KR100717903B1 - Coating method and coating structure of cloth - Google Patents

Coating method and coating structure of cloth Download PDF

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Publication number
KR100717903B1
KR100717903B1 KR1020050109722A KR20050109722A KR100717903B1 KR 100717903 B1 KR100717903 B1 KR 100717903B1 KR 1020050109722 A KR1020050109722 A KR 1020050109722A KR 20050109722 A KR20050109722 A KR 20050109722A KR 100717903 B1 KR100717903 B1 KR 100717903B1
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South Korea
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fabric
layer
coating
surface treatment
treatment agent
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KR1020050109722A
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Korean (ko)
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조성운
강종훈
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강종훈
조성운
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • D06B15/02—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by squeezing rollers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00—Heating or cooling textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/16—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with oil varnishes, i.e. drying oil varnishes, preferably linseed-oil-based; factice (sulfurised oils), Turkish birdlime, resinates reacted with drying oils; naphthenic metal salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/142—Hydrophobic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

본 발명은 직물원단에 수성우레탄층, 또한 수성우레탄층위에 유성우레탄 표면처리제가 형성되도록 하고, 또한 상기 유성우레탄 표면처리제의 위에 유연제층이 형성되도록 하여 직물원단에 방수 및 방풍의 효과를 가지며 그에 따른 뛰어난 보온성을 유지할 수 있으며, 더욱이 상기 직물원단에 수성우레탄층이 형성되고, 상기 수성우레탄층위에 형성된 유성우레탄 표면처리제에 왁스 및 오일성분의 유연제 및 침투제의 첨가에 의하여 일반 직물원단을 실크 스타일과 유사한 부드러운 질감이 형성되도록 하여 직물원단 자체를 고가 고품질의 직물을 형성할 수 있는 직물원단의 코팅구조 및 코팅방법에 관한 것으로, 직물원단 위에 우레탄 코팅층을 형성하는 직물원단의 코팅구조에 있어서, 상기 직물원단(10) 위에 수성우레탄층(20)이 형성되고, 상기 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 형성되고, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형되어 있고, 또한 상기 직물원단(10)위에 수성우레탄층(20)과 상기 유성우레탄 표면처리제(30)가 압압 성형되어, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형되어 있으며, 또한 직물원단 위에 우레탄 코팅층이 도포되어 건조기를 통과하여 건조하는 직물원단의 코팅방법에 있어서, 기 직물원단(10) 위에 수성우레탄층(20)이 도포되어 드라이오븐(120)을 통과하는 건조단계(100)와; 상기 건조단계(100)를 통과한 직물원단(10)을 쿨링로울(210)들을 통과하도록 하는 냉각단계(200)와; 상기 냉각단계(200)를 거친 직물원단(10)이 히팅로울(310)과 실리콘로울(320) 사이를 통과하여 압압하는 압압단계(300)와; 상기 압압단계(300)를 거친 직물원단(10)의 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 코팅하는 2차 코팅(400) 및 건조단계(500)와; 상기 2차 코팅(400) 및 건조단계(500)를 거친 직물원단(10)을 쿨링로울(610)들을 통과하도록 하는 냉각단계(600)와; 상기 냉각단계(600)를 거친 직물원단(10)의 위에 유성우레탄 표면처리제(30) 위에 유연제층(40)가 침지되어 에어오븐(720) 등을 통과하도록 하는 유연제 코팅단계(700);로 이루어져 있다. The present invention is to form a water-based urethane surface treatment agent on the fabric fabric, and also the water-based urethane layer, and also to have a softening agent layer formed on the surface of the oil-based urethane surface treatment agent has the effect of waterproof and windproof on the fabric fabric and accordingly It is possible to maintain excellent heat retention, and furthermore, a water-based urethane layer is formed on the fabric fabric, and the addition of wax and oil-based softeners and penetrants to the oil-based urethane surface treatment agent formed on the water-based urethane layer is similar to that of the silk style. The present invention relates to a coating structure and a coating method of a fabric fabric capable of forming a high-quality fabric of the fabric fabric itself by forming a soft texture. In the coating structure of the fabric fabric forming a urethane coating layer on the fabric fabric, the fabric fabric An aqueous urethane layer 20 is formed on (10), and the aqueous An oily urethane surface treatment agent 30 is formed on the retan layer 20, a softening agent layer 40 is formed on the oily urethane surface treatment agent 30, and an aqueous urethane layer 20 is formed on the fabric fabric 10. ) And the oil-based urethane surface treatment agent 30 are press-molded, and the softener layer 40 is molded on the oil-based urethane surface treatment agent 30, and a urethane coating layer is applied on the fabric fabric to dry through a dryer. In the coating method of the fabric fabric, the drying step 100 is applied to the water-based urethane layer 20 is passed through the dry oven 120 on the fabric fabric 10; A cooling step 200 for passing the fabric fabric 10 passing through the drying step 100 through the cooling rolls 210; A pressing step 300 through which the fabric fabric 10 passed through the cooling step 200 is pressed through the heating roll 310 and the silicon roll 320; A secondary coating (400) and a drying step (500), wherein the oil-based urethane surface treatment agent (30) is coated on the aqueous urethane layer (20) of the fabric fabric (10) through the pressing step (300); A cooling step 600 for passing the fabric fabric 10 through the second coating 400 and the drying step 500 through the cooling rolls 610; Softener coating step (700) to pass through the air oven 720, the softener layer 40 is immersed on the oil-based urethane surface treatment agent 30 on the fabric fabric 10 after the cooling step 600; have.

