CN108164159A - A kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof - Google Patents

A kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof Download PDF

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Publication number
CN108164159A
CN108164159A CN201711427522.XA CN201711427522A CN108164159A CN 108164159 A CN108164159 A CN 108164159A CN 201711427522 A CN201711427522 A CN 201711427522A CN 108164159 A CN108164159 A CN 108164159A
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CN
China
Prior art keywords
glass
layer
low emissivity
glass substrate
hollow
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Pending
Application number
CN201711427522.XA
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Chinese (zh)
Inventor
李刚
金克武
杨勇
姚婷婷
王天齐
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CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd
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CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd
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Application filed by CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd filed Critical CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd
Priority to CN201711427522.XA priority Critical patent/CN108164159A/en
Publication of CN108164159A publication Critical patent/CN108164159A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/225Nitrides
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/213SiO2
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/218V2O5, Nb2O5, Ta2O5
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/28Other inorganic materials
    • C03C2217/281Nitrides
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase
    • C03C2218/154Deposition methods from the vapour phase by sputtering
    • C03C2218/156Deposition methods from the vapour phase by sputtering by magnetron sputtering

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Securing Of Glass Panes Or The Like (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The present invention provides a kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof, it includes indoor glass substrate, and low-emission coated layer, hollow layer, colored film plating layer and outdoor glass substrate are followed successively by outward from indoor glass substrate surface.The indoor glass substrate for being coated with Low emissivity film layer and the outdoor glass substrate for being coated with colored film layer are sent into conjunction piece sizing machine, with spacer bar pad it is hollow shape by two sheet glass surroundings, centre implantation drier, periphery spreads binding agent with sealing strip and is bonded as hollow type glass, and finished product is obtained after being sent into drying machine drying immediately.The configuration of the present invention is simple, it is easily manufactured, solve the problems, such as that Low emissivity hollow glass color is single, and compared with the coloured glass with being obtained using colorant, the advantages that influence to Low emissivity hollow glass heat insulating and optical property is also smaller.

