CN108192452A - A kind of Environment-friendlyexterior exterior wall paint and preparation method thereof - Google Patents
A kind of Environment-friendlyexterior exterior wall paint and preparation method thereof Download PDFInfo
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- CN108192452A CN108192452A CN201810061700.XA CN201810061700A CN108192452A CN 108192452 A CN108192452 A CN 108192452A CN 201810061700 A CN201810061700 A CN 201810061700A CN 108192452 A CN108192452 A CN 108192452A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/06—Polysulfones; Polyethersulfones
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of Environment-friendlyexterior exterior wall paints and preparation method thereof, are related to technical field of environmental protection paint, this kind of coating includes following raw material：Modified complex emulsions, polyethersulfone resin, talcum powder, bauxite, Sodium Polyacrylate, laruyl alcohol oleate, tributyl phosphate, lauric acid amide of ethanol, ethylene glycol, anatase thpe white powder, wetting dispersing agent, anti-irradiation agent and bonding additives.Preparation method is by made from the mixing of above-mentioned raw materials, stirring and grinding.The Environment-friendlyexterior exterior wall paint of the present invention prepares simple and convenient, and cost of material is low, strong adhesive force, and waterproof and sun-proof performance are good, and application scenario is extensive, and service life is long, has a vast market prospect.
Description
Technical field
The present invention relates to technical field of environmental protection paint, and in particular to a kind of Environment-friendlyexterior exterior wall paint and preparation method thereof.
Background technology
The application of coating is relatively broad, is useful in places such as the exterior walls, interior wall and ground of building.Coating exists at present
When being applied in skin, it there are problems that, such as the poor adhesive force of exterior coating, water resistance and light resistance
Can be bad, after skin is coated onto, by exposing to the sun and rain for a long time, the coating of outer layer, which just has, to come off, opens
Phenomenon is split, resistance to ag(e)ing is poor, and service life is short, these all drastically influence the appearance, service life and product of building
Value.Therefore, it is necessary to improve.
Invention content
For problems of the prior art, the present invention provides a kind of Environment-friendlyexterior exterior wall paints and preparation method thereof, should
Kind coating preparation is simple and convenient, and cost of material is low, strong adhesive force, and waterproof and sun-proof performance are good, and application scenario is extensive, service life
It is long, have a vast market prospect.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of Environment-friendlyexterior exterior wall paint, including following raw material by weight：Modified 40-60 parts of complex emulsions, polyether sulfone
45-55 parts of resin, 10-20 parts of talcum powder, 5-15 parts of bauxite, 4-8 parts of Sodium Polyacrylate, 8-12 parts of laruyl alcohol oleate, phosphorus
Sour tributyl 4-8 parts, 3-5 parts of lauric acid amide of ethanol, 5-15 parts of ethylene glycol, 10-20 parts of anatase thpe white powder, wetting and dispersing
1-3 parts of 1-5 parts of agent, 1-3 parts of anti-irradiation agent and bonding additives；
Above-mentioned modification complex emulsions include following ingredient by weight：20-30 parts of methyl methacrylate, propylene
15-25 parts of acid butyl ester, 1-3 parts of methacrylic acid, 3-5 parts of nanometer grade silica, 0.4-0.8 parts of potassium peroxydisulfate, initiator 1-2
Part, 5-15 parts of 1-3 parts of OP-10 emulsifiers, 0.5-1.5 parts of antifoaming agent and deionized water, this kind of lotion is through the following steps that system
：Methyl methacrylate, butyl acrylate, methacrylic acid and nanometer grade silica are mixed to join in container and used
Magnetic agitation 50-60min, then with ultrasonic disperse 40-50min, obtain batch mixing A；By initiator, OP-10 emulsifiers, antifoaming agent and go
Ionized water mixing, the lower potassium peroxydisulfate that adds in of nitrogen protection stir evenly, and whipping temp is 85-95 DEG C, mixing speed 100-
200r/min obtains mixed material B；The batch mixing A and mixed material B are added in reaction vessel, heating water bath keeps the temperature magnetic to 55-75 DEG C
Power stirs 2-3h, mixing speed 180-220r/min；After being cooled to 40 DEG C, instill ammonium hydroxide and adjust pH to 9, obtain this hair
Modification complex emulsions needed for bright raw material.
