CN108187475A - A kind of deodorant compositions and its application - Google Patents
A kind of deodorant compositions and its application Download PDFInfo
- Publication number
- CN108187475A CN108187475A CN201810035220.6A CN201810035220A CN108187475A CN 108187475 A CN108187475 A CN 108187475A CN 201810035220 A CN201810035220 A CN 201810035220A CN 108187475 A CN108187475 A CN 108187475A
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- CN
- China
- Prior art keywords
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- vinegar
- deodorant compositions
- cortex eucommiae
- artemisiae argyi
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 40
- 235000021419 vinegar Nutrition 0.000 claims abstract description 38
- 239000000052 vinegar Substances 0.000 claims abstract description 38
- 239000007788 liquid Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000011187 glycerol Nutrition 0.000 claims abstract description 20
- 241000196324 Embryophyta Species 0.000 claims abstract description 15
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000007297 Gaultheria procumbens Nutrition 0.000 claims abstract description 13
- 229940043350 citral Drugs 0.000 claims abstract description 13
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims abstract description 13
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000012141 concentrate Substances 0.000 claims description 17
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 14
- 229920000053 polysorbate 80 Polymers 0.000 claims description 14
- 241000736246 Pyrola Species 0.000 claims description 12
- 239000010813 municipal solid waste Substances 0.000 claims description 8
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims description 6
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims description 6
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims description 6
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims description 6
- 229940074393 chlorogenic acid Drugs 0.000 claims description 6
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims description 6
- 235000001368 chlorogenic acid Nutrition 0.000 claims description 6
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 6
- ZJDOESGVOWAULF-OGJQONSISA-N Geniposidic acid Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@@H]2C(CO)=CC[C@@H]2C(C(O)=O)=CO1 ZJDOESGVOWAULF-OGJQONSISA-N 0.000 claims description 5
- VYAALAFRWREWLA-BVTMAQQCSA-N Geniposidic acid Natural products CCC1=CC[C@H]2[C@@H]1[C@H](O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)OC=C2C(=O)O VYAALAFRWREWLA-BVTMAQQCSA-N 0.000 claims description 5
- ZJDOESGVOWAULF-UHFFFAOYSA-N Geniposidinsaeure Natural products OC1C(O)C(O)C(CO)OC1OC1C2C(CO)=CCC2C(C(O)=O)=CO1 ZJDOESGVOWAULF-UHFFFAOYSA-N 0.000 claims description 5
- BZPMXJKRKXDRID-UOIKKKDVSA-N Scandoside Natural products OC[C@H]1O[C@@H](O[C@H]2CC=C([C@@H]3[C@@H](O)C=C(CO)[C@H]23)C(=O)O)[C@H](O)[C@@H](O)[C@@H]1O BZPMXJKRKXDRID-UOIKKKDVSA-N 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000003895 organic fertilizer Substances 0.000 claims description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 2
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 2
- 239000011425 bamboo Substances 0.000 claims description 2
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims 1
- 241000333569 Pyrola minor Species 0.000 abstract 1
- 238000000034 method Methods 0.000 description 22
- 230000001877 deodorizing effect Effects 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 16
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 14
- 235000019441 ethanol Nutrition 0.000 description 14
- 238000010790 dilution Methods 0.000 description 12
- 239000012895 dilution Substances 0.000 description 12
- 239000003480 eluent Substances 0.000 description 12
- 239000002023 wood Substances 0.000 description 7
- 238000004821 distillation Methods 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010828 elution Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010936 aqueous wash Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 235000021190 leftovers Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000208688 Eucommia Species 0.000 description 1
- IBFYXTRXDNAPMM-BVTMAQQCSA-N Geniposide Chemical compound O([C@@H]1OC=C([C@@H]2[C@H]1C(=CC2)CO)C(=O)OC)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O IBFYXTRXDNAPMM-BVTMAQQCSA-N 0.000 description 1
- IBFYXTRXDNAPMM-FZEIBHLUSA-N Geniposide Natural products COC(=O)C1=CO[C@@H](O[C@H]2O[C@@H](CO)[C@H](O)[C@@H](O)[C@@H]2O)[C@H]2[C@@H]1CC=C2CO IBFYXTRXDNAPMM-FZEIBHLUSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241000218636 Thuja Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010564 aerobic fermentation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- VGLLGNISLBPZNL-RBUKDIBWSA-N arborescoside Natural products O=C(OC)C=1[C@@H]2C([C@H](O[C@H]3[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O3)OC=1)=C(CO)CC2 VGLLGNISLBPZNL-RBUKDIBWSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 230000002124 endocrine Effects 0.000 description 1
- 210000000750 endocrine system Anatomy 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- -1 nitrogen-containing heterocycle compound Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000005418 vegetable material Substances 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/79—Injecting reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
This application provides a kind of deodorant compositions and its applications.The deodorant compositions include plant vinegar, glycerine, surfactant and water and Cortex Eucommiae leaf extract and/or Folium Artemisiae Argyi extractive liquid and following component：Wintergreen and/or citral.
