CN108178828A - Epoxy resin cured product and composition epoxy resin - Google Patents

Epoxy resin cured product and composition epoxy resin Download PDF

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Publication number
CN108178828A
CN108178828A CN201711449240.XA CN201711449240A CN108178828A CN 108178828 A CN108178828 A CN 108178828A CN 201711449240 A CN201711449240 A CN 201711449240A CN 108178828 A CN108178828 A CN 108178828A
Authority
CN
China
Prior art keywords
epoxy resin
parts
cured product
resin cured
composition epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711449240.XA
Other languages
Chinese (zh)
Inventor
黄慧琳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI HUAYI RESINS Co Ltd
Original Assignee
SHANGHAI HUAYI RESINS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI HUAYI RESINS Co Ltd filed Critical SHANGHAI HUAYI RESINS Co Ltd
Priority to CN201711449240.XA priority Critical patent/CN108178828A/en
Publication of CN108178828A publication Critical patent/CN108178828A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • C08G59/58Amines together with other curing agents with polycarboxylic acids or with anhydrides, halides, or low-molecular-weight esters thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used

Abstract

The present invention proposes a kind of epoxy resin cured product and composition epoxy resin, wherein, epoxy resin cured product includes:45 55 parts of high temperature modification mixture;21 23 parts of aluminium oxide;17 20 parts of isoprene;15 20 parts of n-butanol water glycerin ether;10 13 parts of carbon fiber;12 13 parts of diluent.The curing reaction rate of epoxy resin cured product is fast, and can improve solidification effect.Also, have many advantages, such as that solidification effect is good using the composition epoxy resin of above-mentioned epoxy resin cured product, stability is high and stickiness is good.

Description

Epoxy resin cured product and composition epoxy resin
Technical field
The present invention relates to epoxy resin cured products and composition epoxy resin field.
Background technology
Epoxy resin has superior heat resistance, mechanical property, electrical characteristic and adhesiveness.Epoxy resin is special using this Property, for wiring substrate, circuit board or the sealing material by the circuit board of these multiple stratifications, semiconductor chip, coil, circuit etc. Material.Alternatively, epoxy resin can also be used as the resin of adhesive, coating, fiber-reinforced resin.
However, because epoxy resin is usually more crisp, exist due to using during curing agent solidification or when using ess-strain, Impact in heat, mechanics etc. easily leads to the problem of cracking.
Invention content
The purpose of the present invention is to provide a kind of epoxy resin cured product and composition epoxy resin, for solving existing skill The problem of art.
In order to achieve the above object, the present invention proposes a kind of epoxy resin cured product, including:
45-55 parts of high temperature modification mixture
21-23 parts of aluminium oxide
17-20 parts of isoprene
15-20 parts of n-butanol water glycerin ether
10-13 parts of carbon fiber
12-13 parts of diluent;
Further, in the epoxy resin cured product, the high temperature modification mixture includes aromatic polyamine, acid Acid anhydride, resol, amino resins, dicyandiamide and hydrazides.
Further, in the epoxy resin cured product, the diluent include polypropylene glycol diglycidyl ether, Epoxy propane butyl ether and ethylene glycol diglycidylether.
Also proposed a kind of composition epoxy resin in another aspect of this invention, including at least one amino-compound, Phenolic compound, the liquid epoxies compound, inorganic that at least one range of viscosities is 1000mPa-s~500,000mPa-s Filler and epoxy resin cured product as described above.
Further, in the composition epoxy resin, the phenolic compound includes Benzenediol.
Further, in the composition epoxy resin, the amino-compound includes hydroxyl functional amine compounds Object.
Further, in the composition epoxy resin, the inorganic filler for silicon carbide micro-powder, corundum powder or Graphite microparticles.
Compared with prior art, the beneficial effects are mainly as follows:The curing reaction speed of epoxy resin cured product Rate is fast, and can improve solidification effect.
Specific embodiment
The epoxy resin cured product and composition epoxy resin of the present invention are carried out below in conjunction with schematic diagram more detailed Description, which show the preferred embodiment of the present invention, it should be appreciated that those skilled in the art can change described here Invention, and still realize the advantageous effects of the present invention.Therefore, description below should be understood as those skilled in the art's It is widely known, and it is not intended as limitation of the present invention.
In the present embodiment, it is proposed that a kind of epoxy resin cured product, including:
45-55 parts of high temperature modification mixture
21-23 parts of aluminium oxide
17-20 parts of isoprene
15-20 parts of n-butanol water glycerin ether
10-13 parts of carbon fiber
12-13 parts of diluent;
Wherein, the high temperature modification mixture includes aromatic polyamine, acid anhydrides, resol, amino resins, dicyandiamide And hydrazides.The diluent includes polypropylene glycol diglycidyl ether, epoxy propane butyl ether and ethylene glycol diglycidyl Ether.
Wherein, increased carbon fiber can improve the curing reaction rate of epoxy resin cured product, and reaction effect is good, property Can more it stablize.Compared to traditional epoxy resin cured product, stability can be improved.
Also proposed a kind of composition epoxy resin in another aspect of this invention, including at least one amino-compound, Phenolic compound, the liquid epoxies compound, inorganic that at least one range of viscosities is 1000mPa-s~500,000mPa-s Filler and epoxy resin cured product as described above.
Wherein, the phenolic compound includes Benzenediol.The amino-compound includes hydroxyl functional amine compounds.
In the present embodiment, can be had using above-mentioned epoxy resin cured product in composition epoxy resin good solid Change effect and performance, increased inorganic filler generally can be silicon carbide micro-powder, corundum powder, graphite microparticles, increased inorganic Filler can improve epoxyn intensity.
The preferred embodiment of the present invention is above are only, does not play the role of any restrictions to the present invention.Belonging to any Those skilled in the art, in the range of technical scheme of the present invention is not departed from, to the invention discloses technical solution and Technology contents make the variations such as any type of equivalent replacement or modification, belong to the content without departing from technical scheme of the present invention, still Within belonging to the scope of protection of the present invention.

