CN105949920A - Transparent heat insulation solid coating bar and preparation method thereof - Google Patents
Transparent heat insulation solid coating bar and preparation method thereof Download PDFInfo
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- CN105949920A CN105949920A CN201610333867.8A CN201610333867A CN105949920A CN 105949920 A CN105949920 A CN 105949920A CN 201610333867 A CN201610333867 A CN 201610333867A CN 105949920 A CN105949920 A CN 105949920A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
- C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The invention discloses a transparent heat insulation solid coating bar. The transparent heat insulation solid coating bar is prepared from, by weight, 10%-60% of waterborne film forming resin, 3%-20% of excipient, 10%-50% of heat insulation materials, 5%-15% of an anti-freezing agent, 0.5%-5% of waterborne dispersing agent, 0.5%-10% of sodium hydroxide and the balance water, wherein the sum of weight percentages of the raw materials is 100%. The preparation method includes steps: firstly, preparation of the raw materials; secondly, pouring water into a dispersing kettle, stirring, adding the waterborne dispersing agent, adding the heat insulation materials, and performing high-speed dispersion to obtain heat insulation slurry; thirdly, pouring the heat insulation slurry into a reaction kettle, stirring, heating to 75-90 DEG C, adding the waterborne film forming resin, stirring uniformly, sequentially adding the anti-freezing agent and the excipient, well mixing, adding the sodium hydroxide to regulate a pH value, carrying out heat reaction, discharging, filling and cooling to obtain the transparent heat insulation solid coating bar. The transparent heat insulation solid coating bar has advantages of low production cost and convenience in use and can be removed by water.
Description
Technical field
The present invention relates to a kind of reflective insulation material, refer specifically to a kind of transparent heat-insulated solid and be coated with rod and preparation method thereof.
Background technology
Windowpane is lighting for buildings and the important channel of energy turnover, and the heat dissipation capacity of building doors and windows is at me to have statistical data to show
State accounts for more than the 50% of the total heat dissipation capacity of building external, is 3～5 times of developed country.In recent years, the widely used large-scale window of building and
Glass curtain wall, this considerably increases the energy consumption of building cooling in summer, and the energy-saving material being therefore developed for windowpane is significant.
The most ripe product is patch transparent heat-insulating film on glass, but this kind of product price is higher, energy consumption
Relatively big, also need to certain construction technique during pad pasting, and when needing sunlit heat the most within doors, thermal isolation film but rises
To heat insulation negative interaction, it is unfavorable for warming oneself within doors.In recent years, the exploitation of transparent heat insulating dope is that this problem provides another kind
Solution, but existing transparent heat insulating dope yet suffers from relatively costly, and difficulty of construction is big, it is difficult to removes and is unfavorable for winter sunlight
The shortcomings such as heating, therefore it needs to improve further.
Summary of the invention
The technical problem to be solved is for above-mentioned prior art present situation, and provides production cost low, uses
Convenient, it is possible to clean with water and remove, storage, the transparent heat-insulated solid of one of convenient transportation are coated with rod, and its preparation method technique is simple,
With short production cycle.
The present invention solves the technical scheme that above-mentioned technical problem used:
A kind of transparent heat-insulated solid is coated with rod, and the percentage by weight of each raw material is: aqueous film-forming resin 10% to 60%, excipient 3% to
20%, heat-barrier material 10% to 50%, antifreeze 5% to 15%, aqueous dispersion 0.5% to 5%, sodium hydroxide 0.5% to 10%, remaining
For water, the summation of above-mentioned each composition is 100%.
For optimizing technique scheme, the measure taked also includes:
Above-mentioned aqueous film-forming resin is polyvinylpyrrolidone or elastomeric propylene yogurt liquid.
Above-mentioned excipient is one or more mixture in stearic acid, Palmic acid, lauric acid.
Above-mentioned heat-barrier material is nano antimony tin oxide or nano-indium stannum oxide.
Above-mentioned antifreeze is the one in glycerol, propylene glycol, or the mixture of two kinds.
Above-mentioned aqueous dispersion is ammonium polyacrylate salt or VTES.