1차 코팅, 2차 코팅, 수성우레탄층, 유성우레탄 표면처리제, 유연제층 1st coating, 2nd coating, aqueous urethane layer, oily urethane surface treatment agent, softener layer

Description

직물원단의 코팅구조 및 코팅방법{Coating method and Coating structure of cloth}Coating method and coating structure of fabric

도 1 은 본 발명의 직물원단에 1차 코팅을 위한 개략 예시도,1 is a schematic illustration for the primary coating on the fabric fabric of the present invention,

도 2 는 본 발명의 1차 코팅된 원단을 냉각하는 로울 개략도,2 is a roll schematic diagram of cooling the primary coated fabric of the present invention;

도 3 은 본 발명의 1차 코팅된 원단을 압압하는 로울 개략도,3 is a roll schematic diagram of pressing the primary coated fabric of the present invention,

도 4 는 본 발명의 2차 코팅을 위한 개략 예시도,4 is a schematic illustration for the secondary coating of the present invention;

도 5 는 본 발명의 2차 코팅된 원단을 냉각하는 로울 개략도,5 is a roll schematic diagram of cooling the secondary coated fabric of the present invention;

도 6 은 본 발명의 2차 코팅된 원단에 유연제층을 형성하는 구성도, Figure 6 is a block diagram of forming a softener layer on the secondary coated fabric of the present invention,

도 7a,b,c,d,e 는 본 발명의 직물원단의 코팅구조의 구성예의 단면 확대도. Figure 7a, b, c, d, e is an enlarged cross-sectional view of a configuration example of the coating structure of the fabric fabric of the present invention.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

10 : 직물원단 20 : 수성우레탄층10: fabric fabric 20: aqueous urethane layer

30 : 유성우레탄 표면처리제 40 : 유연제층30 oily urethane surface treatment agent 40 softener layer

50 : 원단공급로울 60 : 원단감기로울50: fabric supply roll 60: fabric winding roll

100 : 건조단계 110 : 1mm나이프100: drying step 110: 1mm knife

120 : 드라이오븐 130 : 안내로울120: dry oven 130: guide roller

200 : 냉각단계 210 : 쿨링로울200: cooling step 210: cooling roll

300 : 압압단계 310 : 히팅로울300: pressing step 310: heating roll

320 : 실리콘로울 400 : 2차 코팅320: silicon roll 400: secondary coating

410 : 5mm나이프 420 : 드라이오븐410: 5 mm knife 420: Dry oven

500 : 건조단계 600 : 냉각단계500: drying step 600: cooling step

610 : 쿨링로울 700 : 유연제코팅단계610: cooling roll 700: softener coating step

710 : 혼합약품탱크 720 : 에어오븐710: mixed chemical tank 720: air oven

730 : 안내로울 730: guide roller

본 발명은 직물원단에 우레탄 코팅층을 형성하는 직물원단의 코팅구조 및 코팅방법에 관한 것으로, 더욱 상세하게는 직물원단에 수성우레탄층, 또한 수성우레탄층위에 유성우레탄 표면처리제가 형성되도록 하고, 또한 상기 유성우레탄 표면처리제의 위에 유연제층이 형성되도록 하여 직물원단에 방수 및 방풍의 효과를 가지며 그에 따른 뛰어난 보온성을 유지할 수 있으며, 더욱이 상기 직물원단에 수성우레탄층이 형성되고, 상기 수성우레탄층위에 형성된 유성우레탄 표면처리제에 왁스 및 오일성분의 유연제 및 침투제의 첨가에 의하여 일반 직물원단을 실크 스타일과 유사한 부드러운 질감이 형성되도록 하여 직물원단 자체를 고가 고품질의 직물을 형성할 수 있는 직물원단의 코팅구조 및 코팅방법에 관한 것이다. The present invention relates to a coating structure and a coating method of the fabric fabric to form a urethane coating layer on the fabric fabric, and more specifically to the aqueous urethane layer on the fabric fabric, and to form an oil-based urethane surface treatment agent on the aqueous urethane layer, The softening agent layer is formed on the oily urethane surface treatment agent to have the effect of waterproofing and windproofing on the fabric fabric and to maintain excellent heat retention accordingly. Furthermore, an aqueous urethane layer is formed on the fabric fabric, and the oily substance formed on the aqueous urethane layer The coating structure and coating of the fabric fabric which can form high quality fabric of the fabric fabric itself by forming a soft texture similar to the silk style by adding wax and oil softener and penetrant to the urethane surface treatment agent. It is about a method.

일반적으로, 직물원단의 코팅가공은 가이드로울에 의해 소정 방향으로 진행되는 직물원단의 표면상에 코팅재가 직접 접촉되도록 배치시킨 상태에서 이 직물의 표면에 코팅재가 도포되도록 하고, 이렇게 도포된 코팅재의 표면을 나이프로 긁어내어 코팅재의 두께를 조절하는 등 일련의 과정을 거치면서 코팅작업을 수행하는 나이프 코팅가공이 사용되고 있다. In general, the coating process of the fabric fabric is such that the coating material is applied to the surface of the fabric in a state in which the coating material is placed in direct contact with the surface of the fabric fabric proceeding in a predetermined direction by the guide roll, and the surface of the coating material thus applied Knife coating is used to perform a coating operation while going through a series of processes, such as scraping a knife to adjust the thickness of the coating material.

각종 직물원단은 사용목적에 따라서 그 표면에 코팅재로서 PU(폴리우레탄), 아크릴, 실리콘 등이 코팅되도록 하고, 또한 상기 코팅된 직물원단은 건조기를 통과하도록 되어 있다. According to the purpose of use, various fabrics are coated with PU (polyurethane), acrylic, silicone, etc. on the surface thereof, and the coated fabric is passed through a dryer.

