CN108192768A - A kind of rubber on table tennis bat detergent and preparation method thereof - Google Patents

A kind of rubber on table tennis bat detergent and preparation method thereof Download PDF

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Publication number
CN108192768A
CN108192768A CN201810054271.3A CN201810054271A CN108192768A CN 108192768 A CN108192768 A CN 108192768A CN 201810054271 A CN201810054271 A CN 201810054271A CN 108192768 A CN108192768 A CN 108192768A
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rubber
table tennis
tennis bat
detergent
surfactant
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CN108192768B (en
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任海波
付贝贝
张伟云
徐文升
王哲
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Henan University of Urban Construction
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Henan University of Urban Construction
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/16Anti-static materials
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of rubber on table tennis bat detergents and preparation method thereof, belong to detergent technical field.The rubber on table tennis bat detergent of the present invention, is made of the component of Fructus Gleditsiae Abnormalis extract and following parts by weight:0.5~3 part of quaternary ammonium salt, 0.5~3 part of surfactant, 0.05~0.2 part of preservative, 0.01~0.2 part of antifoaming agent, 5~20 parts of water.The rubber on table tennis bat detergent of the present invention, Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt, nonionic surface active agent and zwitterionic surfactant are compounded, performance cleaning dirt-removing functions can not only be cooperateed with, and its property is stable, foam is small, wetability is good, also there is antibacterial and anti-static ability simultaneously, ensure that rubber on table tennis bat, there are one good performances.

Description

A kind of rubber on table tennis bat detergent and preparation method thereof
Technical field
The present invention relates to a kind of rubber on table tennis bat detergents and preparation method thereof, belong to detergent technical field.
Background technology
Table tennis is the national ball game in China, since it integrates gymnastics, athletics and recreational, is had in China widely Mass foundation.In enterprise, organ, school and community, open up one or more table tennis places and be almost these units and open Open up the first choice of sports for all activity.Since general place is difficult to the requirement for reaching standardization table tennis venue, table tennis Ball rolls down to be stained with the dirts such as dust, oil stain and is difficult to avoid that, and the batting for passing through racket is adsorbed onto rubber on table tennis bat table on the ground Face;In addition, the sweat stain generated in motion process also can be accidentally adhered on rubber on table tennis bat;These can all pollute table tennis Racket rubber, so as to influence the health of the using effect of racket and user.Also, if these spot long-term existence are in table tennis On racket rubber and without cleaning, can also large effect be generated to the service life of rubber on table tennis bat.
In addition, contacted by racket square stance table tennis with racket rubber hold it is easy to produce static electricity, influence table tennis and send out Rotation direction afterwards reduces the accuracy rate of placement, and then influences the horizontal of paddler and play.
In conclusion it is the work that each table tennis fan must do to the cleaning maintenance of rubber on table tennis bat.
Application publication number is that the Chinese invention patent of CN 106318688A discloses a kind of rubber on table tennis bat cleaning solution, Mass percent shared by its constituent and each ingredient is respectively:Clean carrier 22~31%, quaternary ammonium base 15~21%, fat Alcohol polyoxyethylene ether 4~8%, cocoanut fatty acid diethanolamide 5~9%, sodium sulfate of polyethenoxy ether of fatty alcohol 2~4%, Auxiliary agent 1~3%, surplus are deionized water;The cleaning carrier is epoxy resin, the constituent of the auxiliary agent and each ingredient The percentage for accounting for auxiliary agent quality is respectively stabilizer 55~75%, pH adjusting agent 10~32%, antifoaming agent 10~30%.This is specially Rubber on table tennis bat cleaning solution disclosed in profit is needed using the epoxy resin after activating as carrier, and the activation of epoxy resin needs 200 DEG C or more carry out, and prepare relatively complicated;Raw material is complex, also needs to add in the auxiliary agents such as stabilizer, pH adjusting agent;Separately The dirt-removing power of cleaning solution still needs to be further improved disclosed in the outer patent.
Invention content
The purpose of the present invention is to provide a kind of strong rubber on table tennis bat detergents of dirt-removing power.
Second object of the present invention is to provide a kind of preparation method of above-mentioned rubber on table tennis bat detergent.