Description

A kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof
Technical field:
The invention belongs to glassmaking art, more particularly to a kind of Low emissivity hollow glass and preparation method thereof.
Background technology:
Low emissivity glass, also known as LOW-E glass are the membrane system productions that multiple layer metal or other compounds composition are plated in glass surface Product.While visible ray has high-transmission rate in ensureing sunlight, low emissivity glass can effectively limit infrared light, fully The heat exchange of glass both sides is reduced, making it, optical property is greatly taken on a new look compared with simple glass.
In Application in Building, the use of Low-E glass can achieve the effect that " cool in summer and warm in winter ", have it is excellent it is heat-insulated, Heat-insulating property effect.Although low emissivity glass has the function of heat-insulated, heat preservation, soundproof effect is not satisfactory, therefore existing Hollow glass use is made in low emissivity glass more.Low emissivity hollow glass is generally by a piece of low radiation coated glass(Indoor glass) With a piece of simple glass(Outdoor glass)Composition, it is using high intensity high-air-tightness compound binding agent, two sheet glass are dry with including The space-stop rack of drying prescription bonds, manufactured high-effect sound insulation, heat-protecting glass.
Low emissivity hollow glass in the prior art, in addition to daylighting sun shading and energy-saving effect, beautification, decoration to building Effect is also critically important.And at present Low emissivity hollow glass when using building curtain wall, it is seen that be all often partially blue , Modern commercial buildings and residential houses are higher and higher to the cosmetic requirement of glass, and therefore, various functions and color, which become, to be built The target that teacher of the building pursues.
Glass manufacturer devises the glass of different colours to be suitble to the requirement of different color.In order to obtain different colours Glass, it is main using colorant is added in flint glass at present, glass is made to become coloured glass.But coloured glass yield is few, Production cycle is long, the indoor glass as Low emissivity hollow glass(Coated glass)It uses, it may be because of the long-term storage of original sheet glass It deposits and causes occur film quality problem during plated film;And the outdoor glass as Low emissivity hollow glass uses, and is likely to occur Because colorant concentration is improper, so as to influence the situation of transmission of visible light and hollow glass color.
Invention content:
The present invention be exactly in order to overcome deficiency of the prior art, provide a kind of adjustable Low emissivity hollow glass of surface color and polish and Preparation method.
The present invention provides following technical scheme:
A kind of adjustable Low emissivity hollow glass of surface color and polish, it includes indoor glass substrate, it is characterised in that:Glass indoors Substrate surface is equipped with low-emission coated layer, hollow layer, colored film plating layer and outdoor glass substrate successively outward.
Based on the above technical solution, there can also be technical solution further below:
The colored film plating layer is replaced by least one layer of high refractive index film at least one layer of low refractive index film to be formed by stacking Film structure.
The high refractive index membrane material is niobium oxide(Nb2O5)Or tantalum oxide(Ta2O5)Or silicon nitride(Si3N4);It is described low Refractive index membrane material is silicon nitride(Si3N4)Or silicon oxynitride(SiON)Or silica(SiO2).
A kind of preparation method of the adjustable Low emissivity hollow glass of surface color and polish, it is characterised in that:It includes the following steps, (1)Low-emission coated layer is deposited using magnetron sputtering method on one side external surface of glass substrate indoors;
(2)Magnetron sputtering method deposit high refractive index film is used on the inner surface of outdoor glass substrate side(4a)And low refractive index film (4b), and if two film alternating deposit dried layer, formed film structure;
(3)The indoor glass substrate 1 for being coated with Low emissivity film layer 2 and the outdoor glass substrate 5 for being coated with colored film layer 4 are sent into conjunction piece Two sheet glass surroundings with spacer bar pad are hollow shape by sizing machine, and centre implantation drier, bonding is spread in periphery with sealing strip Agent is bonded as hollow type glass, and finished product is obtained after being sent into drying machine drying immediately.
Again on the basis of above-mentioned preparation method, there can also be further embodiment
The step(2)During middle deposit high refractive index film, Sputtering power density is 1.0~4.0W/cm2, argon flow amount for 20~ 40sccm, operating pressure are 0.3~1.0Pa.
The step(2)During middle deposition low refractive index film, Sputtering power density is 2.0~4.5W/cm2, argon flow amount is 20~40sccm, operating pressure are 0.5~1.2Pa.
Invention advantage:
The configuration of the present invention is simple, easily manufactured, the outdoor glass substrate inner surface passed through in Low emissivity hollow glass increases colored Film plating layer, and the adjustment of the composition and thicknesses of layers using membrane system material, so as to obtain in the Low emissivity of multicolour reflection Empty glass solves the problems, such as that the Low emissivity hollow glass color of Modern commercial buildings and residential houses is single;And with utilization The coloured glass that colorant obtains is compared, and the influence to Low emissivity hollow glass heat insulating and optical property is also smaller.
Description of the drawings:
Fig. 1 is the structure diagram of the present invention;
Fig. 2 is the structure diagram of colored film plating layer in Fig. 1;
Fig. 3 is the reflectance curve of the Low emissivity hollow glass with green reflection that the embodiment of the present invention 1 provides;
Fig. 4 is the reflectance curve of the Low emissivity hollow glass with yellow reflection that the embodiment of the present invention 2 provides.
Specific embodiment:
Embodiment 1
As illustrated in fig. 1 and 2, the adjustable Low emissivity hollow glass of a kind of surface color and polish, it is included in 1 outer surface of indoor glass substrate It is upper that low-emission coated layer 2 is deposited using magnetron sputtering method, colored film plating layer 4 is equipped on outdoor 5 inner surface of glass substrate, it is described Colored film plating layer 4 be to replace the film structure being formed by stacking with low refractive index film 4b by high refractive index film 4a, total number of plies is 19 Layer, the high refractive index film 4a materials are niobium oxide, and using magnetron sputtering method, Sputtering power density 3.5W/cm2, argon gas Flow is 30sccm, operating pressure 0.3Pa, is 56nm per layer film thickness;
The low refractive index film 4b materials are silicon nitride, and using magnetron sputtering method, Sputtering power density 2.8W/cm2, argon gas Flow is 30sccm, operating pressure 0.5Pa, is 62nm per layer film thickness.
The indoor glass substrate 1 for being coated with Low emissivity film layer 2 and the outdoor glass substrate 5 for being coated with colored film layer 4 are sent into conjunction Piece sizing machine, the Low emissivity film layer 2 on the indoor glass substrate 1 is outside, the colored film layer in the outdoor glass substrate 5 4 inwardly, and between Low emissivity film layer 2 and colored film layer 4 between be separated with certain distance.
With spacer bar pad it is hollow shape by two sheet glass surroundings, in the Low emissivity film layer 2 and the centre of colored film layer 4 Drier is implanted into, periphery spreads binding agent with sealing strip and is bonded as hollow type glass, is obtained into after being sent into drying machine drying immediately Product.
The Low emissivity hollow glass surface color and polish adopted the structure is green, and reflectivity is as shown in Figure 3.
Embodiment 2
As illustrated in fig. 1 and 2, the adjustable Low emissivity hollow glass of a kind of surface color and polish, it is included in 1 outer surface of indoor glass substrate It is upper that low-emission coated layer 2 is deposited using magnetron sputtering method, colored film plating layer 4 is equipped on outdoor 5 inner surface of glass substrate, it is described Colored film plating layer 4 be to replace the film structure being formed by stacking with low refractive index film 4b by high refractive index film 4a, total number of plies is 19 Layer, the high refractive index film 4a materials are niobium oxide, and using magnetron sputtering method, Sputtering power density 3.0W/cm2, argon gas Flow is 35sccm, operating pressure 0.5Pa, is 66nm per layer film thickness;
The low refractive index film 4b materials are silicon nitride, and using magnetron sputtering method, Sputtering power density 3.8W/cm2, argon gas Flow is 40sccm, operating pressure 0.8Pa, is 72nm per layer film thickness.
The indoor glass substrate 1 for being coated with Low emissivity film layer 2 and the outdoor glass substrate 5 for being coated with colored film layer 4 are sent into conjunction Piece sizing machine, the Low emissivity film layer 2 on the indoor glass substrate 1 is outside, the colored film layer in the outdoor glass substrate 5 4 inwardly, and between Low emissivity film layer 2 and colored film layer 4 between be separated with certain distance.
With spacer bar pad it is hollow shape by two sheet glass surroundings, in the Low emissivity film layer 2 and the centre of colored film layer 4 Drier is implanted into, periphery spreads binding agent with sealing strip and is bonded as hollow type glass, is obtained into after being sent into drying machine drying immediately Product.
The Low emissivity hollow glass surface color and polish adopted the structure is yellow, and reflectivity is as shown in Figure 4.
The preferred embodiment of the present invention described in detail above.It should be appreciated that those of ordinary skill in the art without Creative work is needed according to the present invention can to conceive and makes many modifications and variations.All technician in the art according to The design of the present invention passes through the available technical side of logical analysis, reasoning, or a limited experiment on the basis of existing technology Case, all should be in the protection domain being defined in the patent claims.

