CN105199472B - A kind of preparation method of airsetting matrix insulation phase-change coating - Google Patents
A kind of preparation method of airsetting matrix insulation phase-change coating Download PDFInfo
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Abstract
The invention discloses a kind of preparation method of airsetting matrix insulation phase-change coating, belong to insulation material technical field for building.Major function filler is used as using aeroge base composite phase-change material, it is compound in certain proportion with filming emulsion, hollow glass micropearl, fiber, dispersant, wetting agent, coalescents, pigment, deionized water, defoamer, thickener etc., high performance airsetting matrix insulation phase-change coating is prepared.The advantage of the invention is that：(1) by regarding aeroge base composite phase-change material as major function filler, there is provided a kind of preparation method of high-performance insulation phase-change coating, insulation phase-change coating prepared by the inventive method, heat-proof quality is excellent, fire-retardant, waterproof and service life are grown；(2) with method reaction process provided by the invention is simple, mild condition, flow are short, it is adapted to industrialized production.
Description
Technical field
The present invention relates to a kind of insulation material technical field for building, more particularly to a kind of airsetting matrix insulation phase-change coating
Preparation method.
Background technology
With the significantly propulsion of China's process of industrialization, rapid development of economy, urbanization degree is improved constantly, and the energy is asked
Topic has become the principal element for restricting economic development, and it is very urgent to save the energy.And the development of energy storage material is saved, with China
It can realize that green, energy-conservation, the strategy of sustainable development are closely related.As China is to the saving energy and the continuous weight of environmental protection
Depending on the energy-conservation energy storage technology of building maintenance structure is also increasingly being strengthened, and especially external walls heating insulation obtains significant progress,
As the important energy-saving building technology in one, China.
Insulation phase-change coating is an important materials for realizing building energy conservation energy storage, can brush on matrix during use, apply
Work is convenient, applicability is wide.The phase transformation component being incubated in phase-change coating can utilize the phase transition process of material, absorb and by environment
Heat stores, and when needed discharges heat, can effectively solve to solve to be caused by time, space or intensity
Heat energy Supply and Demand between mismatch and uneven contradiction.Most widely used in phase-change material is solid-liquid phase change material
, transformation of the solid-state to liquid in its phase transition process be present in material, in order to avoid leakage of the phase-change material under liquid phase state, it is necessary to
Prepare composite phase-change material phase-change material is shaped.Therefore a kind of good sizing phase-change material of stability is developed, and is applied
In insulation phase-change coating field, can effectively prevent due to leakage caused by phase-change material phase transformation.Insulation phase-change coating is applied to
External thermal insulation system, the cold and hot loss that building can be substantially reduced, the effect for improving energy-saving and emission-reduction.
The content of the invention
Goal of the invention：Present invention aims in view of the shortcomings of the prior art, there is provided a kind of excellent thermal insulation performance, it is fire-retardant,
The preparation method of the airsetting matrix insulation phase-change coating of waterproof, anti-leak and service life length.
Technical scheme：A kind of preparation method of new aeroge base insulation phase-change coating of the present invention, including following step
Suddenly：
(1) by silane, organic aldehydes, absolute ethyl alcohol and hydrochloric acid by weight 1：0.2~1：15~30：0.06~0.6 is mixed
Close, 10~30min is stirred at room temperature and is well mixed, above-mentioned solution is sealed, being incubated 6~36h at 20~80 DEG C forms
Wet gel, then remove wet gel in ethanol/water mixed liquor, add organic solvent put in an oven 20~70 DEG C immersion 10~
24h, replace the water in wet gel；Above-mentioned steps are repeated 1~4 time, then the gel soaked after being aged is positioned in baking oven,
60~120 DEG C are warming up to 1~5 DEG C/min heating rate, modified Nano hole dioxy is obtained after 24~120h of constant pressure and dry
SiClx aeroge；
(2) soluble phase transformation core is dissolved in solvent, 1~5h is stirred under the conditions of 10~120 DEG C, makes phase transformation core
It is completely dissolved, obtains phase transformation core homogeneous phase solution；
(3) the improved silica aeroge carrier of above-mentioned preparation is vacuumized into 2~10h under the conditions of 40~200 DEG C, will
The duct of matrix is opened completely, obtains matrix material；
(4) matrix material described in step (3) is scattered in described in step (2) in phase transformation core homogeneous phase solution, 10
2~24h is stirred at~120 DEG C, is subsequently placed in drying box, 24~72h is dried at 40~80 DEG C, obtains improved silica
Aeroge base composite phase-change material；
(5) then deionized water, dispersant, wetting agent, defoamer, coalescents, pigment are added into step by being well mixed
Suddenly the composite phase-change material of improved silica airsetting matrix phase transformation described in (4), hollow glass micropearl, fiber and it is well mixed,
Then filming emulsion, defoamer are added and be well mixed, thickener regulation viscosity is added under stirring condition, obtains airsetting matrix
It is incubated phase-change coating.