To achieve the above object, the technical scheme is that:
A kind of rubber on table tennis bat detergent, is made of the component of Fructus Gleditsiae Abnormalis extract and following parts by weight:Quaternary ammonium salt 0.5 ~3 parts, 0.5~3 part of surfactant, 0.05~0.2 part of preservative, 0.01~0.2 part of antifoaming agent, 5~20 parts of water.
The Fructus Gleditsiae Abnormalis extract is the corresponding active ingredient extracted from gleditsia sinensis.
The Fructus Gleditsiae Abnormalis extract is gleditsia sinensis extracting solution, and the gleditsia sinensis extracting solution is by the preparation method system that includes the following steps :The gleditsia sinensis of 15~30 mass fractions is crushed after impregnating 40~120min in 60~190 parts of water, is filtered to obtain the final product.Above-mentioned side The whole raw material as above-mentioned rubber on table tennis bat detergent of gleditsia sinensis extracting solution made from method.
Above-mentioned 5~20 parts of water refers to add in 5~20 parts of water in addition to gleditsia sinensis extracting solution.
The gleditsia sinensis is cleaned before crushing, drying and processing.The temperature of the drying is 70~110 DEG C.
Above-mentioned gleditsia sinensis is sieved after being pulverized.The sieving was 12~24 mesh sieve.
The quaternary ammonium salt is hexadecyltrimethylammonium chloride, octadecyltrimethylammonium chloride, dodecyl dimethyl Any one or a few in benzyl ammonium chloride.Quaternary ammonium salt also has other than being used as surfactant in table tennis bat Rubber surface prevents the effect of electrostatic;In addition, organic cation positively charged in quaternary ammonium compound can be by band The selective bacterium absorption of negative electrical charge, by infiltration and diffusion, enters cell membrane, so as to block cell across bacterium surface The semi-permeable effect of film, and cell interior is further penetrated through, make cell enzymatic inactivation, it is impossible to protease is generated, so as to make albumen Qualitative change has the function that kill bacterial cell.
The surfactant for nonionic surfactant, in zwitterionic surfactant any one or it is several Kind.
The nonionic surfactant is fatty alcohol polyoxyethylene ether, in lauric acid amide of ethanol, alkyl glycosides Any one or a few.
The preferred lauryl glucosyl of alkyl glycosides.
Above-mentioned nonionic surfactant preferred fat alcohol polyoxyethylene ether.In the fatty alcohol polyoxyethylene ether molecule Ehter bond is not easy to be destroyed by acid, alkali, and stability is high, and water-soluble good, electrolyte-resistant is readily biodegradable, and can be lived with other surfaces Property agent excellent fit 5.
Above-mentioned zwitterionic surfactant is betaines surfactant.
Preferably, the zwitterionic surfactant is dodecanamide propyl hydroxy sulfo lycine, dodecanamide propyl Any one or a few in glycine betaine, cocamidopropyl propyl amide hydroxy sulfo lycine, Cocoamidopropyl betaine.Above-mentioned beet Bases zwitterionic surfactant is nontoxic, irritation is small, and soluble easily in water, dirt-removing power is strong, steady under acid and alkaline condition It is qualitative good, it can be used in compounding with nonionic surface active agent, compatibility is good.Using nonionic surfactant and two Property ionic surface active agent compounding, can cooperate with enhancing gleditsia sinensis extracting solution clean-up performance.
Foregoing preservatives are the preservative that alkaline system is suitble to use.
Preferably, the preservative is any one or a few in sodium benzoate, potassium sorbate, calcium propionate.
Above-mentioned antifoaming agent is polyethers antifoaming agent.
Preferably, the antifoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, gathers Any one or a few in oxypropylene glycerin ether.
For ease of using, rubber on table tennis bat detergent of the invention is dispensed using the spray bottle of different capabilities.
Above-mentioned rubber on table tennis bat detergent when in use, is sprayed on rubber on table tennis bat surface, place 5~10s into Row wiping.
