CN108174869A - A kind of antimicrobial sustained-release agricultural desinsection composite material - Google Patents
A kind of antimicrobial sustained-release agricultural desinsection composite material Download PDFInfo
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- CN108174869A CN108174869A CN201711471620.3A CN201711471620A CN108174869A CN 108174869 A CN108174869 A CN 108174869A CN 201711471620 A CN201711471620 A CN 201711471620A CN 108174869 A CN108174869 A CN 108174869A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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- A—HUMAN NECESSITIES
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- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/14—Boron; Compounds thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract
The invention discloses a kind of antimicrobial sustained-release agricultural desinsection composite materials, its raw material includes sodium alkyl sulfonate, 3 hydroxymethyl tetrahydrofurans, thiophene furan acid, modified sustained release auxiliary agent, modified Antibacterial accessory ingredient, tourmaline powder, flyash, sepiolite powder, 2,4 dichlorphenoxyacetic acids, magnesium phosphate, sodium metasilicate, clay, diatomite, penoxsuam, dichloro quinolinic acid, cetyldimethylethylambromide bromide ammonium, lauryl sodium sulfate, glyceryl linoleate, butyl acetate, potassium dihydrogen phosphate, sodium tetraborate and silane coupling agent KH 550.The agricultural of the present invention has excellent sustained release performance with desinsection composite material, and desinsection raw material can efficiently be discharged by putting into soil, good disinsection effect, and with excellent anti-microbial property, moreover it is possible to effectively avoid causing during desinsection soil harmful bacteria from increasing and impoverishment.
Description
Technical field
Technical field more particularly to a kind of antimicrobial sustained-release agricultural desinsection composite material the present invention relates to insecticidal materials.
Background technology
Insecticide of the prior art is mostly liquid, and kill, this sprinkling are carried out to pest by way of sprinkling
Mode human body is easily entered by air, and can penetrate into soil, the structure of soil is damaged, causes soil poor
It is lean, and a large amount of harmful bacteria can be retained after desinsection, be unfavorable for the growth of plant, and the release of desinsection drug effect is slow, insecticidal effect without
The needs of method meets in actual use.
Invention content
To solve technical problem present in background technology, the present invention proposes a kind of antimicrobial sustained-release agricultural desinsection composite wood
Material has excellent sustained release performance, and desinsection raw material can efficiently be discharged by putting into soil, good disinsection effect, and with excellent
Anti-microbial property, moreover it is possible to effectively avoid causing during desinsection soil harmful bacteria from increasing and impoverishment.
A kind of antimicrobial sustained-release agricultural desinsection composite material proposed by the present invention, raw material include by weight：Alkyl sulphur
Sour sodium 40-60 parts, it is 25-35 parts of 3- hydroxymethyl tetrahydrofurans, 15-35 parts of thiophene furan acid, modified 20-50 part of auxiliary agent of sustained release, modified anti-
15-25 parts of bacterium auxiliary agent, 2-6 parts of tourmaline powder, 1-5 parts of flyash, 3-6 parts of sepiolite powder, 1-3 parts of 2,4- dichlorphenoxyacetic acids,
2-5 parts of magnesium phosphate, 1-6 parts of sodium metasilicate, 3-6 parts of clay, 2-5 parts of diatomite, 1-3 parts of penoxsuam, dichloro quinolinic acid 2-6
Part, 3-6 parts of cetyldimethylethylambromide bromide ammonium, 2-4 parts of lauryl sodium sulfate, 3-5 parts of glyceryl linoleate, acetic acid fourth
2-5 parts of ester, 1-6 parts of potassium dihydrogen phosphate, 4-8 parts of sodium tetraborate, 3-6 parts of silane resin acceptor kh-550.
Preferably, the raw material of modified sustained release auxiliary agent includes by weight：15-25 parts of activated carbon, mass fraction 5-15%
4-8 parts of ferric chloride solution, 3-9 parts of rice straw, 2-6 parts of bentonite, 3-9 parts of lignin, 10-20 parts of distilled water, itaconic acid
4-8 parts, N, 3-9 parts of N- dimethylene formamides, 2-6 parts of ammonium persulfate, 1-5 parts of trimethyl lignin quaternary.