Preferably, the silane is 3- aminopropyl trimethoxysilanes, 3- aminopropyls dimethylethoxysilane or 3- ammonia
One or more in propyl-triethoxysilicane.
Preferably, described organic aldehydes is terephthalaldehyde, 4,4’In-diphenyl-dimethanal or 2 amino-terephthalaldehyde
One or more.
Preferably, described acid is the one or more in hydrochloric acid, nitric acid, formic acid or acetic acid, and concentration is 0.1mol L-1~
0.5mol L-1。
Preferably, the described organic solvent for being used to remove the ethanol/water mixed liquor in wet gel be absolute methanol, it is anhydrous
One or more in ethanol or n-hexane.
Preferably, the phase transformation core is polyalcohols, stearic acid, crystalline hydrate salt, inorganic salts or paraffin class
One or more.
To avoid introducing foreign ion, the solvent is preferably one or both of water or ethanol.
Preferably, the polyalcohols specifically include polyethylene glycol, pentaerythrite, neopentyl glycol, trihydroxy methyl amino first
Alkane, trimethylolpropane, 2,2- dihydroxymethyls-propyl alcohol or trimethylolethane.
Preferably, the stearic acid specifically includes stearic acid, myristic acid, palmitic acid capric acid, laurate, acetic acid or ten
Five alkanoic acids.
Preferably, the crystalline hydrate salt specifically include washing soda, sal glauberi, ten hydrogen phosphate dihydrate sodium,
Calcium chloride hexahydrate, Sodium acetate trihydrate or five water sodium thiosulfate.
Preferably, the inorganic salts specifically include sodium chloride, sodium nitrate, sodium carbonate, sodium sulphate, potassium nitrate, lithium nitrate, chlorine
Change potassium, lithium chloride, lithium chromate or lithium carbonate.
Preferably, need to be by dried production described in step (4) when phase transformation core is inorganic salts described in step (2)
Thing is placed in Muffle furnace, and 1~10h is calcined at 100~500 DEG C, furnace cooling, it is compound to obtain improved silica airsetting matrix
Phase-change material.
Preferably, when phase transformation core described in step (2) is crystalline hydrate salt, the base that will be stirred is needed in step (4)
Body material and phase transformation core mixed solution are put into refrigerator refrigerates 1~24h at -5~5 DEG C, and then heat drying, obtains modified two
Silica aerogel base composite phase-change material.
Preferably, filming emulsion described in step (5), improved silica aeroge base composite phase-change material, hollow glass
Glass microballon, fiber, dispersant, wetting agent, coalescents, pigment, deionized water, defoamer, the mass ratio of thickener are 100：1
~40：1~40：1~40：0.1~10：0.1~10：0.5~15：0~15：10~200：0.1~3：0.1~3.
Beneficial effect：(1) by regarding aeroge base composite phase-change material as major function filler, there is provided a kind of high property
The preparation method of phase-change coating can be incubated, insulation phase-change coating prepared by the inventive method, heat-proof quality is excellent, fire-retardant, waterproof
And service life is grown；(2) with method reaction process provided by the invention is simple, mild condition, flow are short, it is adapted to industrial metaplasia
Production.
Brief description of the drawings
Fig. 1 schemes for the FT-IR of the aerosil after hydrophobically modified；
Fig. 2 is the FT-IR figures that improved silica base loads PEG2000 composite phase-change materials；
Fig. 3 is the DSC figures that improved silica base loads PEG2000 composite phase-change materials.
Embodiment
Technical solution of the present invention is described in detail below by accompanying drawing, but protection scope of the present invention is not limited to
The embodiment.