Description
Technical field
This application provides a kind of deodorant compositions and its applications.
Background technology
Daily life rubbish invariably accompanies the release of foul smell.The stink of rubbish be passed through by the organic principle in rubbish it is thin
Bacterium decomposes and generates.It is organic matter to have 75% to 80% in house refuse, mainly have pericarp, dish leaf dish stalk, leftovers/dish, poultry,
The skin of animal and fish, hair, internal organ, fat, excrement, leftover bits and pieces/watery blood, leaf, waste paper, flowers and plants and body of animal etc. and one
Fixed moisture.During digesting naturally, through under the effects that aerobic/anaerobic fermentation, stench being generated, especially in hot weather
When, since fermentation is accelerated, foul smell becomes more serious.Contained chemical composition has hydrogen sulfide, ammonia in these foul smell
Wait inorganic matters and volatile fatty acid, thio-alcohol, amine, aldehydes, phenols, ketone, ethers and nitrogen-containing heterocycle compound etc. organic
Compound.
These compounds can all cause different degrees of poison to human body respiration, digestion, angiocarpy, endocrine and nervous system
Evil, wherein aromatic compound such as benzene, toluene, styrene etc. can also make human body generate distortion, canceration.In addition to this, domestic animal is raised
It supports the places such as field, bio-feritlizer factory, municipal sewage treatment station, septic tank, public restroom and also generates a large amount of foul smell, influence the mankind
Health.These odor sources can not only endanger relevant staff, also the life of neighbouring resident can be made to be affected.Therefore, it removes
Smelly is a n-th-trem relation n to sanitarian key technology.
The common method of the industrial stench of processing at present has WATER-WASHING METHOD, liquid ablution, active carbon adsorption, ozone oxidation
Method, electrostatic deodorization process, soil deodorization method, combustion method and biological odor removal method etc..But these methods are not strong there are deodorizing capability, deodorization
The problem of effect is poor.
Invention content
One of the application provides a kind of deodorant compositions, including plant vinegar, glycerine, surfactant and water, with
And Cortex Eucommiae leaf extract and/or Folium Artemisiae Argyi extractive liquid, it also comprises the following components：Wintergreen and/or citral.
In a specific embodiment, the plant vinegar is selected from least one of wooden vinegar, bamboo vinegar and careless vinegar.
In a specific embodiment, the surfactant is Tween-80 and/or OP-10.
In a specific embodiment, by volume, the content of the plant vinegar is 2% to 5%, Cortex Eucommiae leaf extract
Content for 1% to 5%, the content of Folium Artemisiae Argyi extractive liquid is 1% to 5%, and the content of glycerine is 1% to 5%, surfactant
Content for 2% to 4%, the content of water is 75% to 92%, and the content of wintergreen is 1% to 4%, and the content of citral is
1% to 4%.
In a specific embodiment, by volume, the content of the plant vinegar is 3%, and Cortex Eucommiae leaf extract contains
It is 2.5% to measure, and the content of Folium Artemisiae Argyi extractive liquid is 2.5%, and the content of glycerine is 2%, and the content of surfactant is 3%, water
Content for 85%, the content of wintergreen is 2%.
In a specific embodiment, by volume, the content of the plant vinegar is 4%, and Cortex Eucommiae leaf extract contains
It is 2.5% to measure, and the content of Folium Artemisiae Argyi extractive liquid is 2.5%, and the content of glycerine is 2%, and the content of surfactant is 3%, water
Content for 84%, the content of citral is 2%.
In a specific embodiment, the plant vinegar is thermal decomposition product of the vegetable material under the conditions of high temperature.
In a specific embodiment, the detailed preparation process of wooden vinegar：Wood shavings is positioned in closed retort,
It is heated at 350 DEG C to 400 DEG C.The crude pyroligneous acid that timber generates is collected through cooling, until no longer generating wood vinegar.Slightly
Wood vinegar is refined using atmospheric distillation, and the distillation component of 60 DEG C to 100 DEG C of harvest obtains pH=1.5-3.7, density is
The acetum pyrolignosum rectificatum liquid of more than 1.001g/ml.
