CN108193511A - A kind of processing method of aqueous polyurethane synthetic fabric - Google Patents

A kind of processing method of aqueous polyurethane synthetic fabric Download PDF

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Publication number
CN108193511A
CN108193511A CN201810083697.1A CN201810083697A CN108193511A CN 108193511 A CN108193511 A CN 108193511A CN 201810083697 A CN201810083697 A CN 201810083697A CN 108193511 A CN108193511 A CN 108193511A
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CN
China
Prior art keywords
slurry
aqueous polyurethane
base fabric
fabric
time
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Pending
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CN201810083697.1A
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Chinese (zh)
Inventor
徐伟
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Jiashan Weir Ni Rong Industry Co Ltd
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Jiashan Weir Ni Rong Industry Co Ltd
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Application filed by Jiashan Weir Ni Rong Industry Co Ltd filed Critical Jiashan Weir Ni Rong Industry Co Ltd
Priority to CN201810083697.1A priority Critical patent/CN108193511A/en
Publication of CN108193511A publication Critical patent/CN108193511A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/14Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics in wound form
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/103Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1685Wear resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

Abstract

The invention discloses a kind of processing methods of aqueous polyurethane synthetic fabric, including base fabric, one layer of aqueous polyurethane is smeared in base fabric side, passing through the aqueous polyurethane in release paper and release paper, so that the aqueous polyurethane of scrim surfaces has irregular figure, then beautified by finishing agent.Document《Poisonous and harmful raw material (product) the substitute catalogue (version in 2016) that country encourages》14th article explicitly points out with waterborne polyurethane resin replacement solvent borne polyurethane production synthetic leather, pass through one layer of aqueous polyurethane slurry of surface smear in base fabric, while so that the base fabric has the characteristic of leather, due to the characteristic of aqueous polyurethane, cause the fabric, it with wear-resisting scratch resistance, and produces pollution-free, greatly increases the feature of environmental protection and service life of the aqueous polyurethane synthetic fabric.Also, in the top finishing finishing agent of the fabric so that the aesthetics of the fabric is greatly promoted.

