet light source of electron-beam excitation fluorescent powder Download PDF

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Publication number
CN108194844A
CN108194844A CN201711497368.3A CN201711497368A CN108194844A CN 108194844 A CN108194844 A CN 108194844A CN 201711497368 A CN201711497368 A CN 201711497368A CN 108194844 A CN108194844 A CN 108194844A
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Prior art keywords
electron
ultraviolet light
light source
deep ultraviolet
beam excitation
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CN201711497368.3A
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CN108194844B (en
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赵健
夏忠平
朱滨
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Shanghai Youwei Photoelectric Technology Co Ltd
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Shanghai Youwei Photoelectric Technology Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21KNON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K2/00Non-electric light sources using luminescence; Light sources using electrochemiluminescence
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08Radiation
    • A61L2/10Ultraviolet radiation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/11Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Epidemiology (AREA)
  • Physics & Mathematics (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Luminescent Compositions (AREA)
  • Discharge Lamps And Accessories Thereof (AREA)

Abstract

The present invention relates to ultraviolet source field more particularly to a kind of deep ultraviolet light sources of electron-beam excitation fluorescent powder.The light source includes fluorescent screen, electron gun and ceramic shell, wherein:The fluorescent screen includes sapphire substrates and coated in the Ultraluminescence bisque in the sapphire substrates;The electron gun is set in the ceramic shell, and for the electron beam that the electron gun generates towards the Ultraluminescence bisque, the Ultraluminescence bisque sends out deep ultraviolet light under the electron-beam excitation through sapphire substrates;The fluorescent screen is by that can cut down becket and the ceramic shell matched seal.The relatively existing mercury lamp of the ultraviolet source of the embodiment of the present application and UV LED etc., have it is pollution-free, it is at low cost, be easy to large-scale production the advantages of, be with a wide range of applications in sterilizing field.