A kind of transparent heat-insulated solid is coated with the preparation method of rod: comprise the following steps:
Step one, preparation raw material；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
Use high speed dispersor high speed dispersion, obtain heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mixing mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value, insulation is anti-
Ying Hou, i.e. obtains transparent heat-insulated solid and is coated with rod finished product after discharging fill cooling.
The rotating speed of above-mentioned high speed dispersor is 2000 r/min to 5000r/min；The time of above-mentioned high speed dispersion is
30min to 90min.
Above-mentioned step 3 regulates pH value to 8 to 9.
The time of above-mentioned insulation reaction is 30 min to 90min.
Compared with prior art, it is an advantage of the current invention that this transparent heat-insulated solid is coated with rod production cost low, easy to use, energy
Enough water cleans to be removed, and product presents in solid form, therefore storage, convenient transportation；Its preparation technology is simple, with short production cycle.
The transparent heat-insulated solid of the present invention is coated with rod and uses aqueous film-forming resin, safety and environmental protection, and common consumer is not required to training
Instruction study just can oneself use, and coats the thermal isolation film of layer of transparent for glass.When the winter need not heat insulation, available to its water spray
Wipe after softening or take off, waiting film the most again in summer in the coming year, so can cover in summer and day not interfere with again the heating in winter.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
A kind of transparent heat-insulated solid is coated with rod, and the percentage by weight of each raw material is: aqueous film-forming resin 10% to 60%, excipient
3% to 20%, heat-barrier material 10% to 50%, antifreeze 5% to 15%, aqueous dispersion 0.5% to 5%, sodium hydroxide 0.5% to 10%,
Remaining is water, and the summation of above-mentioned each composition is 100%.
In embodiment, aqueous film-forming resin is polyvinylpyrrolidone or elastomeric propylene yogurt liquid.
In embodiment, excipient is one or more mixture in stearic acid, Palmic acid, lauric acid.
In embodiment, heat-barrier material is nano antimony tin oxide or nano-indium stannum oxide.
In embodiment, antifreeze is the one in glycerol, propylene glycol, or the mixture of two kinds.
In embodiment, aqueous dispersion is ammonium polyacrylate salt or VTES.
A kind of transparent heat-insulated solid is coated with the preparation method of rod: comprise the following steps:
Step one, preparation raw material；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
It is 2000r/min to 5000r/min high speed dispersor high speed dispersion 30min to 90min with rotating speed, obtains heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mix mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value to 8 to 9,
After insulation reaction 30min to 90min, i.e. obtain transparent heat-insulated solid after discharging fill cooling and be coated with rod finished product.
The transparent heat-insulated solid of the present invention is coated with rod and uses aqueous film-forming resin, safety and environmental protection, and common consumer is not required to training
Instruction study just can oneself use, and coats the thermal isolation film of layer of transparent for glass, uses very convenient.Need not heat insulation in the winter
Time, can use and wipe or take off after its water spray is softened, wait film the most again in summer in the coming year, so can cover in summer and again will not day
Affect the heating in winter.
It is illustrated by below by specific embodiment.
Embodiment one:
Step one, according to following percentage by weight prepare raw material:
Aqueous film-forming resin: polyvinylpyrrolidone 10%
Excipient: stearic acid 5%
Lauric acid 3%
Heat-barrier material: nano antimony tin oxide 20%
Antifreeze: glycerol 5%
Propylene glycol 3%
Aqueous dispersion: VTES 1%
Sodium hydroxide 2%
Remaining is water (51%)；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
It is 2000r/min high speed dispersor high speed dispersion 30min with rotating speed, obtains heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mix mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value to 8, insulation
After reaction 30min, i.e. obtain transparent heat-insulated solid after discharging fill cooling and be coated with rod finished product.