Embodiment 1：
By 3- aminopropyl trimethoxysilanes, terephthalaldehyde, 0.2mol L-1Hydrochloric acid solution and absolute ethyl alcohol with 1：
0.33：20：0.4 mixed in molar ratio, 20min is stirred at room temperature and uniformly mixes, above-mentioned solution is sealed, in 40 DEG C of guarantors
Warm 12h forms gel.Then obtained gel is removed to unnecessary ethanol/water mixed liquor, be immersed in appropriate absolute ethyl alcohol,
Continue after 40 DEG C are incubated 24h, remove the chemical substance of residual.So it is repeated 2 times.Then it is 1 DEG C/min's in programming rate
80 DEG C are warming up under program, modified Nano hole aerosil is obtained after constant pressure and dry 36h.
0.5g PEG2000 is dissolved in 30mL absolute ethyl alcohols, is completely dissolved it under agitation, at 80 DEG C
3h is stirred, obtains uniform solution.0.125g improved silica aeroge is vacuumized into 4h under the conditions of 100 DEG C, by matrix
Duct open completely.Then the improved silica aeroge Jing Guo vacuumize process is scattered in ready PEG2000
In solution, 6h hours are stirred at 80 DEG C, are then put in drying box, 36h is dried at 60 DEG C, improved silica is obtained and bears
Carry PEG composite phase-change materials.
Deionized water, dispersant, wetting agent, defoamer, coalescents, pigment are well mixed, then add modified two
Silica supported PEG composite phase-change materials, hollow glass micropearl, fiber are simultaneously well mixed, and then add filming emulsion, defoamer
Enter and be well mixed, stir and add thickener regulation viscosity, obtain airsetting matrix insulation phase-change coating.Wherein, filming emulsion,
Improved silica load PEG composite phase-change materials, hollow glass micropearl, fiber, dispersant, wetting agent, coalescents, go from
Sub- water, defoamer, the mass ratio of thickener are 100：5：25：5：1：0.5：2：50：0.3：0.3.
Fig. 1 schemes for the FT-IR of the aerosil after hydrophobically modified；Substantially there are Si-O, CH=N- and-CH in figure3
Diffraction maximum, it is provable to have obtained modified Nano hole aerosil；Fig. 2 is that improved silica base loads PEG2000
The FT-IR of composite phase-change material schemes, and substantially has-CH in figure2- and-OH diffraction maximum, be successfully introduced into PEG pieces in composite
Section, it was demonstrated that success synthesis modification titanium dioxide silicon substrate load PEG2000 composite phase-change materials；Fig. 3 loads for improved silica base
The DSC figures of PEG2000 composite phase-change materials, by can be seen that the fusing point of composite phase-change material is 53.85 DEG C in figure, potential heat value is
149.34J·g-1, there is preferable thermal storage performance.
Embodiment 2：
By 3- aminopropyls dimethylethoxysilane, 4,4’- diphenyl-dimethanal, 0.1mol L-1Nitric acid, absolute methanol with
1：0.2：30：0.06 mixed in molar ratio, 10min is stirred at room temperature and uniformly mixes, above-mentioned solution is sealed, at 80 DEG C
It is incubated 6h and forms gel.Then obtained gel is removed to unnecessary ethanol/water mixed liquor, be immersed in appropriate absolute ethyl alcohol
In, continue after 20 DEG C are incubated 10h, remove the chemical substance of residual.So it is repeated 1 times.Then programming rate be 2.5 DEG C/
120 DEG C are warming up under min program, modified Nano hole aerosil is obtained after constant pressure and dry 24h.
0.5g stearic acid is dissolved in 30mL absolute ethyl alcohols, is completely dissolved it under agitation, at 10 DEG C
1h is stirred, obtains uniform solution.0.125g improved silica aeroge is vacuumized into 2h under the conditions of 40 DEG C, by matrix
Open completely in duct.Then the improved silica aeroge Jing Guo vacuumize process is scattered in ready stearic acid solution
In, 2h hours are stirred at 10 DEG C, are then put in drying box, 24h is dried at 40 DEG C, it is hard to obtain improved silica load
Resin acid composite phase-change material.