The rubber on table tennis bat detergent of the present invention prepares Fructus Gleditsiae Abnormalis extract using gleditsia sinensis as raw material, complex quaternary ammonium salts, it is non-from Subtype surfactant, zwitterionic surfactant and other auxiliary agents, property is stable, foam is small, wetting and strong detergency, tool There is antibiotic property and can prevent rubber from generating electrostatic, so as to which rubber on table tennis bat is made to keep good performance.Wherein, gleditsia sinensis (i.e. Chinese honey locust) is the fruit of pulse family Gleditsia plant Chinese honey locust, is good day containing ingredients such as abundant gledinin, gleditschiasaponins Right surface reactive material, also with bacteriostasis.The present invention is by Fructus Gleditsiae Abnormalis extract and quaternary surfactant, non-ionic table Face activating agent and zwitterionic surfactant compounding can not only cooperate with performance cleaning dirt-removing functions, remove table tennis bat very well The dirt of rubber surface attachment, and can sterilize, is antistatic, safety and environmental protection is harmless.
The preparation method of above-mentioned rubber on table tennis bat detergent, includes the following steps:
By Fructus Gleditsiae Abnormalis extract, quaternary ammonium salt, surfactant, preservative, antifoaming agent, water mixing to get.
The Fructus Gleditsiae Abnormalis extract is the corresponding active ingredient extracted from gleditsia sinensis.
The Fructus Gleditsiae Abnormalis extract is gleditsia sinensis extracting solution, and the gleditsia sinensis extracting solution is by the preparation method system that includes the following steps :The gleditsia sinensis of 15~30 mass fractions is crushed after impregnating 40~120min in 60~190 parts of water, is filtered to obtain the final product.
The gleditsia sinensis is cleaned before crushing, drying and processing.The temperature of the drying is 70~110 DEG C.
Above-mentioned gleditsia sinensis is sieved after being pulverized.The sieving was 12~24 mesh sieve.
Above-mentioned mixing for will first be added after Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt mixing surfactant, preservative, antifoaming agent, Water mixing.
The mixing of above-mentioned Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt is:The mixing of Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt solution.
The preparation of the quaternary ammonium salt solution includes the following steps:0.5~3 part of quaternary ammonium salt is dissolved in 3~20 parts of water, mixing To obtain the final product.
The rubber on table tennis bat detergent of the present invention, by Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt, nonionic surface active agent and Zwitterionic surfactant compounds, and can not only cooperate with performance cleaning dirt-removing functions, and its property is stable, foam is small, wetting Property it is good, while also there is antibacterial and anti-static ability, ensure that rubber on table tennis bat there are one good performance.
The preparation method of rubber on table tennis bat detergent of the present invention is simple, and low in raw material price, production cost is relatively low, operation Simplicity, suitable for large-scale industrial production application.
Specific embodiment
Embodiment 1
The rubber on table tennis bat detergent of the present embodiment, is made of the component of gleditsia sinensis extracting solution and following parts by weight:Ten Six 0.5 part of alkyl trimethyl ammonium chlorides, 0.5 part of fatty alcohol polyoxyethylene ether, 0.05 part of potassium sorbate, polyoxyethylene polyoxypropylene 0.05 part of pentaerythrite ether, 5 parts of deionized water;The preparation method of gleditsia sinensis extracting solution is as follows:15 parts of gleditsia sinensis are cleaned after 70 DEG C Drying, then crushed 12 mesh sieve, adds in 75 parts of deionized waters impregnate 60min later, filter to obtain the final product.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 15 parts of gleditsia sinensis are cleaned after 70 DEG C of drying, then crushed 12 mesh sieve, add in 75 parts of deionized waters later 60min is impregnated, filters to obtain gleditsia sinensis extracting solution;
2) 0.5 part of hexadecyltrimethylammonium chloride is put into container, adds in 3 parts of deionized waters and be made into cetyl three Methyl chloride ammonium salt solution;
3) hexadecyltrimethylammonium chloride solution is added in gleditsia sinensis extracting solution and be uniformly mixed, then added 0.5 part of fatty alcohol polyoxyethylene ether, 0.05 part of potassium sorbate and 0.05 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 2 parts go Ionized water, continue to be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 100ml.