Further, above-mentioned exterior coating includes following raw material by weight：Modified 50 parts of complex emulsions, polyether sulfone
50 parts of resin, 15 parts of talcum powder, 10 parts of bauxite, 6 parts of Sodium Polyacrylate, 10 parts of laruyl alcohol oleate, 6 parts of tributyl phosphate,
4 parts of lauric acid amide of ethanol, 10 parts of ethylene glycol, 15 parts of anatase thpe white powder, 3 parts of wetting dispersing agent, 2 parts of levelling agent, anti-spoke
According to 2 parts of 2 parts of agent and bonding additives.
Further, above-mentioned modification complex emulsions include following ingredient by weight：Methyl methacrylate 25
Part, 20 parts of butyl acrylate, 2 parts of methacrylic acid, 4 parts of nanometer grade silica, 0.6 part of potassium peroxydisulfate, 1.5 parts of initiator,
10 parts of 2 parts of OP-10 emulsifiers, 1 part of antifoaming agent and deionized water, this kind of lotion is through the following steps that obtained：By methyl-prop
E pioic acid methyl ester, butyl acrylate, methacrylic acid and nanometer grade silica, which are mixed to join in container, uses magnetic agitation
55min, then with ultrasonic disperse 45min, obtain batch mixing A；By initiator, OP-10 emulsifiers, antifoaming agent and deionized water mixing, nitrogen
It adds in potassium peroxydisulfate under gas shielded to stir evenly, whipping temp is 90 DEG C, and mixing speed 150r/min obtains mixed material B；By described in
Batch mixing A and mixed material B are added in reaction vessel, and heating water bath keeps the temperature magnetic agitation 2.5h, mixing speed 200r/ to 65 DEG C
min；After being cooled to 40 DEG C, instill ammonium hydroxide and adjust pH to 9, obtain the modification complex emulsions needed for the raw material of the present invention.
Preferably, above-mentioned anti-irradiation agent is using ferrocene, -1,3,4- thiadiazoles lanthanums of 2- amino -5- (p- methoxyphenyl)
One kind in complex or 6-benzyl aminopurine copper.
Preferably, above-mentioned bonding additives are using N hydroxymethyl acrylamide, ethyl trimethoxy silane, ten alcohol polyoxy of isomery
It is one or more than one kinds of in vinethene or sodium bicarbonate.
Preferably, above-mentioned initiator is using in hydroxy-cyclohexyl phenyl ketone, azodiisobutyronitrile or azobisisoheptonitrile
One kind.
Preferably, above-mentioned antifoaming agent is using one kind in dimethyl silicone polymer, benzyl carbinol oleate or polyoxypropylene.
The preparation method of above-mentioned Environment-friendlyexterior exterior wall paint, follows the steps below：
(1) raw material is weighed by the weight, above-mentioned whole raw materials is added to and are crushed in beater, add in raw material
The deionized water of gross mass 15%-25% crushes mixing, obtains batch mixing；
(2) batch mixing is transported in high viscosity de-airing mixer, under vacuum conditions by stirring, disperseing, dissolving,
Coating semi-finished product are obtained after homogeneous, emulsification and defoaming, and speed of agitator is set as 600-800r/min, mixing time is set as 2-
3h, whipping temp are controlled at 42-48 DEG C；
(3) the coating semi-finished product are transported in Multifunction colloid mill and are ground processing, particle is thin in control grinding
Degree is less than or equal to 20 μm, obtains the Environment-friendlyexterior exterior wall paint of the present invention.
The present invention has following advantageous effect：The Environment-friendlyexterior exterior wall paint raw material sources of the present invention are extensive, at low cost
It is honest and clean, prepare simple and convenient, free from extraneous odour is environmentally protective without exhaust emission, passes through the improvement to raw materials for production and technique in practice
And optimization, modified complex emulsions, polyethersulfone resin etc. is selected to have excellent performance stabilization, waterproof, heat safe raw material, is cooperateed with a variety of outer
The use of adding assistant so that for the exterior coating of finished product after coating to wall, covering bonding force is strong, and prevents with excellent
Water, sun-proof, ageing-resistant performance wash away experiment of being exposed to the sun repeatedly through technical staff to this kind of exterior coating, and experimental result is not
There is phenomena such as surface layer comes off, cracks, paint film complete and smooth loosens, paint film high specific surface area without bulge, and good decorative property applies
The problems such as being not in sagging, out-of-flatness after whiting brush, application scenario is extensive, and service life is long, has a vast market prospect.