Claims (6)

1. a kind of adjustable Low emissivity hollow glass of surface color and polish, it includes indoor glass substrate(1)It is characterized in that:Indoors Glass substrate(1)Surface is equipped with low-emission coated layer successively outward(2), hollow layer(3), colored film plating layer(4)With outdoor glass Substrate(5).
2. according to the adjustable Low emissivity hollow glass of a kind of surface color and polish described in claim 1, it is characterised in that:Described Colored film plating layer(4)It is by least one layer of high refractive index film(4a)Replace at least one layer of low refractive index film (4b) and be formed by stacking Film structure.
3. a kind of adjustable Low emissivity hollow glass of surface color and polish according to claim 2, it is characterised in that:The height Refractive index membrane material is niobium oxide(Nb2O5)Or tantalum oxide(Ta2O5)Or silicon nitride(Si3N4);The low-refraction membrane material is Silicon nitride(Si3N4)Or silicon oxynitride(SiON)Or silica(SiO2).
4. a kind of preparation method of the adjustable Low emissivity hollow glass of surface color and polish, it is characterised in that:It includes the following steps, (1)Low-emission coated layer is deposited using magnetron sputtering method on one side external surface of glass substrate indoors;
(2)Magnetron sputtering method deposit high refractive index film is used on the inner surface of outdoor glass substrate side(4a)And low refractive index film (4b) if two film alternating deposit dried layer, forms film structure;
(3)The indoor glass substrate 1 for being coated with Low emissivity film layer 2 and the outdoor glass substrate 5 for being coated with colored film layer 4 are sent into conjunction piece Two sheet glass surroundings with spacer bar pad are hollow shape by sizing machine, and centre implantation drier, bonding is spread in periphery with sealing strip Agent is bonded as hollow type glass, and finished product is obtained after being sent into drying machine drying immediately.
5. a kind of preparation method of the adjustable Low emissivity hollow glass of surface color and polish, feature according to claim 4 exist In:The step(2)Middle deposit high refractive index film(4a)When, Sputtering power density is 1.0~4.0W/cm2, argon flow amount 20 ~40sccm, operating pressure are 0.3~1.0Pa.
6. a kind of preparation method of the adjustable Low emissivity hollow glass of surface color and polish, feature according to claim 4 exist In:The step(2)During middle deposition low refractive index film (4b), Sputtering power density is 2.0~4.5W/cm2, argon flow amount is 20~40sccm, operating pressure are 0.5~1.2Pa.
CN201711427522.XA 2017-12-26 2017-12-26 A kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof Pending CN108164159A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201711427522.XA CN108164159A (en) 2017-12-26 2017-12-26 A kind of adjustable Low emissivity hollow glass of surface color and polish and preparation method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109734330A (en) * 2019-02-18 2019-05-10 东莞市银泰丰光学科技有限公司 A kind of colored glazed glass and its processing method with crystal texture
CN110963714A (en) * 2018-09-25 2020-04-07 汉能移动能源控股集团有限公司 Colored glass, preparation method thereof and colored solar cell module
CN111302652A (en) * 2020-04-08 2020-06-19 东莞南玻工程玻璃有限公司 Flat-bent matched double-silver coated glass and preparation method thereof
CN111747658A (en) * 2020-07-01 2020-10-09 天津耀皮工程玻璃有限公司 Colorful color-changing coated glass and preparation method thereof
CN114562184A (en) * 2021-12-24 2022-05-31 广东卫屋防火科技有限公司 Hollow glass with high-temperature-resistant and fireproof functions for buildings and preparation method thereof
CN115144945A (en) * 2022-06-22 2022-10-04 长春理工大学 Cosmetic mirror light filtering film with chromaticity adjusting function and cosmetic mirror

