CN104710883B - A kind of glass door and window clear dope and preparation method thereof - Google Patents
A kind of glass door and window clear dope and preparation method thereof Download PDFInfo
- Publication number
- CN104710883B CN104710883B CN201510125658.XA CN201510125658A CN104710883B CN 104710883 B CN104710883 B CN 104710883B CN 201510125658 A CN201510125658 A CN 201510125658A CN 104710883 B CN104710883 B CN 104710883B
- Authority
- CN
- China
- Prior art keywords
- nano
- glass door
- clear dope
- agent
- window
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011521 glass Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000839 emulsion Substances 0.000 claims abstract description 31
- 239000008367 deionised water Substances 0.000 claims abstract description 27
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 27
- 239000011248 coating agent Substances 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical class OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- 239000011806 microball Substances 0.000 claims abstract description 12
- 239000013530 defoamer Substances 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 44
- 239000007788 liquid Substances 0.000 claims description 28
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000009413 insulation Methods 0.000 claims description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 15
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 12
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000908 ammonium hydroxide Substances 0.000 claims description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- -1 polyethylene Ethylene oxide Polymers 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 6
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 6
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000003760 magnetic stirring Methods 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 210000000481 breast Anatomy 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 238000010008 shearing Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000004134 energy conservation Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 230000005540 biological transmission Effects 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 238000005520 cutting process Methods 0.000 description 10
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical group CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 7
- 238000005265 energy consumption Methods 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DYJFXZAVYGPICR-UHFFFAOYSA-N benzene;silicon Chemical compound [Si].C1=CC=CC=C1 DYJFXZAVYGPICR-UHFFFAOYSA-N 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of glass door and window clear dope, which includes following components with coating：Silicone modified styrene-acrylate emulsion, modified Nano tin-antiomony oxide, nano-titanium dioxide, hollow glass micro-ball, auxiliary agent and deionized water, wherein auxiliary agent include wetting agent, dispersant, defoamer, coalescents, levelling agent and thickener；The present invention also designs a kind of preparation method of glass door and window clear dope, this is simple and practicable, manufacturing cost is cheap, polluted in manufacturing process few, the coating prepared can not only take into account heat-insulated and light transmission, but also have the advantages that corrosion-resistant, ageing-resistant, mechanical performance is excellent, while the coating also energy conservation and environmental protection, it is cheap.
Description
Technical field
This hair is related to a kind of door and window coating and preparation method thereof, and in particular to a kind of glass for windows and doors clear dope and its
Preparation method.
Background technology
It is energy saving increasingly to receive global concern with the increasingly depleted of non-regeneration energy.In China, energy is built
Consumption rises year by year, has accounted for the 32% of national total energy consumption, theme of the door and window as building, and energy loss, can be with than being up to 51%
Building energy consumption is reduced by improving the heat insulation and preservation effect of window, door glass energy consumption is light with foot is lifted in building energy consumption field
The status of weight, building energy conservation can be effectively improved by improving the energy saving of door and window.The incubation and thermal insulation function of exterior wall door and window is to influence building
The direct factor of energy consumption.There are two methods to improve building energy conservation, one kind is to reduce transparency area to reduce energy consumption, but
This method can be to room daylighting and it is beautiful cause certain destruction, a kind of is that the heat insulation for improving glass itself could reach
To energy saving purpose, this method is relatively adapted to the trend of Developing.
A kind of new energy-saving material to grow up during nanometer heat isolation paint.The reflected solar energy that the coating can select
Amount, reduces absorption of the object to solar radiant energy to reach heat insulation.Insulating moulding coating have isolation-type paint, reflection-type coating and
Three kinds of radiativity coating.Isolation-type paint introduces the composition of lower thermal conductivity in the coating, reduces heat transfer and realizes heat insulation,
Have the advantages that heat conduction is low, resistant to chemical etching；Reflection-type coating reaches heat-insulated effect using the principle for reflecting visible ray and infrared light
Fruit, energy-saving effect is apparently higher than heat insulation type coating, and paint adhesion is good, weatherability is strong, and the nonirritant smell of solvent, reduces
The influence of construction team's surrounding enviroment, is widely used in energy-saving heat-insulating coating.
The content of the invention
The technical problems to be solved by the invention are that shortcoming existing in the prior art, proposes a kind of glass door for more than
Window clear dope and preparation method thereof, the preparation method is simple and practicable, and manufacturing cost is cheap, and few, system is polluted in manufacturing process
It is standby go out coating can not only take into account heat-insulated and light transmission, but also with it is corrosion-resistant, ageing-resistant, that mechanical performance is excellent etc. is excellent
Point, while the coating also energy conservation and environmental protection, it is cheap.