이러한 코팅공정 중에서 직물의 표면에 코팅액을 도포한 후에는 건조를 하여야 하는데, 자연건조를 하게 되면 시간이 많이 소요되므로 열을 가하는 건조기를 통과하게 하여 열처리(건조)를 하고 있다. In this coating process, the coating solution is applied to the surface of the fabric and then dried. However, since it takes a lot of time to dry naturally, heat is passed through a dryer to apply heat.

섬유직물에 코팅을 하려면 PU, 아크릴, 실리콘 등의 수지를 유기용제(톨루엔, MEK, 솔벤트, 물 등)에 일정비율로 희석시켜 직물의 표면에 코팅하는 것으로, 열처리기 내부에 유입시켜 건조를 하는 과정에서 수지의 유기용제가 증발하여 직물원단에의 코팅에 불량품이 발생하는 경우도 있고, 또한 직물원단에 코팅제의 형성으로 직물원단에 방수 및 방풍의 효과를 가질 수 있으나, 직물원단이 코팅제의 형성으로 원래의 직물원단에 비하여 부드러움이 떨어지는 문제가 있었다.In order to coat textile fabrics, PU, acrylic, silicone and other resins are diluted in organic solvents (toluene, MEK, solvent, water, etc.) in a certain ratio and coated on the surface of the fabric. In some cases, the organic solvent of the resin evaporates and defective products may be generated in the coating on the fabric. Also, the formation of the coating on the fabric may have the effect of waterproofing and windproof the fabric. As a result, there was a problem that the softness is lower than the original fabric.

본 발명은 상기의 문제를 해소하기 위한 것으로, 본 발명은 직물원단 위에 수성우레탄층과 또한 수성우레탄층위에 유성우레탄 표면처리제의 형성으로 직물원단에 방수 및 방풍의 효과를 가지며 그에 따른 뛰어난 보온성을 유지할 수 있도록 함을 목적으로 한다. 또한 본 발명은 상기 수성우레탄층과 또한 수성우레탄층위에 유성우레탄 표면처리제가 형성된 직물원단 위에 유연제층의 형성으로, 일반 직물원단을 실크 스타일과 유사한 부드러운 질감이 형성되도록 하여 직물원단 자체를 고가 고품질의 직물을 형성할 수 있도록 함을 목적으로 한다. 또한 상기 수성우레탄층과 또한 수성우레탄층위에 유성우레탄 표면처리제가 형성된 직물원단이 히팅로울과 실리콘로울의 사이를 압압되어 통과하도록 함으로서, 직물원단에 수성우레탄층과 유성우레탄 표면처리제가 확실하게 점착 코팅되어 직물원단으로부터 코팅재가 분리이탈을 방지할 수 있고, 또한 직물원단에 방수 및 방풍의 효과를 가지며 그에 따른 뛰어난 보온성을 확실하게 유지할 수 있는 직물원단의 코팅구조 및 코팅방법을 제공하고자 한다. The present invention is to solve the above problems, the present invention has the effect of waterproofing and windproof to the fabric fabric by forming an aqueous urethane layer on the fabric fabric and also an oil-based urethane surface treatment agent on the aqueous polyurethane layer and thereby maintain excellent heat retention The purpose is to make it possible. In another aspect, the present invention is the formation of a softener layer on the water-based urethane layer and the fabric fabric on which the oil-based urethane surface treatment agent is formed on the water-based urethane layer, so that a soft texture similar to the silk style can be formed, the fabric fabric itself is expensive and high quality The purpose is to be able to form a fabric. In addition, the fabric fabric having the oil-based urethane surface treatment agent formed on the water-based urethane layer and the water-based urethane layer is pressed through the heating roll and the silicone roll, so that the water-based urethane layer and the oil-based urethane surface treatment agent are reliably coated on the fabric fabric. The coating material from the fabric fabric to prevent separation and separation, and also has a waterproof and windproof effect on the fabric fabric and to provide a coating structure and coating method of the fabric fabric can be surely maintained excellent thermal insulation.

본 발명은 직물원단 위에 우레탄 코팅층을 형성하는 직물원단의 코팅구조에 있어서, 상기 직물원단 위에 수성우레탄층이 형성되고, 상기 수성우레탄층위에 유성우레탄 표면처리제가 형성되고, 상기 유성우레탄 표면처리제의 위에 유연제층이 성형됨을 기본특징으로 한다.The present invention, in the coating structure of the fabric fabric to form a urethane coating layer on the fabric fabric, an aqueous urethane layer is formed on the fabric fabric, the oil-based urethane surface treatment agent is formed on the aqueous urethane layer, on the oil-based urethane surface treatment agent It is a basic feature that the softening agent layer is molded.

상기 본 발명의 상기 직물원단위에 수성우레탄층과 상기 유성우레탄 표면처리제가 압압 성형되어, 상기 유성우레탄 표면처리제의 위에 유연제층이 성형되어 있다.The aqueous urethane layer and the oil-based urethane surface treatment agent are press-molded on the raw fabric unit of the present invention, and a softening agent layer is formed on the oil-based urethane surface treatment agent.