In a specific embodiment, the Cortex Eucommiae leaf extract adds 40v% to 60v% ethanol waters by folium cortex eucommiae
Extraction by being concentrated under reduced pressure, after then crossing column by D101 type macroreticular resins, then adds 30v% to 50v% ethanol aqueous wash
It is de-, then by after ethanol evaporation, the first concentrate is obtained, in mass, Geniposidic acid 3% is contained in first concentrate
To 6%.
In a specific embodiment, the detailed process for obtaining the Cortex Eucommiae leaf extract is as follows：Add into extractor
Enter folium cortex eucommiae and the ethanol water that volume content is 40v% to 60v%, wherein, quality (kg)/volume of folium cortex eucommiae and ethyl alcohol
It is 1 than (L):5 to 1:7, be heated at reflux and (boil) extraction 1 to 3 hour, obtain extracting solution, -0.25 to -
It is concentrated under reduced pressure under 0.75Mpa, until the concentrate of 0.5 to 1 times of Cortex Eucommiae leaf quality, concentrate pass through D101 type macropore trees
Fat is 30v% to 50v% ethanol aqueous wash after the distillation washing column of 8 to 10 times of Cortex Eucommiae leaf qualities, then with volume content
It takes off, the content of Geniposidic acid in on-line checking eluent, stops washing after the mass content of the ingredient is less than 0.5% in eluent
It is de-, eluent is evaporated concentration, obtains the first concentrate (Cortex Eucommiae leaf extract), in mass, first concentrate
In contain Geniposidic acid 3% to 6%.
In a specific embodiment, the Folium Artemisiae Argyi extractive liquid is carried by folium artemisiae argyi by 40v% to 60v% ethanol waters
It takes, by being concentrated under reduced pressure, after then crossing column by AB-8 type macroreticular resins, then adds 50v% to 70v% ethanol aqueous wash
It is de-, then by after ethanol evaporation, the second concentrate is obtained, in mass, chlorogenic acid 4% to 6% is contained in second concentrate.
In a specific embodiment, the detailed process for obtaining the Folium Artemisiae Argyi extractive liquid is as follows：It is added in into extractor
Folium artemisiae argyi and the ethanol water that volume content is 40v% to 60v%, wherein, folium cortex eucommiae and the second that volume content is 50% concentration
The quality (kg) of alcohol/volume ratio (L) is 1:5 to 1:7, extraction 1 to 3 hour is heated at reflux and (boiled), is extracted
Liquid is concentrated under reduced pressure under -0.25 to -0.75Mpa, until the concentrate of 0.5 to 1 times of folium artemisiae argyi quality, concentrate pass through AB-
8 type macroreticular resins are 50v% to 70v% ethyl alcohol after the distillation washing column of 8 to 10 times of folium artemisiae argyi quality, then with volume content
Aqueous solution elutes, the content of on-line checking eluent Content of Chlorogenic Acid, stops after the mass content of the ingredient is less than 0.5% in eluent
It only elutes, eluent is evaporated concentration, obtains the second concentrate (Folium Artemisiae Argyi extractive liquid), in mass, second concentration
Contain chlorogenic acid 4% to 6% in liquid.
The two of the application provide to fill out according to the deodorant compositions described in any one in one of the application for rubbish
It buries a kind of in field, garbage transfer station, public restroom, city septic tank, black and odorous water, organic fertilizer factory and penkeeping field
Using.
The advantageous effect of the application：
The application obtains a kind of extraordinary deodorant compositions of deodorizing effect, and it is especially suitable for refuse landfill, rubbish
Rubbish terminal, public restroom, city septic tank, black and odorous water, organic fertilizer factory or penkeeping field.
Specific embodiment
With reference to embodiment, the invention will be further described, but the exemplary only explanation of the embodiment of the present invention, should
No matter embodiment does not form limitation of the invention under any circumstance.
Unless otherwise instructed, it is use herein to reagent be commercially available.
The wooden commercially available acquisition of vinegar, can also voluntarily be prepared.
The detailed preparation process of wooden vinegar：100kg wood shavings is positioned in closed retort, to wood shavings with not
400 DEG C of the temperature occurred higher than tar is heated and generates crude pyroligneous acid.Stop heating no longer to generate wood vinegar.Timber produces
Raw crude pyroligneous acid is collected through cooling.Crude pyroligneous acid is refined using atmospheric distillation.The steaming of 60 DEG C to 100 DEG C of harvest
Component is evaporated, obtains pH=2.0, density is the acetum pyrolignosum rectificatum liquid of 1.001g/ml
The detailed preparation process of Cortex Eucommiae leaf extract：It is 50% that 10kg folium cortex eucommiaes are added in into extractor with volume content
Ethyl alcohol 50L is heated at reflux extraction 2 hours, obtains extracting solution, and decompression (- 0.5MPa) is concentrated into 5L, and concentrate is big by D101 types
Hole resin after distilling washing column with 100L, then with volume content is 50% ethanol elution, Geniposide in on-line checking eluent
The content of thuja acid stops elution after the mass content of the ingredient is less than 0.5% in eluent, eluent is evaporated concentration,
Until the mass content of the Geniposidic acid in concentrate stops concentration, as Cortex Eucommiae leaf extract when being 5%.Cool down standby
With.