Description

A kind of processing method of aqueous polyurethane synthetic fabric
Technical field
The present invention relates to fabric manufacture field, it particularly relates to a kind of processing method of aqueous polyurethane synthetic fabric.
Background technology
At present, the manufacturing method of well known artificial synthetic leather, it is necessary to first manufacture a base material, be typically by various raw materials And solvent bearing is in one or several dipping tanks, and base fabric guiding is made its impregnation by material in the dipping tank, then will The base fabric, which is introduced in a sink, makes its surface gelatinization solidification, reuses electric heating drying equipment and is dried to form synthesis skin Leather base material;A musculus cutaneus (or epithelium) must be separately remanufactured, recycles cement that base material is made to be bonded to each other with musculus cutaneus.
No matter the manufacture of base material or musculus cutaneus has used a large amount of solvent, meeting in the manufacturing process of well known synthetic leather Serious environmental pollution is caused, contains dimethylformamide (Dimethyl in solvent as wet type synthetic leather uses Formamide abbreviation DMF), it can be absorbed via skin or can cause to be poisoned by lung sucking, be by the poison control centre of tubulation, according to regulation Factory must be provided with gas collection and using washing and the equipment of exhaust-gas treatment, the monitoring and record at its that factory and government also must be at any time Reason process, therefore the processing of its exhaust gas and waste water is fairly time consuming laborious, it is careless slightly to cause serious pollution.
The manufacturing process of the synthetic leather of another dry type is the butanone (methyl used using resin rubbing method Ethyl ketone abbreviation MEK) it can cause the acute toxic hepatitis of human body, and dimethylbenzene (Xylene) has the height flammable Property, it can be lighted easily by heat, spark or flame, easily generate fire, empty gas and water can be polluted;In addition, fitting makes Cement also contains solvent, inevitably also has aforementioned bad phenomenon.
Chinese law patent of invention CN200510001620.8 refers to high water repellency artificial leather and its manufacturing method, provides One base fabric;It forms the polyurethane resin with dryingagent and is impregnated with layer in the base fabric;Form the polyurethane with dryingagent Resin coated layer is in the base fabric;The impregnation layer and the coating layer are solidified, wash and dry, to form a water repellency artificial skin Leather;And it is impregnated with processing fluouine water extraction agent again, to form a high water repellency artificial leather.Although the isolation water that the patent solves Problem so that the anti-siphon 0.2cm 0.1cm 0.3cm of leather are more than 1cm water absorption rates 32%21%40% and are more than 100%, still Very poor there are permeability, and not wear-resisting not scratch resistance, the problem of service life is short, also existing leather color is single, no With aesthetics.
For the problems in the relevant technologies, currently no effective solution has been proposed.
Invention content
For the problems in the relevant technologies, the present invention proposes a kind of processing method of aqueous polyurethane synthetic fabric, with gram Take the above-mentioned technical problem present in existing the relevant technologies.
The technical proposal of the invention is realized in this way:
A kind of processing method of aqueous polyurethane synthetic fabric, includes the following steps:
Configuration slurry for the first time, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred, Treat the sticky slurry that as configuration is completed of slurry.
Above-mentioned sticky slurry is put into blender, passes through the bubble in the sticky slurry of blender by mechanical foaming It stirs out, treats that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin.
Base fabric is soaked, and enabling base fabric, the first roller presses against base fabric and is immersed in the water, and one end of base fabric is placed on by the first roller On conveyer belt, it is transmitted immersion.
Squezzing is plated, from the transmission belt upload base fabric sending and soak, by second tin roller and third roller it Between eliminate moisture extra in base fabric, also, be hot type roller on second tin roller and third roller, can plate base fabric On fold.
Soaking paste material is applied, the base fabric of smooth out wrinkles is transmitted to and is applied at dipping machine, then by the above-mentioned slurry for removing bubble removing, is passed through The scraper of painting dipping machine is uniformly applied to the surface of the base fabric of smooth out wrinkles, stands 1-2 minutes and forms first time processing materials.
Drying, by the later base fabric of above-mentioned standing, is transmitted to inside 60 meters of dryer by conveyer belt, is dried, Form second of processing materials of the material softening on surface.
Leveling, second of processing materials after drying, is squeezed by the 4th roller, obtains semi-finished product.
Winding winds obtained semi-finished product, and constant temperature storage is for use.
Second of configuration slurry, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred, Treat the sticky slurry that as configuration is completed of slurry.
Above-mentioned sticky slurry is put into blender, passes through the bubble in the sticky slurry of blender by mechanical foaming It stirs out, treats that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin.
Release paper is arranged, the release paper for purchasing is sprawled, checks whether there is fold.
Coating surface layer, the release paper that will have been checked are sent to by conveyer belt and applied under dipping machine, enable what stirring was completed by scraper Slurry is uniformly applied to the surface of release paper, forms first time paper product.
Drying, first time paper product is sent to inside 90 ° -150 ° of dryer, dries moisture.
Fitting by first time paper product with carrying being bonded on one side for slurry in semi-finished product, forms third timeization Work material.
Drying, above-mentioned third time processing materials by 100 ° -150 ° of dryer, are dried, and are formed the 4th time and are added Work material.
The release paper on the 4th processing materials is removed in stripping, forms finished product.
This method is preferred, the frequency of the blender not be less than 1000 revs/min.
This method is preferred, and the speed of the conveyer belt is 10cm/s.
This method is preferred, and first 30 meters of drying temperature of the dryer is 60 °, latter 30 meters of baking of the dryer Dry temperature is 160 °.
This method is preferred, and the temperature of the 4th cylinder surface is between 60 ° -150 °.
This method is preferred, and the first time processing paper is sent to by conveyer belt to be applied under dipping machine, is enabled and stirred by scraper The slurry of completion is uniformly applied to the surface of release paper, forms second of paper product, and second of paper product is transmitted To 90 ° -150 ° of dryers, moisture is dried, then be bonded.