또한, 본 발명의 직물원단 위에 우레탄 코팅층이 도포되어 건조기를 통과하여 건조하는 직물원단의 코팅방법에 있어서의 상기 직물원단 위에 수성우레탄층이 도포되어 드라이오븐을 통과하는 건조단계와; 상기 건조단계를 통과한 직물원단을 쿨링로울들을 통과하도록 하는 냉각단계와; 상기 냉각단계를 거친 직물원단이 히팅로울과 실리콘로울 사이를 통과하여 압압하는 압압단계와; 상기 압압단계를 거친 직물원단의 수성우레탄층위에 유성우레탄 표면처리제가 코팅하는 2차 코팅 및 건조단계와; 상기 2차 코팅 및 건조단계를 거친 직물원단을 쿨링로울들을 통과하도록 하는 냉각단계와; 상기 냉각단계를 거친 직물원단의 위에 유성우레탄 표면처리제 위에 유연제가 침지되어 에어오븐 등을 통과하도록 하는 유연제 코팅단계로 이루어진 직물원단의 코팅방법을 특징으로 한다. In addition, a drying step of applying a water-based urethane layer on the fabric fabric in the coating method of the fabric fabric in which the urethane coating layer is applied on the fabric fabric of the present invention and dried through a dryer; A cooling step of passing the fabric fabric passing the drying step through cooling rolls; A pressing step of pressing the fabric through the cooling step through a heating roll and a silicon roll; A secondary coating and drying step of coating the oil-based urethane surface treatment agent on the aqueous urethane layer of the fabric step through the pressing step; A cooling step of passing the fabric rolls through the second coating and drying steps through cooling rolls; It characterized in that the coating method of the fabric fabric consisting of a softener coating step to pass through the air oven by the softener is immersed on the surface of the oil-based urethane surface treatment agent after the cooling step.

본 발명의 구성 및 작용에 대하여 상세히 설명하면 다음과 같다.Hereinafter, the configuration and operation of the present invention will be described in detail.

도 1 은 본 발명의 직물원단에 1차 코팅을 위한 개략 예시도이고, 또한 도 2 는 본 발명의 1차 코팅된 원단을 냉각하는 로울 개략도이며, 또한 도 3 은 본 발명의 1차 코팅된 원단을 압압하는 로울 개략도이고, 또한 도 4 는 본 발명의 2차 코팅을 위한 개략 예시도이며, 또한 도 5 는 본 발명의 2차 코팅된 원단을 냉각하는 로울 개략도이고, 또한 도 6 은 본 발명의 2차 코팅된 원단에 유연제층을 형성하는 구성도이며, 또한 도 7a,b,c,d,e 는 본 발명의 직물원단의 코팅구조의 구성예의 단면 확대도이다.Figure 1 is a schematic illustration for the primary coating on the fabric fabric of the present invention, Figure 2 is a roll schematic diagram for cooling the primary coated fabric of the present invention, also Figure 3 is a primary coated fabric of the present invention Figure 4 is a schematic diagram of a roll for compressing the secondary coating of the present invention, and Figure 5 is a schematic view of the roll for cooling the secondary coated fabric of the present invention, and also Figure 6 Figure 7a, b, c, d, e is a cross-sectional enlarged view of the configuration of the coating structure of the fabric fabric of the present invention forming a softener layer on the secondary coated fabric.

본 발명의 직물원단의 코팅구조는 도 7a,b,c,d,e에 나타낸 바와 같이 직물원단에 수성우레탄층(20), 유성우레탄 표면처리제(30) 및 유연제층(40)가 형성된 것에 특징이 있다.The coating structure of the fabric fabric of the present invention is characterized in that the aqueous urethane layer 20, the oil-based urethane surface treatment agent 30 and the softening agent layer 40 is formed on the fabric fabric as shown in Figure 7a, b, c, d, e There is this.

상기 직물원단에 수성우레탄층(20), 유성우레탄 표면처리제(30) 및 유연제층(40)의 형성은 상기 직물원단(10) 위에 수성우레탄층(20)이 형성되고, 상기 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 형성되고, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형되어 있다. The aqueous urethane layer 20, the oil-based urethane surface treatment agent 30 and the softening agent layer 40 is formed on the fabric fabric, the aqueous urethane layer 20 is formed on the fabric fabric 10, the aqueous urethane layer 20 The oil-based urethane surface treatment agent 30 is formed on the above-mentioned, and the softening agent layer 40 is molded on the oil-based urethane surface treatment agent 30.

또한, 본 발명의 직물원단의 코팅구조는 상기 직물원단(10)위에 수성우레탄층(20)과 상기 유성우레탄 표면처리제(30)가 압압 성형되어, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형되어 있다. In addition, the coating structure of the fabric fabric of the present invention is formed by pressing the aqueous urethane layer 20 and the oil-based urethane surface treatment agent 30 on the fabric fabric 10, the softener layer on the oil-based urethane surface treatment agent 30 40 is molded.

상기 수성우레탄층은 The aqueous urethane layer

H2O 55∼60%, H 2 O 55-60%,

포름알데히드(Formaldehyde : HCHO) 0.1%Formaldehyde (HCHO) 0.1%

시안에틸렌(Acrylonitrile : CH2CHCN) 0.1%Cyanethylene (Acrylonitrile: CH 2 CHCN) 0.1%

고분자화되지 않은 단량체 0.5%
아세트산(CM COOH) 10.3%
아세트 알데히드(Cn3 CnO) 27%∼32%0.5% unpolymerized monomer
Acetic acid (CM COOH) 10.3%
Acetaldehyde (Cn 3 CnO) 27% to 32%

F-500 2% 이다.
(F-500 : 제품명으로서 수성계열의 물질의 점도를 올려 사용자의 사용을 용이하게 하는 제품)F-500 is 2%.
(F-500: Product name that raises the viscosity of water-based materials to facilitate user's use)