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1524721A (en) * 2003-09-18 2004-09-01 上海耀华皮尔金顿玻璃股份有限公司 Glass for sun-shading type locomotive
CN201825875U (en) * 2010-09-28 2011-05-11 重庆航星玻璃技术有限公司 Low-radiation energy-saving decorative hollow glass
CN202865120U (en) * 2012-09-24 2013-04-10 南京二十六度建筑节能工程有限公司 Dichroic energy-saving glass with sunshade function
CN203126059U (en) * 2012-10-08 2013-08-14 朱杨 Color-changeable sunshading glass and color-changeable sunshading hollow glass
CN203201442U (en) * 2013-01-04 2013-09-18 朱杨 Intelligent sun-shading hollow glass
CN207659336U (en) * 2017-12-26 2018-07-27 中建材蚌埠玻璃工业设计研究院有限公司 A kind of adjustable Low emissivity hollow glass of surface color and polish

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1524721A (en) * 2003-09-18 2004-09-01 上海耀华皮尔金顿玻璃股份有限公司 Glass for sun-shading type locomotive
CN201825875U (en) * 2010-09-28 2011-05-11 重庆航星玻璃技术有限公司 Low-radiation energy-saving decorative hollow glass
CN202865120U (en) * 2012-09-24 2013-04-10 南京二十六度建筑节能工程有限公司 Dichroic energy-saving glass with sunshade function
CN203126059U (en) * 2012-10-08 2013-08-14 朱杨 Color-changeable sunshading glass and color-changeable sunshading hollow glass
CN203201442U (en) * 2013-01-04 2013-09-18 朱杨 Intelligent sun-shading hollow glass
CN207659336U (en) * 2017-12-26 2018-07-27 中建材蚌埠玻璃工业设计研究院有限公司 A kind of adjustable Low emissivity hollow glass of surface color and polish

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110963714A (en) * 2018-09-25 2020-04-07 汉能移动能源控股集团有限公司 Colored glass, preparation method thereof and colored solar cell module
CN109734330A (en) * 2019-02-18 2019-05-10 东莞市银泰丰光学科技有限公司 A kind of colored glazed glass and its processing method with crystal texture
CN111302652A (en) * 2020-04-08 2020-06-19 东莞南玻工程玻璃有限公司 Flat-bent matched double-silver coated glass and preparation method thereof
CN111747658A (en) * 2020-07-01 2020-10-09 天津耀皮工程玻璃有限公司 Colorful color-changing coated glass and preparation method thereof
CN114562184A (en) * 2021-12-24 2022-05-31 广东卫屋防火科技有限公司 Hollow glass with high-temperature-resistant and fireproof functions for buildings and preparation method thereof
CN115144945A (en) * 2022-06-22 2022-10-04 长春理工大学 Cosmetic mirror light filtering film with chromaticity adjusting function and cosmetic mirror
CN115144945B (en) * 2022-06-22 2024-05-14 长春理工大学 Cosmetic mirror filter film with chromaticity adjusting function and cosmetic mirror

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Application publication date: 20180615