The present invention solve above technical problem technical solution be：
A kind of glass door and window clear dope, the glass door and window include following components according to the mass fraction with coating：
40-45 parts of silicone modified styrene-acrylate emulsion
15-20 parts of modified Nano tin-antiomony oxide
5-10 parts of nano-titanium dioxide
3-5 parts of hollow glass micro-ball
23-34 parts of auxiliary agent
20-30 parts of deionized water；
Wherein, auxiliary agent includes following components according to the mass fraction：
2-3 parts of wetting agent
6-8 parts of dispersant
4-6 parts of defoamer
4-6 parts of coalescents
2-4 parts of levelling agent
5-7 parts of thickener；
A diameter of 10-250 μm of hollow glass micro-ball.
Further technical solution is the present invention：
In foregoing glass door and window clear dope, wetting agent is octyl phenol polyoxyethylene ether wetting agent, dispersion machine 5040
Dispersant, defoamer are W-082 organic silicon defoamers, and coalescents are dipropylene coalescents, and levelling agent is poly- ammonia
2020 levelling agent of ester, thickener are ASE60 thickeners.
In foregoing glass door and window clear dope, the preparation method of silicone modified styrene-acrylate emulsion is as follows：
（1）3/4ths composite emulsifying liquid is added in deionized water, stirring and dissolving, then adds monomer benzene second
Alkene, butyl acrylate, acrylic acid, low whipping speed stir 50-60min under conditions of being 500-600r/min, pre-emulsification are made
Liquid；
Wherein, compound emulsifying agent is the mixture of nonylphenol polyoxyethylene ether and lauryl sodium sulfate, polyoxyethylene nonyl phenyl
Vinethene and the mass ratio of lauryl sodium sulfate are 3:1；The mass ratio of butyl acrylate and acrylic acid is 1:1.5；
（2）Equipped with electric mixer, thermometer and dropping funel, reflux condensing tube four-hole boiling flask in, add carbonic acid
The compound emulsifying agent of hydrogen sodium, deionized water and remaining a quarter, stirring are allowed to dissolve and are uniformly dispersed；
（3）After being warming up to 60-65 DEG C, the initiator of half is added, 1/5th pre-emulsification is added dropwise in 30min
Liquid, becomes blue in 80-82 DEG C of insulation reaction to liquid；
Wherein, wherein initiator is ammonium persulfate；
（4）Silane coupling reagent KH-570 is mixed into remaining pre-emulsion, by pre-emulsion and remaining in 3-4h
Initiator solution is instilled in flask, drips rear insulation reaction 1-2h；
（5）It is cooled to room temperature after complete reaction, adjusts pH value 7-8 with ammonium hydroxide, filtering obtains organosilicon-modified styrene-acrylic
Lotion.
In foregoing glass door and window clear dope, the preparation method of modified Nano tin-antiomony oxide is as follows：
（1）It is 7 by volume by polymerized monomer acrylic acid and deionized water:3 mix, and then add stannic chloride pentahydrate
20min is stirred under magnetic stirring apparatus with antimony trichloride, homogeneous system is obtained, then adds ammonium persulfate solution, and use magnetic force
Blender carries out heating stirring, until polymerization-filling is complete, that is, obtains the presoma of tin-antiomony oxide；
（2）Then presoma is heat-treated, dry 2-3h at 250 DEG C, is grinding after cooling in present thermostatic drying chamber
Ground in alms bowl, be placed in Muffle furnace, heat 700 DEG C with the heating rate of 40 DEG C/min under air atmosphere, calcine 4-5h,
Obtain nano antimony tin oxide；
（3）Nano antimony tin oxide is placed in 120 DEG C of vacuum drying chamber, after predrying 4h, addition is equipped with anhydrous second
In the conical flask of alcohol, disperse 30-40min with ultrasonic wave, transfer them in dry three-neck flask, be placed in 70 DEG C of constant temperature
In water-bath, and at the uniform velocity stirred under the rotating speed of 200-250r/min, KH-570 silane coupler solutions are added dropwise, react 5-6h
Afterwards, filter, and washed with absolute ethyl alcohol, take its filter cake dry 40-60min in 120 DEG C of vacuum drying chamber, that is, be modified
Nano antimony tin oxide.
The present invention have also been devised a kind of preparation method of glass door and window clear dope, the glass door and window clear dope
Preparation method comprises the following steps that：
(1) by nano-titanium dioxide and modified Nano tin-antiomony oxide and deionized water, it is added in dispersion bucket, while stirring
While sequentially adding required wetting agent, dispersant and defoamer, mixing speed 100-150r/min, stirs 20-30min；
（2）Then it is 8-9 to adjust pH with ammonium hydroxide, and it is scattered with 800-1000 r/min shearings then to add hollow glass micro-ball
30-40min, obtains pre-dispersed liquid；
（3）2-3h will be sanded with dispersion liquid again, then ultrasonic disperse 20-25min, be filtered after standing 2h, that is, obtain containing changing
The water nano function slurry of property nano antimony tin oxide and nano-titanium dioxide；
（4）Silicone modified styrene-acrylate emulsion is put into stainless steel Scattered Kettle, starts to stir, in cutting for 400 r/min
Under cutting dissipates, deionized water is sequentially added, coalescents, levelling agent, thickener, after low velocity shear disperses 20-30min, then add
Enter the above-mentioned water nano function slurry prepared, accelerate stirring to 800-1200 r/min, shear scattered 1.5-2h, stand 2h
After filter, that is, glass door and window clear dope is made.