Deionized water, dispersant, wetting agent, defoamer, coalescents, pigment are well mixed, then add modified two
Silica supported stearic acid composite phase-change material, hollow glass micropearl, fiber are simultaneously well mixed, then by filming emulsion, defoaming
Agent is added and is well mixed, and is stirred and is added thickener regulation viscosity, obtains airsetting matrix insulation phase-change coating.Wherein, film forming
Emulsion, improved silica load stearic acid composite phase-change material, hollow glass micropearl, fiber, dispersant, wetting agent, film forming
Auxiliary agent, pigment, deionized water, defoamer, the mass ratio of thickener are 100：1：40：1：0.1：10：15：1：200：0.1：0.1.
Embodiment 3：
By 3- aminopropyl triethoxysilanes, 2 amino-terephthalaldehyde, 0.5mol L-1Formic acid, n-hexane is with 1：1：
15：0.6 mixed in molar ratio, 30min is stirred at room temperature and uniformly mixes, above-mentioned solution is sealed, 36h is incubated at 20 DEG C
Form gel.Then obtained gel is removed to unnecessary ethanol/water mixed liquor, be immersed in appropriate absolute ethyl alcohol, is continued
After 70 DEG C are incubated 24h, the chemical substance of residual is removed.So it is repeated 4 times.Then in the program that programming rate is 5 DEG C/min
Under be warming up to 60 DEG C, modified Nano hole aerosil is obtained after constant pressure and dry 120h.
0.5g paraffin is dissolved in 30mL absolute ethyl alcohols, is completely dissolved it under agitation, is stirred at 120 DEG C
5h is mixed, obtains uniform solution.0.125g improved silica aeroge is vacuumized into 10h under the conditions of 200 DEG C, by matrix
Open completely in duct.Then the improved silica aeroge Jing Guo vacuumize process is scattered in ready paraffin solution
In, 24h hours are stirred at 120 DEG C, are then put in drying box, 72h is dried at 80 DEG C, obtain improved silica load
Paraffin composite phase change material.
By deionized water, dispersant, wetting agent, defoamer, coalescents, pigment by well mixed, then addition modification
Silicon dioxide carried paraffin composite phase change material, hollow glass micropearl, fiber are simultaneously well mixed, then by filming emulsion, defoaming
Agent is added and is well mixed, and is stirred and is added thickener regulation viscosity, obtains airsetting matrix insulation phase-change coating.Wherein, film forming
Emulsion, improved silica load paraffin composite phase change material, hollow glass micropearl, fiber, dispersant, wetting agent, film forming help
Agent, pigment, deionized water, defoamer, the mass ratio of thickener are 100：40：1：40：10：0.1：0.5：15：10：3：3.
Embodiment 4：
3- aminopropyl trimethoxysilanes, terephthalaldehyde, 0.2mol L-1Acetic acid solution and absolute ethyl alcohol with 1：
0.33：20：0.4 mixed in molar ratio, 20min is stirred at room temperature and uniformly mixes, above-mentioned solution is sealed, in 20 DEG C of guarantors
Warm 36h forms gel.Then obtained gel is removed to unnecessary ethanol/water mixed liquor, be immersed in appropriate absolute ethyl alcohol,
Continue after 40 DEG C are incubated 24h, remove the chemical substance of residual.So it is repeated 2 times.Then it is 1 DEG C/min's in programming rate
80 DEG C are warming up under program, modified Nano hole aerosil is obtained after constant pressure and dry 120h.
8g lithium nitrates are dissolved in 10mL deionized water, are completely dissolved it under agitation, are stirred at 40 DEG C
3h is mixed, obtains uniform solution.The improved silica aeroge of the above-mentioned preparations of 3.5g is vacuumized into 4h under the conditions of 100 DEG C, will
Open completely in the duct of matrix.Then the improved silica aeroge Jing Guo vacuumize process is scattered in ready nitric acid
In lithium solution, 6h hours are stirred at 80 DEG C, are then put in drying box, 20h is dried at 110 DEG C.Products therefrom is placed in horse
Not in stove, 2h, furnace cooling are calcined at 310 DEG C.Obtain the aerogel carried lithium nitrate composite phase-change material of improved silica.