또한, 유성우레탄 표면처리제는In addition, the oil-based urethane surface treatment agent

폴리우레탄(Polyurethane(resin)) 10%Polyurethane (resin) 10%

메틸에틸렌(Methyl ethly ketone(M.E.K)) 38%Methyl ethly ketone (M.E.K) 38%

N.N-디메틸포름아미드(N.N-Dimethyl formamide(DMF)) 17%N.N-Dimethyl formamide (DMF) 17%

이소프로필알콜(1sopropyl alcohol 0.5%) 18%Isopropyl alcohol (1sopropyl alcohol 0.5%) 18%

톨루엔 11%Toluene 11%

첨가제(벤젠,에테르,아제토 등의 용제) 4%4% of additives (solvents such as benzene, ether, and azeto)

실리카(Silica) 2%이다Silica is 2%

또한, 유연제층은 In addition, the softener layer is

H2O 100%(순도)H 2 O 100% (purity)

침투제 5∼10%5-10% Penetrant

유연제 10∼15%으로 이루어져 있다.It consists of 10 to 15% of the softening agent.

다음, 본 발명의 직물원단의 코팅방법는 도 1 내지 도 6에 나타낸 바와 같은 일련의 과정을 거친다. Next, the coating method of the fabric fabric of the present invention is subjected to a series of processes as shown in Figs.

직물원단 위에 우레탄 코팅층이 도포되어 건조기를 통과하여 건조하는 직물원단의 코팅방법에 있어서, 상기 직물원단(10) 위에 수성우레탄층(20)이 도포되어 드라이오븐(120)을 통과하는 건조단계(100)와; 상기 건조단계(100)를 통과한 직물원단(10)을 쿨링로울(210)들을 통과하도록 하는 냉각단계(200)와; 상기 냉각단계(200)를 거친 직물원단(10)이 히팅로울(310)과 실리콘로울(320) 사이를 통과하여 압압하는 압압단계(300)와; 상기 압압단계(300)를 거친 직물원단(10)의 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 코팅하는 2차 코팅(400) 및 건조단계(500)와; 상기 2차 코팅(400) 및 건조단계(500)를 거친 직물원단(10)을 쿨링로울(610)들을 통과하도록 하는 냉각단계(600)와; 상기 냉각단계(600)를 거친 직물원단 (10)의 위에 유성우레탄 표면처리제(30) 위에 유연제층(40)가 침지되어 에어오븐(720) 등을 통과하도록 하는 유연제 코팅단계(700);로 이루어져 있다.In the coating method of the fabric fabric is a urethane coating layer is applied on the fabric fabric and dried through a dryer, the drying step 100 is applied to the water-based urethane layer 20 on the fabric fabric 10 and passes through a dry oven 120 (100) )Wow; A cooling step 200 for passing the fabric fabric 10 passing through the drying step 100 through the cooling rolls 210; A pressing step 300 through which the fabric fabric 10 passed through the cooling step 200 is pressed through the heating roll 310 and the silicon roll 320; A secondary coating (400) and a drying step (500), wherein the oil-based urethane surface treatment agent (30) is coated on the aqueous urethane layer (20) of the fabric fabric (10) through the pressing step (300); A cooling step 600 for passing the fabric fabric 10 through the second coating 400 and the drying step 500 through the cooling rolls 610; Softener coating step 700 to pass through the air oven 720, the softener layer 40 is immersed on the oil-based urethane surface treatment agent 30 on the fabric fabric 10 after the cooling step 600; have.

상기 직물원단(10) 위에 수성우레탄층(20)이 도포되어 드라이오븐(120)을 통과하는 건조단계(100)에서는 도 1 에 나타낸 바와 같이 코팅 및 건조기를 거치게 되는 데, 우선, 직물원단(10)을 기계투입하기 전에 1mm 나이프(110)를 사용할 경우 1㎡(Meter Square) 직물원단(10)의 넓이에 20g∼30g 고형분을 남게 한다. 1차 드라이오븐(120)의 온도 170℃ 셋팅, 또한 2차 드라이오븐(120)의 온도를 150℃로 셋팅한다.In the drying step 100 where the aqueous urethane layer 20 is applied on the fabric fabric 10 and passes through the dry oven 120, the coating and the dryer are subjected to the coating and dryer as shown in FIG. 1. In the case of using 1mm knife 110 before the machine is put into a 1m (Meter Square) fabric of the fabric 10 to the area of 20g to 30g solids remain. The temperature of the primary dry oven 120 is set at 170 ° C, and the temperature of the secondary dry oven 120 is set at 150 ° C.

상기 수성우레탄층은 The aqueous urethane layer

H2O 55∼60%, H 2 O 55-60%,

포름알데히드(Formaldehyde : HCHO) 0.1%Formaldehyde (HCHO) 0.1%

시안에틸렌(Acrylonitrile : CH2CHCN) 0.1%Cyanethylene (Acrylonitrile: CH 2 CHCN) 0.1%

고분자화되지 않은 단량체 0.5%
아세트산(CM COOH) 10.3%
아세트 알데히드(Cn3 CnO) 27%∼32%0.5% unpolymerized monomer
Acetic acid (CM COOH) 10.3%
Acetaldehyde (Cn 3 CnO) 27% to 32%

F-500 2% 이다.
(F-500 : 제품명으로서 수성계열의 물질의 점도를 올려 사용자의 사용을 용이하게 하는 제품)F-500 is 2%.
(F-500: Product name that raises the viscosity of water-based materials to facilitate user's use)