Preferably, modified sustained release auxiliary agent is prepared by following technique：It is dried after activated carbon is washed, then adds in chlorination
Ferrous solution is uniformly mixed, and heating water bath is cooled to room temperature, and is then washed with deionized, and then heating calcining, is cooled to room temperature
Obtain material a；Then rice straw, bentonite, lignin and distilled water are added in into material a to be uniformly mixed, be subsequently added into clothing
Health acid, N, N- dimethylenes formamide, ammonium persulfate and trimethyl lignin quaternary are uniformly mixed, water bath with thermostatic control stirring, cold
But to room temperature, suction filtration obtains sediment, then by drying precipitate, is cooled to room temperature to obtain modified sustained release auxiliary agent.
Preferably, modified sustained release auxiliary agent is prepared by following technique：It is dried after activated carbon is washed, then adds in quality
Score is that the ferric chloride solution of 5-15% is uniformly mixed, and in 80-100 DEG C of heating water bath 8-12h, is cooled to room temperature, then spends
Ion water washing is then warming up to 250-350 DEG C of calcining 4-6h, is cooled to room temperature to obtain material a；Then it is added in into material a
Rice straw, bentonite, lignin and distilled water are uniformly mixed, and are subsequently added into itaconic acid, N, N- dimethylenes formamide, over cure
Sour ammonium and trimethyl lignin quaternary are uniformly mixed, and are stirred, are cooled to room temperature in 50-60 DEG C of water bath with thermostatic control, and suction filtration is sunk
Starch then by drying precipitate, is cooled to room temperature to obtain modified sustained release auxiliary agent.
Preferably, the raw material of modified Antibacterial accessory ingredient includes by weight：6-9 parts of sodium-based montmorillonite, 4-8 parts of aluminum stearate,
4-7 parts of lanthanum chloride solution that 2-6 parts of the sodium chloride solution that mass fraction is 5-15%, mass fraction are 15-35%, mass fraction
4-8 parts of 2-6 parts of 4-8 parts of 2-6 parts of silver nitrate solution, chitosan, DMAC N,N' dimethyl acetamide, ethyl acrylate, silicon for 4-8%
2-6 parts of alkane coupling agent kh-570.
Preferably, modified Antibacterial accessory ingredient is prepared by following technique：By sodium-based montmorillonite, aluminum stearate and mass fraction
Sodium chloride solution for 5-15% is uniformly mixed, stirring, filtering means dehydration, then drying roasts, being subsequently placed in mass fraction is
In the lanthanum chloride solution of 15-35%, stirring, filtering means dehydration is dried, is then roasted, and is subsequently placed in the nitre that mass fraction is 4-8%
In sour silver solution, 2-4h is stirred, material A is obtained after drying；Chitosan and n,N-dimethylacetamide are uniformly mixed, stirred,
Then it heats up, keeps the temperature, be then passed through nitrogen, add in material A and ethyl acrylate is uniformly mixed, stir, it is even then to add in silane
Connection agent KH-570 is uniformly mixed, and is heated up, and is kept the temperature, stirring, is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
Preferably, modified Antibacterial accessory ingredient is prepared by following technique：By sodium-based montmorillonite, aluminum stearate and mass fraction
Sodium chloride solution for 5-15% is uniformly mixed, and stirs 1-3h, filtering means dehydration, then drying roasts 0.5- in 450-550 DEG C
1.5h is subsequently placed in the lanthanum chloride solution that mass fraction is 15-35%, stirs 1-3h, filtering means dehydration, and drying is subsequently placed in
180-220 DEG C of roasting 0.5-1.5h, is subsequently placed in the silver nitrate solution that mass fraction is 4-8%, stirs 2-4h, after drying
To material A；Chitosan and n,N-dimethylacetamide are uniformly mixed, 20-40min is stirred in 650-850r/min rotating speeds, connects
It and is warming up to 75-85 DEG C, keep the temperature 1-3h, be then passed through nitrogen, add in material A and ethyl acrylate is uniformly mixed, in 450-