Beneficial effects of the present invention:Document《Poisonous and harmful raw material (product) the substitute catalogue of country's encouragement (2016 Version)》14th article explicitly point out with waterborne polyurethane resin substitute solvent borne polyurethane production synthetic leather, by the surface of base fabric Smear one layer of aqueous polyurethane slurry so that while the base fabric has the characteristic of leather, due to the characteristic of aqueous polyurethane, make The fabric, there is wear-resisting scratch resistance, and produce pollution-free, greatly increase the feature of environmental protection of the aqueous polyurethane synthetic fabric And service life.
Also, in the top finishing finishing agent of the fabric so that the aesthetics of the fabric is greatly promoted.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel's all other embodiments obtained, shall fall within the protection scope of the present invention.
According to an embodiment of the invention, a kind of processing method of aqueous polyurethane synthetic fabric is provided.
A kind of processing method of aqueous polyurethane synthetic fabric according to embodiments of the present invention, includes the following steps:
Slurry is configured in S101 for the first time, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred It mixes, treats the sticky slurry that as configuration is completed of slurry;
Above-mentioned sticky slurry is put into blender, by the sticky slurry of blender by S102 mechanical foamings Bubble agitation goes out, and treats that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin;
S103 base fabrics are soaked, and enabling base fabric, the first roller presses against base fabric and is immersed in the water, and one end of base fabric is put by the first roller It puts on a moving belt, is transmitted immersion;
S104 squezzing is plated, and the base fabric sent and soaked from transmission belt upload is rolled by second tin roller and third Moisture extra in base fabric is eliminated, also, be hot type roller on second tin roller and third roller between cylinder, can plated Fold in base fabric;
S105 applies soaking paste material, and the base fabric of smooth out wrinkles is transmitted to and is applied at dipping machine, then by the above-mentioned slurry for removing bubble removing, The surface of the base fabric of smooth out wrinkles is uniformly applied to by the scraper for applying dipping machine, 1-2 minutes is stood and forms first time processing materials;
S106 is dried, and by the later base fabric of above-mentioned standing, is transmitted to inside 60 meters of dryer, is dried by conveyer belt It is dry, form second of processing materials of the material softening on surface;
S107 is flattened, and second of processing materials after drying are squeezed by the 4th roller, obtain half into Product;
S108 is wound, and obtained semi-finished product are wound, and constant temperature storage is for use;
Slurry is configured in S109 for the second time, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred It mixes, treats the sticky slurry that as configuration is completed of slurry;
Above-mentioned sticky slurry is put into blender, by the sticky slurry of blender by S1010 mechanical foamings Bubble agitation goes out, and treats that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin;
S1011 arranges release paper, and the release paper for purchasing is sprawled, checks whether there is fold;
S1012 coating surface layers, the release paper that will have been checked are sent to by conveyer belt and applied under dipping machine, are enabled and stirred by scraper The slurry of completion is uniformly applied to the surface of release paper, forms first time paper product;
S1013 is dried, and first time paper product is sent to inside 90 ° -150 ° of dryer, dries moisture, is formed Dry the first time processing paper of moisture;
S1014 is bonded, and by first time paper product with carrying being bonded on one side for slurry in semi-finished product, forms third Secondary chemical material;
S1015 is dried, and above-mentioned third time processing materials by 100 ° -150 ° of dryer, are dried, and forms the Four processing materials;
S1016 is removed, and the release paper on the 4th processing materials is removed, and forms finished product.
In addition, in one embodiment, for blender, the frequency of the blender not be less than 1000 revs/min Clock.Blender can enable the bubble in slurry eliminate completely when 1000 revs/min.
In addition, in one embodiment, for conveyer belt, the speed of the conveyer belt is 10cm/s.Using the party Case so that conveyer belt can adapt to the various operations to base fabric and release paper.
In addition, in one embodiment, for dryer, latter 30 meters of drying temperature of the dryer is 160°.Using the program so that first 30 meters of dryer can be dried, and latter 30 meters carry out drying softening, greatly increase The compactness of slurry and base fabric.
In addition, in one embodiment, for the 4th roller, the temperature of the 4th cylinder surface is at 60 ° -150 ° Between.Using the program so that semi-finished product can ensure that the temperature on surface is inconvenient, convenient for being pasted with first time paper product It closes.
In addition, in one embodiment, for first time processing paper, the first time processing paper of the drying moisture leads to It crosses conveyer belt and is sent to and apply under dipping machine, the slurry for stirring being enabled to complete by scraper is uniformly applied to the surface of release paper, forms the Second of paper product is sent to inside 90 ° -150 ° of dryer by secondary operation paper product, dries moisture, then carry out Fitting.Using the program so that processing paper can carry out repeatedly smearing and thicken according to demand for the first time.
The processing method of a kind of aqueous polyurethane synthetic fabric surface-beautifying according to embodiments of the present invention, including following step Suddenly:
S1017 finishing agent dispensings according to demand, the finishing agent of different colours are mixed, obtains desired color, stirred, It is placed on coating machine;
S1018 handles finished product, and finished product is laid on a moving belt, is covered with paint, lacquer, colour wash, etc. under being transmitted to coating machine, forms the It is primary to cover with paint, lacquer, colour wash, etc. product;
S1019 is dried, and the first time for covering with paint, lacquer, colour wash, etc. completion is covered with paint, lacquer, colour wash, etc. product, is sent in 120 ° or so of dryer, is dried It is dry;
S1020 is cooled down, and the first time after drying is covered with paint, lacquer, colour wash, etc. product, by the roller of cold water injection, is cooled down, forms beautification Finished product.
In conclusion by means of the above-mentioned technical proposal of the present invention, pass through document《The poisonous and harmful raw material that country encourages (product) substitute catalogue (version in 2016)》14th article explicitly points out with waterborne polyurethane resin replacement solvent borne polyurethane production Synthetic leather passes through one layer of aqueous polyurethane slurry of surface smear in base fabric so that while the base fabric has the characteristic of leather, Due to the characteristic of aqueous polyurethane so that the fabric has wear-resisting scratch resistance, and produces pollution-free, greatly increases the water The feature of environmental protection and service life of property polyurethane synthetic fabric, also, in the top finishing finishing agent of the fabric so that the fabric Aesthetics greatly promoted.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (7)