Embodiment 2
The rubber on table tennis bat detergent of the present embodiment, is made of the component of gleditsia sinensis extracting solution and following parts by weight:Ten Six 1 part of alkyl trimethyl ammonium chlorides, 2 parts of fatty alcohol polyoxyethylene ether, 0.1 part of potassium sorbate, polyoxyethylene polyoxypropylene season penta Four 0.1 part of alcohol ethers, 10 parts of deionized water;The preparation method of above-mentioned gleditsia sinensis extracting solution includes the following steps:20 parts of gleditsia sinensis are weighed to wash Only it after 110 DEG C of drying, then crushed 24 mesh sieve, add in 110 parts of deionized waters impregnate 100min later, filter to obtain the final product.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 20 parts of gleditsia sinensis are weighed to clean after 110 DEG C of drying, 24 mesh sieve is then crushed, adds in 110 parts of deionizations later 100min is impregnated in water, filters to obtain gleditsia sinensis extracting solution;
2) it weighs 1 part of hexadecyltrimethylammonium chloride to be put into container, adds in 5 parts of deionized waters and be made into cetyl three Methyl chloride ammonium salt solution;
3) hexadecyltrimethylammonium chloride solution is added in gleditsia sinensis extracting solution and be uniformly mixed, then add 2 Part fatty alcohol polyoxyethylene ether, 0.1 part of potassium sorbate and 0.1 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 5 parts of deionizations Water, continue to be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 50ml.
Embodiment 3
The rubber on table tennis bat detergent of the present embodiment, is made of the component of gleditsia sinensis extracting solution and following parts by weight:Ten Eight 0.5 part of alkyl trimethyl ammonium chlorides, 0.5 part of fatty alcohol polyoxyethylene ether, 0.05 part of sodium benzoate, polypropylene glycerol aether 0.05 part, 5 parts of deionized water;The preparation method of above-mentioned gleditsia sinensis extracting solution includes the following steps:Weigh 25 parts of gleditsia sinensis clean after 90 DEG C of drying, then crushed 20 mesh sieve, add in 95 parts of deionized waters impregnate 80min later, filter to obtain the final product.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 25 parts of gleditsia sinensis are weighed to clean after 90 DEG C of drying, 20 mesh sieve is then crushed, adds in 95 parts of deionized waters later Middle immersion 80min filters to obtain gleditsia sinensis extracting solution;
2) it weighs 0.5 part of octadecyltrimethylammonium chloride to be put into container, adds in 3 parts of deionized waters and be made into octadecyl Trimethyl ammonia chloride ammonium salt solution;
3) octadecyltrimethylammonium chloride solution is added in gleditsia sinensis extracting solution and be uniformly mixed, then added 0.5 part of fatty alcohol polyoxyethylene ether, 0.05 part of sodium benzoate, 0.05 part of polypropylene glycerol aether, 2 parts of deionized waters, continue to stir Mix be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 100ml.
Embodiment 4
The rubber on table tennis bat detergent of the present embodiment, is made of the raw material of gleditsia sinensis extracting solution and following parts by weight:Ten Eight 1 part of alkyl trimethyl ammonium chlorides, 1 part of dodecanamide propyl hydroxy sulfo lycine, 0.1 part of potassium sorbate, polyoxypropylene glyceryl 0.1 part of ether, 10 parts of deionized water.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 30 parts of gleditsia sinensis are weighed to clean after 100 DEG C of drying, 12 mesh sieve is then crushed, adds in 190 parts of deionizations later 120min is impregnated in water, filters to obtain gleditsia sinensis extracting solution;
2) it weighs 1 part of octadecyltrimethylammonium chloride to be put into container, adds in 5 parts of deionized waters and be made into octadecyl three Methyl chloride ammonium salt solution;
3) octadecyltrimethylammonium chloride solution is added in gleditsia sinensis extracting solution and be uniformly mixed, then add 1 Part dodecanamide propyl hydroxy sulfo lycine, 0.1 part of potassium sorbate, 0.1 part of polypropylene glycerol aether, 5 parts of deionized waters, continue Be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 50ml.