The beneficial effects of the invention are as follows：
（1）Glass door and window clear dope prepared by the present invention can not only take into account heat-insulated and light transmission, but also have
Have the advantages that corrosion-resistant, ageing-resistant, mechanical performance is excellent, and this coating not only energy conservation and environmental protection, but also economic and practical, it has
There are good economic benefit and social benefit.
（2）The modified Nano tin-antiomony oxide and nano-titanium dioxide added in the present invention can realize coating itself it is heat-insulated and
Self-cleaning dual-use function, while daylighting demand is met, has preferable heat-insulated and clean performance concurrently.
（3）The silicon benzene lotion obtained in the present invention with organosilicon modification by copolymerization styrene-acrylic emulsion, is in cinnamic acid polymer
The siloxanes with alkoxy is introduced on main chain, produces three-dimensional netted cross-linked structure, so that high temperature resistant, weather-proof row organosilicon,
The high colour retention, pliability of chemical-resistant, low-surface-energy, water repellency and preferable stain resistance etc. and acrylic polymer
And affordable etc. combines, it is set to have both advantageous characteristics concurrently.
（4）Nano antimony tin oxide is modified using KH-570 silane coupling agents in the present invention, can be caused modified
The stability of nano antimony tin oxide be greatly improved.
（5）The hydroxyl of KH-570 silane coupling agents and nano antimony tin oxide particle surface forms hydrogen bond and compares model in the present invention
De Huali is strong, and organo silane coupling agent can be firmly fixed on to the surface of powder, is coated on the silicon on the surface of nano-powder
The organic group of alkane coupling agent institute band can be effectively combined with organic dispersing agent, what improves dispersion efficiency from.
Embodiment
Embodiment 1
The present embodiment provides a kind of glass door and window clear dope, the glass door and window included according to the mass fraction with coating with
Lower component：
Silicone modified styrene-acrylate emulsion：45 parts, modified Nano tin-antiomony oxide：20 parts, nano-titanium dioxide：It is 10 parts, hollow
Glass microsphere：5 parts of deionized waters：30 parts, octyl phenol polyoxyethylene ether wetting agent：3 parts, 5040 dispersants：8 parts, W-082 is organic
Silicon defoaming agent：6 parts, dipropylene coalescents：6 parts, 2020 levelling agent of polyurethane：4 parts, ASE60 thickeners：7 parts；
A diameter of 110 μm of hollow glass micro-ball.
The preparation method of silicone modified styrene-acrylate emulsion is as follows：
（1）3/4ths composite emulsifying liquid is added in deionized water, stirring and dissolving, then adds monomer benzene second
Alkene, butyl acrylate, acrylic acid, low whipping speed stir 50min under conditions of being 550r/min, pre-emulsion are made；
Wherein, compound emulsifying agent is the mixture of nonylphenol polyoxyethylene ether and lauryl sodium sulfate, polyoxyethylene nonyl phenyl
Vinethene and the mass ratio of lauryl sodium sulfate are 3:1；The mass ratio of butyl acrylate and acrylic acid is 1:1.5；
（2）Equipped with electric mixer, thermometer and dropping funel, reflux condensing tube four-hole boiling flask in, add carbonic acid
The compound emulsifying agent of hydrogen sodium, deionized water and remaining a quarter, stirring are allowed to dissolve and are uniformly dispersed；
（3）After being warming up to 60 DEG C, the ammonium persulfate of half is added, 1/5th pre-emulsification is added dropwise in 30min
Liquid, becomes blue in 80 DEG C of insulation reactions to liquid；
（4）Silane coupling reagent KH-570 is mixed into remaining pre-emulsion, by pre-emulsion and remaining is drawn in 3h
Send out agent solution to instill in flask, drip rear insulation reaction 1h；
（5）It is cooled to room temperature after complete reaction, adjusts pH value 7 with ammonium hydroxide, filtering obtains organosilicon-modified styrene-acrylic breast
Liquid.
The preparation method of modified Nano tin-antiomony oxide is as follows：
（1）It is 7 by volume by polymerized monomer acrylic acid and deionized water:3 mix, and then add stannic chloride pentahydrate
20min is stirred under magnetic stirring apparatus with antimony trichloride, homogeneous system is obtained, then adds ammonium persulfate solution, and use magnetic force
Blender carries out heating stirring, until polymerization-filling is complete, that is, obtains the presoma of tin-antiomony oxide；
（2）Then presoma is heat-treated, dry 2h at 250 DEG C in present thermostatic drying chamber, in mortar after cooling
Middle grinding, be placed in Muffle furnace, heat 700 DEG C with the heating rate of 40 DEG C/min under air atmosphere, calcine 5h, to obtain the final product
To nano antimony tin oxide；
（3）Nano antimony tin oxide is placed in 120 DEG C of vacuum drying chamber, after predrying 4h, addition is equipped with anhydrous second
In the conical flask of alcohol, disperse 35min with ultrasonic wave, transfer them in dry three-neck flask, be placed in 70 DEG C of thermostatted water
In bath, and at the uniform velocity stirred under the rotating speed of 200r/min, KH-570 silane coupler solutions are added dropwise, after reacting 6h, filtered, and
Washed with absolute ethyl alcohol, take its filter cake dry 60min in 120 DEG C of vacuum drying chamber, that is, obtain modified Nano tin-antiomony oxide.