Specific embodiment
The specific embodiment of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and is not intended to limit the protection scope of the present invention and limits the scope of the invention.
In the present invention it is raw materials used choose it is as shown in table 1 below：
Table 1
| Raw material | Choose ground |
| Modified complex emulsions, polyethersulfone resin and Sodium Polyacrylate | Qingdao Yu Zhou Chemical Co., Ltd.s |
| Laruyl alcohol oleate, tributyl phosphate and lauric acid amide of ethanol | Shandong Lu Ke Chemical Co., Ltd.s |
| Ethylene glycol, wetting dispersing agent, anti-irradiation agent and bonding additives | Tianjin Kai Tong chemical reagent Co., Ltd |
| Talcum powder, bauxite and anatase thpe white powder | Lingshou County Hua Sheng mineral products processings factory |
Embodiment 1
A kind of Environment-friendlyexterior exterior wall paint, raw materials for production are as follows：Modified complex emulsions 40kg, polyethersulfone resin 45kg, talcum powder
10kg, bauxite 5kg, Sodium Polyacrylate 4kg, laruyl alcohol oleate 8kg, tributyl phosphate 4kg, lauric acid amide of ethanol
3kg, ethylene glycol 5kg, anatase thpe white powder 10kg, wetting dispersing agent 1kg, anti-irradiation agent 1kg and bonding additives 1kg；
Above-mentioned modification complex emulsions include following component：Methyl methacrylate 20kg, butyl acrylate 15kg, methyl
Acrylic acid 1kg, nanometer grade silica 3kg, potassium peroxydisulfate 0.4kg, initiator 1kg, OP-10 emulsifier 1kg, antifoaming agent
0.5kg and deionized water 5kg；
This kind of lotion is through the following steps that obtained：First by methyl methacrylate, butyl acrylate, methacrylic acid
It is mixed to join in container with magnetic agitation 50min with nanometer grade silica, then with ultrasonic disperse 40min, obtains batch mixing A；It
Afterwards by initiator, OP-10 emulsifiers, antifoaming agent and deionized water mixing, potassium peroxydisulfate is added under nitrogen protection and is stirred evenly,
Whipping temp is controlled at 85 DEG C, and mixing speed is set as 100r/min, obtains mixed material B；Then above-mentioned batch mixing A and mixed material B are added in
Into reaction vessel, heating water bath keeps the temperature magnetic agitation 2h to 55 DEG C, and mixing speed is set as 180r/min；It is cooled to 40
After DEG C, instill ammonium hydroxide and adjust pH to 9, obtain the modification complex emulsions needed for the raw material of the present invention.
Wherein, above-mentioned anti-irradiation agent uses -1,3,4- thiadiazoles Lanthanide complex of 2- amino -5- (p- methoxyphenyl)；
Above-mentioned bonding additives use N hydroxymethyl acrylamide；
Above-mentioned initiator uses azodiisobutyronitrile；
Preferably, above-mentioned antifoaming agent uses dimethyl silicone polymer.
The preparation method of above-mentioned Environment-friendlyexterior exterior wall paint, follows the steps below：
(1) first the above-mentioned whole raw materials weighed are added to and crushed in beater, add in raw material gross mass 15% go from
Sub- water crushes mixing, obtains batch mixing；
(2) above-mentioned batch mixing is transported in high viscosity de-airing mixer again, under vacuum conditions by stirring, disperseing, molten
Coating semi-finished product are obtained after solution, homogeneous, emulsification and defoaming, and speed of agitator is set as 600r/min, mixing time is set as 2h, stirs
Temperature control is mixed at 42 DEG C；
(3) it is 20 μm finally above-mentioned coating semi-finished product to be transported in Multifunction colloid mill and be ground to grain fineness, that is, is made
Obtain Environment-friendlyexterior exterior wall paint of the invention.