직물원단(10)이 원단공급로울(50)로부터 상기 코팅 및 드라이오븐 등을 거치도록 세팅하여 주행하도록 한다. 상기 원단공급로울(50)의 직물원단(10)은 코팅장치인 수성우레탄 공급 나이프(110)를 통과하면서, 직물원단(10)의 1㎡의 넓이에 수성우레탄의 고형분을 20g∼30g이 도포되게 된다. 또한 상기 직물원단(10)에 수성우레탄층의 도포시에 도포액의 중량으로 인한 원단 처짐을 방지하기 위하여 지지대(도시생략)등이 형성된다.The fabric fabric 10 is set to go through the coating and dry oven, etc. from the fabric supply roll 50 to run. The fabric fabric 10 of the fabric supply roll 50 is passed through the water-based urethane supply knife 110, which is a coating device, so that 20g to 30g of solid content of the water-based urethane is applied to the area of 1m 2 of the fabric fabric 10. do. In addition, a support (not shown) is formed to prevent the fabric from sagging due to the weight of the coating liquid when the aqueous urethane layer is applied to the fabric fabric 10.

직물원단(10)은 안내로울(130)들에 의하여 안내되어 주행하게 된다. 상기 안내로울(130)들 및 직물원단(10)은 구동원(도시생략)과 연결되어 주행할 수 있도록 되어 있다.The fabric fabric 10 is guided by the guide rolls 130 to travel. The guide rolls 130 and the fabric fabric 10 are connected to a driving source (not shown) to travel.

또한, 상기 주행은 직물원단에 도포액이 도포되어 전진 할 수 있도록 하며, 또한 백나이프(도시생략)는 직물원단이 변사 처짐 방지 및 좌우차 없이 도포량을 일정하게 유지하며 동시에 도포량 조절하게 된다.In addition, the driving is to advance the coating liquid is applied to the fabric fabric, and also the back knife (not shown) is to prevent the sagging of the fabric fabric and to maintain a constant coating amount without the difference between the left and right to adjust the amount of coating at the same time.

상기와 같이 도포된 직물원단(10)은 안내로울(130)들에 안내되어 드라이오븐(120)에 진입되며, 대략 60초간 건조가 행하도록 한다. The fabric fabric 10 applied as described above is guided to the guide rolls 130 to enter the dry oven 120, and to dry for about 60 seconds.

상기 드라이오븐(120)들을 통과한 직물원단(10)은 도 2 에 나타낸 바와 같이 쿨링로울(210)들로 이루어진 냉각단계(200)를 거치게 하여 쿨링로울(210)들에 의한 직물원단(10) 자체 열을 없애는 과정을 거친다.The fabric fabric 10 passing through the dry oven 120 is subjected to the cooling step 200 made of the cooling rolls 210 as shown in FIG. 2 to the fabric fabric 10 by the cooling rolls 210. It goes through the process of removing its own heat.

상기 냉각단계(200)를 거친 직물원단(10)은 다시 도 3에 나타낸 바와 같이 히팅로울(310)과 실리콘로울(320) 사이를 통과하여 압압하는 압압단계(300)를 거치게 된다.The fabric fabric 10 subjected to the cooling step 200 is subjected to the pressing step 300 of pressing through the heating roll 310 and the silicon roll 320 as shown in FIG. 3 again.

상기 압압단계에서는 히팅로울(310)과 실리콘로울(320)들이 직물원단(10)을 다림(눌림)작용과 또한 고온과 고압을 이용하여, 직물원단(10)의 수성우레탄층(20)의 코팅면을 최대한 매끄럽게 유지하는 작용을 행하게 된다. In the pressing step, the heating roll 310 and the silicon rolls 320 press the fabric fabric 10 and press the high temperature and high pressure to coat the aqueous urethane layer 20 of the fabric fabric 10. The action is to keep the surface as smooth as possible.

코팅 및 건조단계(100)와 냉각단계(200) 및 압압단계(300)들을 별도로 설치하여 원단공급로울들에 감아 이동하도록 하여도 된다.The coating and drying step 100, the cooling step 200, and the pressing step 300 may be separately installed to be wound around the fabric supply rollers.

바람직하기로는, 상기 코팅 및 건조단계(100), 냉각단계(200) 및 압압단계 (300)를 일련의 연속단계 시스템의 자동처리로 행하도록 하는 것이 작업능률의 향상을 도모할 수 있다. Preferably, the coating and drying step 100, the cooling step 200 and the pressing step 300 to be performed by the automatic treatment of a series of continuous step system may improve the work efficiency.

또한, 상기 수성우레탄층(20)이 형성된 직물원단(10)은 상기 압압단계(300)를 거친 후에, 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 코팅하는 도 4에 나타낸 바와 같이 2차 코팅(400) 및 건조단계(500)를 거치도록 한다.In addition, the fabric fabric 10 formed with the aqueous urethane layer 20 after the pressing step 300, as shown in Figure 4 coated with an oil-based urethane surface treatment agent 30 on the aqueous urethane layer 20 The secondary coating 400 and the drying step 500 to pass through.

우선, 직물원단(10)을 2차 코팅(400) 및 건조단계(500)의 기계에 투입하기 전에 5mm 나이프(410)를 1,2차 과정에 사용하도록 하고, 1차 드라이오븐(420)의 온도 150℃ 셋팅, 또한 2차 드라이오븐(420)의 온도를 150℃로 셋팅하며, 직물원단(10)이 상기 드라이오븐(420)들을 60초간 통과하도록 하여 건조하도록 한다. First, before the fabric fabric 10 is introduced into the machine of the secondary coating 400 and the drying step 500, the 5mm knife 410 is used in the first and second processes, and the primary dry oven 420 Setting the temperature 150 ° C, and also set the temperature of the secondary dry oven 420 to 150 ° C, the fabric fabric 10 to pass through the dry oven (420) for 60 seconds to dry.