The preparation method of above-mentioned glass door and window clear dope, the glass door and window are specifically walked with the preparation method of clear dope
It is rapid as follows：
(1) by nano-titanium dioxide and modified Nano tin-antiomony oxide and deionized water, it is added in dispersion bucket, while stirring
While required octyl phenol polyoxyethylene ether wetting agent, 5040 dispersants and W-082 organic silicon defoamers are sequentially added, stirring speed
Spend for 120r/min, stirring 30min；
（2）Then it is 9 to adjust pH with ammonium hydroxide, then adds hollow glass micro-ball and shears scattered 35min with 900r/min, obtains
To pre-dispersed liquid；
（3）2-3h will be sanded with dispersion liquid again, then ultrasonic disperse 25min, be filtered after standing 2h, that is, obtain receiving containing modification
The water nano function slurry of rice tin-antiomony oxide and nano-titanium dioxide；
（4）Silicone modified styrene-acrylate emulsion is put into stainless steel Scattered Kettle, starts to stir, in cutting for 400 r/min
Under cutting dissipates, deionized water is sequentially added, dipropylene coalescents, 2020 levelling agent of polyurethane, ASE60 thickeners,
After low velocity shear disperses 25min, the above-mentioned water nano function slurry prepared is added, accelerates to stir to 1200 r/min,
The scattered 2h of shearing, filters after standing 2h, that is, glass door and window clear dope is made.
Embodiment 2
The present embodiment provides a kind of glass door and window clear dope, the glass door and window included according to the mass fraction with coating with
Lower component：
Silicone modified styrene-acrylate emulsion：40 parts, modified Nano tin-antiomony oxide：15 parts, nano-titanium dioxide：5 parts, hollow glass
Glass microballoon：3 parts of deionized waters：20 parts, octyl phenol polyoxyethylene ether wetting agent：Part, 5040 dispersants：6 parts, W-082 organosilicons
Defoamer：4 parts, dipropylene coalescents：4 parts, 2020 levelling agent of polyurethane：2 parts, ASE60 thickeners：5 parts；
A diameter of 50 μm of hollow glass micro-ball.
The preparation method of silicone modified styrene-acrylate emulsion is as follows：
（1）3/4ths composite emulsifying liquid is added in deionized water, stirring and dissolving, then adds monomer benzene second
Alkene, butyl acrylate, acrylic acid, low whipping speed stir 60min under conditions of being 500r/min, pre-emulsion are made；
Wherein, compound emulsifying agent is the mixture of nonylphenol polyoxyethylene ether and lauryl sodium sulfate, polyoxyethylene nonyl phenyl
Vinethene and the mass ratio of lauryl sodium sulfate are 3:1；The mass ratio of butyl acrylate and acrylic acid is 1:1.5；
（2）Equipped with electric mixer, thermometer and dropping funel, reflux condensing tube four-hole boiling flask in, add carbonic acid
The compound emulsifying agent of hydrogen sodium, deionized water and remaining a quarter, stirring are allowed to dissolve and are uniformly dispersed；
（3）After being warming up to 65 DEG C, the ammonium persulfate of half is added, 1/5th pre-emulsification is added dropwise in 30min
Liquid, becomes blue in 81 DEG C of insulation reactions to liquid；
（4）Silane coupling reagent KH-570 is mixed into remaining pre-emulsion, by pre-emulsion and remaining is drawn in 4h
Send out agent solution to instill in flask, drip rear insulation reaction 1h；
（5）It is cooled to room temperature after complete reaction, adjusts pH value 8 with ammonium hydroxide, filtering obtains organosilicon-modified styrene-acrylic breast
Liquid.
The preparation method of modified Nano tin-antiomony oxide is as follows：
（1）It is 7 by volume by polymerized monomer acrylic acid and deionized water:3 mix, and then add stannic chloride pentahydrate
20min is stirred under magnetic stirring apparatus with antimony trichloride, homogeneous system is obtained, then adds ammonium persulfate solution, and use magnetic force
Blender carries out heating stirring, until polymerization-filling is complete, that is, obtains the presoma of tin-antiomony oxide；
（2）Then presoma is heat-treated, dry 3h at 250 DEG C in present thermostatic drying chamber, in mortar after cooling
Middle grinding, be placed in Muffle furnace, heat 700 DEG C with the heating rate of 40 DEG C/min under air atmosphere, calcine 5h, to obtain the final product
To nano antimony tin oxide；
（3）Nano antimony tin oxide is placed in 120 DEG C of vacuum drying chamber, after predrying 4h, addition is equipped with anhydrous second
In the conical flask of alcohol, disperse 30min with ultrasonic wave, transfer them in dry three-neck flask, be placed in 70 DEG C of thermostatted water
In bath, and at the uniform velocity stirred under the rotating speed of 250r/min, KH-570 silane coupler solutions are added dropwise, after reacting 5h, filtered, and
Washed with absolute ethyl alcohol, take its filter cake dry 50min in 120 DEG C of vacuum drying chamber, that is, obtain modified Nano tin-antiomony oxide.