The detailed preparation process of Folium Artemisiae Argyi extractive liquid：10kg folium artemisiae argyis and volume content are added in into extractor as 40% ethyl alcohol
50L is heated at reflux extraction 2 hours, obtains extracting solution, and decompression (- 0.5MPa) is concentrated into 5L, and concentrate passes through AB-8 type macropore trees
Fat is 50% ethanol elution after 100L distillation washing columns, then with volume content, and on-line checking eluent Content of Chlorogenic Acid contains
It measures, stops elution after the mass content of the ingredient is less than 0.5% in eluent, eluent is evaporated concentration, until concentrating
Stop concentration, as Folium Artemisiae Argyi extractive liquid when the mass content of chlorogenic acid in liquid is 4%.It is spare after cooling.
Each component content in formula as below is by volume.
Embodiment 1
Preparation method：By volume, wintergreen 1%, Tween-80 1%, OP-10 1%, wooden vinegar 2%, glycerine 1%,
Cortex Eucommiae leaf extract 1%, Folium Artemisiae Argyi extractive liquid 1%, water 92%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 2
Preparation method：By volume, wintergreen 4%, Tween-80 2%, OP-10 2%, wooden vinegar 4%, glycerine 3%,
Cortex Eucommiae leaf extract 5%, Folium Artemisiae Argyi extractive liquid 5%, water：75%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 3
Preparation method：By volume, wintergreen 2%, Tween-80 1.5%, OP-10 1.5%, wooden vinegar 3%, glycerine
2%, Cortex Eucommiae leaf extract 2.5%, Folium Artemisiae Argyi extractive liquid 2.5%, water：85%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 4
Preparation method：By volume, citral 1%, Tween-80 1%, OP-10 1%, wooden vinegar 3%, glycerine 1%,
Cortex Eucommiae leaf extract 1%, Folium Artemisiae Argyi extractive liquid 1%, water：91%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 5
Preparation method：By volume, citral 4%, Tween-80 2%, OP-10 2%, wooden vinegar 5%, glycerine 5%,
Cortex Eucommiae leaf extract 5%, Folium Artemisiae Argyi extractive liquid 5%, water：78%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 6
Preparation method：By volume, citral 2%, Tween-80 1.5%, OP-10 1.5%, wooden vinegar 4%, glycerine
2%, Cortex Eucommiae leaf extract 2.5%, Folium Artemisiae Argyi extractive liquid 2.5%, water：84%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 7
Preparation method：By volume, Cortex Eucommiae extracting solution 2.5%, wintergreen 2%, Tween-80 1.5%, OP-10
1.5%, wooden vinegar 3%, glycerine 2%, water：90%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 8
Preparation method：By volume, Cortex Eucommiae extracting solution 2.5%, citral 2%, Tween-80 1.5%, OP-10
1.5%, wooden vinegar 4%, glycerine 2%, water：89%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 9
Preparation method：By volume, Folium Artemisiae Argyi extractive liquid 2.5%, wintergreen 2%, Tween-80 1.5%, OP-10
1.5%, wooden vinegar 3%, glycerine 2%, water：90%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Embodiment 10
Preparation method：By volume, Folium Artemisiae Argyi extractive liquid 2.5%, citral 2%, Tween-80 1.5%, OP-10
1.5%, wooden vinegar 4%, glycerine 2%, water：89%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Comparative example 1
Preparation method：By volume, wintergreen 2%, Tween-80 1.5%, OP-10 1.5%, wooden vinegar 3%, glycerine
2%, water：90%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
Comparative example 2
Preparation method：By volume, citral 2%, Tween-80 1.5%, OP-10 1.5%, wooden vinegar 4%, glycerine
2%, water：89%.
It is sprayed in smelly source exposure after 10 times of dilution, by 100mL/m2It is sprayed.
Deodorizing effect is carried out by the triangle odor bag method in the measure (GB/T 14675-1993) of air quality stench
It measures, the results are shown in Table 1.