Embodiment two:
Step one, according to following percentage by weight prepare raw material:
Aqueous film-forming resin: elastomeric propylene yogurt liquid 30%
Excipient: stearic acid 8%
Palmic acid 3%
Heat-barrier material: nano-indium stannum oxide 15%
Antifreeze: glycerol 10%
Aqueous dispersion: ammonium polyacrylate salt 1.5%
Sodium hydroxide 3.5%
Remaining is water (29%)；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
It is 5000r/min high speed dispersor high speed dispersion 90min with rotating speed, obtains heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mix mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value to 9, insulation
After reaction 90min, i.e. obtain transparent heat-insulated solid after discharging fill cooling and be coated with rod finished product.
Embodiment three:
Step one, according to following percentage by weight prepare raw material:
Aqueous film-forming resin: polyvinylpyrrolidone 20%
Excipient: stearic acid 8%
Heat-barrier material: nano antimony tin oxide 25%
Antifreeze: propylene glycol 12%
Aqueous dispersion: VTES 2%
Sodium hydroxide 2%
Remaining is water (31%)；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
It is 4000r/min high speed dispersor high speed dispersion 60min with rotating speed, obtains heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mix mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value to 8.5, protect
After temperature reaction 60min, i.e. obtain transparent heat-insulated solid after discharging fill cooling and be coated with rod finished product.
Embodiment four:
In the present embodiment, the percentage by weight of each component raw material is as follows:
Aqueous film-forming resin: elastomeric propylene yogurt liquid 30%
Excipient: stearic acid 5%
Palmic acid 5%
Lauric acid 5%
Heat-barrier material: nano-indium stannum oxide 15%
Antifreeze: propylene glycol 10%
Aqueous dispersion: VTES 0.5%
Sodium hydroxide 3.5%
Remaining is water (26%).
Embodiment five:
In the present embodiment, the percentage by weight of each component raw material is as follows:
Aqueous film-forming resin: polyvinylpyrrolidone 20%
Excipient: stearic acid 5%
Lauric acid 8%
Heat-barrier material: nano antimony tin oxide 20%
Antifreeze: glycerol 6%
Propylene glycol 7%
Aqueous dispersion: VTES 5%
Sodium hydroxide 6%
Remaining is water (23%).
Embodiment six:
In the present embodiment, the percentage by weight of each component raw material is as follows:
Aqueous film-forming resin: polyvinylpyrrolidone 60%
Excipient: Palmic acid 3%
Heat-barrier material: nano antimony tin oxide 10%
Antifreeze: glycerol 5%
Aqueous dispersion: ammonium polyacrylate salt 1%
Sodium hydroxide 0.5%
Remaining is water (20.5%).
Embodiment seven:
In the present embodiment, the percentage by weight of each component raw material is as follows:
Aqueous film-forming resin: elastomeric propylene yogurt liquid 40%
Excipient: stearic acid 3%
Palmic acid 3%
Heat-barrier material: nano-indium stannum oxide 10%
Antifreeze: propylene glycol 7%
Aqueous dispersion: ammonium polyacrylate salt 1%
Sodium hydroxide 10%
Remaining is water (26%).
Highly preferred embodiment of the present invention illustrates, those of ordinary skill in the art the various changes made or remodeling are the most not
Can depart from the scope of the present invention.
Claims (10)
1. a transparent heat-insulated solid is coated with rod, it is characterized in that: the percentage by weight of each raw material is: aqueous film-forming resin 10% to
60%, excipient 3% to 20%, heat-barrier material 10% to 50%, antifreeze 5% to 15%, aqueous dispersion 0.5% to 5%, sodium hydroxide
0.5% to 10%, remaining is water, and the summation of above-mentioned each composition is 100%.
The transparent heat-insulated solid of one the most according to claim 1 is coated with rod, it is characterized in that: described aqueous film-forming resin is poly-
Vinylpyrrolidone or elastomeric propylene yogurt liquid.
The transparent heat-insulated solid of one the most according to claim 2 be coated with rod, it is characterized in that: described excipient be stearic acid,
One or more mixture in Palmic acid, lauric acid.
The transparent heat-insulated solid of one the most according to claim 3 is coated with rod, it is characterized in that: described heat-barrier material is nano oxygen
Change stannum antimony or nano-indium stannum oxide.