The preparation method of above-mentioned glass door and window clear dope, the glass door and window are specifically walked with the preparation method of clear dope
It is rapid as follows：
(1) by nano-titanium dioxide and modified Nano tin-antiomony oxide and deionized water, it is added in dispersion bucket, while stirring
While required octyl phenol polyoxyethylene ether wetting agent, 5040 dispersants and W-082 organic silicon defoamers are sequentially added, stirring speed
Spend for 100r/min, stirring 20min；
（2）Then it is 8 to adjust pH with ammonium hydroxide, then adds hollow glass micro-ball and shears scattered 30min with 800r/min, obtains
To pre-dispersed liquid；
（3）2h will be sanded with dispersion liquid again, then ultrasonic disperse 20min, and be filtered after standing 2h, that is, obtain containing modified Nano
The water nano function slurry of tin-antiomony oxide and nano-titanium dioxide；
（4）Silicone modified styrene-acrylate emulsion is put into stainless steel Scattered Kettle, starts to stir, in cutting for 400 r/min
Under cutting dissipates, deionized water is sequentially added, dipropylene coalescents, 2020 levelling agent of polyurethane, ASE60 thickeners,
After low velocity shear disperses 30min, the above-mentioned water nano function slurry prepared is added, accelerates stirring to 1000r/min, cuts
Cutting dissipates 1.5h, is filtered after standing 2h, that is, glass door and window clear dope is made.
Embodiment 3
The present embodiment provides a kind of glass door and window clear dope, the glass door and window included according to the mass fraction with coating with
Lower component：
Silicone modified styrene-acrylate emulsion：42 parts, modified Nano tin-antiomony oxide：18 parts, nano-titanium dioxide：8 parts, hollow glass
Glass microballoon：4 parts of deionized waters：25 parts, octyl phenol polyoxyethylene ether wetting agent：3 parts, 5040 dispersants：7 parts, W-082 organosilicons
Defoamer：5 parts, dipropylene coalescents：5 parts, 2020 levelling agent of polyurethane：3 parts, ASE60 thickeners：6 parts；
A diameter of 80 μm of hollow glass micro-ball.
The preparation method of silicone modified styrene-acrylate emulsion is as follows：
（1）3/4ths composite emulsifying liquid is added in deionized water, stirring and dissolving, then adds monomer benzene second
Alkene, butyl acrylate, acrylic acid, low whipping speed stir 55min under conditions of being 600r/min, pre-emulsion are made；
Wherein, compound emulsifying agent is the mixture of nonylphenol polyoxyethylene ether and lauryl sodium sulfate, polyoxyethylene nonyl phenyl
Vinethene and the mass ratio of lauryl sodium sulfate are 3:1；The mass ratio of butyl acrylate and acrylic acid is 1:1.5；
（2）Equipped with electric mixer, thermometer and dropping funel, reflux condensing tube four-hole boiling flask in, add carbonic acid
The compound emulsifying agent of hydrogen sodium, deionized water and remaining a quarter, stirring are allowed to dissolve and are uniformly dispersed；
（3）After being warming up to 62 DEG C, the ammonium persulfate of half is added, 1/5th pre-emulsification is added dropwise in 30min
Liquid, becomes blue in 82 DEG C of insulation reactions to liquid；
（4）Silane coupling reagent KH-570 is mixed into remaining pre-emulsion, by pre-emulsion and remaining is drawn in 4h
Send out agent solution to instill in flask, drip rear insulation reaction 2h；
（5）It is cooled to room temperature after complete reaction, adjusts pH value 8 with ammonium hydroxide, filtering obtains organosilicon-modified styrene-acrylic breast
Liquid.
The preparation method of modified Nano tin-antiomony oxide is as follows：
（1）It is 7 by volume by polymerized monomer acrylic acid and deionized water:3 mix, and then add stannic chloride pentahydrate
20min is stirred under magnetic stirring apparatus with antimony trichloride, homogeneous system is obtained, then adds ammonium persulfate solution, and use magnetic force
Blender carries out heating stirring, until polymerization-filling is complete, that is, obtains the presoma of tin-antiomony oxide；
（2）Then presoma is heat-treated, dry 2h at 250 DEG C in present thermostatic drying chamber, in mortar after cooling
Middle grinding, be placed in Muffle furnace, heat 700 DEG C with the heating rate of 40 DEG C/min under air atmosphere, calcine 4h, to obtain the final product
To nano antimony tin oxide；
（3）Nano antimony tin oxide is placed in 120 DEG C of vacuum drying chamber, after predrying 4h, addition is equipped with anhydrous second
In the conical flask of alcohol, disperse 40min with ultrasonic wave, transfer them in dry three-neck flask, be placed in 70 DEG C of thermostatted water
In bath, and at the uniform velocity stirred under the rotating speed of 220r/min, KH-570 silane coupler solutions are added dropwise, after reacting 5h, filtered, and
Washed with absolute ethyl alcohol, take its filter cake dry 40min in 120 DEG C of vacuum drying chamber, that is, obtain modified Nano tin-antiomony oxide.