Claims (7)

1. a kind of epoxy resin cured product, which is characterized in that including:
45-55 parts of high temperature modification mixture
21-23 parts of aluminium oxide
17-20 parts of isoprene
15-20 parts of n-butanol water glycerin ether
10-13 parts of carbon fiber
12-13 parts of diluent.
2. epoxy resin cured product as described in claim 1, which is characterized in that it is more that the high temperature modification mixture includes aromatic series Amine, acid anhydrides, resol, amino resins, dicyandiamide and hydrazides.
3. epoxy resin cured product as described in claim 1, which is characterized in that the diluent shrinks including polypropylene glycol two Glycerin ether, epoxy propane butyl ether and ethylene glycol diglycidylether.
4. a kind of composition epoxy resin, which is characterized in that including at least one amino-compound, phenolic compound, at least one Liquid epoxies compound, inorganic filler and such as claim 1 that kind range of viscosities is 1000mPa-s~500,000mPa-s To the epoxy resin cured product described in any one of 3.
5. composition epoxy resin as claimed in claim 4, which is characterized in that the phenolic compound includes Benzenediol.
6. composition epoxy resin as claimed in claim 4, which is characterized in that the amino-compound includes hydroxyl functional Amine compounds.
7. composition epoxy resin as claimed in claim 4, which is characterized in that the inorganic filler is silicon carbide micro-powder, just Beautiful micro mist or graphite microparticles.
CN201711449240.XA 2017-12-27 2017-12-27 Epoxy resin cured product and composition epoxy resin Pending CN108178828A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711449240.XA CN108178828A (en) 2017-12-27 2017-12-27 Epoxy resin cured product and composition epoxy resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711449240.XA CN108178828A (en) 2017-12-27 2017-12-27 Epoxy resin cured product and composition epoxy resin

Publications (1)

Publication Number Publication Date
CN108178828A true CN108178828A (en) 2018-06-19

Family

ID=62547792

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711449240.XA Pending CN108178828A (en) 2017-12-27 2017-12-27 Epoxy resin cured product and composition epoxy resin

Country Status (1)

Country Link
CN (1) CN108178828A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113816712A (en) * 2021-10-15 2021-12-21 钟祥绿景环保科技有限公司 Calcination-free production process of phosphogypsum environment-friendly building material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104105756A (en) * 2012-01-26 2014-10-15 东丽株式会社 Resin composition and semiconductor mounting substrate obtained by molding same
CN105143301A (en) * 2012-12-14 2015-12-09 蓝立方知识产权有限责任公司 Modified epoxy resins
CN105778050A (en) * 2016-03-25 2016-07-20 南通市福来特化工有限公司 Epoxy resin curing agent
CN106280885A (en) * 2016-08-16 2017-01-04 湖北巴司特科技有限公司 A kind of high-efficiency and energy-saving type bicomponent epoxy resin coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104105756A (en) * 2012-01-26 2014-10-15 东丽株式会社 Resin composition and semiconductor mounting substrate obtained by molding same
CN105143301A (en) * 2012-12-14 2015-12-09 蓝立方知识产权有限责任公司 Modified epoxy resins
CN105778050A (en) * 2016-03-25 2016-07-20 南通市福来特化工有限公司 Epoxy resin curing agent
CN106280885A (en) * 2016-08-16 2017-01-04 湖北巴司特科技有限公司 A kind of high-efficiency and energy-saving type bicomponent epoxy resin coating and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113816712A (en) * 2021-10-15 2021-12-21 钟祥绿景环保科技有限公司 Calcination-free production process of phosphogypsum environment-friendly building material

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SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
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Application publication date: 20180619