By deionized water, dispersant, wetting agent, defoamer, coalescents, pigment by well mixed, then addition modification
Aerosil load lithium nitrate composite phase-change material, hollow glass micropearl, fiber are simultaneously well mixed, then by film forming breast
Liquid, defoamer are added and are well mixed, and are stirred and are added thickener regulation viscosity, obtain airsetting matrix insulation phase-change coating.Its
In, it is the aerogel carried lithium nitrate composite phase-change material of filming emulsion, improved silica, hollow glass micropearl, fiber, scattered
Agent, wetting agent, coalescents, pigment, deionized water, defoamer, the mass ratio of thickener are 100：10：5：15：1：2：1：2：
80：0.3：0.3.
Embodiment 5：
By 3- aminopropyl trimethoxysilanes, terephthalaldehyde, 0.2mol L-1Hydrochloric acid solution and absolute ethyl alcohol with 1：
0.33：20：0.4 mixed in molar ratio, 20min is stirred at room temperature and uniformly mixes, above-mentioned solution is sealed, in 40 DEG C of guarantors
Warm 12h forms gel.Then obtained gel is removed to unnecessary ethanol/water mixed liquor, be immersed in appropriate absolute ethyl alcohol,
Continue after 40 DEG C are incubated 24h, remove the chemical substance of residual.So it is repeated 2 times.Then it is 1 DEG C/min's in programming rate
80 DEG C are warming up under program, modified Nano hole aerosil is obtained after constant pressure and dry 36h.
8g washing sodas are dissolved in 10mL deionized water, are completely dissolved it under agitation, in 40 DEG C
Lower stirring 3h, obtain uniform solution.The improved silica aeroge of the above-mentioned preparations of 3.5g is vacuumized under the conditions of 100 DEG C
4h, the duct of matrix is opened completely.Then the improved silica aeroge Jing Guo vacuumize process is scattered in and be ready to
Washing soda solution in, at 80 DEG C stir 6h hours, be then put in drying box, at 110 DEG C dry 20h.Gained
Product is placed in Muffle furnace, and 2h, furnace cooling are calcined at 310 DEG C.The aerogel carried lithium nitrate of improved silica is obtained to answer
Close phase-change material.
By deionized water, dispersant, wetting agent, defoamer, coalescents, pigment by well mixed, then addition modification
Aerosil load washing soda composite phase-change material, hollow glass micropearl, fiber are simultaneously well mixed, then will be into
Film emulsion, defoamer are added and are well mixed, and are stirred and are added thickener regulation viscosity, obtain the insulation phase transformation of airsetting matrix and apply
Material.Wherein, the aerogel carried washing soda composite phase-change material of filming emulsion, improved silica, hollow glass micropearl, fibre
Dimension, dispersant, wetting agent, coalescents, pigment, deionized water, defoamer, the mass ratio of thickener are 100：10：5：15：1：
2：1：2：80：0.3：0.3.
As described above, although the present invention has been represented and described with reference to specific preferred embodiment, but it must not be explained
For to the limitation of itself of the invention., can be right under the premise of the spirit and scope of the present invention that appended claims define are not departed from
Various changes can be made in the form and details for it.
Claims (9)
1. a kind of preparation method of airsetting matrix insulation phase-change coating, it is characterised in that comprise the following steps：
(1) by silane, organic aldehydes, absolute ethyl alcohol and acid by weight 1:0.2~1:15~30:0.06~0.6 mixing, in room
10~30min of the lower stirring of temperature is well mixed, and above-mentioned solution is sealed, and being incubated 6~36h at 20~80 DEG C forms wet gel,
Then the ethanol/water mixed liquor in wet gel is removed, organic solvent is added and puts 20~70 DEG C of 10~24h of immersion in an oven, put
The water changed in wet gel；Above-mentioned steps are repeated 1~4 time, then the gel soaked after being aged are positioned in baking oven, with 1~5
DEG C/min heating rate is warming up to 60~120 DEG C, obtain modified Nano hole silica gas after 24~120h of constant pressure and dry
Gel；
(2) soluble phase transformation core is dissolved in solvent, 1~5h is stirred under the conditions of 10~120 DEG C, makes phase transformation core complete
Dissolving, obtain phase transformation core homogeneous phase solution；
(3) the improved silica aeroge carrier of above-mentioned preparation is vacuumized into 2~10h under the conditions of 40~200 DEG C, by matrix
Duct open completely, obtain matrix material；
(4) matrix material described in step (3) is scattered in described in step (2) in phase transformation core homogeneous phase solution, 10~120
2~24h is stirred at DEG C, is subsequently placed in drying box, 24~72h is dried at 40~80 DEG C, obtains improved silica airsetting
Matrix composite phase-change material；
(5) deionized water, dispersant, wetting agent, defoamer, coalescents, pigment are mixed in proportion, then adds step
Suddenly improved silica aeroge base composite phase-change material described in (4), hollow glass micropearl, fiber and it is well mixed, then
Filming emulsion, defoamer are added and be well mixed, thickener regulation viscosity is added under stirring condition, obtains the insulation of airsetting matrix
Phase-change coating；
The filming emulsion, improved silica aeroge base composite phase-change material, hollow glass micropearl, fiber, dispersant, profit
Humectant, coalescents, pigment, deionized water, defoamer, the mass ratio of thickener are 100:1~40:1~40:1~40:0.1
~10:0.1~10:0.5~15:0~15:10~200:0.1~3:0.1~3.