The preparation method of above-mentioned glass door and window clear dope, the glass door and window are specifically walked with the preparation method of clear dope
It is rapid as follows：
(1) by nano-titanium dioxide and modified Nano tin-antiomony oxide and deionized water, it is added in dispersion bucket, while stirring
While required octyl phenol polyoxyethylene ether wetting agent, 5040 dispersants and W-082 organic silicon defoamers are sequentially added, stirring speed
Spend for 150r/min, stirring 25min；
（2）Then it is 8 to adjust pH with ammonium hydroxide, then adds hollow glass micro-ball and shears scattered 40min with 1000r/min,
Obtain pre-dispersed liquid；
（3）2h will be sanded with dispersion liquid again, then ultrasonic disperse 22min, and be filtered after standing 2h, that is, obtain containing modified Nano
The water nano function slurry of tin-antiomony oxide and nano-titanium dioxide；
（4）Silicone modified styrene-acrylate emulsion is put into stainless steel Scattered Kettle, starts to stir, in cutting for 400 r/min
Under cutting dissipates, deionized water is sequentially added, dipropylene coalescents, 2020 levelling agent of polyurethane, ASE60 thickeners,
After low velocity shear disperses 20min, the above-mentioned water nano function slurry prepared is added, accelerates stirring to 800 r/min, cuts
Cutting dissipates 1.2h, is filtered after standing 2h, that is, glass door and window clear dope is made.
In addition to the implementation, the present invention can also have other embodiment.It is all to use equivalent substitution or equivalent transformation shape
Into technical solution, all fall within the protection domains of application claims.
Claims (4)
1. a kind of glass door and window clear dope, it is characterised in that the glass door and window is included following according to the mass fraction with coating
Component：
Wherein, the auxiliary agent includes following components according to the mass fraction：
A diameter of 10-250 μm of the hollow glass micro-ball；
The preparation method of the modified Nano tin-antiomony oxide is as follows：
(1) it is 7 by volume by polymerized monomer acrylic acid and deionized water:3 mix, and then add stannic chloride pentahydrate and three
Antimony chloride stirs 20min under magnetic stirring apparatus, obtains homogeneous system, then adds ammonium persulfate solution, and use magnetic agitation
Device carries out heating stirring, until polymerization-filling is complete, that is, obtains the presoma of tin-antiomony oxide；
(2) and then to presoma it is heat-treated, then dries 2-3h at 250 DEG C in thermostatic drying chamber, after cooling in mortar
Grinding, be placed in Muffle furnace, heat 700 DEG C with the heating rate of 40 DEG C/min under air atmosphere, calcine 4-5h, to obtain the final product
To nano antimony tin oxide；
(3) nano antimony tin oxide is placed in 120 DEG C of vacuum drying chamber, after predrying 4h, added equipped with absolute ethyl alcohol
In conical flask, disperse 30-40min with ultrasonic wave, transfer them in dry three-neck flask, be placed in 70 DEG C of water bath with thermostatic control
In pot, and at the uniform velocity stirred under the rotating speed of 200-250r/min, KH-570 silane coupler solutions are added dropwise, after reacting 5-6h, taken out
Filter, and washed with absolute ethyl alcohol, its filter cake dry 40-60min in 120 DEG C of vacuum drying chamber is taken, that is, obtains modified Nano
Tin-antiomony oxide.
2. glass door and window clear dope according to claim 1, it is characterised in that：The wetting agent is octylphenol polyethylene
Ethylene oxide ether wetting agent, the dispersant are 5040 dispersants, and the defoamer is W-082 organic silicon defoamers, described
Coalescents be dipropylene coalescents, the levelling agent is 2020 levelling agent of polyurethane, the thickener
For ASE60 thickeners.