550r/min rotating speeds stir 10-14h, then add in Silane coupling reagent KH-570 and are uniformly mixed, be warming up to 90-110 DEG C, keep the temperature 5-
15min stirs 10-20min in 1500-2500r/min rotating speeds, is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
A kind of antimicrobial sustained-release agricultural desinsection composite material of the present invention, raw material include sodium alkyl sulfonate, 3- methylols
Tetrahydrofuran, thiophene furan acid, modified sustained release auxiliary agent, modified Antibacterial accessory ingredient, tourmaline powder, flyash, sepiolite powder, 2,4- dichloro-benzenes
Fluoroacetic acid, magnesium phosphate, sodium metasilicate, clay, diatomite, penoxsuam, dichloro quinolinic acid, cetyldimethylethylambromide bromide
Ammonium, lauryl sodium sulfate, glyceryl linoleate, butyl acetate, potassium dihydrogen phosphate, sodium tetraborate and silane coupling agent KH-
550.Wherein, then modified sustained release auxiliary agent adds in ferric chloride solution and is uniformly mixed, water-bath adds by being dried after activated carbon is washed
Heat is cooled to room temperature, and is then washed with deionized, and then heating calcining, is cooled to room temperature to obtain material a；Then to material a
Middle addition rice straw, bentonite, lignin and distilled water are uniformly mixed, and are subsequently added into itaconic acid, N, N- dimethylene formyls
Amine, ammonium persulfate and trimethyl lignin quaternary are uniformly mixed, and water bath with thermostatic control stirring is cooled to room temperature, and suction filtration is precipitated
Object then by drying precipitate, is cooled to room temperature to obtain modified sustained release auxiliary agent.Wherein, modified Antibacterial accessory ingredient is by the way that sodium base is covered
De- soil, aluminum stearate and mass fraction are uniformly mixed for the sodium chloride solution of 5-15%, are stirred, filtering means dehydration, then drying roasts
It burns, is subsequently placed in the lanthanum chloride solution that mass fraction is 15-35%, stirring, filtering means dehydration, then drying is roasted, then put
In the silver nitrate solution for being 4-8% in mass fraction, 2-4h is stirred, material A is obtained after drying；By chitosan and N, N- dimethyl
Acetamide is uniformly mixed, and stirring then heats up, and keeps the temperature, and is then passed through nitrogen, adds in material A and ethyl acrylate is uniformly mixed,
Then stirring adds in Silane coupling reagent KH-570 and is uniformly mixed, heats up, keep the temperature, stirring is cooled to room temperature to obtain modified antibacterial and helps
Agent.The agricultural of the present invention has excellent sustained release performance with desinsection composite material, and desinsection original can efficiently be discharged by putting into soil
Material, good disinsection effect, and with excellent anti-microbial property, moreover it is possible to effectively avoid causing during desinsection soil harmful bacteria increase and
Impoverishment.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
Bright rather than for limiting the invention, any modification made on the basis of the present invention, equivalent replacement etc. are in this hair
In bright protection domain.
In embodiment, the antimicrobial sustained-release agricultural desinsection composite material, raw material include by weight：Alkyl sulphur
Sour sodium 40-60 parts, it is 25-35 parts of 3- hydroxymethyl tetrahydrofurans, 15-35 parts of thiophene furan acid, modified 20-50 part of auxiliary agent of sustained release, modified anti-
15-25 parts of bacterium auxiliary agent, 2-6 parts of tourmaline powder, 1-5 parts of flyash, 3-6 parts of sepiolite powder, 1-3 parts of 2,4- dichlorphenoxyacetic acids,
2-5 parts of magnesium phosphate, 1-6 parts of sodium metasilicate, 3-6 parts of clay, 2-5 parts of diatomite, 1-3 parts of penoxsuam, dichloro quinolinic acid 2-6
Part, 3-6 parts of cetyldimethylethylambromide bromide ammonium, 2-4 parts of lauryl sodium sulfate, 3-5 parts of glyceryl linoleate, acetic acid fourth
2-5 parts of ester, 1-6 parts of potassium dihydrogen phosphate, 4-8 parts of sodium tetraborate, 3-6 parts of silane resin acceptor kh-550.
Modified sustained release auxiliary agent is prepared by following technique：It is dried after 15-25 parts of activated carbons are washed by weight, then
It adds in the ferric chloride solution that 4-8 parts of mass fractions are 5-15% to be uniformly mixed, in 80-100 DEG C of heating water bath 8-12h, be cooled to
Then room temperature is washed with deionized, be then warming up to 250-350 DEG C of calcining 4-6h, be cooled to room temperature to obtain material a；Then
3-9 parts of rice straws, 2-6 parts of bentonites, 3-9 parts of lignin and 10-20 parts of distilled water are added in into material a to be uniformly mixed, and are connect
4-8 parts of itaconic acids of addition, 3-9 parts of N, N- dimethylenes formamide, 2-6 parts of ammonium persulfates and 1-5 parts of trimethyl lignin seasons
Ammonium salt is uniformly mixed, and is stirred, is cooled to room temperature in 50-60 DEG C of water bath with thermostatic control, and suction filtration obtains sediment, then does sediment
It is dry, it is cooled to room temperature to obtain modified sustained release auxiliary agent.
Modified Antibacterial accessory ingredient is prepared by following technique：By weight by 6-9 parts of sodium-based montmorillonites, 4-8 parts of stearic acid
The sodium chloride solution that aluminium and 2-6 parts of mass fractions are 5-15% is uniformly mixed, and stirs 1-3h, filtering means dehydration, drying, Ran Houyu
450-550 DEG C of roasting 0.5-1.5h, is subsequently placed in the lanthanum chloride solution that 4-7 parts of mass fractions are 15-35%, stirs 1-3h,
Filtering means dehydration, drying are subsequently placed in 180-220 DEG C of roasting 0.5-1.5h, are subsequently placed in the nitre that 2-6 parts of mass fractions are 4-8%
In sour silver solution, 2-4h is stirred, material A is obtained after drying；4-8 parts of chitosans and 2-6 parts of DMAC N,N' dimethyl acetamides are mixed
Uniformly, 20-40min is stirred in 650-850r/min rotating speeds, is then warming up to 75-85 DEG C, kept the temperature 1-3h, be then passed through nitrogen,
It adds in material A and 4-8 parts of ethyl acrylates is uniformly mixed, stir 10-14h in 450-550r/min rotating speeds, then add in 2-6 parts
Silane coupling reagent KH-570 is uniformly mixed, and is warming up to 90-110 DEG C, keeps the temperature 5-15min, is stirred in 1500-2500r/min rotating speeds
10-20min is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
Embodiment 1
A kind of antimicrobial sustained-release agricultural desinsection composite material, raw material include by weight：50 parts of sodium alkyl sulfonate, 3- hydroxyls
30 parts of methyltetrahydrofuran, 25 parts of thiophene furan acid, modified 35 parts of auxiliary agent of sustained release, modified 20 parts of Antibacterial accessory ingredient, 4 parts of tourmaline powder, powder
3 parts of coal ash, 4.5 parts of sepiolite powder, 2 parts of 2,4- dichlorphenoxyacetic acids, 3.5 parts of magnesium phosphate, 3 parts of sodium metasilicate, 4.5 parts of clay, silicon
3.5 parts of diatomaceous earth, 2 parts of penoxsuam, 4 parts of dichloro quinolinic acid, 4.5 parts of cetyldimethylethylambromide bromide ammonium, dodecyl
3 parts of sodium sulphate, 4 parts of glyceryl linoleate, 3.5 parts of butyl acetate, 3 parts of potassium dihydrogen phosphate, 6 parts of sodium tetraborate, silane coupling agent
4.5 parts of KH-550.
Modified sustained release auxiliary agent is prepared by following technique：It is dried after 20 parts of activated carbons are washed by weight, Ran Houjia
Enter the ferric chloride solution that 6 parts of mass fractions are 10% to be uniformly mixed, in 90 DEG C of heating water bath 10h, be cooled to room temperature, then spend
Ion water washing is then warming up to 300 DEG C of calcining 5h, is cooled to room temperature to obtain material a；Then 6 parts of rice are added in into material a
Stalk, 4 parts of bentonites, 6 parts of lignin and 15 parts of distilled water are uniformly mixed, and are subsequently added into 6 parts of itaconic acids, 6 parts of N, bis- methylenes of N-
Base formamide, 4 parts of ammonium persulfates, 3 parts of trimethyl lignin quaternaries are uniformly mixed, and are stirred in 55 DEG C of waters bath with thermostatic control, are cooled to room
Temperature, suction filtration obtain sediment, then by drying precipitate, are cooled to room temperature to obtain modified sustained release auxiliary agent.
Modified Antibacterial accessory ingredient is prepared by following technique：By weight by 7.5 parts of sodium-based montmorillonites, 6 parts of aluminum stearates
It is uniformly mixed with 4 parts of mass fractions for 10% sodium chloride solution, stirs 2h, filtering means dehydration, drying, then in 500 DEG C of roastings
1h is subsequently placed in the lanthanum chloride solution that 5.5 parts of mass fractions are 25%, stirs 2h, filtering means dehydration, and drying is subsequently placed in 200
DEG C roasting 1h, be subsequently placed in 4 parts of mass fractions be 6% silver nitrate solution in, stir 3h, obtain material A after drying；By 6 parts
Chitosan and 4 parts of n,N-dimethylacetamide are uniformly mixed, and are stirred 30min in 750r/min rotating speeds, are then warming up to 80 DEG C, protect
Warm 2h is then passed through nitrogen, adds in material A and 6 parts of ethyl acrylates are uniformly mixed, and stirs 12h in 500r/min rotating speeds, then
It adds in 4 parts of Silane coupling reagent KH-570s to be uniformly mixed, is warming up to 100 DEG C, keep the temperature 10min, stirred in 2000r/min rotating speeds
15min is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
Embodiment 2
A kind of antimicrobial sustained-release agricultural desinsection composite material, raw material include by weight：40 parts of sodium alkyl sulfonate, 3- hydroxyls
35 parts of methyltetrahydrofuran, 15 parts of thiophene furan acid, modified 50 parts of auxiliary agent of sustained release, modified 15 parts of Antibacterial accessory ingredient, 6 parts of tourmaline powder, powder
1 part of coal ash, 6 parts of sepiolite powder, 1 part of 2,4- dichlorphenoxyacetic acids, 5 parts of magnesium phosphate, 1 part of sodium metasilicate, 6 parts of clay, diatomite 2
Part, 3 parts of penoxsuam, 2 parts of dichloro quinolinic acid, 6 parts of cetyldimethylethylambromide bromide ammonium, 2 parts of lauryl sodium sulfate,
5 parts of glyceryl linoleate, 2 parts of butyl acetate, 6 parts of potassium dihydrogen phosphate, 4 parts of sodium tetraborate, 6 parts of silane resin acceptor kh-550.
Modified sustained release auxiliary agent is prepared by following technique：It is dried after 15 parts of activated carbons are washed by weight, Ran Houjia
Enter the ferric chloride solution that 8 parts of mass fractions are 5% to be uniformly mixed, in 100 DEG C of heating water bath 8h, be cooled to room temperature, then spend
Ion water washing is then warming up to 350 DEG C of calcining 4h, is cooled to room temperature to obtain material a；Then 9 parts of rice are added in into material a
Stalk, 2 parts of bentonites, 9 parts of lignin and 10 parts of distilled water are uniformly mixed, and are subsequently added into 8 parts of itaconic acids, 3 parts of N, bis- methylenes of N-
Base formamide, 6 parts of ammonium persulfates and 1 part of trimethyl lignin quaternary are uniformly mixed, and are stirred, are cooled in 60 DEG C of waters bath with thermostatic control
Room temperature, suction filtration obtain sediment, then by drying precipitate, are cooled to room temperature to obtain modified sustained release auxiliary agent.
Modified Antibacterial accessory ingredient is prepared by following technique：By weight by 6 parts of sodium-based montmorillonites, 8 parts of aluminum stearates and 2
The sodium chloride solution that part mass fraction is 15% is uniformly mixed, and stirs 1h, filtering means dehydration, drying, then in 550 DEG C of roastings
0.5h is subsequently placed in the lanthanum chloride solution that 7 parts of mass fractions are 15%, stirs 3h, filtering means dehydration, and drying is subsequently placed in 180
DEG C roasting 1.5h, be subsequently placed in 2 parts of mass fractions be 8% silver nitrate solution in, stir 2h, obtain material A after drying；By 8
Part chitosan and 2 parts of n,N-dimethylacetamide are uniformly mixed, and are stirred 20min in 850r/min rotating speeds, are then warming up to 85 DEG C,
1h is kept the temperature, is then passed through nitrogen, material A is added in and 8 parts of ethyl acrylates is uniformly mixed, stirs 14h in 450r/min rotating speeds, so
2 parts of Silane coupling reagent KH-570s are added in afterwards to be uniformly mixed, and are warming up to 110 DEG C, are kept the temperature 5min, are stirred in 2500r/min rotating speeds
10min is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
Embodiment 3
A kind of antimicrobial sustained-release agricultural desinsection composite material, raw material include by weight：60 parts of sodium alkyl sulfonate, 3- hydroxyls
25 parts of methyltetrahydrofuran, 35 parts of thiophene furan acid, modified 20 parts of auxiliary agent of sustained release, modified 25 parts of Antibacterial accessory ingredient, 2 parts of tourmaline powder, powder
5 parts of coal ash, 3 parts of sepiolite powder, 3 parts of 2,4- dichlorphenoxyacetic acids, 2 parts of magnesium phosphate, 6 parts of sodium metasilicate, 3 parts of clay, diatomite 5
Part, 1 part of penoxsuam, 6 parts of dichloro quinolinic acid, 3 parts of cetyldimethylethylambromide bromide ammonium, 4 parts of lauryl sodium sulfate,
3 parts of glyceryl linoleate, 5 parts of butyl acetate, 1 part of potassium dihydrogen phosphate, 8 parts of sodium tetraborate, 3 parts of silane resin acceptor kh-550.
Modified sustained release auxiliary agent is prepared by following technique：It is dried after 25 parts of activated carbons are washed by weight, Ran Houjia
The ferric chloride solution for entering 4 parts of mass fractions 15% is uniformly mixed, and in 80 DEG C of heating water bath 12h, is cooled to room temperature, then spend from
Sub- water washing is then warming up to 250 DEG C of calcining 6h, is cooled to room temperature to obtain material a；Then 3 parts of rice straw are added in into material a
Stalk, 6 parts of bentonites, 3 parts of lignin and 20 parts of distilled water are uniformly mixed, and are subsequently added into 4 parts of itaconic acids, 9 parts of N, N- dimethylenes
Formamide, 2 parts of ammonium persulfates and 5 parts of trimethyl lignin quaternaries are uniformly mixed, and are stirred in 50 DEG C of waters bath with thermostatic control, are cooled to room
Temperature, suction filtration obtain sediment, then by drying precipitate, are cooled to room temperature to obtain modified sustained release auxiliary agent.
Modified Antibacterial accessory ingredient is prepared by following technique：By weight by 9 parts of sodium-based montmorillonites, 4 parts of aluminum stearates and 6
The sodium chloride solution that part mass fraction is 5% is uniformly mixed, and stirs 3h, filtering means dehydration, then drying roasts 1.5h in 450 DEG C,
It is subsequently placed in the lanthanum chloride solution that 4 parts of mass fractions are 35%, stirs 1h, filtering means dehydration, drying is subsequently placed in 220 DEG C of roastings
0.5h is burnt, is subsequently placed in the silver nitrate solution that 6 parts of mass fractions are 4%, is stirred 4h, material A is obtained after drying；By 4 parts of shells
Glycan and 6 parts of n,N-dimethylacetamide are uniformly mixed, and 40min is stirred in 650r/min rotating speeds, are then warming up to 75 DEG C, heat preservation
3h is then passed through nitrogen, adds in material A and 4 parts of ethyl acrylates are uniformly mixed, and 10h, Ran Houjia are stirred in 550r/min rotating speeds
Enter 6 parts of Silane coupling reagent KH-570s to be uniformly mixed, be warming up to 90 DEG C, keep the temperature 15min, 20min is stirred in 1500r/min rotating speeds,
It is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of antimicrobial sustained-release agricultural desinsection composite material, which is characterized in that its raw material includes by weight：Sodium alkyl sulfonate
40-60 parts, 25-35 parts of 3- hydroxymethyl tetrahydrofurans, 15-35 parts of thiophene furan acid, modified 20-50 part of auxiliary agent of sustained release, modification antibacterial help
15-25 parts of agent, 2-6 parts of tourmaline powder, 1-5 parts of flyash, 3-6 parts of sepiolite powder, 1-3 parts of 2,4- dichlorphenoxyacetic acids, phosphoric acid
2-5 parts of magnesium, 1-6 parts of sodium metasilicate, 3-6 parts of clay, 2-5 parts of diatomite, 1-3 parts of penoxsuam, 2-6 parts of dichloro quinolinic acid, ten
Six 3-6 parts of alkyl dimethyl ethyl ammonium bromides, 2-4 parts of lauryl sodium sulfate, 3-5 parts of glyceryl linoleate, butyl acetate 2-5
Part, 1-6 parts of potassium dihydrogen phosphate, 4-8 parts of sodium tetraborate, 3-6 parts of silane resin acceptor kh-550.
2. antimicrobial sustained-release agricultural desinsection composite material according to claim 1, which is characterized in that modified sustained release auxiliary agent
Raw material includes by weight：15-25 parts of activated carbon, 4-8 parts of ferric chloride solution, the rice straw 3-9 that mass fraction is 5-15%
Part, 2-6 parts of bentonite, 3-9 parts of lignin, 10-20 parts of distilled water, 4-8 parts of itaconic acid, N, 3-9 parts of N- dimethylene formamides,
2-6 parts of ammonium persulfate, 1-5 parts of trimethyl lignin quaternary.
3. antimicrobial sustained-release agricultural desinsection composite material according to claim 1 or 2, which is characterized in that modified sustained release helps
Agent is prepared by following technique：It is dried after activated carbon is washed, then adds in ferric chloride solution and be uniformly mixed, heating water bath,
It is cooled to room temperature, is then washed with deionized, then heating calcining, is cooled to room temperature to obtain material a；Then into material a
Add in rice straw, bentonite, lignin and distilled water are uniformly mixed, be subsequently added into itaconic acid, N, N- dimethylenes formamide,
Ammonium persulfate and trimethyl lignin quaternary are uniformly mixed, and water bath with thermostatic control stirring is cooled to room temperature, and suction filtration obtains sediment,
Then it by drying precipitate, is cooled to room temperature to obtain modified sustained release auxiliary agent.
4. according to claim 1-3 any one of them antimicrobial sustained-release agricultural desinsection composite materials, which is characterized in that modified slow
Auxiliary agent is released to be prepared by following technique：It is dried after activated carbon is washed, then adds in the iron chloride that mass fraction is 5-15%
Solution is uniformly mixed, and in 80-100 DEG C of heating water bath 8-12h, is cooled to room temperature, is then washed with deionized, be then warming up to
250-350 DEG C of calcining 4-6h, is cooled to room temperature to obtain material a；Then rice straw, bentonite, lignin are added in into material a
It is uniformly mixed with distilled water, is subsequently added into itaconic acid, N, N- dimethylenes formamide, ammonium persulfate and trimethyl lignin quaternary ammonium
Salt is uniformly mixed, and is stirred, is cooled to room temperature in 50-60 DEG C of water bath with thermostatic control, and suction filtration obtains sediment, then by drying precipitate,
It is cooled to room temperature to obtain modified sustained release auxiliary agent.
5. according to claim 1-4 any one of them antimicrobial sustained-release agricultural desinsection composite materials, which is characterized in that modified anti-
The raw material of bacterium auxiliary agent includes by weight：6-9 parts of sodium-based montmorillonite, 4-8 parts of aluminum stearate, the chlorination that mass fraction is 5-15%
The silver nitrate solution 2-6 that 4-7 parts of lanthanum chloride solution that 2-6 parts of sodium solution, mass fraction are 15-35%, mass fraction are 4-8%
Part, 4-8 parts of chitosan, 2-6 parts of DMAC N,N' dimethyl acetamide, 4-8 parts of ethyl acrylate, 2-6 parts of Silane coupling reagent KH-570.
6. according to claim 1-5 any one of them antimicrobial sustained-release agricultural desinsection composite materials, which is characterized in that modified anti-
Bacterium auxiliary agent is prepared by following technique：By the sodium chloride solution that sodium-based montmorillonite, aluminum stearate and mass fraction are 5-15%
It being uniformly mixed, stirring, filtering means dehydration, then drying roasts, be subsequently placed in the lanthanum chloride solution that mass fraction is 15-35%,
Then stirring, filtering means dehydration, drying roast, be subsequently placed in the silver nitrate solution that mass fraction is 4-8%, stir 2-4h, dry
Material A is obtained after dry；Chitosan and n,N-dimethylacetamide are uniformly mixed, stirs, then heats up, keeps the temperature, is then passed through
Nitrogen, adds in material A and ethyl acrylate is uniformly mixed, and stirs, and then adds in Silane coupling reagent KH-570 and is uniformly mixed, rises
Temperature is kept the temperature, stirring, is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
7. according to claim 1-6 any one of them antimicrobial sustained-release agricultural desinsection composite materials, which is characterized in that modified anti-
Bacterium auxiliary agent is prepared by following technique：By the sodium chloride solution that sodium-based montmorillonite, aluminum stearate and mass fraction are 5-15%
It is uniformly mixed, stirs 1-3h, filtering means dehydration, then drying roasts 0.5-1.5h in 450-550 DEG C, is subsequently placed in mass fraction
In the lanthanum chloride solution of 15-35%, to stir 1-3h, filtering means dehydration, drying is subsequently placed in 180-220 DEG C of roasting 0.5-1.5h,
It is subsequently placed in the silver nitrate solution that mass fraction is 4-8%, stirs 2-4h, material A is obtained after drying；By chitosan and N, N-
Dimethylacetylamide is uniformly mixed, and is stirred 20-40min in 650-850r/min rotating speeds, is then warming up to 75-85 DEG C, keeps the temperature 1-
3h is then passed through nitrogen, adds in material A and ethyl acrylate is uniformly mixed, and stirs 10-14h in 450-550r/min rotating speeds, so
Silane coupling reagent KH-570 is added in afterwards to be uniformly mixed, and is warming up to 90-110 DEG C, is kept the temperature 5-15min, turns in 1500-2500r/min
Speed stirring 10-20min is cooled to room temperature to obtain modified Antibacterial accessory ingredient.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108977009A (en) * | 2018-06-20 | 2018-12-11 | 天长市金陵电子有限责任公司 | A kind of electrostatic spraying antimicrobial antirust coating and preparation method thereof |
| CN111592690A (en) * | 2020-05-29 | 2020-08-28 | 安徽江淮汽车集团股份有限公司 | Antibacterial agent, preparation method thereof and antibacterial thermoplastic plastic |
| CN111944536A (en) * | 2018-09-23 | 2020-11-17 | 邓文武 | Preparation method of heavy metal contaminated soil remediation agent |
| CN113208033A (en) * | 2021-05-18 | 2021-08-06 | 干将新材料有限公司 | Antibacterial deoxidizing agent and preparation method thereof |
| CN114557356A (en) * | 2022-02-25 | 2022-05-31 | 江苏仁信作物保护技术有限公司 | Mixed pesticide containing 2,4-D and picloram and preparation method thereof |
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| CN107410359A (en) * | 2017-07-26 | 2017-12-01 | 安徽省圣丹生物化工有限公司 | A kind of weeding composite that can adjust soil |
| CN107439538A (en) * | 2017-07-26 | 2017-12-08 | 安徽省圣丹生物化工有限公司 | A kind of efficient weeding composite of high slow release |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410359A (en) * | 2017-07-26 | 2017-12-01 | 安徽省圣丹生物化工有限公司 | A kind of weeding composite that can adjust soil |
| CN107439538A (en) * | 2017-07-26 | 2017-12-08 | 安徽省圣丹生物化工有限公司 | A kind of efficient weeding composite of high slow release |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977009A (en) * | 2018-06-20 | 2018-12-11 | 天长市金陵电子有限责任公司 | A kind of electrostatic spraying antimicrobial antirust coating and preparation method thereof |
| CN111944536A (en) * | 2018-09-23 | 2020-11-17 | 邓文武 | Preparation method of heavy metal contaminated soil remediation agent |
| CN111944536B (en) * | 2018-09-23 | 2021-12-28 | 邓文武 | Preparation method of heavy metal contaminated soil remediation agent |
| CN111592690A (en) * | 2020-05-29 | 2020-08-28 | 安徽江淮汽车集团股份有限公司 | Antibacterial agent, preparation method thereof and antibacterial thermoplastic plastic |
| CN113208033A (en) * | 2021-05-18 | 2021-08-06 | 干将新材料有限公司 | Antibacterial deoxidizing agent and preparation method thereof |
| CN114557356A (en) * | 2022-02-25 | 2022-05-31 | 江苏仁信作物保护技术有限公司 | Mixed pesticide containing 2,4-D and picloram and preparation method thereof |
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Application publication date: 20180619 |