The transparent heat-insulated solid of one the most according to claim 4 be coated with rod, it is characterized in that: described antifreeze be glycerol, third
One in glycol, or the mixture of two kinds.
The transparent heat-insulated solid of one the most according to claim 5 is coated with rod, it is characterized in that: described aqueous dispersion is poly-third
Enoic acid ammonium salt or VTES.
A kind of transparent heat-insulated solid the most according to claim 1 is coated with the preparation method of rod: it is characterized in that: include following step
Rapid:
Step one, preparation raw material；
Step 2, Jiang Shui pour Scattered Kettle into, add aqueous dispersion, be slow added into heat-barrier material after 15min after starting stirring,
Use high speed dispersor high speed dispersion, obtain heat-insulating slurry；
Step 3, pour heat-insulating slurry into reactor, stir and be warming up to 75 DEG C to 90 DEG C, add aqueous film-forming resin and fully stir
Mixing mix homogeneously, sequentially add antifreeze, excipient mix homogeneously, be eventually adding sodium hydroxide key joint pH value, insulation is anti-
Ying Hou, i.e. obtains transparent heat-insulated solid and is coated with rod finished product after discharging fill cooling.
A kind of transparent heat-insulated solid the most according to claim 7 is coated with the preparation method of rod: it is characterized in that: described high speed is divided
The rotating speed dissipating machine is 2000r/min to 5000r/min；The time of described high speed dispersion is 30min to 90min.
A kind of transparent heat-insulated solid the most according to claim 8 is coated with the preparation method of rod: it is characterized in that: described step 3
Middle regulation pH value is to 8 to 9.
A kind of transparent heat-insulated solid the most according to claim 9 is coated with the preparation method of rod: it is characterized in that: described insulation
The time of reaction is 30min to 90min.
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| CN201610333867.8A CN105949920A (en) | 2016-05-19 | 2016-05-19 | Transparent heat insulation solid coating bar and preparation method thereof |
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| CN101108946A (en) * | 2007-07-12 | 2008-01-23 | 深圳清华大学研究院 | Nano transparent insulating paint and its preparing process |
| CN101550307A (en) * | 2009-05-14 | 2009-10-07 | 复旦大学 | Transparent heat insulation coating material, preparation method and application thereof |
| CN101906261A (en) * | 2010-05-09 | 2010-12-08 | 邹侯招 | Thermal insulating glass coating with high leveling property |
| CN102408806A (en) * | 2011-11-03 | 2012-04-11 | 浙江大学 | High-emission transparent heat-insulating paint in atmospheric window regions and preparation method thereof |
| CN103540178A (en) * | 2013-10-22 | 2014-01-29 | 李俊强 | Solid construction paint and preparation method thereof |
| CN104710883A (en) * | 2015-03-23 | 2015-06-17 | 苏州市神龙门窗有限公司 | Transparent coating for glass window and door and preparation method of transparent coating |
-
2016
- 2016-05-19 CN CN201610333867.8A patent/CN105949920A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5518810A (en) * | 1993-06-30 | 1996-05-21 | Mitsubishi Materials Corporation | Infrared ray cutoff material and infrared cutoff powder use for same |
| CN101108946A (en) * | 2007-07-12 | 2008-01-23 | 深圳清华大学研究院 | Nano transparent insulating paint and its preparing process |
| CN101550307A (en) * | 2009-05-14 | 2009-10-07 | 复旦大学 | Transparent heat insulation coating material, preparation method and application thereof |
| CN101906261A (en) * | 2010-05-09 | 2010-12-08 | 邹侯招 | Thermal insulating glass coating with high leveling property |
| CN102408806A (en) * | 2011-11-03 | 2012-04-11 | 浙江大学 | High-emission transparent heat-insulating paint in atmospheric window regions and preparation method thereof |
| CN103540178A (en) * | 2013-10-22 | 2014-01-29 | 李俊强 | Solid construction paint and preparation method thereof |
| CN104710883A (en) * | 2015-03-23 | 2015-06-17 | 苏州市神龙门窗有限公司 | Transparent coating for glass window and door and preparation method of transparent coating |
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Application publication date: 20160921 |