According to table 1 as a result, from the embodiment 1-10 deodorizing effects being formulated and the deodorizing effect of the formula of comparative example 1 and 2
Comparison it is found that add in the deodorant liquid after Cortex Eucommiae leaf extract and Folium Artemisiae Argyi extractive liquid, either remove instant air foul smell
Or the continuity of deodorizing effect is all substantially better than the formula for containing only wood vinegar.As it can be seen that Cortex Eucommiae leaf extract and folium artemisiae argyi extraction
Liquid plays more crucial effect in terms of deodorizing effect.Particularly from the embodiment 1-6 deodorizing effects being formulated and embodiment
The comparison of the deodorizing effect of 7-10 formulas is it is found that when Cortex Eucommiae leaf extract and Folium Artemisiae Argyi extractive liquid exist with formula jointly, and two
Synergistic effect is produced between person, improves the deodorizing effect of formula.In addition, from embodiment interpretation of result, and carried in folium cortex eucommiae
Be not that content is The more the better in the use scope for taking liquid and Folium Artemisiae Argyi extractive liquid, but there are one range, Cortex Eucommiae leaf extract with
The content of both Folium Artemisiae Argyi extractive liquids is respectively 1% to 5%, according to embodiment it is found that in usage amount 2.5% best results.
Table 1
Although the application is described with reference to specific embodiment, it should be appreciated by those skilled in the art
In the case of the real spirit and scope without departing from the application, the various changes that can carry out.Furthermore, it is possible to this Shen
Main body, spirit and scope please are variously changed to adapt to specific situation, material, material compositions and method.All
These changes are included in the range of claims hereof.
Claims (10)
1. a kind of deodorant compositions, including plant vinegar, glycerine, surfactant and water and Cortex Eucommiae leaf extract and/or
Folium Artemisiae Argyi extractive liquid also comprises the following components：
Wintergreen and/or citral.
2. deodorant compositions according to claim 1, which is characterized in that the plant vinegar is selected from wooden vinegar, bamboo vinegar and careless vinegar
At least one of.
3. deodorant compositions according to claim 1 or 2, which is characterized in that the surfactant for Tween-80 and/
Or OP-10.
4. deodorant compositions as claimed in any of claims 1 to 3, which is characterized in that by volume, the plant
The content of vinegar is 2% to 5%, and the content of Cortex Eucommiae leaf extract is 1% to 5%, and the content of Folium Artemisiae Argyi extractive liquid is 1% to 5%, third
The content of triol is 1% to 5%, and the content of surfactant is 2% to 4%, and the content of water is 75% to 92%, wintergreen
Content is 1% to 4%, and the content of citral is 1% to 4%.
5. deodorant compositions according to claim 4, which is characterized in that by volume, the content of the plant vinegar is
3%, the content of Cortex Eucommiae leaf extract is 2.5%, and the content of Folium Artemisiae Argyi extractive liquid is 2.5%, and the content of glycerine is 2%, surface
The content of activating agent is 3%, and the content of water is 85%, and the content of wintergreen is 2%.
6. deodorant compositions according to claim 4, which is characterized in that by volume, the content of the plant vinegar is
4%, the content of Cortex Eucommiae leaf extract is 2.5%, and the content of Folium Artemisiae Argyi extractive liquid is 2.5%, and the content of glycerine is 2%, surface
The content of activating agent is 3%, and the content of water is 84%, and the content of citral is 2%.
7. deodorant compositions as claimed in any of claims 1 to 6, which is characterized in that the plant vinegar is plant
Thermal decomposition product of the material under the conditions of high temperature.
8. deodorant compositions as claimed in any of claims 1 to 7, which is characterized in that the Cortex Eucommiae leaf extract
It is extracted by folium cortex eucommiae plus 40v% to 60v% ethanol waters, by being concentrated under reduced pressure, after crossing column by D101 type macroreticular resins,
Again plus 30v% is eluted to 50v% ethanol waters, after ethanol evaporation, obtains the first concentrate, in mass, described the
Contain Geniposidic acid 3% to 6% in one concentrate.
9. deodorant compositions as claimed in any of claims 1 to 8, which is characterized in that the Folium Artemisiae Argyi extractive liquid by
Folium artemisiae argyi is extracted by 40v% to 60v% ethanol waters, is concentrated under reduced pressure, and after crossing column by AB-8 type macroreticular resins, then is added
50v% is eluted to 70v% ethanol waters, after ethanol evaporation, obtains the second concentrate, in mass, second concentration
Contain chlorogenic acid 4% to 6% in liquid.
10. deodorant compositions according to any one in claim 1-9 for refuse landfill, garbage transfer station,
A kind of application in public restroom, city septic tank, black and odorous water, organic fertilizer factory and penkeeping field.
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