상기 유성우레탄 표면처리제는The oil-based urethane surface treatment agent

폴리우레탄(Polyurethane(resin)) 10%Polyurethane (resin) 10%

메틸에틸렌(Methyl ethly ketone(M.E.K)) 38%Methyl ethly ketone (M.E.K) 38%

N.N-디메틸포름아미드(N.N-Dimethyl formamide(DMF)) 17%N.N-Dimethyl formamide (DMF) 17%

이소프로필알콜(1sopropyl alcohol 0.5%) 18%Isopropyl alcohol (1sopropyl alcohol 0.5%) 18%

톨루엔 11%Toluene 11%

첨가제(벤젠,에테르,아제토 등의 용제) 4%4% of additives (solvents such as benzene, ether, and azeto)

실리카(Silica) 2%이다Silica is 2%

상기 2차 코팅(400)은 앞서 설명한 1차 코팅 및 건조단계와 같은 시스템과 동일한 것으로, 다만, 1,2차 과정에 5mm의 나이프(410)들을 형성한 것이어서, 그 구성에 대한 상세 설명은 생략하기로 한다. The secondary coating 400 is the same as the system of the first coating and drying step described above, but, 5 mm knives 410 are formed in the first and second processes, detailed description of the configuration is omitted. Let's do it.

상기 2차 코팅(400) 및 건조단계(500)를 거친 직물원단(10)은 다시 도 5에 나타낸 바와 같은 쿨링로울(610)들을 통과하도록 하는 냉각단계(600)를 거쳐 직물원단(10)을 냉각하도록 한다.After the second coating 400 and the drying step 500, the fabric fabric 10 passes through the fabric fabric 10 through a cooling step 600 to pass through the cooling rolls 610 as shown in FIG. Allow it to cool.

상기 냉각단계(600)를 거친 직물원단(10)의 위에 유성우레탄 표면처리제(30) 위에 유연제층(40)가 침지되어 에어오븐(720) 등을 통과하도록 하는 유연제 코팅단계(700)를 거친다.The softener layer 40 is immersed on the oily urethane surface treatment agent 30 on the fabric fabric 10 that has undergone the cooling step 600 and passes through the softener coating step 700 for passing through the air oven 720 and the like.

상기 유연제 코팅단계(700)는 우선 도 6 에 나타낸 바와 같이 혼합약품탱크(710) 및 에어오븐(720)들을 거치게 되는 데, 직물원단(10)을 기계투입하기 전에 에어오븐(720)을 120℃로 셋팅한다. 또한 혼합약품탱크(710)에는 H2O : 100%(순도), 침투제 : 5∼10%, 유연제 : 10∼15%용액이 수용되도록 한다. The softener coating step 700 is first subjected to the mixed chemical tank 710 and the air oven 720 as shown in FIG. Set to. In addition, in the mixed chemical tank 710, H 2 O: 100% (purity), penetrant: 5 to 10%, softener: 10 to 15% solution is to be accommodated.

직물원단(10)이 원단공급로울(50)로부터 상기 혼합액품탱크(710)에 침지 및 에어오븐(720) 등을 거치도록 세팅하여 주행하도록 한다.The fabric fabric 10 is set so as to pass through the immersion and the air oven 720, etc. from the fabric supply roll 50 to the mixed liquid product tank 710.

유연제 코팅단계(700)에서 도 6에 나타낸 바와 같이 직물원단(10)은 원단공급로울(50)로부터 유연제의 혼합약품탱크(710)를 침지되어 통과하게 되며, 이어서 에어오븐(720)들에 안내로울(730)들에 의하여 안내 주행하도록 하여 원단감기로울(60)에 감겨지게 한다.In the softening agent coating step 700, as shown in Figure 6, the fabric fabric 10 is immersed through the mixed chemical tank 710 of the softening agent from the fabric supply roll 50, and then guided to the air ovens 720 Guide rolls by the rolls 730 are wound around the fabric roll 60.

이상과 같이, 본 발명은 직물원단에 수성우레탄층, 또한 수성우레탄층위에 유성우레탄 표면처리제가 형성되도록 하고, 또한 상기 유성우레탄 표면처리제의 위에 유연제층이 형성되도록 하여 직물원단에 방수 및 방풍의 효과를 가지며 그에 따른 뛰어난 보온성을 유지할 수 있으며, 더욱이 상기 직물원단에 수성우레탄층이 형성되고, 상기 수성우레탄층위에 형성된 유성우레탄 표면처리제에 왁스 및 오일성분의 유연제 및 침투제의 첨가에 의하여 일반 직물원단을 실크 스타일과 유사한 부드러운 질감이 형성되도록 하여 직물원단 자체를 고가 고품질의 직물을 형성할 수 있다. As described above, the present invention is to form an oil-based urethane surface treatment agent on the water-based urethane layer, and also the water-based urethane layer on the fabric fabric, and also to form a softening agent layer on the oil-based urethane surface treatment agent, the effect of waterproof and windproof on the fabric fabric It is possible to maintain excellent heat retention accordingly, and furthermore, a water-based urethane layer is formed on the fabric fabric, and the general fabric fabric by adding a wax and oil-based softener and penetrant to the oil-based urethane surface treatment agent formed on the water-based urethane layer By forming a soft texture similar to the silk style, the fabric fabric itself can form expensive and high quality fabric.