1. a kind of processing method of aqueous polyurethane synthetic fabric, which is characterized in that include the following steps:
Configuration slurry for the first time, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred, and waits to starch Expect that sticky is the slurry that configuration is completed;
Above-mentioned sticky slurry is put into blender, passes through the bubble agitation in the sticky slurry of blender by mechanical foaming Go out, treat that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin;
Base fabric is soaked, and enabling base fabric, the first roller presses against base fabric and is immersed in the water by the first roller, and one end of base fabric is placed on transmission It takes, is transmitted immersion;
Squezzing is plated, the base fabric sent and soaked from transmission belt upload, by being gone between second tin roller and third roller It is hot type roller in addition to moisture extra in base fabric, also, on second tin roller and third roller, can plates in base fabric Fold;
Soaking paste material is applied, the base fabric of smooth out wrinkles is transmitted to and is applied at dipping machine, then by the above-mentioned slurry for removing bubble removing, is soaked by applying The scraper of machine is uniformly applied to the surface of the base fabric of smooth out wrinkles, stands 1-2 minutes and forms first time processing materials;
Drying, by the later base fabric of above-mentioned standing, is transmitted to inside 60 meters of dryer by conveyer belt, is dried, and is formed Second of processing materials of the material softening on surface;
Leveling, second of processing materials after drying, is squeezed by the 4th roller, obtains semi-finished product;
Winding winds obtained semi-finished product, and constant temperature storage is for use;
Second of configuration slurry, by aqueous polyurethane and thickener according to 10:The 1 additional suitable quantity of water of ratio is stirred, and waits to starch Expect that sticky is the slurry that configuration is completed;
Above-mentioned sticky slurry is put into blender, passes through the bubble agitation in the sticky slurry of blender by mechanical foaming Go out, treat that surface without the slurry that apparent bubble is that stirring is completed, slurry is put into and applies dipping machine storage bin;
Release paper is arranged, the release paper for purchasing is sprawled, checks whether there is fold;
Coating surface layer, the release paper that will have been checked are sent to by conveyer belt and applied under dipping machine, and the slurry of stirring completion is enabled by scraper The surface of release paper is uniformly applied to, forms first time paper product;
Drying, first time paper product is sent to inside 90 ° -150 ° of dryer, dries moisture, forms drying moisture Processing paper for the first time;
Fitting by first time paper product with carrying being bonded on one side for slurry in semi-finished product, forms third time chemical industry object Material;
Drying, above-mentioned third time processing materials by 100 ° -150 ° of dryer, are dried, and form the 4th machining object Material;
The release paper on the 4th processing materials is removed in stripping, forms finished product.
2. the processing method of aqueous polyurethane synthetic fabric according to claim 1, which is characterized in that the blender Frequency not be less than 1000 revs/min.
3. the processing method of aqueous polyurethane synthetic fabric according to claim 1, which is characterized in that the conveyer belt Speed is 10cm/s.
4. the processing method of aqueous polyurethane synthetic fabric according to claim 1, which is characterized in that the dryer First 30 meters of drying temperature is 60 °, and latter 30 meters of drying temperature of the dryer is 160 °.
5. the processing method of aqueous polyurethane synthetic fabric according to claim 1, which is characterized in that the 4th roller The temperature on surface is between 60 ° -150 °.
6. the processing method of aqueous polyurethane synthetic fabric according to claim 1, which is characterized in that the drying moisture First time processing paper by conveyer belt be sent to apply dipping machine under, by scraper enable stirring complete slurry be uniformly applied to it is release The surface of paper forms second of paper product, second of paper product is sent to inside 90 ° -150 ° of dryer, dries Solid carbon dioxide point, then be bonded.
7. a kind of processing method of aqueous polyurethane synthetic fabric surface-beautifying, which is characterized in that for described in claim 1 Aqueous polyurethane synthetic fabric, includes the following steps:
Finishing agent dispensing according to demand, the finishing agent of different colours is mixed, obtains desired color, stirred, be placed on covering with paint On machine;
Finished product is handled, finished product is laid on a moving belt, is covered with paint, lacquer, colour wash, etc. under being transmitted to coating machine, is formed and covers with paint, lacquer, colour wash, etc. production for the first time Product;
It is dry, the first time for covering with paint, lacquer, colour wash, etc. completion is covered with paint, lacquer, colour wash, etc. into product, is sent in 120 ° or so of dryer, is dried;
First time after drying is covered with paint, lacquer, colour wash, etc. product, by the roller of cold water injection, is cooled down, form the finished product of beautification by cooling.
CN201810083697.1A 2018-01-29 2018-01-29 A kind of processing method of aqueous polyurethane synthetic fabric Pending CN108193511A (en)

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