Embodiment 2
A kind of Environment-friendlyexterior exterior wall paint, raw materials for production are as follows：Modified complex emulsions 50kg, polyethersulfone resin 50kg, talcum powder
15kg, bauxite 10kg, Sodium Polyacrylate 6kg, laruyl alcohol oleate 10kg, tributyl phosphate 6kg, lauric acid amide of ethanol
4kg, ethylene glycol 10kg, anatase thpe white powder 15kg, wetting dispersing agent 3kg, levelling agent 2kg, anti-irradiation agent 2kg and bonding additives
2kg；
Above-mentioned modification complex emulsions include following component：Methyl methacrylate 25kg, butyl acrylate 20kg, methyl
Acrylic acid 2kg, nanometer grade silica 4kg, potassium peroxydisulfate 0.6kg, initiator 1.5kg, OP-10 emulsifier 2kg, antifoaming agent
1kg and deionized water 10kg；
This kind of lotion is through the following steps that obtained：First by above-mentioned methyl methacrylate, butyl acrylate, methyl-prop
Olefin(e) acid and nanometer grade silica are mixed to join in container with magnetic agitation 55min, then with ultrasonic disperse 45min, obtain batch mixing
A；Again by initiator, OP-10 emulsifiers, antifoaming agent and deionized water mixing, it is equal that potassium peroxydisulfate stirring is added under nitrogen protection
Even, whipping temp is controlled at 90 DEG C, and mixing speed is set as 150r/min, obtains mixed material B；The batch mixing A and mixed material B are added to
In reaction vessel, heating water bath keeps the temperature magnetic agitation 2.5h to 65 DEG C, and mixing speed is controlled in 200r/min；It is cooled to 40
After DEG C, instill ammonium hydroxide and adjust pH to 9, obtain the modification complex emulsions needed for the raw material of the present invention.
Wherein, above-mentioned anti-irradiation agent is using one kind in 6-benzyl aminopurine copper；
Above-mentioned bonding additives use two kinds of mixtures of ethyl trimethoxy silane and sodium bicarbonate, and quality between the two
Than being 1:2；
Above-mentioned initiator uses hydroxy-cyclohexyl phenyl ketone；
Above-mentioned antifoaming agent uses polyoxypropylene.
The preparation method of above-mentioned Environment-friendlyexterior exterior wall paint, follows the steps below：
(1) first the above-mentioned whole raw materials weighed are added to and crushed in beater, add in raw material gross mass 20% go from
Sub- water crushes mixing, obtains batch mixing；
(2) above-mentioned batch mixing is transported in high viscosity de-airing mixer again, under vacuum conditions by stirring, disperseing, molten
Coating semi-finished product being obtained after solution, homogeneous, emulsification and defoaming, and speed of agitator is set as 700r/min, mixing time is set as 2.5h,
Whipping temp is controlled at 45 DEG C；
(3) it is 15 μm finally above-mentioned coating semi-finished product to be transported in Multifunction colloid mill and be ground to grain fineness, that is, is made
Obtain Environment-friendlyexterior exterior wall paint of the invention.
Embodiment 3
A kind of Environment-friendlyexterior exterior wall paint, raw materials for production are as follows：Modified complex emulsions 60kg, polyethersulfone resin 55kg, talcum powder
20kg, bauxite 15kg, Sodium Polyacrylate 8kg, laruyl alcohol oleate 12kg, tributyl phosphate 8kg, lauric acid amide of ethanol
5kg, ethylene glycol 15kg, anatase thpe white powder 20kg, wetting dispersing agent 5kg, anti-irradiation agent 3kg and bonding additives 3kg；
Above-mentioned modification complex emulsions include following component：Methyl methacrylate 30kg, butyl acrylate 25kg, methyl
Acrylic acid 3kg, nanometer grade silica 5kg, potassium peroxydisulfate 0.8kg, initiator 2kg, OP-10 emulsifier 3kg, antifoaming agent
1.5kg and deionized water 15kg；
This kind of lotion is through the following steps that obtained：First by above-mentioned methyl methacrylate, butyl acrylate, methyl-prop
Olefin(e) acid and nanometer grade silica are mixed to join in container with magnetic agitation 60min, then with ultrasonic disperse 50min, obtain batch mixing
A；Again by initiator, OP-10 emulsifiers, antifoaming agent and deionized water mixing, it is equal that potassium peroxydisulfate stirring is added under nitrogen protection
Even, whipping temp is set as 95 DEG C, and mixing speed is set as 200r/min, obtains mixed material B；Above-mentioned batch mixing A and mixed material B are added to
In reaction vessel, heating water bath keeps the temperature magnetic agitation 3h to 75 DEG C, and mixing speed is set as 220r/min；It is cooled to 40 DEG C
Afterwards, it instills ammonium hydroxide and adjusts pH to 9, obtain the modification complex emulsions needed for the raw material of the present invention.