Claims (3)

직물원단 위에 우레탄 코팅층을 형성하는 직물원단의 코팅구조에 있어서, In the coating structure of the fabric fabric to form a urethane coating layer on the fabric fabric, 상기 직물원단(10) 위에 수성우레탄층(20)이 형성되고, 상기 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 형성되고, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형됨을 특징으로 하는 직물원단의 코팅구조.An aqueous urethane layer 20 is formed on the fabric fabric 10, an oil-based urethane surface treating agent 30 is formed on the aqueous urethane layer 20, and a softening agent layer 40 is formed on the oil-based urethane surface treating agent 30. ) Is a coating structure of the fabric fabric, characterized in that molded. 제 1 항에 있어서, 상기 직물원단(10)위에 수성우레탄층(20)과 상기 유성우레탄 표면처리제(30)가 압압 성형되어, 상기 유성우레탄 표면처리제(30)의 위에 유연제층(40)이 성형됨을 특징으로 하는 직물원단의 코팅구조. According to claim 1, wherein the aqueous urethane layer 20 and the oil-based urethane surface treatment agent 30 is pressed on the fabric fabric 10, the softener layer 40 is formed on the oil-based urethane surface treatment agent 30 Coating structure of fabric fabric, characterized in that. 직물원단 위에 우레탄 코팅층이 도포되어 건조기를 통과하여 건조하는 직물원단의 코팅방법에 있어서, In the coating method of the fabric fabric is a urethane coating layer is applied on the fabric fabric and dried through a dryer, 상기 직물원단(10) 위에 수성우레탄층(20)이 도포되어 드라이오븐(120)을 통과하는 건조단계(100)와; 상기 건조단계(100)를 통과한 직물원단(10)을 쿨링로울(210)들을 통과하도록 하는 냉각단계(200)와; 상기 냉각단계(200)를 거친 직물원단(10)이 히팅로울(310)과 실리콘로울(320) 사이를 통과하여 압압하는 압압단계(300)와; 상기 압압단계(300)를 거친 직물원단(10)의 수성우레탄층(20)위에 유성우레탄 표면처리제(30)가 코팅하는 2차 코팅(400) 및 건조단계(500)와; 상기 2차 코팅(400) 및 건조단계(500)를 거친 직물원단(10)을 쿨링로울(610)들을 통과하도록 하 는 냉각단계(600)와; 상기 냉각단계(600)를 거친 직물원단(10)의 위에 유성우레탄 표면처리제(30) 위에 유연제층(40)가 침지되어 에어오븐(720) 등을 통과하도록 하는 유연제 코팅단계(700);로 이루어짐을 특징으로 하는 직물원단의 코팅방법. A drying step 100 having a water-based urethane layer 20 coated on the fabric fabric 10 and passing through the dry oven 120; A cooling step 200 for passing the fabric fabric 10 passing through the drying step 100 through the cooling rolls 210; A pressing step 300 through which the fabric fabric 10 passed through the cooling step 200 is pressed through the heating roll 310 and the silicon roll 320; A secondary coating (400) and a drying step (500), wherein the oil-based urethane surface treatment agent (30) is coated on the aqueous urethane layer (20) of the fabric fabric (10) through the pressing step (300); A cooling step (600) through which the fabric fabric (10) passed through the secondary coating (400) and the drying step (500) passes through the cooling rolls (610); Softener coating step 700 to pass through the air oven 720, the softener layer 40 is immersed on the oil-based urethane surface treatment agent 30 on the fabric fabric 10, the cooling step (600); Coating method of the fabric fabric, characterized in that.
KR1020050109722A 2005-11-16 2005-11-16 Coating method and coating structure of cloth KR100717903B1 (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101220687B1 (en) 2012-06-29 2013-01-10 코오롱인더스트리 주식회사 Textile coating solution with graphite, manufacturing method of textile coated with graphite and textile coated with graphite
KR101242008B1 (en) 2011-10-18 2013-03-11 주식회사 썬문인터내셔널 Method for forming a shibori of cotton and a shibori formed by the method
KR101342640B1 (en) 2013-04-08 2013-12-20 주식회사 진명 Coating apparatus of fabric
KR101503649B1 (en) 2014-08-25 2015-03-17 이교흥 Coating apparatus of fabric
KR20150100343A (en) * 2014-02-25 2015-09-02 석명희 Method for processing of Wet Face
KR20170071792A (en) 2015-12-16 2017-06-26 콜로디스 바이오사이언스, 인코포레이티드 Functional coating composition and fabric using the same
KR101931656B1 (en) 2017-04-19 2018-12-21 이화선 Apparatus and method for manufacturing film yarn sheet coated natural stone

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101242008B1 (en) 2011-10-18 2013-03-11 주식회사 썬문인터내셔널 Method for forming a shibori of cotton and a shibori formed by the method
KR101220687B1 (en) 2012-06-29 2013-01-10 코오롱인더스트리 주식회사 Textile coating solution with graphite, manufacturing method of textile coated with graphite and textile coated with graphite
KR101342640B1 (en) 2013-04-08 2013-12-20 주식회사 진명 Coating apparatus of fabric
KR20150100343A (en) * 2014-02-25 2015-09-02 석명희 Method for processing of Wet Face
KR101582402B1 (en) 2014-02-25 2016-01-04 석명희 Method for processing of Wet Face
KR101503649B1 (en) 2014-08-25 2015-03-17 이교흥 Coating apparatus of fabric
KR20170071792A (en) 2015-12-16 2017-06-26 콜로디스 바이오사이언스, 인코포레이티드 Functional coating composition and fabric using the same
KR101931656B1 (en) 2017-04-19 2018-12-21 이화선 Apparatus and method for manufacturing film yarn sheet coated natural stone

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