2. the preparation method of airsetting matrix insulation phase-change coating according to claim 1, it is characterised in that：In step (1)
The silane is 3- aminopropyl trimethoxysilanes, 3- aminopropyls dimethylethoxysilane or 3- aminopropyl triethoxysilanes
In one or more.
3. the preparation method of airsetting matrix insulation phase-change coating according to claim 1, it is characterised in that the phase transformation core
Material is the one or more of polyalcohols, stearic acid, crystalline hydrate salt, inorganic salts or paraffin class.
4. the preparation method of airsetting matrix insulation phase-change coating according to claim 3, it is characterised in that the polyalcohol
Class is polyethylene glycol, pentaerythrite, neopentyl glycol, trishydroxymethylaminomethane, trimethylolpropane, 2,2- dihydroxymethyls-the third
Alcohol or trimethylolethane.
5. the preparation method of airsetting matrix insulation phase-change coating according to claim 3, it is characterised in that the stearic acid
Class is stearic acid, myristic acid, palmitic acid capric acid, laurate, acetic acid or pentadecanoic acid.
6. the preparation method of airsetting matrix insulation phase-change coating according to claim 3, it is characterised in that the crystallization water
Conjunction salt is that washing soda, sal glauberi, ten hydrogen phosphate dihydrate sodium, calcium chloride hexahydrate, Sodium acetate trihydrate or five water are thio
Sodium sulphate.
7. the preparation method of airsetting matrix insulation phase-change coating according to claim 3, it is characterised in that the inorganic salts
For sodium chloride, sodium nitrate, sodium carbonate, sodium sulphate, potassium nitrate, lithium nitrate, potassium chloride, lithium chloride, lithium chromate or lithium carbonate.
8. the preparation method of airsetting matrix insulation phase-change coating according to claim 1, it is characterised in that in step (2)
When the phase transformation core is inorganic salts, dried product described in step (4) need to be placed in Muffle furnace, 100~500
1~10h is calcined at DEG C, furnace cooling, obtains improved silica aeroge base composite phase-change material.
9. the preparation method of airsetting matrix insulation phase-change coating according to claim 1, it is characterised in that in step (2)
When the phase transformation core is crystalline hydrate salt, the matrix material and phase transformation core mixed solution that will be stirred are needed in step (4)
It is put into refrigerator and refrigerates 1~24h at -5~5 DEG C, then heat drying, obtains improved silica aeroge base composite phase-change material
Material.
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Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100481282B1 (en) * | 2002-04-30 | 2005-04-07 | 주식회사 에네트 | Paint Composition Using a Phase Change Material |
| TW200946664A (en) * | 2008-05-05 | 2009-11-16 | Queen Win Technology Co Ltd | Coating containing phase change energy storage material and application thereof |
| CN103756646B (en) * | 2014-02-11 | 2017-01-04 | 北京科技大学 | A kind of preparation method of metallic organic framework base composite phase-change material |
| CN104528741B (en) * | 2014-12-17 | 2016-08-24 | 北京科技大学 | A kind of organic modified nano hole aerosil and preparation method thereof |
| CN104559508A (en) * | 2014-12-29 | 2015-04-29 | 三棵树涂料股份有限公司 | Phase change microcapsule-containing thermal insulation coating and preparation method thereof |
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2015
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