3. glass door and window clear dope according to claim 1, it is characterised in that：The organosilicon-modified styrene-acrylic breast
The preparation method of liquid is as follows：
(1) 3/4ths compound emulsifying agent is added in deionized water, stirring and dissolving, then adds monomer styrene, third
Olefin(e) acid butyl ester, acrylic acid, low whipping speed stir 50-60min under conditions of being 500-600r/min, pre-emulsion are made；
Wherein, the compound emulsifying agent is the mixture of nonylphenol polyoxyethylene ether and lauryl sodium sulfate, and nonyl phenol gathers
Ethylene oxide ether and the mass ratio of lauryl sodium sulfate are 3:1；The butyl acrylate and the mass ratio of acrylic acid are 1:
1.5；
(2) equipped with electric mixer, thermometer and dropping funel, reflux condensing tube four-hole boiling flask in, add sodium acid carbonate,
The compound emulsifying agent of deionized water and remaining a quarter, stirring are allowed to dissolve and are uniformly dispersed；
(3) after being warming up to 60-65 DEG C, the initiator of half is added, 1/5th pre-emulsion is added dropwise in 30min,
Become blue in 80-82 DEG C of insulation reaction to liquid；
Wherein, the initiator is ammonium persulfate；
(4) Silane coupling reagent KH-570 is mixed into remaining pre-emulsion, by pre-emulsion and remaining initiation in 3-4h
Agent solution is instilled in flask, drips rear insulation reaction 1-2h；
(5) it is cooled to room temperature after complete reaction, adjusts pH value 7-8 with ammonium hydroxide, filtering obtains silicone modified styrene-acrylate emulsion.
4. the preparation method of glass door and window clear dope according to claim 1, it is characterised in that：The glass door and window is used
The preparation method of clear dope comprises the following steps that：
(1) by nano-titanium dioxide and modified Nano tin-antiomony oxide and deionized water, be added in dispersion bucket, stir while
Required wetting agent, dispersant and defoamer are sequentially added, mixing speed 100-150r/min, stirs 20-30min；
(2) it is 8-9 and then to adjust pH with ammonium hydroxide, then adds hollow glass micro-ball and shears scattered 30- with 800-1000r/min
40min, obtains pre-dispersed liquid；
(3) 2-3h is sanded in dispersion liquid again, then ultrasonic disperse 20-25min, is filtered after standing 2h, that is, obtain containing modified Nano
The water nano function slurry of tin-antiomony oxide and nano-titanium dioxide；
(4) silicone modified styrene-acrylate emulsion is put into stainless steel Scattered Kettle, starts to stir, disperseed in the shearing of 400r/min
Under, deionized water is sequentially added, coalescents, levelling agent, thickener, after low velocity shear disperses 20-30min, add above-mentioned
The water nano function slurry prepared, accelerates stirring to 800-1200r/min, shearing and disperses 1.5-2h, filtered after standing 2h,
Glass door and window clear dope is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510125658.XA CN104710883B (en) | 2015-03-23 | 2015-03-23 | A kind of glass door and window clear dope and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510125658.XA CN104710883B (en) | 2015-03-23 | 2015-03-23 | A kind of glass door and window clear dope and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104710883A CN104710883A (en) | 2015-06-17 |
| CN104710883B true CN104710883B (en) | 2018-05-04 |
Family
ID=53410621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510125658.XA Active CN104710883B (en) | 2015-03-23 | 2015-03-23 | A kind of glass door and window clear dope and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104710883B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199578B (en) * | 2015-10-10 | 2018-03-27 | 贵州省万山特区丹缘朱砂工艺品有限公司 | The upper color technique of color calligraphy and painting on a kind of cinnabar |
| CN105199519A (en) * | 2015-11-04 | 2015-12-30 | 无锡艾绿科技有限公司 | Heat insulating coating for transparent window and preparation method of heat insulating coating |
| CN105295578A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Silicone-modified styrene-acrylic emulsion coating and preparation method thereof |
| CN105315819A (en) * | 2015-12-07 | 2016-02-10 | 苏州市神龙门窗有限公司 | Thermal-insulating anti-oxidation coating for outdoor doors and windows and preparation method thereof |
| CN105349032A (en) * | 2015-12-14 | 2016-02-24 | 梅照付 | Environment-friendly, heat-insulating, waterproof and heat-resisting type coating for building external wall and preparation method of environment-friendly, heat-insulating, waterproof and heat-resisting type coating |
| CN105462488A (en) * | 2015-12-14 | 2016-04-06 | 梅照付 | Method for preparing environment-friendly, thermal-insulating, water-proof and thermal resistant coating for building external wall |
| CN105949920A (en) * | 2016-05-19 | 2016-09-21 | 浙江大学宁波理工学院 | Transparent heat insulation solid coating bar and preparation method thereof |
| CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
| CN109354991B (en) * | 2016-12-12 | 2021-02-09 | 重庆亚美欧眼镜有限公司 | Preparation method of environment-friendly coating capable of improving comfort of glasses frame |
| CN107311515A (en) * | 2017-07-19 | 2017-11-03 | 铜仁市万山区丹凤朱砂工艺品研发检测鉴定中心有限公司 | A kind of cinnabar handicraft and preparation method thereof |
| CN108587336A (en) * | 2018-04-16 | 2018-09-28 | 合肥天沃能源科技有限公司 | A kind of water nano thermal-insulating external-wall coating and preparation method thereof |