Embodiment 5
The rubber on table tennis bat detergent of the present embodiment, is made of the component of gleditsia sinensis extracting solution and following parts by weight:Ten 1 part of dialkyl dimethyl benzyl ammonium chloride, 2 parts of octadecyltrimethylammonium chloride, cocamidopropyl propyl amide hydroxy sulfo lycine 1 Part, 2 parts of lauric acid amide of ethanol, 0.1 part of calcium propionate, 0.1 part of sodium benzoate, 0.01 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 15 parts of deionized water;The preparation method of above-mentioned gleditsia sinensis extracting solution includes the following steps:18 parts of gleditsia sinensis are weighed to clean after 100 DEG C of bakings It is dry, it then crushed 12 mesh sieve, add in 85 parts of deionized waters impregnate 40min later, filter to obtain the final product.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 18 parts of gleditsia sinensis are weighed to clean after 100 DEG C of drying, 12 mesh sieve is then crushed, adds in 85 parts of deionized waters later Middle immersion 40min filters to obtain gleditsia sinensis extracting solution;
2) 2 parts of octadecyltrimethylammonium chloride are weighed, 1 part of dodecyl benzyl dimethyl ammonium chloride is put into container, It adds in 10 parts of deionized waters and is made into quaternary ammonium salt solution;
3) quaternary ammonium salt solution is added in gleditsia sinensis extracting solution obtained by step 1) and be uniformly mixed, then add 1 portion of coconut palm Oleamide hydroxysultaine, 2 parts of lauric acid amide of ethanol, 0.1 part of calcium propionate, 0.1 part of sodium benzoate, 0.01 part it is poly- Ethylene oxide polyoxy propyl alcohol amidogen ether, 5 parts of deionized waters, continue to be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 50ml.
Embodiment 6
The rubber on table tennis bat detergent of the present embodiment, is made of the component of gleditsia sinensis extracting solution and following parts by weight:Ten 2 parts of dialkyl dimethyl benzyl ammonium chloride, 1.5 parts of Cocoamidopropyl betaine, 1 part of lauryl glucosyl, calcium propionate 0.1 part, 0.2 part of polypropylene glycerol aether, 20 parts of deionized water;The preparation method of above-mentioned gleditsia sinensis extracting solution includes the following steps: It weighs 30 parts of gleditsia sinensis to clean after 90 DEG C of drying, then crushed 12 mesh sieve, add in 180 parts of deionized waters impregnate later 70min is filtered to obtain the final product.
The preparation method of the rubber on table tennis bat detergent of the present embodiment, includes the following steps:
1) 30 parts of gleditsia sinensis are weighed to clean after 90 DEG C of drying, 12 mesh sieve is then crushed, adds in 180 parts of deionized waters later Middle immersion 70min filters to obtain gleditsia sinensis extracting solution;
2) 2 parts of dodecyl benzyl dimethyl ammonium chlorides are weighed to be put into container, 10 parts of deionized waters is added in and is made into 12 Zephiran solution;
3) dodecyl benzyl dimethyl ammonium chloride solution is added in gleditsia sinensis extracting solution obtained by step 1) and be stirred It is even, it is sweet then to add 1.5 parts of Cocoamidopropyl betaines, 1 part of alkyl glycosides, 0.1 part of calcium propionate, 0.2 part of polyoxypropylene Oily ether, 10 parts of deionized waters, continue to be uniformly mixed to get;
4) rubber on table tennis bat detergent obtained by step 3) is dispensed using the spray bottle of 50ml.
Experimental example
The test of stability, wetability and soil removal efficiency is carried out to the rubber on table tennis bat detergent in embodiment 1-6:
The test of stability:Each sample is placed in Clear glass bottles and jars, stands 30 days at -10 DEG C and 50 DEG C respectively, observation As a result.
The test of wetability is the progress contact angle survey on " Double Happiness hurricane III " and " friendship 729-5 " rubber on table tennis bat Amount.
Clean-up performance test method is specially:Take the sheet glass of 15cm × 15cm, check weighing W1, on glass one layer of coating weigh about 50 grams of dirt (is made of the component of following mass percent:Chicken fat 50%, vegetable oil 20%, flour 20%, catsup 5%, Particulate sugar 5%), check weighing W2, 5 grams of detergents are uniformly sprayed on glass, after being placed at room temperature for 15min, are rinsed with water, are dried, Check weighing W3, soil removal efficiency is calculated further according to following formula:Soil removal efficiency=[(W2-W3)/(W2-W1)] × 100%.Test result is as shown in table 1.
The performance test data of rubber on table tennis bat detergent in 1 embodiment 1-6 of table
By 1 content of table it is found that the rubber on table tennis bat detergent of the present invention at -10 DEG C still without there is icing phenomenon, 50 DEG C For clear state, excellent in stability;Contact angle with rubber on table tennis bat is 2 °~4 °, and contact angle is small, is close to 0, illustrates this The wetability of detergent and rubber on table tennis bat is good, further improves its clean-up performance;In addition the decontamination of the rubber on table tennis bat Ability is strong, and soil removal efficiency is up to 99%.