Description

A kind of deep ultraviolet light source of electron-beam excitation fluorescent powder
Technical field
This application involves ultraviolet source field more particularly to a kind of deep ultraviolet light sources of electron-beam excitation fluorescent powder.
Background technology
Deep ultraviolet light source is widely used in radiation sterilizing field, and current most common deep ultraviolet light source is mercury lamp, but mercury lamp Containing mercury, mercury pollution is all be easy to cause during production and use, while generate purple during mercury lamp by way of gas discharge Outer light, the spectral line of mercury lamp are the continuous spectrum of ultraviolet region, and application efficiency is low, simultaneously because electrode temperature is high when mercury lamp works, Cause its service life shorter.
UV-LED has the characteristics that mercury-free, energy saving, portable, is a kind of ultraviolet source that can substitute mercury lamp, but UV-LED Transfer efficiency is low, while its higher manufacture cost and relatively low output power limit are in the application in sterilizing field.
Invention content
The embodiment of the present application provides a kind of deep ultraviolet light source of electron-beam excitation fluorescent powder, with provide it is a kind of it is pollution-free, Power is high, deep ultraviolet light source at low cost.
In order to achieve the above objectives, the embodiment of the present application provides a kind of deep ultraviolet light source of electron-beam excitation fluorescent powder, institute It states light source and includes fluorescent screen, electron gun and ceramic shell, wherein:
The fluorescent screen includes sapphire substrates and coated in the Ultraluminescence bisque in the sapphire substrates;
The electron gun is set in the glass shell, and the electron beam that the electron gun generates is towards the Ultraluminescence Bisque, the Ultraluminescence bisque send out deep ultraviolet light under the electron-beam excitation through sapphire substrates;
The fluorescent screen is by that can cut down becket and the ceramic shell matched seal.
The deep ultraviolet light source of electron-beam excitation fluorescent powder as described in claim 1, which is characterized in that the Ultraluminescence Bisque includes host material and active ions, and the host material is yttrium phosphate.
Further, the active ions are Bi2+, Pr3+Or Gd3+In any one.
Further, the electron beam that the electron gun generates excites the fluorescence in a manner of focusing on scanning or area projection Bisque.
Further, the electron gun is thermal electron rifle or field emission gun,.
Further, the operating voltage of the electron gun is 5kv~20kv.
Further, the Ultraluminescence bisque is used as adhesive coated in the sapphire substrates by aluminium oxide.
Further, the electron gun is by that can cut down becket and the ceramic shell matched seal.
Deep ultraviolet light source provided by the embodiments of the present application includes fluorescent screen, electron gun and ceramic shell, electron gun fluorescence Screen is all placed in ceramic shell, and the fluorescent powder in electron-beam excitation fluorescent screen is generated by electron gun, so as to send out deep ultraviolet light, The application uses sapphire that can cut down ring as light-emitting window by metal and carry out matched seal with ceramic shell, so as to easy In accomplishing scale production, cost is reduced, while sapphire compares and glass good heat dissipation effect, can significantly improve light source Light power, the light source of the application is pollution-free, at low cost, is easy to mass produce.
Description of the drawings
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or it will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments described in application, for those of ordinary skill in the art, in the premise of not making the creative labor property Under, it can also be obtained according to these attached drawings other attached drawings.
The schematic diagram of the deep ultraviolet light source of the electron-beam excitation fluorescent powder of one embodiment of Fig. 1 the application.
Specific embodiment
In order to make those skilled in the art better understand the technical solutions in the application, below in conjunction with the application reality The attached drawing in example is applied, the technical solution in the embodiment of the present application is clearly and completely described, it is clear that described implementation Example is merely a part but not all of the embodiments of the present application.Based on the embodiment in the application, this field is common Technical staff's all other embodiments obtained without making creative work should all belong to the application protection Range.
Below in conjunction with the accompanying drawings, the specific embodiment of the embodiment of the present application is described in further detail.
With reference to figure 1, the deep ultraviolet light source of the electron-beam excitation fluorescent powder of the embodiment of the present application is outer including electron gun 1, ceramics Shell 2 and fluorescent screen, wherein fluorescent screen include sapphire substrates 3 and coated in the Ultraluminescence bisques in sapphire substrates 3 4.Sapphire substrates used in this application are preferably sapphire single-crystal, and sapphire chemical property is stablized, while has to ultraviolet light There is good transmitance, it is often more important that sapphire compares glass with more good heat conductivity, the embodiment of the present application Using sapphire substrates as the light-emitting window of deep ultraviolet light source, due to the good heat conductivity of sapphire, the embodiment of the present application In compare glass material substrate can use bigger energy deexcitation fluorescent powder generate deep ultraviolet light, so as to significantly carry The light power of high unit area inner light source.The Ultraluminescence bisque 4 used in the embodiment of the present application includes host material and swashs Ion living, the host material are yttrium phosphate, and active ions are preferably Bi2+, Pr3+Or Gd3+In any one.Yttrium phosphate has There is the advantages of phonon energy is low, and chemical stability is good, by adulterating Bi2+, Pr3+Or Gd3+Ion, under electron-beam excitation so as to The deep ultraviolet light of different wave length can be sent out.Ultraluminescence bisque 4 is used as binding agent by aluminium oxide and is applied in the embodiment of the present application It overlays in the sapphire substrates, sapphire main component is aluminium oxide, can be precious with indigo plant during using aluminium oxide as binding agent Aluminium oxide in stone forms chemical bonds, so as to improve the adhesiveness of fluorescent powder, in the embodiment of the present application, by alumina bound Agent can be coated in by way of silk-screen printing in sapphire substrates after being mixed with fluorescent powder, then complete to apply after heat drying It covers, further, alumina binder can be alumina sol.
In the embodiment of the present application, electron gun 1 is set in ceramic shell 2, is protected by ceramic shell 2, and can be led to It crosses ceramic shell 2 and required vacuum environment is provided, the embodiment of the present application electron gun is thermal electron rifle or field emission electron Rifle, the operating voltage of electron gun is preferably 5kv~20kv;Further, the electron beam that electron gun generates is to focus on scanning or face The mode of product projection excites the phosphor powder layer, and the electron beam that electron gun 1 generates is towards Ultraluminescence bisque 4, ultraviolet fluorescence powder Layer 4 sends out deep ultraviolet light under electron-beam excitation through sapphire substrates.In the deep ultraviolet light source of the prior art, mercury lamp is to make Ultraviolet light is generated, but mercury has severe toxicity with the mode of gas discharge, pollute environment, while gas discharge mode short life, intensity is not It is modulated;Another kind is UV-LED deep ultraviolet lamps, is to generate deep ultraviolet light, electroluminescent mode by electroluminescent mode It is limited by material, on the one hand can only send out the light of specific wavelength, another aspect transfer efficiency is low, and light extraction general power is low, limit Its application in the industry is made.And the deep ultraviolet light source of the application is generated by way of electron gun excitated fluorescent powder, is led to It crosses and excites different fluorescent powders, the deep ultraviolet light of different wave length can be generated, while can be by adjusting the work electricity of electron gun For pressure so as to adjust light power, another aspect the application uses sapphire substrates to avoid glass to dark purple as light-emitting window The absorption of outer light, so as to significantly improve the transfer efficiency of light source, embodiments herein is produced by electron-beam excitation fluorescent powder The mode of raw deep ultraviolet light has long lifespan, and stability is good, it is efficient the advantages of.
In the embodiment of the present application, fluorescent screen by the way that becket 5 and 2 matched seal of ceramic shell can be cut down,.The application is real It is using sapphire as substrate to apply fluorescent screen in example, and sapphire main component is aluminium oxide, be ceramic shell main component it One, therefore the coefficient of thermal expansion comparison match of sapphire and ceramic shell, it is most common envelope in electrovacuum element that can cut down metal Engagement gold, cuts down becket, so as to realize of fluorescent screen and ceramic shell by using with what ceramic shell matched With sealing-in.Using sapphire substrates and ceramic shell in the embodiment of the present application, light power, while process for sapphire-based are not only increased Bottom and ceramic shell are due to coefficient of thermal expansion comparison match, so as to the matched seal both realized by the way that metal can be cut down, and Common glass shell almost impermeable deep ultraviolet light;Although envelope of quartz glass is thoroughly ultraviolet strong, difficulty of processing is big, can not scale Metaplasia is produced;Also one kind is using simple glass as shell, using quartz glass as light-emitting window, but quartz glass and common glass Glass coefficient of thermal expansion is different, and sealing-in difficulty is big.The application using sapphire substrates as light-emitting window, then with can cut down becket can be with Realize the matched seal with ceramic shell, such mode compares and glass shell, is easy to reduce cost, realizes extensive raw Production.The embodiment of the present application electron gun can also realize matched seal with ceramic shell by that can cut down becket.
Further, the embodiment of the present application further includes reflecting layer 6, is coated on phosphor powder layer by way of vapor deposition, Fine aluminium reflecting layer of the preferred thickness for 100nm or so, so that the deep ultraviolet light generated after electron-beam excitation fluorescent powder is concentrated Towards light-emitting surface project, reduce deep ultraviolet light towards light source internal project and caused by go out light loss.
Deep ultraviolet light source provided by the embodiments of the present application includes fluorescent screen, electron gun and ceramic shell, passes through electron gun The fluorescent powder in electron-beam excitation fluorescent screen is generated, so as to send out deep ultraviolet light, the application is optical window using sapphire substrates Mouth can significantly improve the light power of light source, while fluorescent screen carries out matched seal by that can cut down becket with ceramic shell, It is easy to reduce production cost, accomplishes scale production.The relatively existing mercury lamp of the ultraviolet source of the embodiment of the present application and UV-LED Deng, have it is pollution-free, it is at low cost, be easy to large-scale production the advantages of, be with a wide range of applications in sterilizing field.
Particular embodiments described above has carried out the purpose, technical solution and advantageous effect of the application further in detail It describes in detail bright, it should be understood that the foregoing is merely the specific embodiment of the embodiment of the present application, is not used to limit this Shen Protection domain please, all any modification, equivalent substitution, improvement and etc. within spirit herein and principle, done, should all wrap It is contained within the protection domain of the application.