| CN109021760A (en) * | 2018-07-11 | 2018-12-18 | 合肥帧讯低温科技有限公司 | A kind of waterproof heat-insulating coating and preparation method thereof for inner wall of the pipe |
| CN109825144B (en) * | 2019-02-27 | 2021-02-12 | 江西省龙海化工有限公司 | Preparation method of water-based normal-temperature self-crosslinking self-cleaning heat-insulating coating |
| CN115124254B (en) * | 2022-08-16 | 2023-03-21 | 广东福临门世家智能家居有限公司 | Sun-proof energy-saving nano constant temperature glass and manufacturing method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63281837A (en) * | 1987-05-14 | 1988-11-18 | Takiron Co Ltd | Infrared absorptive laminate |
| CN101643200B (en) * | 2009-08-31 | 2012-02-08 | 石家庄铁道学院 | Preparation method of antimony-doped tin oxide nano-powder |
| CN102020898B (en) * | 2010-10-28 | 2012-08-22 | 华南理工大学 | Nanometer transparent heat insulation coating and preparation method thereof |
| CN102827320A (en) * | 2012-09-17 | 2012-12-19 | 上海富臣化工有限公司 | Styrene acrylic emulsion for interior wall coating material, and preparation method thereof |
-
2015
- 2015-03-23 CN CN201510125658.XA patent/CN104710883B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104710883A (en) | 2015-06-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104710883B (en) | A kind of glass door and window clear dope and preparation method thereof | |
| CN101665648B (en) | Preparation method of heat-reflecting insulation coating | |
| CN105331220B (en) | A kind of composite metal roof insulation water-repellent paint and preparation method thereof | |
| CN101845124B (en) | Water-based hydrophobic nano-resin, glass thermal insulating coating and preparation method | |
| CN109825144B (en) | Preparation method of water-based normal-temperature self-crosslinking self-cleaning heat-insulating coating | |
| CN102241937B (en) | POSS (polyhedral oligomeric silsesquioxane)-modified aqueous nano transparent heat-insulation coating and preparation method thereof | |
| CN105131764B (en) | A kind of reflective insulation texture paint and preparation method thereof | |
| CN106497200A (en) | Heat-insulating slurry and preparation method thereof and water-borne heat-insulating glass coating and preparation method thereof | |
| CN103172291B (en) | Polycarboxylic-acid water reducing agent synthesized at normal temperature, and preparation method and application method thereof | |
| CN105837763A (en) | Silane polycarboxylate water-reducing agent and preparation method thereof | |
| CN106189640A (en) | A kind of preparation method of modified aqueous acrylic acid cold coating | |
| CN106634334A (en) | Thermal-insulation waterproof building paint and preparation method thereof | |
| CN105153863B (en) | A kind of preparation method of photocatalyst organosilicon-modified acrylate emulsion paint | |
| CN109705692A (en) | A kind of elastic compounded emulsion and preparation method thereof with super contaminated resistance | |
| CN104448117B (en) | A kind of aqueous hybrid acrylic acid ester emulsion and preparation method thereof | |
| CN107987601A (en) | A kind of two-component insulation putty for architectural exterior wall and preparation method thereof | |
| CN108102482A (en) | A kind of reflective heat-insulation paint and preparation method thereof | |
| CN105693900A (en) | Preparation method of nano calcium carbonate/vinyl chloride in-situ polymerization composite resin | |
| CN102796230A (en) | Method for preparing silicone acrylic emulsion with high solid content and high silicon content | |
| CN106146755A (en) | A kind of preparation method of high solids content silicone acrylic emulsion | |
| US20230416432A1 (en) | Infrared absorbent dispersion, transparent heat-insulating organic glass, and manufacturing method thereof | |
| CN105884961A (en) | Preparation method of high-weather-resistance high-elasticity fluorine-silicon-modified acrylic emulsion for building thermal-insulation paints | |
| CN106519873A (en) | Glass thermal insulation paint and preparation method thereof | |
| CN109111547A (en) | A kind of silicone modified acrylic emulsion waterproofing agent and the preparation method and application thereof | |
| CN101787238B (en) | Preparation method for high stain-resistant and thermal-insulating type UV curing fluorine coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Jiang Jianying Inventor after: Jiang Yunying Inventor after: Gu Lianying Inventor before: Huang Longhai Inventor before: Huang Yaoqiong Inventor before: Wu Lei |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151203 Address after: Wuzhong District Suzhou City, Jiangsu Province town 215156 Jian Feng Village 7 groups Applicant after: SUZHOU WUZHONG DISTRICT XUKOU HARVEST MACHINERY FITTINGS FACTORY Address before: 215156, Suzhou, Jiangsu province Wuzhong District Xu town and Feng Road, No. 388 Applicant before: Dragon Lord door and window company limited of Suzhou City |
|
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Aiyun Inventor before: Jiang Jianying Inventor before: Jiang Yunying Inventor before: Gu Lianying |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180314 Address after: 215100 Jiangsu province Suzhou Wuzhong Economic Development Zone the River Street Wuzhong Road No. 1368 Building 1 Applicant after: Suzhou Wei you Intellectual Property Operation Co., Ltd. Address before: Wuzhong District Suzhou City, Jiangsu Province town 215156 Jian Feng Village 7 groups Applicant before: SUZHOU WUZHONG DISTRICT XUKOU HARVEST MACHINERY FITTINGS FACTORY |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |