CN108164966A - A kind of environmental protection and energy-saving building Side fascia and preparation method thereof - Google Patents

A kind of environmental protection and energy-saving building Side fascia and preparation method thereof Download PDF

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Publication number
CN108164966A
CN108164966A CN201810021437.1A CN201810021437A CN108164966A CN 108164966 A CN108164966 A CN 108164966A CN 201810021437 A CN201810021437 A CN 201810021437A CN 108164966 A CN108164966 A CN 108164966A
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China
Prior art keywords
parts
energy
environmental protection
side fascia
building side
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Application number
CN201810021437.1A
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Chinese (zh)
Inventor
张倩
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Suzhou Research And Development Corp Mstar Technology Ltd
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Suzhou Research And Development Corp Mstar Technology Ltd
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Priority to CN201810021437.1A priority Critical patent/CN108164966A/en
Publication of CN108164966A publication Critical patent/CN108164966A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2255Oxides; Hydroxides of metals of molybdenum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fireproofing Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of environmental protection and energy-saving building Side fascia and preparation method thereof, which is prepared by the raw material of following parts by weight:30 ~ 60 parts of makrolon, 10 ~ 20 parts of ferromanganese ore slag, 8 ~ 17 parts of polyimide fiber, 5 ~ 12 parts of vermiculite power, 3 ~ 8 parts of molybdenum trioxide, 2 ~ 9 parts of boric acid, 4 ~ 13 parts of latex powder, 2 ~ 9 parts of blanc fixe, 2 ~ 7 parts of volcanic ash, 3 ~ 8 parts of granite stone powder, 4 ~ 12 parts of calcium carbonate, 3 ~ 9 parts of petroleum ether, 2 ~ 6 parts of silicon carbide, 3 ~ 8 parts of alkaline glass fiber, 1 ~ 4 part of fire retardant, 45 ~ 80 parts of water.The environmental protection and energy-saving building Side fascia of the present invention reaches A grades of building fire protection, while have both good heat preservation energy-saving and the feature of environmental protection, has wider application range.

Description

A kind of environmental protection and energy-saving building Side fascia and preparation method thereof
Technical field
Environmental protection and energy-saving building Side fascia the present invention relates to a kind of application of building material field and preparation method thereof.
Background technology
Building energy consumption is one of importance of China's energy consumption, and annual building energy consumption accounts for about the 1/3 of total energy consumption.With building Energy-efficient implementation and development, thermal insulation material are increasingly liked by people.Currently used architecture exterior wall insulating materials are main Including planks such as polystyrene foam plate, polyurethane foam board, expansion polyphenyl plate, extruded polystyrene board, phenolic resin plates.These are protected Although warm plank has certain energy-saving heat preserving effect, the fire retardant performance of most of planks is not good enough, especially polyphenyl second Alkene cystosepiment and polyurethane foam board are unable to reach the requirement of building fire protection, can be generated after the burning of these planks in addition a large amount of harmful Gas is highly detrimental to environmental protection and health of people.Therefore, in order to preferably develop, to building exterior wall material in addition to requiring its tool Standby good energy-saving heat preserving performance requires its fire retardant performance also higher and higher.
Invention content
The invention mainly solves the technical problem of providing a kind of environmental protection and energy-saving building Side fascia and preparation method thereof, the rings It protects energy saving building Side fascia and overcomes the problem of traditional building exterior wall material fire protection flame retarding is insufficient, while have both good guarantor The warm energy saving and feature of environmental protection.
In order to solve the above technical problems, the technical solution adopted by the present invention is:A kind of environmental protection and energy-saving building Side fascia is provided, It is prepared by the raw material of following parts by weight:30 ~ 60 parts of makrolon, 10 ~ 20 parts of ferromanganese ore slag, polyimide fiber 8 ~ 17 Part, 5 ~ 12 parts of vermiculite power, 3 ~ 8 parts of molybdenum trioxide, 2 ~ 9 parts of boric acid, 4 ~ 13 parts of latex powder, 2 ~ 9 parts of blanc fixe, volcanic ash 2 ~ 7 Part, 3 ~ 8 parts of granite stone powder, 4 ~ 12 parts of calcium carbonate, 3 ~ 9 parts of petroleum ether, 2 ~ 6 parts of silicon carbide, 3 ~ 8 parts of alkaline glass fiber, resistance Fire 1 ~ 4 part of agent, 45 ~ 80 parts of water.
In a preferred embodiment of the present invention, the environmental protection and energy-saving building Side fascia, by the raw material of following parts by weight It is prepared:38 parts of makrolon, 13 parts of ferromanganese ore slag, 10 parts of polyimide fiber, 6 parts of vermiculite power, 6 parts of molybdenum trioxide, boron 3 parts of acid, 8 parts of latex powder, 5 parts of blanc fixe, 4 parts of volcanic ash, 4 parts of granite stone powder, 6 parts of calcium carbonate, 7 parts of petroleum ether, carbonization 5 parts of silicon, 4 parts of alkaline glass fiber, 2 parts of fire retardant, 62 parts of water.
In a preferred embodiment of the present invention, the fire retardant is ethyl-bis- (tetrabromo phthalimides), hydrogen-oxygen Change the mixture of aluminium and dialkyl phosphinic acid aluminium, the weight ratio of three is 4:1:3.
The present invention also provides the preparation methods of above-mentioned environmental protection and energy-saving building Side fascia, include the following steps:
By weight, makrolon, ferromanganese ore slag, granite stone powder, petroleum ether, blanc fixe, volcanic ash and water are placed in and stirred It mixes in device and is mixed evenly, whipping temp is 50 ~ 65 DEG C;Then polyimide fiber, molybdenum trioxide, zinc borate, breast are added in After rubber powder, vermiculite power, alkaline glass fiber and fire retardant stir evenly, 76 ~ 85 DEG C are warming up to, adds calcium carbonate and silicon carbide It is stirred, mixing time is 5 ~ 10 hours, obtains mixture;Finally mixture is placed in calender at 120 ~ 160 DEG C Calendering formation obtains environmental protection and energy-saving building Side fascia.
In a preferred embodiment of the present invention, the mixing time is 8 hours.
In a preferred embodiment of the present invention, in the calender at 138 DEG C calendering formation.
The beneficial effects of the invention are as follows:The environmental protection and energy-saving building Side fascia of the present invention overcomes traditional building exterior wall material The problem of fire protection flame retarding is insufficient, while good heat preservation energy-saving and the feature of environmental protection are had both, there is wider application range;The present invention Preparation method it is simple, be suitble to industrial-scale production.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example is only the part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
The embodiment of the present invention includes:A kind of environmental protection and energy-saving building Side fascia, is prepared by the raw material of following parts by weight:Poly- carbonic acid 38 parts of ester, 13 parts of ferromanganese ore slag, 10 parts of polyimide fiber, 6 parts of vermiculite power, 6 parts of molybdenum trioxide, 3 parts of boric acid, 8 parts of latex powder, 5 parts of blanc fixe, 4 parts of volcanic ash, 4 parts of granite stone powder, 6 parts of calcium carbonate, 7 parts of petroleum ether, 5 parts of silicon carbide, alkali glass are fine 4 parts of dimension, 2 parts of fire retardant, 62 parts of water.
Preferably, the fire retardant is ethyl-bis- (tetrabromo phthalimides), aluminium hydroxide and dialkyl phosphinic acid The mixture of aluminium, the weight ratio of three is 4:1:3.
The preparation method of the environmental protection and energy-saving building Side fascia of the present embodiment, includes the following steps:
By weight, makrolon, ferromanganese ore slag, granite stone powder, petroleum ether, blanc fixe, volcanic ash and water are placed in and stirred It mixes in device and is mixed evenly, whipping temp is 56 DEG C;Then polyimide fiber, molybdenum trioxide, zinc borate, latex are added in After powder, vermiculite power, alkaline glass fiber and fire retardant stir evenly, 82 DEG C are warming up to, adds calcium carbonate and silicon carbide stirring Mixing, mixing time are 8 hours, obtain mixture;Mixture is finally placed in calender the calendering formation at 138 DEG C, is obtained To environmental protection and energy-saving building Side fascia.
Embodiment 2
The embodiment of the present invention includes:A kind of environmental protection and energy-saving building Side fascia, is prepared by the raw material of following parts by weight:Poly- carbonic acid 30 parts of ester, 10 parts of ferromanganese ore slag, 8 parts of polyimide fiber, 5 parts of vermiculite power, 3 parts of molybdenum trioxide, 2 parts of boric acid, 4 parts of latex powder, 2 parts of blanc fixe, 2 parts of volcanic ash, 3 parts of granite stone powder, 4 parts of calcium carbonate, 3 parts of petroleum ether, 2 parts of silicon carbide, alkali glass are fine 3 parts of dimension, 1 part of fire retardant, 45 parts of water.
Preferably, the fire retardant is ethyl-bis- (tetrabromo phthalimides), aluminium hydroxide and dialkyl phosphinic acid The mixture of aluminium, the weight ratio of three is 4:1:3.
The preparation method of the environmental protection and energy-saving building Side fascia of the present embodiment, includes the following steps:
By weight, makrolon, ferromanganese ore slag, granite stone powder, petroleum ether, blanc fixe, volcanic ash and water are placed in and stirred It mixes in device and is mixed evenly, whipping temp is 50 DEG C;Then polyimide fiber, molybdenum trioxide, zinc borate, latex are added in After powder, vermiculite power, alkaline glass fiber and fire retardant stir evenly, 76 DEG C are warming up to, adds calcium carbonate and silicon carbide stirring Mixing, mixing time are 5 hours, obtain mixture;Mixture is finally placed in calender the calendering formation at 120 DEG C, is obtained To environmental protection and energy-saving building Side fascia.
Embodiment 3
The embodiment of the present invention includes:A kind of environmental protection and energy-saving building Side fascia, is prepared by the raw material of following parts by weight:Poly- carbonic acid 60 parts of ester, 20 parts of ferromanganese ore slag, 17 parts of polyimide fiber, 12 parts of vermiculite power, 3 ~ 8 parts of molybdenum trioxide, 9 parts of boric acid, latex powder 13 parts, 9 parts of blanc fixe, 7 parts of volcanic ash, 8 parts of granite stone powder, 12 parts of calcium carbonate, 9 parts of petroleum ether, 6 parts of silicon carbide, alkalinity 8 parts of glass fibre, 4 parts of fire retardant, 80 parts of water.
Preferably, the fire retardant is ethyl-bis- (tetrabromo phthalimides), aluminium hydroxide and dialkyl phosphinic acid The mixture of aluminium, the weight ratio of three is 4:1:3.
The preparation method of the environmental protection and energy-saving building Side fascia of the present embodiment, includes the following steps:
By weight, makrolon, ferromanganese ore slag, granite stone powder, petroleum ether, blanc fixe, volcanic ash and water are placed in and stirred It mixes in device and is mixed evenly, whipping temp is 65 DEG C;Then polyimide fiber, molybdenum trioxide, zinc borate, latex are added in After powder, vermiculite power, alkaline glass fiber and fire retardant stir evenly, 85 DEG C are warming up to, adds calcium carbonate and silicon carbide stirring Mixing, mixing time are 10 hours, obtain mixture;Mixture is finally placed in calender the calendering formation at 160 DEG C, is obtained To environmental protection and energy-saving building Side fascia.
It is obtained by performance test, the environmental protection and energy-saving building Side fascia prepared by embodiment 1 ~ 3, which obtains fire-protection rating and reaches, to be built A grades of fire prevention is built, coefficient of heat transfer is below 0.08W/mK, reaches the requirement of building heat preservation, safe to use energy saving, meets practical answer Use demand.
The environmental protection and energy-saving building Side fascia of the present invention overcomes that traditional building exterior wall material fire protection flame retarding is insufficient to ask Topic, while good heat preservation energy-saving and the feature of environmental protection are had both, there is wider application range;The preparation method of the present invention is simple, fits Close industrial-scale production.
The foregoing is merely the embodiment of the present invention, are not intended to limit the scope of the invention, every to utilize this hair The equivalent structure or equivalent flow shift that bright description is made directly or indirectly is used in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of environmental protection and energy-saving building Side fascia, which is characterized in that be prepared by the raw material of following parts by weight:Makrolon 30 ~ 60 parts, 10 ~ 20 parts of ferromanganese ore slag, 8 ~ 17 parts of polyimide fiber, 5 ~ 12 parts of vermiculite power, 3 ~ 8 parts of molybdenum trioxide, boric acid 2 ~ 9 Part, 4 ~ 13 parts of latex powder, 2 ~ 9 parts of blanc fixe, 2 ~ 7 parts of volcanic ash, 3 ~ 8 parts of granite stone powder, 4 ~ 12 parts of calcium carbonate, petroleum ether 3 ~ 9 parts, 2 ~ 6 parts of silicon carbide, 3 ~ 8 parts of alkaline glass fiber, 1 ~ 4 part of fire retardant, 45 ~ 80 parts of water.
2. environmental protection and energy-saving building Side fascia according to claim 1, which is characterized in that prepared by the raw material of following parts by weight It forms:38 parts of makrolon, 13 parts of ferromanganese ore slag, 10 parts of polyimide fiber, 6 parts of vermiculite power, 6 parts of molybdenum trioxide, boric acid 3 Part, 8 parts of latex powder, 5 parts of blanc fixe, 4 parts of volcanic ash, 4 parts of granite stone powder, 6 parts of calcium carbonate, 7 parts of petroleum ether, silicon carbide 5 Part, 4 parts of alkaline glass fiber, 2 parts of fire retardant, 62 parts of water.
3. environmental protection and energy-saving building Side fascia according to claim 1, which is characterized in that the fire retardant is ethyl-bis- (four Bromine phthalimide), the mixture of aluminium hydroxide and dialkyl phosphinic acid aluminium, the weight ratio of three is 4:1:3.
4. such as the preparation method of claim 1 ~ 3 any one of them environmental protection and energy-saving building Side fascia, it is characterised in that including such as Lower step:
By weight, makrolon, ferromanganese ore slag, granite stone powder, petroleum ether, blanc fixe, volcanic ash and water are placed in and stirred It mixes in device and is mixed evenly, whipping temp is 50 ~ 65 DEG C;Then polyimide fiber, molybdenum trioxide, zinc borate, breast are added in After rubber powder, vermiculite power, alkaline glass fiber and fire retardant stir evenly, 76 ~ 85 DEG C are warming up to, adds calcium carbonate and silicon carbide It is stirred, mixing time is 5 ~ 10 hours, obtains mixture;Finally mixture is placed in calender at 120 ~ 160 DEG C Calendering formation obtains environmental protection and energy-saving building Side fascia.
A kind of 5. preparation method of environmental protection and energy-saving building Side fascia according to claim 4, which is characterized in that the stirring Time is 8 hours.
A kind of 6. preparation method of environmental protection and energy-saving building Side fascia according to claim 4, which is characterized in that the calendering In machine at 138 DEG C calendering formation.
CN201810021437.1A 2018-01-10 2018-01-10 A kind of environmental protection and energy-saving building Side fascia and preparation method thereof Withdrawn CN108164966A (en)

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CN201810021437.1A CN108164966A (en) 2018-01-10 2018-01-10 A kind of environmental protection and energy-saving building Side fascia and preparation method thereof

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113107136A (en) * 2021-04-08 2021-07-13 史琼 Modular self-bearing crust external wall panel and preparation technology

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103568396A (en) * 2012-08-02 2014-02-12 上海杰事杰新材料(集团)股份有限公司 Light-weight and high-strength thermoplastic composite material sandwich board and production method thereof
CN104844069A (en) * 2015-04-12 2015-08-19 李孟平 Building thermal insulation and flame retardant composite material and preparation method thereof
CN106747010A (en) * 2016-12-30 2017-05-31 安徽华普环境修复材料科技有限公司 A kind of external wall special fireproof heat preservation plate material
CN106832635A (en) * 2016-12-30 2017-06-13 安徽华普环境修复材料科技有限公司 A kind of fire-retardant heat insulation composite sandwich plate
CN106830784A (en) * 2016-12-30 2017-06-13 安徽华普环境修复材料科技有限公司 A kind of building exterior wall heat preserving sheet material
CN107353552A (en) * 2017-07-20 2017-11-17 合肥安力电力工程有限公司 A kind of flame retardant distribution box sheathing material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103568396A (en) * 2012-08-02 2014-02-12 上海杰事杰新材料(集团)股份有限公司 Light-weight and high-strength thermoplastic composite material sandwich board and production method thereof
CN104844069A (en) * 2015-04-12 2015-08-19 李孟平 Building thermal insulation and flame retardant composite material and preparation method thereof
CN106747010A (en) * 2016-12-30 2017-05-31 安徽华普环境修复材料科技有限公司 A kind of external wall special fireproof heat preservation plate material
CN106832635A (en) * 2016-12-30 2017-06-13 安徽华普环境修复材料科技有限公司 A kind of fire-retardant heat insulation composite sandwich plate
CN106830784A (en) * 2016-12-30 2017-06-13 安徽华普环境修复材料科技有限公司 A kind of building exterior wall heat preserving sheet material
CN107353552A (en) * 2017-07-20 2017-11-17 合肥安力电力工程有限公司 A kind of flame retardant distribution box sheathing material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113107136A (en) * 2021-04-08 2021-07-13 史琼 Modular self-bearing crust external wall panel and preparation technology

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Application publication date: 20180615