Claims (8)

1. a kind of deep ultraviolet light source of electron-beam excitation fluorescent powder, which is characterized in that the light source include fluorescent screen, electron gun, And ceramic shell, wherein:
The fluorescent screen includes sapphire substrates and coated in the Ultraluminescence bisque in the sapphire substrates;
The electron gun is set in the ceramic shell, and the electron beam that the electron gun generates is towards the ultraviolet fluorescence powder Layer, the Ultraluminescence bisque send out deep ultraviolet light under the electron-beam excitation through sapphire substrates;
The fluorescent screen is by that can cut down becket and the ceramic shell matched seal.
2. the deep ultraviolet light source of electron-beam excitation fluorescent powder as described in claim 1, which is characterized in that the ultraviolet fluorescence powder Layer includes host material and active ions, and the host material is yttrium phosphate.
3. the deep ultraviolet light source of electron-beam excitation fluorescent powder as claimed in claim 2, which is characterized in that the active ions are Bi2+, Pr3+Or Gd3+In any one.
4. the deep ultraviolet light source of electron-beam excitation fluorescent powder as described in claim 1, which is characterized in that the electron gun generates Electron beam excite the phosphor powder layer in a manner of focusing on scanning or area and project.
5. the deep ultraviolet light source of electron-beam excitation fluorescent powder as claimed in claim 6, which is characterized in that the electron gun is heat Launching electronics rifle or field emission gun,.
6. the deep ultraviolet light source of electron-beam excitation fluorescent powder as claimed in claim 7, which is characterized in that the work of the electron gun Make voltage as 5kv~20kv.
7. the deep ultraviolet light source of electron-beam excitation fluorescent powder as described in claim 1, which is characterized in that the ultraviolet fluorescence powder Layer is used as adhesive coated in the sapphire substrates by aluminium oxide.
8. the deep ultraviolet light source of electron-beam excitation fluorescent powder as described in claim 1, which is characterized in that the electron gun passes through Becket and the ceramic shell matched seal can be cut down.
CN201711497368.3A 2017-12-31 2017-12-31 Deep ultraviolet light source for exciting fluorescent powder by electron beam Active CN108194844B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112552900A (en) * 2020-12-29 2021-03-26 东北师范大学 Preparation method of ultraviolet light source based on up-conversion phosphor powder light conversion

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CN1476640A (en) * 2001-10-12 2004-02-18 ���ǻ�ѧ��ҵ��ʽ���� Light-emitting device and its mfg. method
JP2006079873A (en) * 2004-09-08 2006-03-23 National Institute For Materials Science Solid far-ultraviolet-ray emitting device
CN101438406A (en) * 2004-11-19 2009-05-20 皇家飞利浦电子股份有限公司 Light-emitting device with inorganic housing
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Publication number Priority date Publication date Assignee Title
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CN112552900B (en) * 2020-12-29 2023-12-22 东北师范大学 Preparation method of ultraviolet light source based on up-conversion fluorescent powder light conversion

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