Wherein, above-mentioned anti-irradiation agent uses ferrocene；
Above-mentioned bonding additives use heterogeneous ten alcohol polyoxyethylene ether；
Above-mentioned initiator uses azobisisoheptonitrile；
Above-mentioned antifoaming agent uses benzyl carbinol oleate.
The preparation method of above-mentioned Environment-friendlyexterior exterior wall paint, follows the steps below：
(1) first the above-mentioned whole raw materials weighed are added to and crushed in beater, add in raw material gross mass 25% go from
Sub- water crushes mixing, obtains batch mixing；
(2) above-mentioned batch mixing is transported in high viscosity de-airing mixer again, under vacuum conditions by stirring, disperseing, molten
Coating semi-finished product are obtained after solution, homogeneous, emulsification and defoaming, and speed of agitator is set as 800r/min, mixing time is set as 3h, stirs
Temperature control is mixed at 48 DEG C；
(3) it is 20 μm finally the coating semi-finished product to be transported in Multifunction colloid mill and be ground to grain fineness, that is, is made
Obtain Environment-friendlyexterior exterior wall paint of the invention.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Example is applied the present invention is described in detail, it for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example modifies or carries out equivalent replacement to which part technical characteristic.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of Environment-friendlyexterior exterior wall paint, which is characterized in that including following raw material by weight：Modified complex emulsions 40-60
Part, 45-55 parts of polyethersulfone resin, 10-20 parts of talcum powder, 5-15 parts of bauxite, 4-8 parts of Sodium Polyacrylate, laruyl alcohol oleate
8-12 parts, 4-8 parts of tributyl phosphate, 3-5 parts of lauric acid amide of ethanol, 5-15 parts of ethylene glycol, anatase thpe white powder 10-20
Part, 1-5 parts of wetting dispersing agent, 1-3 parts of anti-irradiation agent and 1-3 parts of bonding additives；
The modified complex emulsions include following ingredient by weight：20-30 parts of methyl methacrylate, butyl acrylate
15-25 parts, 1-3 parts of methacrylic acid, 3-5 parts of nanometer grade silica, 0.4-0.8 parts of potassium peroxydisulfate, 1-2 parts of initiator, OP-
5-15 parts of 10 1-3 parts of emulsifiers, 0.5-1.5 parts of antifoaming agent and deionized water, this kind of lotion is through the following steps that obtained：It will
Methyl methacrylate, butyl acrylate, methacrylic acid and nanometer grade silica are mixed to join in container to be stirred with magnetic force
It mixes 50-60min, then with ultrasonic disperse 40-50min, obtains batch mixing A；By initiator, OP-10 emulsifiers, antifoaming agent and deionized water
Mixing, the lower potassium peroxydisulfate that adds in of nitrogen protection stir evenly, and whipping temp is 85-95 DEG C, mixing speed 100-200r/min,
Obtain mixed material B；The batch mixing A and mixed material B are added in reaction vessel, heating water bath keeps the temperature magnetic agitation 2- to 55-75 DEG C
3h, mixing speed 180-220r/min；After being cooled to 40 DEG C, instill ammonium hydroxide adjust pH to 9 to get.
2. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that including following original by weight
Material：Modified 50 parts of complex emulsions, 50 parts of polyethersulfone resin, 15 parts of talcum powder, 10 parts of bauxite, 6 parts of Sodium Polyacrylate, laruyl alcohol
10 parts of oleate, 6 parts of tributyl phosphate, 4 parts of lauric acid amide of ethanol, 10 parts of ethylene glycol, 15 parts of anatase thpe white powder, wetting
2 parts of 3 parts of dispersant, 2 parts of levelling agent, 2 parts of anti-irradiation agent and bonding additives.
3. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that the modified complex emulsions include following
Ingredient by weight：25 parts of methyl methacrylate, 20 parts of butyl acrylate, 2 parts of methacrylic acid, nanoscale titanium dioxide
4 parts of silicon, 0.6 part of potassium peroxydisulfate, 1.5 parts of initiator, 10 parts of 2 parts of OP-10 emulsifiers, 1 part of antifoaming agent and deionized water, this kind of breast
Liquid is through the following steps that obtained：By methyl methacrylate, butyl acrylate, methacrylic acid and nanometer grade silica
It is mixed to join in container with magnetic agitation 55min, then with ultrasonic disperse 45min, obtains batch mixing A；Initiator, OP-10 are emulsified
Agent, antifoaming agent and deionized water mixing, the lower potassium peroxydisulfate that adds in of nitrogen protection stir evenly, and whipping temp is 90 DEG C, stirs speed
It spends for 150r/min, obtains mixed material B；The batch mixing A and mixed material B are added in reaction vessel, heating water bath keeps the temperature magnetic to 65 DEG C
Power stirs 2.5h, mixing speed 200r/min；After being cooled to 40 DEG C, instill ammonium hydroxide adjust pH to 9 to get.
4. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that the anti-irradiation agent is ferrocene, 2-
One kind in -1,3,4- thiadiazoles Lanthanide complex of amino -5- (p- methoxyphenyl) or 6-benzyl aminopurine copper.
5. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that the bonding additives are N- methylols third
It is one or more than one kinds of in acrylamide, ethyl trimethoxy silane, heterogeneous ten alcohol polyoxyethylene ether or sodium bicarbonate.
6. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that the initiator is hydroxy-cyclohexyl benzene
One kind in base ketone, azodiisobutyronitrile or azobisisoheptonitrile.
7. a kind of Environment-friendlyexterior exterior wall paint according to claim 1, which is characterized in that the antifoaming agent is polydimethylsiloxanes
One kind in alkane, benzyl carbinol oleate or polyoxypropylene.
8. a kind of preparation method of Environment-friendlyexterior exterior wall paint as described in claim 1-7 any one, which is characterized in that including with
Lower step：
(1) raw material is weighed by the weight, whole raw materials is added to and are crushed in beater, add in raw material gross mass
The deionized water of 15%-25% crushes mixing, obtains batch mixing；
(2) batch mixing is transported in high viscosity de-airing mixer, under vacuum conditions by stirring, disperseing, dissolving,
After matter, emulsification and defoaming coating semi-finished product, and speed of agitator be 600-800r/min, mixing time 2-3h, whipping temp
It is 42-48 DEG C；
(3) the coating semi-finished product are transported in Multifunction colloid mill and are ground processing, grain fineness is small in control grinding
In equal to 20 μm, you can.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030873A (en) * | 2010-10-27 | 2011-04-27 | 华南理工大学 | Method for preparing nano silicon/polyacrylate composite emulsion |
| CN104277722A (en) * | 2014-10-20 | 2015-01-14 | 常熟市鑫磊木业制造厂 | Adhesive for wood floor |
| CN106519107A (en) * | 2016-10-31 | 2017-03-22 | 湖南航天三丰科工有限公司 | Nanoparticle-modified acrylate emulsion and preparation method and application thereof |
| CN106987162A (en) * | 2017-06-03 | 2017-07-28 | 合肥佳洋电子科技有限公司 | A kind of environmental protection interiro wall latex paint and preparation method thereof |
| CN107189676A (en) * | 2017-07-19 | 2017-09-22 | 合肥广民建材有限公司 | A kind of waterproof sun-proof exterior coating and preparation method thereof |
-
2018
- 2018-01-23 CN CN201810061700.XA patent/CN108192452A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030873A (en) * | 2010-10-27 | 2011-04-27 | 华南理工大学 | Method for preparing nano silicon/polyacrylate composite emulsion |
| CN104277722A (en) * | 2014-10-20 | 2015-01-14 | 常熟市鑫磊木业制造厂 | Adhesive for wood floor |
| CN106519107A (en) * | 2016-10-31 | 2017-03-22 | 湖南航天三丰科工有限公司 | Nanoparticle-modified acrylate emulsion and preparation method and application thereof |
| CN106987162A (en) * | 2017-06-03 | 2017-07-28 | 合肥佳洋电子科技有限公司 | A kind of environmental protection interiro wall latex paint and preparation method thereof |
| CN107189676A (en) * | 2017-07-19 | 2017-09-22 | 合肥广民建材有限公司 | A kind of waterproof sun-proof exterior coating and preparation method thereof |
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Application publication date: 20180622 |