Claims (10)

1. a kind of rubber on table tennis bat detergent, which is characterized in that be made of the component of Fructus Gleditsiae Abnormalis extract and following parts by weight: 0.5~3 part of quaternary ammonium salt, 0.5~3 part of surfactant, 0.05~0.2 part of preservative, 0.01~0.2 part of antifoaming agent, water 5~20 Part.
2. rubber on table tennis bat detergent according to claim 1, which is characterized in that the Fructus Gleditsiae Abnormalis extract is carried for gleditsia sinensis Liquid is taken, the gleditsia sinensis extracting solution is made by the preparation method included the following steps:After the gleditsia sinensis of 15~30 mass fractions is crushed 40~120min is impregnated in 60~190 parts of water, is filtered to obtain the final product.
3. rubber on table tennis bat detergent according to claim 1, which is characterized in that the quaternary ammonium salt is cetyl three Any one or a few in ammonio methacrylate, octadecyltrimethylammonium chloride, dodecyl benzyl dimethyl ammonium chloride.
4. rubber on table tennis bat detergent according to claim 1, which is characterized in that the surfactant is nonionic Any one or a few in surfactant, zwitterionic surfactant.
5. rubber on table tennis bat detergent according to claim 4, which is characterized in that the nonionic surfactant is Any one or a few in fatty alcohol polyoxyethylene ether, lauric acid amide of ethanol, alkyl glycosides.
6. rubber on table tennis bat detergent according to claim 4, which is characterized in that the zwitterionic surfactant For dodecanamide propyl hydroxy sulfo lycine, lauroylamidopropyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine, cocounut oil acyl Any one or a few in amine propyl betaine.
7. rubber on table tennis bat detergent according to claim 1, which is characterized in that the preservative for sodium benzoate, Any one or a few in potassium sorbate, calcium propionate.
8. rubber on table tennis bat detergent according to claim 1, which is characterized in that the antifoaming agent gathers for polyoxyethylene Any one or a few in oxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
9. a kind of preparation method of rubber on table tennis bat detergent as described in claim 1, which is characterized in that including following step Suddenly:
By Fructus Gleditsiae Abnormalis extract, quaternary ammonium salt, surfactant, preservative, antifoaming agent, water mixing to get.
10. the preparation method of rubber on table tennis bat detergent according to claim 9, which is characterized in that the mixing is Surfactant, preservative, antifoaming agent, water mixing first will be added after Fructus Gleditsiae Abnormalis extract and quaternary ammonium salt mixing.
CN201810054271.3A 2018-01-19 2018-01-19 Table tennis bat rubber cleaning agent and preparation method thereof Expired - Fee Related CN108192768B (en)

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CN108944112A (en) * 2018-07-28 2018-12-07 黄智慧 A kind of preparation method for exempting from alcohol fountain solution
CN108998288A (en) * 2018-09-17 2018-12-14 佛山市森昂生物科技有限公司 A kind of rubber on table tennis bat detergent and preparation method thereof
CN111019772A (en) * 2019-10-21 2020-04-17 广东莱雅新化工科技有限公司 Cleaning agent
CN115418282A (en) * 2022-09-06 2022-12-02 杭州西子卫生消毒药械有限公司 Ash removing and dyeing paste for medical instruments and preparation method and application thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108944112A (en) * 2018-07-28 2018-12-07 黄智慧 A kind of preparation method for exempting from alcohol fountain solution
CN108998288A (en) * 2018-09-17 2018-12-14 佛山市森昂生物科技有限公司 A kind of rubber on table tennis bat detergent and preparation method thereof
CN111019772A (en) * 2019-10-21 2020-04-17 广东莱雅新化工科技有限公司 Cleaning agent
CN115418282A (en) * 2022-09-06 2022-12-02 杭州西子卫生消毒药械有限公司 Ash removing and dyeing paste for medical instruments and preparation method and application thereof
CN115418282B (en) * 2022-09-06 2023-05-12 杭州西子卫生消毒药械有限公司 Ash removal dye paste for medical instrument and preparation method and application thereof

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